HELLENISTIC GLAZED WARES FROM ATHENS AND SOUTHERN ITALY: ANALYTICAL TECHNIQUES AND IMPLICATIONS

The original intention of the project, conceived in the context of the British School at Rome's excavation and survey programme in the Bradano basin (based on Gravina) was to establish the composition patterns of Hellenistic glazed wares from sites in southern Apulia, and then to use these to trace the trading patterns of the area, against a control group of sherds from the Athenian Agora. It proved possible to distinguish Attic from Apulian sherds by their nickel and chromium content, and average-link-cluster-analysis by computer showed that Gnathian ware from Taranto could be distinguished from seven other south Italian groups, suggesting that speciality wares were made of clays from special beds. Because of the geological homogeneity of the area no further distinctions could be made, but some sherds were also analysed petrologically and by heavy mineral analysis, for a methodological comparison. The very homogeneous geology, coupled with the fineness of the wares showed these methods to be at the limits of their usefulness. Only very generalized conclusions could be drawn concerning the origin of the pottery from the petrological evidence; the micro-mineralogical data showed that interesting differences existed between pottery from the main Apulian sites, but these could equally have reflected natural variations occurring within fairly homogeneous clay deposits.     

ROMAN POTTERY FROM AUGUSTA PRAETORIA (AOSTA,ITALY): A PROVENANCE STUDY

Forty-five sherds of Roman pottery, 21 terrae sigillutae and 24 common wares excavated in Augusta Praeroria, were analysed for 12 elements by atomic absorption and emission spectroscopy. Hierarchical agglomerative cluster analysis, principal component analysis, and non-linear mapping were performed on the analytical data in order to classify the objects in groups which could account for different provenances; soft independent modelling of class analogy (SIMCA) and K nearest neighbours (KNN) were used for solving doubtful assignments. The classification results indicate that local productions of terra sigillatu can be easily distinguished from the imported ones, and that common wares have compositional patterns which differ from those of both local and imported terrae sigillatue.     

Can the Raman spectrum of anatase in artwork and archaeology be used for dating purposes? Identification by Raman microscopy of anatase in decorative coatings on Neolithic (Yangshao) pottery from Henan,China

Scanning electron microscopy/energy dispersive X-ray analysis has earlier shown that the white background layer (slip) on painted pottery sherds (Yangshao culture, Henan, China, 4200 BC) is composed of kaolinitic clay containing titanium in the assumed form of TiO₂ at just 1 wt%. The same samples of white slip have now been studied by Raman microscopy, revealing bands characteristic of anatase, but none from the majority species, the matrix of kaolinitic clay. These results highlight the extraordinarily intense Raman scattering from even trace amounts of anatase and thus the need to recognise that, although the colours of archaeological artefacts are almost always determined by the nature of the matrix, the Raman spectrum may be determined by a highly scattering trace component such as anatase. The significance of anatase as a potential date-marker pigment on works of art and archaeological artefacts is discussed.     

Chemical characterization of ancient pottery from sudan by x‐ray fluorescence spectrometry (xrf), electron microprobe analyses (empa) and inductively coupled plasma mass spectrometry (ICP–MS)*

Sixty‐four sherds and seven natural clays from prehistoric sites in northwestern Sudan have been submitted to petrological and chemical analysis using XRF spectrometry, EMPA and ICP–MS. According to their texture, the sherds form five different groups. The high contents of P₂O₅ (more than 0.5 wt%) discerned in 19 samples and the variation of the P₂O₅ content in two samples of the same vessel can be explained by post‐depositional processes or by the ancient organic contents (e.g., milk) of the vessel. Chemical classification of the pottery bulk suggests that vessels were made locally, as only sherds from the same area show homogeneity of data.     

