The palaeo-Christian glass mosaic of St. Prosdocimus (Padova,Italy): archaeometric characterisation of tesserae with antimony- or phosphorus-based opacifiers

The present paper reports the results of archaeometric characterisation of the opaque tesserae, intentionally coloured with antimony- or phosphorus-based opacifiers, coming from one of the two only palaeo-Christian glass mosaics known in the Veneto region (Italy), i.e., the mosaic which decorated the votive chapel of St. Prosdocimus in Padova. In particular, 55 tesserae belonging to glass types “White”, “Blue”, “Yellow”, “Green” and “Brown” are examined here. The multi-methodological approach (SEM-EDS, EMPA, XRPD, imaging spectroscopy coupled, in some cases, with XAS) gave valuable insights into the complexities of palaeo-Christian glass mosaic production technologies. Two main groups are identified, one characterised by glassy matrixes and opacifiers (calcium or lead antimonate) typical of the Roman period and comprising all “White”, “Blue”, and “Yellow” tesserae and some “Green” ones, and the other characterised by glassy matrixes and an opacifier (calcium phosphate) typical of the 6th century AD, composed of “Green” and “Brown” tesserae. This suggests that, during that century there was a gradual change from older to “new” production technologies: although new opacifiers such as calcium phosphate started to be used, the frequent use of antimony-based ones (43/55 samples) supports the hypothesis that their systematic use was extended until the 6th century, although re-using old tesserae cannot be completely excluded. In addition, comparisons with compositional groups already identified in the “gold” tesserae of the same mosaic and tesserae from Ravenna demonstrate that both the same “base compositions” of the glass were used to produce transparent and opaque glass. This evidence, coupled with the results of the historical-artistic study, suggests technological connections between Padova and Ravenna, the capital of Byzantine mosaics in Italy. Micro-structural observations and chemical analyses of the Paduan antimony-based opacified glass demonstrate that different processes and raw materials were used in their production. Both in situ and ex situ crystallisation can be identified for calcium and lead antimonate in Paduan tesserae, whereas the production of tesserae opacified with calcium phosphate generally appears to be highly standardised. Although the opacifiers used in the Paduan tesserae support technological transitions, the colouring elements identified here, i.e., iron and manganese for white, yellow, brown and some green tesserae, cobalt for blue, and copper for blue and green, suggest continuity, because their use is widely testified in the production of both transparent and opaque glass artefacts dating from the Bronze Age until Medieval times, from whichever archaeological site the samples come. Peculiar relationships among the oxidation states of colouring elements, their contents in the glassy matrix, the types of opacifiers used, and the final colour of tesserae were identified. In addition, the correlations of cobalt and/or copper with other elements, together with identification of relics of colouring and “metallic” droplets, allow us to speculate on possible sources and production technologies. Lastly, identification of newly formed crystalline inclusions in tesserae also yields information on kiln temperatures, which ranged between 900 and 1150 °C, a range easily reached in the furnaces of the 6th century AD.     

Middle Bronze Age metallurgy in the Levant: evidence from the weapons of Byblos

This paper constitutes a synthesis of a technological investigation on copper base alloy weapons from Byblos. Most of the weapons are typical of the Middle Bronze Age in the Levant. Methods such as metallographic examination and chemical analyses by EDS were used to identify the different stages of the chaîne opératoire used in the making of these weapons. The results reveal precise information regarding the production of several types of weapons such as the type and performance of the moulds used for casting and the deformation process. Furthermore, these results highlight the contribution of economic and cultural factors in the choice of components in a copper base alloy recipe. Finally, the use of silver–copper brazes for joining copper base alloy objects is recorded for the first time for the period and region concerned.     

The production of speiss (iron arsenide) during the Early Bronze Age in Iran

In this paper, analyses of some unusual slag samples from the prehistoric site of Tepe Hissar in northeastern Iran are presented. These slags are the remains of a five-thousand-year-old pyrotechnological process that produced speiss, a quasi-metallic material usually formed as an accidental by-product of copper or lead smelting. We argue that the “speiss slags” from Tepe Hissar suggest the intentional production of iron–arsenic alloy (“speiss”) in prehistory. Why the Tepe Hissar metalworkers produced speiss is a question that requires further investigation, but our preliminary assessment suggests that it was to provide arsenic as an alloying component for arsenical copper, the preferred copper alloy during much of the Early Bronze Age in Iran, and widely used across the ancient world. This recognition significantly advances our understanding of the early stages of metallurgy in the Old World.     

