The in situ preservation of archaeological remains: using lysimeters to assess the impacts of saturation and seasonality

Recent research has studied the effects of seasonal variability on waterlogged burial environments. In a new approach to the study of archaeological contexts, the use of controlled laboratory conditions via lysimeters has enabled new insights into the nature of short term fluctuations in saturation, and the impact that these can have on burial contexts. In addition, the protocols used have facilitated interesting insights into burial environments and the way in which fluctuations in saturation and seasonality can impact on the contained organic components within them.     

Investigating the processes necessary for satisfactory freeze-drying of waterlogged archaeological wood

Preliminary studies into methods for improving and safeguarding the preservation of waterlogged archaeological wooden artefacts are presented. Mannitol, sorbitol and trehalose have been tested as replacements for polyethylene glycol (PEG) as a treatment prior to freeze-drying of wooden archaeological objects. The highest anti-shrink efficiency achieved in this short experiment was (70 ± 15) % using a 20% weight per volume solution of sorbitol after soaking for one week. The collapse or eutectic temperature of each solution used was determined using a freeze-drying microscope. Importantly, it was noted that the collapse temperature of the solutions was reduced by several degrees after use for treatment of the wood samples for one month. A freeze-drying microscope with a cold light source has been used to observe the real-time freeze-drying behaviour of various treatments inside a thin section of wood, confirming that this novel technique is indeed possible and useful. Lastly, the effects of magnesium phytate as an iron chelator have been studied. It was found that the treatment lowers the collapse temperature of a PEG 600/2000 solution by roughly 3 °C meaning that objects must be freeze-dried at a correspondingly lower temperature. Iron K-edge X-ray absorption near-edge spectroscopy analysis showed that the treatment extracted approximately half of the iron(III) ions present in the timbers.     

Selected physical parameters to characterize the state of preservation of waterlogged archaeological wood: a practical guide for their determination

Non-destructive and destructive methods for determining the physical parameters of waterlogged wood such as the porosity, the water content, the wet and dry bulk densities plus the density of the cell wall material are presented. Considerations in respect to determination of masses, volumes and sampling size are discussed.     

Southwest Scottish Crannogs: using in situ studies to assess preservation in wetland archaeological contexts

This paper presents the results of in situ monitoring of waterlogged burial contexts in southwest Scotland. The sites investigated are Iron Age crannogs (lake dwellings) which have a proven waterlogged archaeological component, and which are being assessed as part of a national program of study by the Scottish Wetland Archaeology Programme (SWAP) team. A monthly monitoring program commenced in July of 2004. To date, monitoring of water levels, pH, and redox potential, has been undertaken for a period of 17 months in order to encompass any seasonal variability at the sites studied. The results have proven robust in that an ‘ideal’ site for in situ preservation has been identified from the five sites investigated, and the monitoring has highlighted external variables and seasonal impacts that have the potential to influence the long-term in situ preservation at the remaining sites studied. In general, these results have expanded upon our knowledge of the potential for the preservation of existing archaeological remains within such contexts. This study represents the first stage of monitoring aimed at developing a holistic understanding of in situ conditions at the crannog sites studied in southwest Scotland.     

How an integrated diagnostic approach can help in a correct evaluation of the state of preservation of waterlogged archaeological wooden artefacts

Artefacts made of wood coming from archaeological excavations provide insights into human cultural behaviour of the past. They show how man utilised natural resources and how the development of woodworking techniques and artistic endeavour were developed. Within archaeological contexts, waterlogged anaerobic conditions generally preserve the appearance of artefacts, although wood is subject to severe decay processes. The said conditions can transform the original material into a new one, thus demonstrating specific differences from those of the “fresh” wood of the same species. In order to assess these new properties correctly, an integrated diagnostic approach is needed, one which includes a multidisciplinary (micromorphological, physical and chemical) evaluation of the state of preservation.     

Reasoned use of chemical parameters for the diagnostic evaluation of the state of preservation of waterlogged archaeological wood

Waterlogged archaeological wood undergoes decay processes that depend on both the burial conditions and the constituting species, and which cause the depletion of the structural components of wood cells. To quantitatively assess the state of preservation of the decayed material, specific parameters are usually measured by means of both chemical and physical analyses. In this paper an innovative approach in the use of the data obtained from these kinds of measurements is developed. A series of 132 archaeological wood samples of different wood species, burial times and states of preservation, and coming from different sites in Italy, was analysed. Their residual chemical composition, maximum water content and basic density were measured, and a reasoned use of these parameters was carried out through their elaboration, with the aim of both evaluating eventual incongruence or anomalies in the raw physical and chemical data (which has never been accomplished so far) and directly comparing in a reliable way the analytical results obtained from archaeological samples with very different states of preservation. This approach allowed defining the effective values of chemical parameters related to wood decay according to a same reference basis of calculation among the various data. By this way, it was possible to state that lignin can be also attacked by the agents causing biotic decay, and that in hardwoods its decay is more related to the burial conditions than to the wood species. Instead, the mechanism of polysaccharide depletion is diversified: conifers showed a uniform behaviour whereas hardwoods were more species-dependent. Moreover, in addition to the chemical composition, also anatomical factors influence the carbohydrate rate of decay in waterlogged wood.     