Classical and Hellenistic black glaze ware in the Mediterranean: A study by epithermal neutron activation analysis

Fifteen chemical elements have been measured quantitatively by epithermal neutron activation analysis in 58 sherds of black glaze pottery found in Carthage/Tunis (23 sherds), the Athenian Agora (9 sherds), Sicily (7 sherds), and several sites in Southern Italy (19 sherds). Detailed statistical analysis of the results clearly distinguishes five separate groups: (a) one of local Carthage/Tunis origin; (b) one of probable Sicilian origin; (c) a large group of Attic origin comprising sherds found at the Athenian Agora and at Carthage/Tunis; and (d) two separate groups from S Italy.     

A LYONS BRANCH OF THE POTTERY-MAKING FIRM OF ATEIUS OF AREZZO

Fifty-one waster sherds of Terra Sigillata (～20-0 b.c. ) from Arezzo, Italy and Lyons, France have been chemically analysed for twenty-eight elements by neutron activation and seven by X-ray fluorescence. Most of the elemental abundances were measured with high precision and cross-comparisons of the two techniques of measurement (and sample preparation) give added insight as to their relative precision, the calibration differences and the extent to which volatile materials such as carbonate or water influence the results. The sherds from Arezzo formed a homogeneous and distinctive chemical group while all but two of those from Lyons were classified into three such groups. Two of the Lyons groups (MML A and MML B) were from Montée de La Muette and one was from Loyasse. Four additional sherds from houses excavated in Strasbourg and one from Lyons, all of which bore the signature of the famous Anetine pottery-making firm of Ateius, were also analyzed by the same techniques. These signed sherds all had the same composition pattern and it closely matched one of those from Montée de La Muette (MML A) in Lyons. It is therefore suggested that these five sherds bearing the Ateius signature were made in the general vicinity of Lyons and were part of the output of an as yet unknown Gallic branch of the firm of Ateius.     

A STUDY OF ANCIENT CHINESE PORCELAIN WARES OF THE SONG‐YUAN DYNASTIES FROM CIZHOU AND DING KILNS WITH ENERGY DISPERSIVE X‐RAY FLUORESCENCE*

Multi‐variable statistical analysis based on energy dispersive X‐ray fluorescence measurements on both porcelain body and glaze is employed to give clear and consistent classification of porcelain sherds from northern China of different styles from the Song‐Yuan dynasties (Ding and Cizhou styles), and also from the Sui‐Tang dynasties (Xing style). However, the observed separation is less clear for Cizhou style sherds produced at neighbouring kiln sites. Imitation Ding porcelain samples produced by ancient Cizhou potters are also analysed.     

Provenance of Red‐Figure Pottery of the Classical Period Excavated at Olympia

Neutron activation analysis (NAA) has been applied to a set of red‐figure pottery fragments excavated in Olympia, in Elis: (a) to determine the provenance of these vases, since this is difficult by archaeological means, and the vessels might be local Elean or Attic, Corinthian or Italian products; and (b) to determine the characteristic elemental pattern of the clay paste prepared by the potters of this Elean region. Included for comparison are several Corinthian sherds excavated in Kyme, Italy, that are archaeologically classified as exports from Corinthia to Italy, and fragments of local Italian Corinthian imitations. The majority of the red‐figure vases were made locally in the north‐western Peloponnese and show the elemental pattern termed OlyA, which is represented in many vases and clay samples from this region that were known previously. It is not very different from the well‐known pattern of the north‐eastern Peloponnese (Argolid/Corinth) termed MYBE (Mycenae/Berbati), but can be separated by its lower Cs, Rb and K concentrations, as proven by many sherds from the Argolid and wasters from Berbati. Only a few red‐figure vessels are imports from Attica, but none come from Italy.     