Trace element and Pb isotope provenance analyses of native copper in northwestern North America: results of a recent pilot study using INAA,ICP-MS,and LA-MC-ICP-MS

Several indigenous groups in northwestern North America used native copper prior to EuroAmerican contact. The Arctic, Subarctic, and Northwest Coast culture areas all have archaeological finds and geological sources of native copper. The copper-rich region of south-central Alaska and southwestern Yukon has often been credited as the source of archaeological native copper found on the Northwest Coast despite the presence of native copper sources further south. This paper presents the results of a pilot study using INAA, ICP-MS, and LA-MC-ICP-MS to assess the potential for native copper provenance research in Alaska and the Yukon Territory. Discrete native copper sources could be distinguished from one another intra-regionally. Difficulties associated with future native copper provenance research in northwestern North America are discussed.     

LA-ICP-MS analysis of quartzite from the Upper Gunnison Basin,Colorado

We report the results of LA-ICP-MS analysis of 402 quartzite samples representing 48 collection loci in the Upper Gunnison Basin (UGB), Colorado and determine the extent to which the sources can be geochemically discriminated from one another using this non-destructive technique. The ability to differentiate among the sources would open the door to provenance studies of the quartzite chipped-stone tools and debitage that constitute 95% or more of most of the 3000-plus prehistoric site assemblages documented in the UGB. Our samples represent prehistorically quarried and non-quarried quartzite sources, including outcrop (primary) and gravel (secondary) deposits. The results reveal spatial and chronological trends in quartzite elemental composition that can be exploited for provenance determinations of quartzite artifacts from UGB sites, albeit using an assemblage-based sourcing strategy that differs from the familiar approach of “matching” obsidian artifacts to their statistically likeliest geological source. We offer a preliminary version of a sourcing protocol for UGB quartzite.     

Shepherds and plants in the Alps: multi-proxy archaeobotanical analysis of neolithic dung from “La Grande Rivoire” (Isère,France)

The analysis of phytoliths, pollen, charcoal and other macroremains was carried out in the neolithic shelter of “La Grande Rivoire”, Vercors massif (French Alps). The results show the predominance of tree species, in the form of phytoliths, clustered pollen, stomata, small branches charcoal, needles, bark, buds… The practice of leaf fodder is already known in the alpine and circum-alpine area from archaeological and historical sources. The analyses of the neolithic dung levels of “La Grande Rivoire” illustrate the use of leafy and flowering tree branches as fodder. The results also suggest that some species were used for special purpose in relation with the tending of livestock (litter, dietary supplement, veterinary practices).     

Black limestones used in antiquity: the petrographic,isotopic and EPR database for provenance determination

We compiled a database of some of the most important black limestone quarries used in Roman times to be able to determine the provenance of ancient artifacts. For this purpose, we adopted a multimethod approach using the techniques commonly applied to study the provenance of white marbles: petrographic observations, carbon and oxygen isotope composition, electron paramagnetic resonance (EPR) spectra characteristics. Few black limestones were quarried and traded in ancient times; indeed, the importance of most of these quarries was restricted to the areas in which they were located. In this work, we selected a limited number of quarries that produced material believed to have been exported and used throughout the Mediterranean area; most of the quarries selected are found in northern Tunisia, i.e. the Roman proconsular Africa: Djebel Oust, Djebel Azeiz, Ain al Ksir and (presumably) Thala. The “Nero Chiota” limestone quarried on the Aegean island of Chios (Greece) was also included in the database.     

LEAD ISOTOPE CHARACTERISTICS OF THE CYPRUS COPPER ORE DEPOSITS APPLIED TO PROVENANCE STUDIES OF COPPER OXHIDE INGOTS

Nearly 200 new lead isotope analyses of sulphidic and oxidized ores from 26 copper mines on Cyprus show that the mines from different geological regions group in five distinctive isotopic groups, each with a substructure, related to the geological history of the ore formation. Comparison of lead isotope compositions of Bronze Age artefacts with these data can in many cases reveal the actual mines from which the copper for particular artefacts was obtained. The particular case of the provenance of the copper for 78 Late Bronze Age copper ‘oxhide ingots’found in Cyprus, Crete, Greece, Sardinia, Turkey and Bulgaria is discussed. The data show that all oxhide ingots so far analysed, dating to the fourteenth century BC and later, were made of copper consistent isotopically with only one mining region in the geographical north of Cyprus, and especially the Apliki mine. The study provides further evidence which supports the validity of the conventional approach to the use of lead isotope analysis for provenancing metals; this evidence is antithetical to recent suggestions of a model for the production of copper oxhide ingots which involved widespread mixing of copper from a number of ore sources throughout the Mediterranean.     