Genetic analysis of archaeological wood remains: first results and prospects

A total of 51 ancient oak wood samples originating from various European archaeological sites, dating from the Neolithic period to the 18th century, were assayed for the presence of reproducible chloroplast (cp) DNA sequences. Five polymorphic chloroplast fragments were targeted. Only five of the samples could be fully genetically characterised, revealing four different oak cpDNA haplotypes. In all cases, the haplotypes detected on ancient woods and the haplotypes characterised from fresh samples from the same localities matched. Overall, this congruence is consistent with a genetic continuity between ancient and modern European oaks, confirming the hypothesis that the mapped genetic patterns largely reflect the original structure that established during the post-glacial. This stability of the genetic structure implies that, in the future, the technique could be used to infer or confirm the transport of wood by man, providing interesting perspectives for the genetic analysis of ancient woods.     

Mineral weathering in forest soils and its relevance to the preservation of the buried archaeological resource

There is more woodland in Britain now than for many centuries and considering many international climate change mitigation policies, woodland cover, both in Britain and internationally, is being promoted. However, neither the management of existing woodlands nor their expansion should be at the expense of important archaeological evidence. Due to the large number of known archaeological sites, the large areas of land with uninvestigated archaeological potential and the expanding woodland cover, suitable mitigation strategies need to be developed to allow preservation in situ of important sites. An understanding of how woodland soils and the buried archaeological resource interact is, therefore, essential. This paper utilises ongoing environmental research into the mineral weathering rates in forest soils and considers its application to artefact preservation. The study concludes that soil water pH, its movement, and the saturation of dissolved ions in the soil solution are major factors determining both mineral and artefact longevity. A simple guide to artefact longevity based on these properties is proposed and a geochemical model for predicting loss is tested. These tools could be applied to any soil or individual horizon irrespective of land-use.     

Reburial of shipwrecks in marine sediments: a long-term study on wood degradation

Historical shipwrecks in marine environments are continuously decomposed by wood-degrading organisms, adapted to this specific environment. To protect the wrecks from degradation and to preserve the unique remains for future generations, reburial of wrecks using various covering materials has been suggested as a long-term preservation method. The following experiment was carried out to study the bio-protective effect of sediment. Sound oak, pine, and birch samples were buried above and within marine sediment in Marstrand harbour, and retrieved for analysis after 6, 12, 24, and 36 months. Macroscopic as well as light-microscopic examinations were carried out on each occasion. Marine borers (shipworm, Limnoria), soft rot and tunnelling bacteria were wood degraders immediately above the seabed; soft rot, tunnelling bacteria, and erosion bacteria were active 10 cm below the seabed; erosion bacteria were the only degraders at a depth of 43 cm below the seabed. The wood species had different durability towards the decay agents. After 3 years, wood samples above the seabed were totally decomposed, whereas wood was highly protected at 43 cm depth in sediment. In the sediment, decay decreased significantly with depth of burial. The results suggest that reburial of shipwrecks in marine sediment can be recommended as a simple and efficient method for long-term preservation of the wooden cultural heritage.     

The use of a high-resolution 3D Chirp sub-bottom profiler for the reconstruction of the shallow water archaeological site of the Grace Dieu (1439), River Hamble,UK

The remains of Henry V's flagship, the Grace Dieu, currently lie buried within the inter-tidal sediments of the River Hamble (S. England). Previous archaeological investigations have been hindered by difficult excavation conditions resulting in a poor understanding of the dimensions, shape and degradation state of the hull's deeper structure. This study therefore aimed to image, characterize and reconstruct the buried remains of this vessel using a high-resolution 3D acoustic sub-bottom Chirp system with RTK-GPS positioning capability. The accurate navigation and high-resolution data that were acquired enabled the construction of a full 3D image of the site that not only identified the remains of the wooden hull, but also features buried within it. In addition, the degradation state of these buried wooden remains were investigated by calculating reflection coefficients while a hypothetical larger reconstruction of the Grace Dieu's hull was achieved, through the use of the ShipShape ship design software package.     