Pottery Styles during the Early Jomon Period: Geochemical Perspectives on the Moroiso and Ukishima Pottery Styles

Energy‐dispersive X‐ray fluorescence (EDXRF) was used to determine the minor and trace element chemistry of 92 Early Jomon pottery sherds. The sherds came from four contemporary sites in the Kanto region and belong to either the Moroiso or Ukishima style of pottery. Principal components analysis (PCA) and discriminant analysis indicate that there are four major groups in the data set, which correspond to site location. Furthermore, for sites having both Moroiso and Ukishima pottery, the statistical tests indicate that both styles of pottery were made from the same or geochemically similar raw materials. This suggests that both styles were probably made at the same site, and indicates that if the different pottery styles are reflecting ethnic identity, then intermarriage between ethnic groups is occurring. Alternatively, the pottery styles could be reflecting some sort of social interaction between groups.     

Non-destructive chemical characterization of ceramic sherds from Shipwreck 31CR314 and Brunswick Town, North Carolina

The purpose of this study was to chemically and texturally characterize ceramic oil jar sherds from North Carolina Shipwreck 31CR314 and to explore the utility of environmental scanning electron microscopy/X-ray energy dispersive spectrometry (SEM/EDS) for that purpose. The oil jar sherds, widely dispersed about Shipwreck 31CR314, are morphologically similar to each other, which suggests they could be from a single jar, but with so few joins this could not be concluded with certainty. Therefore, an aim of this study was to investigate whether chemical or textural characterization of the sherds might reveal unique attributes that could distinguish individual jars; results of characterization perhaps could give information on their origin and possibly site formation processes, such as whether environmental forces could have scattered sherds of a single jar during and after sinking of the ship. Previous studies have indicated this shipwreck is likely the remnants of the Queen Anne's Revenge, flagship of the pirate Blackbeard. Sherds from this shipwreck were compared with similar oil jar sherds excavated from a land site, Brunswick Town, North Carolina, to explore the use of composition and texture as hallmarks. The chemical components of the artifacts were determined by SEM/EDS. This method of analysis is valuable for archaeological research because it is rapid and non-destructive to the ceramic artifacts. Both groups of lead-glazed coarse red earthenware sherds were texturally similar except for the glazed sides of all 31CR314 sherds that exhibited small tracks of unique crescent-shaped marks. These marks may be due to manufacturing effects and immersion in seawater, and the marks may serve as hallmarks for individual jars or potentially individual manufacturers. The sherds were generally similar in composition, but the two groups exhibited distinct differences. Brunswick Town sherds consistently contained more phosphate on unglazed sides, an average 1.46 wt.% P₂O₅, and also contained trace elements not detected in the Shipwreck 31CR314 sherds. These distinct differences could be due to different manufacturing origins for Shipwreck 31CR314 and Brunswick Town ceramics but also could reflect their subjection to different environments during use and loss prior to archaeological recovery.     

Elemental characterisation of Barbar ceramics from Tell Abraq

The early second millennium levels at Tell Abraq have yielded over 600 fragments of friable, red-ridged pottery with exploding lime grits which is superficially indistinguishable from contemporary, so-called 'Barbar'pottery on Bahrain (1). The Bahraini origin of the Tell Abraq Barbar sherds has been demonstrated by means of proton-induced x-ray and gamma-ray emission (PIXE/PIGME) analysis. In addition, the results of x-ray fluorescence (XRF) of Barbar pottery from Saar on Bahrain (2) have been re-examined, showing that the subgroups which characterise the Tell Abraq material correspond to those found in the Saar corpus. The techniques used on the Tell Abraq and Saar material – PIXE/PIGME and XRF – are compared.     

Characterization of Iron age pottery from eastern Turkey by laser- induced breakdown spectroscopy (LIBS)

Selected pottery sherds coming from the Ayanis, Dilkaya and Karagündüz excavations in eastern Turkey and dated from the Early to Middle Iron Age were examined as regards their composition by using laser-induced breakdown spectroscopy (LIBS). The objective of the study was first to investigate the potential of the LIBS technique in the compositional analysis of pottery and further to explore correlations in spectral data, by using chemometrics methods that would possibly enable discrimination among different sherds. This work is part of a broader study aiming to examine clay variability both before and during the Urartian State period and to explore possible relationships and differences among pottery objects from fortresses and settlements or settlements and cemeteries on the basis of the clay composition of sherds. Preliminary results demonstrate that by using the LIBS technique it is possible to analyse pottery sherds in qualitative and semi-quantitative ways, providing information on the clay and slip composition. Furthermore, encouraging results have been obtained by carrying out principal component analysis (PCA) on the LIBS spectra, which suggest that in certain cases, it is possible to directly correlate spectral information with the origin of pottery sherds.     