The production technology of Egyptian blue and green frits from second millennium BC Egypt and Mesopotamia

The microstructures and chemical compositions of some 55 Egyptian blue and green frit samples from New Kingdom Egypt and 15th century BC Mesopotamia are determined using analytical scanning electron microscopy, the main focus being on frit cakes, powder residues, and frit vessel and bead fragments from one of the “factory areas” at Amarna in Middle Egypt. Replicate Egyptian blue frits produced in the laboratory are similarly investigated. Comparison of the microstructures of the ancient and replicate samples suggest that frit cakes are the primary product, and that these were ground to produce the powder, and then moulded to shape and refired to produce the vessels and beads. Egyptian blue and green frits are shown to be distinct pigments, the pigment produced depending on the relative proportions of copper oxide and lime in the mixtures. The bulk and glass phase compositions are used to try to infer the different sources of the quartz, lime, copper and alkali flux used in the production of frits from Egypt and Mesopotamia. An estimate is made of the scale of production of Egyptian blue frit in New Kingdom Egypt.     

Evaluation of treated and un-treated Nubia Sandstone using ultrasonic as a non-destructive technique

Deterioration factors, both “exogenous” and “endogenous”, are major sources of damaging monumental stones in Egypt. In the current study, the change state of one of the major Egyptian stones (Nubia Sandstone) is investigated and evaluated before and after consolidation by the use of wave velocity as a new method for detecting its elasticity modulus. Wave velocity propagation (Vp) is one of the most important and effective methods for estimating the durability of monumental stones without using any other harmful method as a compressive strength. This technique is usually used for a number of purposes, the first of which is the qualification of masonry building through its morphology and detection of internal defects (e.g. voids and cracks). The second is the examination of the changes of material physical properties, and the control conservation procedures. Third, it is used with some samples of Nubia sandstone for a laboratory test. The study concludes that the durability of samples increases due to the increase of material compacting as a direct result of using consolidant materials. Using the Vp as a non-destructive technique in examining monumental materials gives the same results of other harmful techniques.     

Non-destructive provenance study of cuneiform tablets using portable X-ray fluorescence (pXRF)

Portable X-Ray Fluorescence (pXRF) apparatus of the last generation was tested to determine its potential for routine provenance determination of clay cuneiform tablets, which cannot be analyzed by “classical” intrusive methods. A group of tablets from Hattuša (Bo?azköy) and from el Amarna, which were previously provenanced using optical mineralogy (OM) and instrumental neutron activation analysis (INAA), was analyzed by pXRF and the results were used to establish the grouping according to their elemental concentrations. These groups were compared with the previous results retrieved by OM and INAA in order to confirm their validity. The results corroborate the high potential of the pXRF for non-destructive study of well-defined, ‘closed’ assemblages of clay-derived, delicate artifacts, such as cuneiform tablets, bullae, and fine-ware pottery. Consequently, a group of previously unexamined tablets from Hattuša was analyzed by pXRF and the results are discussed with implications on future research.     

Colour in Minoan faience

The microstructures and chemical compositions of some 15 faience objects from Crete spanning the period from Middle Minoan IIIA through to Late Minoan IA are determined using analytical scanning electron microscopy. The Minoan faience is compared with replicate faience beads produced in the laboratory using various combinations of manganese, copper and iron as colorants. The alkali contents of the replicate beads are varied so that the colorants are present both as ions in a glass phase and as particulate oxides. These data are then used to try to infer the original colour of the Minoan faience, the great majority of which has suffered severe weathering during burial. The results suggest that instead of the present day “hallmark greys and browns” and “subtle greens and blues”, Minoan faience originally exhibited a wide range of colours, including bright turquoise blue, purple and violet, and pale yellow-green and greenish turquoise.     

