The ‘invisible’ product: developing markers for identifying dung in archaeological contexts

Dung is one of the most valuable resources in arid countries: traditional communities all over the world use it for heating, cooking, building and decorative purposes. It is commonly assumed that the same happened in the past, especially after the domestication of herbivores in the 11th millennium B.C. The presence and use of dung in archaeological contexts has been routinely studied through different techniques among which spherulites (calcium carbonates that form in animals guts) and small seeds assemblages’ analyses. However all the proxies considered so far to trace dung can be unreliable, especially when used singularly. After a review of the traditional methods used to trace dung in archaeological contexts, this paper presents the results of an ethnographic study on 11 modern dung cakes collected in northern India that were analysed for chemical, spherulite and phytolith content. Our results show that the lack of spherulites cannot be taken as absence of dung input and that the combination of phytolith and chemical signatures can be a reliable proxy for the inference of dung presence in archaeological contexts.     

Fuel, Fire and Heat: an experimental approach to highlight the potential of studying ash and char remains from archaeological contexts

As in traditional societies today ancient societies probably selected different fuels to meet specific heat requirements. Char and ash, the end products of fire, are often found in abundance in archaeological contexts. These end products can provide information regarding (i) the original fuel resource and type, (ii) the characteristics of the fire and (iii) combined with other archaeological evidence shed further light on possible socio-economic activity(-ies) associated with that fire. The three main fuel resources would have been (i) modern vegetation, (ii) fossil fuel and (iii) animal by-products. Local availability and abundance would have influenced the choice made.In this study an experimental approach was adopted to try and distinguish between the three different fuel resources that are known to have been used by ancient societies (and continue to be used by traditional societies today) from their char and ash remains to help determine original fuel-type and understand the relative heating properties. For this end one fuel-type from each fuel resource listed above, namely wood, peat and cow dung, was chosen.     

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC AND ISOTOPIC ANALYSIS OF CARBONIZED RESIDUES FROM SUBARCTIC CANADIAN PREHISTORIC POTTERY

Late prehistoric pottery is found in abundance at archaeological sites around Southern Indian Lake. Black residues, found on the two dominant vessel forms, flat plates and round pots, are presumed to be the remains of prehistoric meals. ¹³C cross-polarization magic-angle-spinning nuclear magnetic resonance spectroscopy (CPMAS NMR) and¹³C and¹⁵ N isotopic ratios and C/N ratios are used to reconstruct prehistoric diet and to shed light on possible uses for the plates. Samples of foods were cooked in clay pots, on a wood fire, to simulate the conditions of burning that could have produced the residue. Decomposition of carbohydrates, protein, and fat during cooking is studied with ¹³C CPMAS NMR, and the effect of cooking on isotopic and C/N ratios documented. Predominantly fish and fat were cooked in the pots, whereas the residues from plates contain a greater proportion of fat and could have been used as frying pans or possibly as fat-burning lamps placed on the ashes of a wood fire.     

Identifying Threshing Floors in the Archaeological Record: A Test Case at Iron Age Tel Megiddo,Israel

Abstract

The identification of activity areas in archaeological sites is an important part of archaeological research contributing to the reconstruction of past ways of life. The threshing floor is an activity area that relates to subsistence practices in agricultural societies, yet identifying threshing floors in the archaeological record is difficult. We present a geoarchaeological study conducted at an Iron Age layered feature unearthed in 1998 at Tel Megiddo, Israel, in which we tested a previous assumption that it represents the remains of a threshing floor. Using micromorphology, mineralogy, elemental analysis, phytoliths, and dung spherulites, we show that the materials comprising the bulk of the layers in the Megiddo feature include large amounts of wood ash and the inorganic remains of livestock dung. Based on these results, coupled with ethnographic data on threshing floors and observations on the macroscopic traits of the feature under consideration, we conclude that the layered feature at Megiddo does not represent a threshing floor but a single-household trash heap. We suggest that the interpretation of similar features at other archaeological sites as threshing floors be reevaluated.     