Preliminary Provenance Research on Chinese Neolithic Pottery: Huating (Xinyi County) and Three Yellow River Valley Sites

Instrumental neutron activation analysis (INAA) was applied to sherds from the important site of Huating and, for comparison, several Neolithic sites in the valley of the Yellow River. We hoped to compare the compositions of two stylistically different ceramics found at Huating, and to evaluate the degree of compositional clustering and inter‐site resolution that could be expected in an area that is noted for its extensive, and possibly very homogeneous, loess deposits. In addition, pottery sherds from Huating have been examined by microscopic petrography. All of these results will provide needed input in the planning of research towards the formation of a Neolithic/Shang Dynasty ceramic database for future use in archaeological research in China.     

Defining the provenance of red slipped pottery from Texas and Oklahoma by petrographic methods

Ceramics are among the most important artifacts that archaeologists use to reconstruct patterns of prehistoric trade and exchange. Petrographic analysis of ceramic thin-sections, in addition to providing detailed technological data, enables the identification of sand-tempering agents. These raw materials are potentially important evidence for ceramic provenance, assuming that such common materials themselves would not have been traded. Here we apply methods developed by sedimentary petrographers to the problem of determining the provenance of Red Slipped sherds from late Prehistoric (c. AD 1000–1400) sites in the Caddoan area and contemporaneous Plains Village sites. Modal frequencies of different kinds of quartz, feldspars and lithic grains are used to construct several triangular graphs that reveal compositional patterns indicative of provenance. Sherds from the Plains Village sites exhibit higher frequencies of lithic grains, feldspars and polycrystalline quartz relative to the sherds from sites in eastern Texas and eastern Oklahoma. While anomalous sherds were identified, the longstanding assumption that Red Slipped sherds in Plains Village contexts were traded from the Caddoan area is not supported by these data. These methods have strong application potentials for other, geologically diverse portions of North America.     

THE UTILIZATION OF TRACE CHEMICAL COMPOSITION TO CORRELATE BRITISH POST-MEDIEVAL POTTERY WITH EUROPEAN KILN SITE MATERIALS

This study uses X-ray fluorescent analysis to compare the trace chemical composition of seventeen pottery sherds excavated from sites in Britain with the trace analyses of twenty four sherds from continental sources. Results indicate that certain elements, notably zirconium, titanium, rubidium, and strontium show little variation within a particular sherd and are consistent among samples from the same source. Certain other elements appear to show wide variation which is possibly attributable to firing conditions, burial or is connected with the glaze. The comparisons of analyses indicate that nine of the seventeen British sherds can be closely correlated with particular continental sources. Tentative correlation is suggested for five sherds. The remaining three sherds clearly do not come from any of the sources investigated.     

Dairying in antiquity. III. Evidence from absorbed lipid residues dating to the British Neolithic

Absorbed lipid residue analysis has previously demonstrated that dairying was a major component of animal husbandry in Britain during both the Iron Age and Bronze Age. As a continuation of this research into the antiquity of dairying, the incidence of dairy fats associated with pottery vessels from six Neolithic sites from Southern Britain is presented herein. A total of 438 potsherds from Windmill Hill, Abingdon Causewayed Enclosure, Hambledon Hill, Eton Rowing Lake, Runnymede Bridge and Yarnton Floodplain were submitted for organic residue analysis. To date, this constitutes the largest number of sherds investigated from one particular archaeological period. The compound-specific stable isotope values of the major fatty acid components in animal fats, namely C_16:0 and C_18:0, enable absorbed lipids in pottery vessels to be classified to commodity group, i.e. ruminant adipose, dairy and non-ruminant adipose fats can be distinguished. The lipid extracts were relatively well preserved, and dairy fats were observed in approximately 25% of all of the sherds, demonstrating that milk was a valued commodity in the British Neolithic. These results confirm that dairying was an established component of the agricultural practices that reached Britain in the 5^th Millennium BC.     