In a nutshell: the identification and archaeological application of experimentally defined correlates of Macrozamia seed processing

This paper describes the methods and results of ethnographically-based replicative seed processing experiments conducted on Australian Macrozamia moorei seeds. Archaeological evidence indicates that these seeds were consumed by Australian hunter–gatherers in both the Pleistocene and Holocene. The experiments identified three features indicative of human processing and tested the effect of different processing variables (striking position, indentor type, thermal modification and presence of outer flesh) on the frequency of these diagnostic criteria. The results demonstrate that it is possible to use the physical modifications on individual seed specimens to identify the anthropogenic fracture of seeds and specific methods used to process them. These criteria were used in the analysis of M. moorei seeds from mid-Holocene-aged archaeological sites in central Queensland, Australia. The results indicate that seeds with and without sarcotesta were processed using a wooden indentor via side striking techniques.     

Starch grain characterization of Prosopis chilensis (Mol.) Stuntz and P. flexuosa DC,and the analysis of their archaeological remains in Andean South America

The fruit (pods) of Prosopis (Fabaceae) are frequently recovered from pre-Hispanic Argentinian archaeological sites, suggesting that this genus was of importance in ancient economies in this region. Yet it is only recently that archaeobotanists have begun to carry out systematic research into this genus. Therefore many questions remain to be addressed concerning the food value of Prosopis fruit, and its potential contribution. This paper examines starch from the pods of two species, Prosopis flexuosa and Prosopis chilensis, for the purposes of describing and classifying their morphological features and biometrical parameters. Pods of both species were gathered from two extremes (northern and southern) of the Hualfín Valley, Catamarca, Argentina. Starch abundance is estimated and compared with that of Zea mays, an economically important plant with high concentrations of starch. This paper reveals that Prosopis pods contain very low amounts of starch compared to starch-rich edible species. Despite this, the recovery of Prosopis starch grains can be successfully used to assess archaeological tool uses. Prosopis starch grains were found to be highly variable in shape. Grain size ranged between 10 and 20 μm. Granule irregularity and the high birefringence under polarized light are two of the most important diagnostic features. No significant statistical differences were found in the structure (morphology, size and hilum) of the starch of the same species from both localities. Finally, the implications for the role of this plant in past societies are discussed.     

Remote sensing applications and archaeological research in the Northern Lagoon of Venice: the case of the lost settlement of Constanciacus

“Vicus Constanciacus” is a project for the recovery, protection and evaluation of the historical and archaeological heritage of Constanciacus, an ancient small group of islands in the Northern Lagoon of Venice, of which currently just two emerged strips survive, namely: the abandoned islands of Sant’Ariano and La Cura. Exploring the area lying between the mainland and the lagoon represents an important opportunity for reconstructing the history of Venice before the well known medieval city and market arose. Through survey and excavations of the Constanciacus area, the project aims to shed new light on early patterns of occupation in the Northern Venetian Lagoon; to explore the communication network between the mainland and the sea; and to examine the evolution of settlements along the commercial routes of the Lagoon through time.     

Locally diagnostic phytoliths of wild rice (Zizania palustris L.) from Minnesota,USA: comparison to other wetland grasses and usefulness for archaeobotany and paleoecological reconstructions

Wild rice (Zizania spp.) is an important native grain of north-central North America, with spiritual and subsistence significance to many native peoples. Due to lack of suitable proxies, its past distribution and pattern of use are poorly known. This study demonstrates the diagnostic value of silica phytoliths from Z. palustris as a proxy tool to detect its past occurrence in a variety of paleoenvironmental and archaeological contexts. Our main findings are: 1) Dominant wetland grass species in Minnesota produce phytoliths distinct from Zizania phytoliths; 2) Closely related Leersia oryzoides produces a few Zizania-like phytolith morphotypes; however, these potential confusers can be identified based on 2-D and 3-D morphologies; 3) Z. palustris produces a wide variety of phytolith morphotypes, many of which are only found in certain parts of the plant (e.g., Inflorescence Type 1 from the spikelet); 4) Z. palustris produces 23 locally diagnostic phytolith morphotypes that can be used to determine the presence and abundance of wild rice in modern and paleo lake sediments; and 5) Wild rice phytolith Inflorescence Type 1 is the morphotype most likely to be observed in archaeological contexts, and may be unequivocally diagnostic for the genera Zizania.     

Prouille,Madrid, Rome: the evolution of the earliest Dominican Instituta for nuns

The lifestyles of the three earliest Dominican women's communities were formulated according to their specific historical conditions and exigencies during the years 1206–21. Initially, the women associated with the preaching mission of Diego of Osma and Dominic Guzman were based at Prouille in the Languedoc and followed the Augustinian Rule. The development of the first instituta for Dominican nuns was the result of 15 years of overseeing the lives of the sisters. However, enclosure, and the institutional requirement for its observance, only came about in 1220 with the establishment of San Sisto, when St Dominic wrote an instituta specifically intended for a cloistered nunnery. This paper retraces and elucidates the historical development of the first Dominican instituta for women, and considers the remarkable choice of the Augustinian Rule as the basis for an enclosed women's order.     