Wotan and the ‘archetypal Ergriffenheit’: Mystical union, national spiritual rebirth and culture-creating capacity in C. G. Jung's ‘Wotan’ essay

This article analyses the 1936 “Wotan” essay by Swiss psychologist Carl Gustav Jung in light of one of its reigning motifs, Ergriffenheit. First, this term is examined within the works of Protestant theologian Rudolf Otto and Indologist Jakob Wilhelm Hauer, who used it to describe what they claimed to be the original religious experience, a state of being deeply stirred or even seized by the “the holy” or by “the ultimate reality.” The article then examines antecedents in Jung's theory of states of psychic seizure, in which two halves of the psyche come into conflict, the resolution of which leads to an increased capacity to create the arts of culture. The analysis then moves to the “Wotan” essay itself, where Jung brings together his own theory of psychic seizure with the theory of the original religious experience as proposed by the above-named scholars of religion in order to suggest that, under National Socialism, the Germans were in the midst of a collective confrontation with their own inner divinity, which should lead to a national spiritual rebirth. The article then investigates the works of several of the men Jung mentions in the essay, as well as his use of ancient Germanic mythology, to support his claim. Through his portrait of the Germanic archetype Wotan, Jung psychologizes and thereby essentializes the Romantic image of the Germans as “a people of poets and philosophers” as well as that of a Nietzschean “master-race.” In conclusion, the article argues that, at least in 1936, Jung's attitude towards Hitler and National Socialism was much more favorable than has previously been recognized.     

Provenance of Early Bronze Age metal artefacts in Western Switzerland using elemental and lead isotopic compositions and their possible relation with copper minerals of the nearby Valais

Ten Early Bronze Age (BzA1, 2200–2000 BC) copper artefacts from the central Valais region from Switzerland were studied for their elemental composition and lead isotope ratios. In order to answer the archaeological question of a local copper supply, a database for copper minerals across the Valais (Switzerland) has been established. This database contains 69 data on lead isotope ratios as well as additional information on the minerals and geochemical associations for copper minerals from 38 locations in the Valais. Comparisons of the artefacts were also made with data pertaining to minerals from various deposits from Europe and Anatolia taken from the literature. The provenance of the materials is very diverse. Some of the data are compatible with the data from the copper mineral deposits of the Valais region. Moreover, three copper lunulae were identified as possibly Tuscan, which suggests contacts between Italy and the Valais region. This pattern also establishes a multiplicity of provenances for the metal and cultural influences in the Alpine environment of the Rhone Valley of Switzerland at the beginning of the Early Bronze Age.     

Ballistically anomalous stone projectile points in Australia

The emergence of stone-tipped projectile weaponry was an important event in hominin evolution. A common archaeological approach to identifying projectile weapons is to extrapolate from optimal values of ballistically-relevant attributes as determined from ethnographic North American weapons and modern experiments. Among the most significant of these attributes is “tip cross-sectional area” (TCSA) because it determines a point's efficiency in penetrating an animal. The warranting argument for projecting these data onto prehistoric artefacts is that past “research and development” necessarily led to stone projectiles with optimal TCSA values for a given delivery system. However, our test of this warranting argument, involving analysis of 132 hafted ethnographic Australian stone projectile points and 102 hafted knives, demonstrates that Aborigines did not optimize TCSA values, thus offering a challenge to TCSA-based narratives about the first appearance of projectile weaponry. This illustrates the difficulty of inferring ancient stoneworkers' design intentions from narrowly-defined optimal values. Instead, tool designs should be considered in the context of the reduction sequences that produced them and the dynamics of transmission of those reduction sequences across generations.     

“Copper people” of the bronze age: The reconstruction of their health and social status

“After you shall arise another kingdom inferior to you, and yet a third kingdom of bronze, which shall rule over all the earth” Dan. 2: 39 The Metal Age opened up new prospects for mankind and led to the emergence of a new category of professionals – miners, founders, smiths. With relation to the Bronze Age, these may be called “copper people.” The article explores new methods that can be used to identify their skeletal remains in museum collections. Based on biological data, certain aspects of the lifestyle of a male (presumably a smith) buried in an Abashevo collective grave at Pepkino, the Republic of Mari-El, Volga Federal District, and of other individuals buried in the same grave are reconstructed. Morphological, paleopathological, radiographic, and computer tomography examination of skeletal remains, as well as the results of histological, atomic absorption, and isotopic analyses of bone tissue provide information concerning diet, physiological stress, beginning of professional specialization, and the effects of heavy physical stress on their health status.     