Environment,cooking strategies and containers

This paper is an exercise in theory building that explores container form, function, and distribution. Using ethnographic data, environmental reconstructions, and archaeological information, containers are examined within the framework of the container complex, the group of containers used within a system. The results reveal a robust patterning between stone boiling and direct fire boiling and environmental thresholds. It also shows that container fabric used in these cooking strategies patterns by environmental variables. The results are models of the distribution of cooking strategies and the container fabrics used for cooking that can then be applied to the archaeological record.     

Ashes to ashes, charcoal to dust: micromorphological evidence for ash-induced disintegration of charcoal in Early Neolithic (LBK) soil features in Elsloo (The Netherlands)

Charcoal and other forms of charred organic material - an important part of the archaeological record - consist of benzenoids. Such components are unstable in basic or alkaline conditions. Since ashes are alkaline, this means that archaeological charcoal may have been disintegrated and lost if they were buried together with ashes, e.g. as in fireplaces. Ash may also cause clay translocation in decalcified loess because of the disaggregating effect of K⁺ ions in the soil solutions. We investigated the interplay of these two processes, using micromorphological samples from the Early Neolithic site at the Joannes Riviusstraat in Elsloo. Evidence for charcoal disintegration was found in the form of cavities in charcoal fragments, most commonly filled in with thick reddish limpid clay coatings. The combination of cavities and clay coatings are evidence for the disintegration of charcoal under the influence of ash. Ash may also have been instrumental in preserving small bone fragments in these decalcified well-drained loess soils. The evidence of ash-induced charcoal disintegration implies that charcoal preservation in the archaeological record is dependent on (1) whether or not is was buried alongside with ashes, and (2) on various soil characteristics that determine that determine how quickly the ash-derived alkalinity and potassium ions are leached.     

Stable carbon and oxygen isotopic compositions of wood ash: an experimental study with archaeological implications

Wood ash, composed mainly of the mineral calcite, is an important component in many archaeological sites. Identification of wood ash in the archaeological record is often difficult due to mixing of ash with other calcitic components of geogenic origin and/or due to diagenetic changes. A recent empirical study using the stable isotope compositions of carbon (δ¹³C) and oxygen (δ¹⁸O) in wood ash enabled the identification of mixtures of wood ash with geogenic calcite and to follow diagenetic changes due to partial dissolution and re-precipitation of ash in two prehistoric cave sites in Israel. Little however is known about the processes responsible for the isotopic compositions of wood ash in relation to formation at various temperatures and the influence on isotopic composition of ash from a variety of plant species. Here we present an experimental study of wood ash formed by burning three C3 tree species and one C4 desert bush at different temperatures. The results indicate that there are significant differences in the isotopic compositions of carbon and oxygen between wood ash that forms by combustion at a relatively low temperature (500 °C) and at a higher temperature (900 °C). In addition, we show that the isotopic composition of carbon and oxygen in high temperature wood ash approaches equilibrium over a period of several months and that the carbon isotopic composition of low temperature wood ash may reflect the photosynthetic pathway of the burnt woody species. Lastly, we show that the isotopic compositions obtained from wood ash prepared at different temperatures do not reflect a temperature dependent fractionation process, but a mixing line between calcite that formed by low temperature combustion and calcite formed by high temperature combustion which later underwent re-carbonation with atmospheric CO₂. In addition, we suggest that exchange processes may possibly occur during combustion between decomposing calcium-oxalate and atmospheric O₂, CO₂ and CO. The archaeological implications of this study are discussed in relation to identification of wood ash in the archaeological record, identification of fuel sources and burning temperatures, and diagenetic changes expected in karstic cave environments. The method presented here can be applied at any archaeological site.     

Subsistence practices in an arid environment: a geoarchaeological investigation in an Iron Age site,the Negev Highlands,Israel