A short note on starch and xylem of Colocasia esculenta (taro) in archaeological deposits from Pitcairn Island,southeast Polynesia

We present results of starch analysis of archaeological deposits from Pitcairn Island. High concentrations of starch grains preserved in cell membranes, and xylem tracheary elements, consistent with introduced Colocasia esculenta (taro) were found. Because of limited age control, we are uncertain if the microfossils are prehistoric. Problems associated with identifying taxa with small starch grains in extractions from weathered deposits are highlighted.     

First dendroarchaeological dates of prehistoric contexts in South America: chullpas in the Central Andes

Despite the existence of long-lived tree species with excellent tree-ring characteristics, the use of dendrochronological techniques for dating archaeological contexts has been very limited in South America. Recent research in the Bolivian Altiplano of the Central Andes has yielded a network of Polylepis tarapacana chronologies that goes back to the 13th century. This species was regularly used by local populations since pre-Columbian times as raw material for beams, lintels, hooks and other architectural features in houses, storage chambers, and sepulchers. The aim of this study is to argue in favor of the potential of P. tarapacana for providing high resolution dates of significant archaeological events during the pre-Columbian era. The chronology of chullpas (burial towers and storage chambers) in the southern Andean Altiplano is used as a case study. Growth rings from P. tarapacana have provided several centennial-length dendrochronological records including a reference regional chronology covering the last 786 years in the Central Andean highlands. Based on this long reference chronology calendar years were assigned to woody pieces from pre-Hispanic chullpas. Dendroarchaeological results are consistent with contextual evidence and most radiocarbon dates from woody samples and related archaeological items. Our results indicate that P. tarapacana has a high potential for providing annually-resolved tree-ring dates for archaeological contexts in the Altiplano since the early 13th century.     

A short note on starch and xylem of Ipomoea batatas (sweet potato) in archaeological deposits from northern New Zealand

This study examines preservation of microfossils identified as introduced Ipomoea batatas in soils from northern New Zealand. Starch grains and xylem cells showed highly variable preservation, from good to extremely poor. For starch grains, the latter included brown-staining, expansion and distortion of the grain and vacuole, loss of the Maltese cross, pitting, cracking, fragmentation and disintegration. Degraded xylem showed similar brown-staining, occasional cracking, cross-wise fragmentation, with wall pits becoming progressively less visible or showing distortion, expansion and coalescence.     

Florentine alum mining in the Hospitaller islands: the appalto of 1442

This article publishes a document from the archives of the Order of Saint John recording the Hospitallers’ concession of an alum exploration and mining monopoly, an appalto, to a group of Florentines in 1442, and examines the implications of this agreement for the economic development of the Latin East in this period. This enterprise forms part of a pattern showing Florentine merchants attempting to extend their activities further up the alum supply chain and so to gain increasing control over a commodity of vital importance to their city’s economy, for which they had been dependent on the Genoese who dominated the trade. This development in turn forms part of a wider fifteenth-century trend of the Florentines interloping in areas of activity previously the preserve of other communities, principally the Venetians and Genoese, with a long-established maritime, territorial, diplomatic and commercial position in the eastern Mediterranean. It also forms part of a pattern of new speculative alum mining enterprises in the Aegean in the mid-fifteenth century, calling into question the traditional view that the alum trade was afflicted by a glut at this time, and thus also the traditional explanation of the ensuing consolidation of alum firms. The article also compares this document with a previously published contract issued the preceding year, concluding that the differences between them reflect the developing familiarity of the Hospitaller leadership with the mining business, while their common characteristics confirm the currency of the term appalto in the mining business of this period as denoting a monopoly. It tentatively concludes that this effort to establish an alum mining industry in Hospitaller territory was probably ultimately unsuccessful.     

Distinguishing nonhuman predation on birds: pattern of damage done by the white-tailed eagle Haliaetus albicilla, with comments on the punctures made by the golden eagle Aquila chrysaetos

The study presents criteria to distinguish some of the nonhuman predation on birds whose remains may also be found at archaeological sites. Specifically, it deals with fragmentation patterns of bird bones in uneaten food remains of the white-tailed eagle Haliaetus albicilla and discusses perforations in victims' bones done by the white-tailed and golden eagles. The food remains show very low degree of fragmentation; bones of the pectoral girdle and wing predominate while head and leg elements are poorly represented. The proportion of perforated sterna differs between the two species of eagles and it is suggested that the differences are attributed to the species of prey rather than the way of handling them by the raptors.