On the provenance and manufacture of red-slipped fine ware from ancient Cassope (NW Greece): evidence by X-ray analytical methods

Energy-dispersive X-ray fluorescence spectroscopy was used to characterize red-slipped pottery (2nd–1st century BC) from ancient Cassope, north-western Greece. The compositional data were statistically treated by principal component analysis and chemical groups were established, representing locally produced and imported items. Mineralogical investigation by X-ray diffraction indicated firing temperatures in the range from 850 to 1000 °C for most of the sherds, while one group consisted of over-fired items, possibly in excess of 1050 °C. The morphology and elemental composition of the ceramic bodies and surface slips were examined through scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The analyses revealed that different pottery groups exhibit surface slips of different nature, in terms of thickness, degree of vitrification and elemental composition. Overall, the diversity in technological characteristics of the examined sherds is indicative of the socio-economic conditions prevailing in Cassopaea during the late Hellenistic period.     

THE DATING OF ANCIENT CHINESE CELADON BY INAA AND PATTERN RECOGNITION METHODS*

In 2005, sherds of a special type of ancient Longquan celadon ware were excavated at Maojiawan, in the city of Beijing, China. Although archaeologists agree that these sherds were fired in the period between the Yuan and Ming Dynasties, their specific date is unclear. In order to solve this problem, five other groups of ancient Longquan celadon sherds of known date were selected as reference samples. The elemental body composition of all the sherds was determined by Instrumental Neutron Activation Analysis (INAA). Using the same principles as in provenance research, pattern recognition methods were used to build classification functions to specify the date of the unknown sherds. After analysing the experimental data by discriminant analysis, three classification functions were built. All the unknown sherds were classified as Ming Dynasty. This prediction is well in accordance with the fact that these sherds are similar to other Longquan Ming celadon, and so they should be fired in the same dynasty. This also verified the judgement of the Beijing Institute of Cultural Relics.     

FINE WARE FROM LOCRI EPIZEPHIRI: A PROVENANCE STUDY BY INDUCTIVELY COUPLED PLASMA EMISSION SPECTROSCOPY

Fifty-six sherds of fine ware from Locri Epizephiri were analysed by inductively coupled plasma optical emission spectroscopy (ICPOES) and flame emission spectroscopy (FES). The sherds had been excavated on the archaeological areas of Marasà Sud, Centocamere and San Cono, and represent local and imported products from the seventh to the second century BC. The samples were dissolved by fusion with lithium metaborate and analysed for nine elements (Al, Fe, Ca, Mg, Ti, Mn, Sr, Ba and Cr) by ICPOES, while Na and K were determined by FES. The analytical data were subjected to hierarchical agglomerative clustering and principal components analysis to classify the sherds into compositional groups. The results obtained indicated that Corinthian, Attic and Ionian products or imitations may be classified in a few separate groups, while most local products are found in a unique, large group.     

A PROVENANCE STUDY OF POTTERY FROM ARCHAEOLOGICAL SITES NEAR CANOSA,PUGLIA (ITALY)*

Studies have been carried out to assess the provenance of selected pottery excavated at archaeological sites near Canosa, Puglia (Italy). Sixty-six sherds, ranging in date from the mid-seventh century BC to the beginning of the third century BC, were analysed by atomic absorption spectroscopy and 16 elements were determined. The analysis data were subjected to multivariate classification procedures. Tests showed that the majority of the examined sherds came from ancient local kilns; a probable Ionian origin was established for some other sherds, while the rest were of unknown origin.