Coupling lead isotope analysis and petrography to characterize fabrics of storage and trade containers from Hala Sultan Tekke (Cyprus)*

Lead isotopes, thin‐ and sherd‐section analyses are coupled on pottery‐vessel fragments excavated from the Late Bronze Age site of Hala Sultan Tekke (south‐east Cyprus) and representing fabrics used for the production of storage and trade containers. The fabrics of the sherds are first described according to general macroscopic observations. Based on the different fabrics identified, a petrographic analysis is carried out on thin sections and compared to lead isotope results on the same samples. This study shows that a specific fabric corresponds to a specific lead isotopic composition and proposes different sources for the various groups of associated sherds/fabrics. It also demonstrates the compatibility and complementarity of petrography and lead isotopes within pottery provenance study.     

Sources of archaeological dacite in northern New Mexico

For years archaeologists in New Mexico, particularly in the northern Rio Grande region have noticed a very fine-grained what appeared to be mafic or basalt raw material source in late Paleoindian and Archaic contexts in northern New Mexico and southern Colorado. Indeed, a number of Folsom, Cody, Plainview, and Archaic bifaces are produced from this material. It appeared that there were at least two possible very fine-grained volcanics that could be the sources for these raw materials – San Antonio Mountain in far northern New Mexico, in the Taos Plateau Volcanic Field, and Cerros del Rio, on the east side of Bandelier National Monument right above the Rio Grande. After reconnaissance collections at the two probable sources, the short story is that the vast majority of “basalt” artifacts were indeed produced from one of these sources, but they are petrologically dacite and silicic volcanic rocks. An additional dacite source, called here the “Newman Dome”, also in the Taos Plateau Volcanic Field was discovered in the 1980s, but remained mainly discussed in the gray literature by CRM archaeologists. Examination of various Paleoindian and Archaic collections from the northern and middle Rio Grande indicates a strong preference for this silicic rock for the production of chipped stone tools, and in concert with obsidian source provenance studies has increased our ability to reconstruct procurement and range in these preceramic periods. These high-alkali dacite sources are easily discriminated with their trace element compositions, and based on this study, procurement seems to be dominantly restricted to these three sources in the region. Here I discuss the petrology, geochemistry, and some of the archaeological issues of these sources and their utility in the Southwest archaeological endeavor in an effort to bring these important prehistoric raw materials into the published realm.     

Non-ferrous metallurgy from the Phoenician site of La Fonteta (Alicante, Spain): a study of provenance

The lead isotope composition of 22 samples from the excavation of the Phoenician site of La Fonteta (Guardamar del Segura, Alicante, Spain) has been analysed in a preliminary study of their provenance. These materials span chronologically from the first half of the 8th century BC to the middle of the 6th century BC.The samples have been selected to include materials used in lead and silver production, as well as in copper-based metallurgy. Therefore, lead droplets, galena nodules and fragments of litharge have been analysed, together with a fragment of a copper ingot, an object, a melting waste composed of a Cu–Pb alloy, and two fragments of a material that we have provisionally labelled ‘Pb–Cu cupellation debris’.All these materials have been initially analysed by X-Ray Fluorescence-Spectrometry to identify their bulk compositions. Some of them have been also analysed by SEM–EDX and ICP–OES. Subsequently, lead isotope analyses (LIA) have been performed using Thermal Ionization Mass Spectrometry (TIMS). The new LIA data obtained has been compared with published lead isotope data from the Mediterranean area. The identification of different groups suggests a significant complexity of the internal and external trade routes during the Orientalising period. For this reason, the provenance study of these materials is especially important in shedding light on the commercial dynamics that the Phoenicians established with native people to control the raw materials and to commercialise finished products.     

On the origins of extractive metallurgy: new evidence from Europe

The beginnings of extractive metallurgy in Eurasia are contentious. The first cast copper objects in this region emerge c. 7000 years ago, and their production has been tentatively linked to centres in the Near East. This assumption, however, is not substantiated by evidence for copper smelting in those centres. Here, we present results from recent excavations from Belovode, a Vin?a culture site in Eastern Serbia, which has provided the earliest direct evidence for copper smelting to date. The earliest copper smelting activities there took place c. 7000 years ago, contemporary with the emergence of the first cast copper objects. Through optical, chemical and provenance analyses of copper slag, minerals, ores and artefacts, we demonstrate the presence of an established metallurgical technology during this period, exploiting multiple sources for raw materials. These results extend the known record of copper smelting by more than half a millennium, with substantial implications. Extractive metallurgy occurs at a location far away from the Near East, challenging the traditional model of a single origin of metallurgy and reviving the possibility of multiple, independent inventions.