The Negev Highlands (southern Israel) is an arid zone characterized by settlement oscillations. One settlement peak occurred in the early Iron Age IIA (late 10th and early 9th centuries BC). The most conspicuous structure in many sites of this period is an oval compound comprised of an internal courtyard surrounded by rooms. Two hypotheses for the function of these oval compounds are that they served as Israelite fortresses which guarded the southern border and routes of the Solomonic kingdom, or that they represent local agro-pastoral groups. In order to gather more information regarding the subsistence practices conducted in these oval compounds, we carried out a small-scale excavation at the site of Atar Haroa. We focused on sediment sampling and used several geoarchaeological, as well as isotopic, techniques in order to identify macroscopic and microscopic remains related to animal husbandry and crop agriculture. The remains identified from the archaeological sediments were compared with modern reference materials collected from abandoned Bedouin camps. The excavation included two half rooms and several test pits in the courtyard of the oval compound, featuring one Iron Age occupation level composed of gray sediments and relatively small amounts of pottery, bones and macro-botanical charred remains. Micromorphological, mineralogical, dung spherulite and isotopic analyses carried out on the gray occupational sediments from the rooms show that they originate from wood ash and dung, both used as fuel. Similar analyses of the gray sediments in the courtyard show that they originate only from degraded livestock dung. Phytolith analyses show that the gray anthropogenic sediments have similar concentrations of phytoliths as in control (yellowish) sediments and in the dung of winter free-grazing desert livestock and lichen-grazing black dwarf Bedouin goats. Phytoliths indicative of cereal crops are completely absent in the archaeological dung remains, indicating that cereal crops were not processed by the site inhabitants. Based on ethnographic and archaeological parallels, and on the presence of grinding stones and absence of sickle blades in the excavated rooms, we infer that the inhabitants at the oval compound at Atar Haroa subsisted on livestock herding and bought or exchanged cereal grains. Our results support the hypothesis that the inhabitants at the oval compound at Atar Haroa were desert-adapted pastoralists, rather than garrisoned soldiers.     

A Study of the Techniques Used to Make Laohudong Guan Ware in China in the Southern Song Dynasty

Through a combination of analysis and synthesis of Laohudong Guan ware shards from Hangzhou City in southern China, some new hypotheses concerning Guan ware manufacture can be proposed. These suggest that the complex microstructures seen in Guan ware glazes, and which contribute significantly to their jade‐like qualities, may owe much to layers of fine bubbles trapped during the glazing process. It is also proposed that the multi‐layer glazing methods used at the Guan ware kilns at Hangzhou may have helped initially to disguise the relatively coarse and ferruginous clays used for Guan ware manufacture. Once established, the layered glazing technique was used for its own sake—eventually yielding wares that could comprise more glaze than clay. Raw materials and firing temperatures were also explored for this study, and these suggest the use of porcelain‐stone/wood ash mixtures for glaze‐making, with 20–30% calcareous wood ash being the usual amounts. The average heat‐work for the glaze firing seems to have been equivalent to Orton Cone 7, giving a typical finishing temperature of ～1215°C. A single biscuit firing and a single glaze firing seem likely for most Laohudong Guan wares. Studies of the losses that occur in the preparation of calcareous wood ashes suggest that very large quantities of botanic material must have been burned to provide ash for glaze‐making at the Laohudong kiln. From the environmental perspective, a combination of thick glazes and heavy wood‐ash usage would have placed great demands on local fuel supplies.     

Archaeobotanical inference of Bronze Age land use and land cover in the eastern Mediterranean

Charcoal and charred seeds at five Bronze Age archaeological sites discern ancient land use in the eastern Mediterranean. Seed frequencies of orchard crops, annual cereals and pulses, and wild or weedy plants are used to characterize plant utilization at different archaeological sites on the island of Cyprus, in the Rift Valley of Jordan, and in the Jabbul Plain and along the upper Euphrates River valley in Syria. Seed to charcoal ratios provide proxies to determine the relative usage of dung versus wood for fuel across the ancient Mediterranean landscape. Greater charcoal and lower charred seed values are interpreted to represent a wooded environment, while higher amounts of charred seeds and minimal wood charcoal suggest a much great use of dung as a fuel source. Interestingly, Politiko-Troullia (Cyprus, Cypriot archaeological sites are, by convention, named for the nearest modern village (Politiko), followed by an italicized toponym (Troullia) referring to the plot of land that incorporates the site) has the lowest seed to charcoal ratio, suggesting its residents primarily burned wood and that the landscape surrounding Troullia remained relatively wooded during the Bronze Age. In contrast, villagers at Tell el-Hayyat (Jordan) utilized a mixture of wood and dung, in contrast to Tell Abu en-Ni’aj (Jordan), and especially Umm el-Marra and Tell es-Sweyhat (Syria), where inhabitants relied solely on dung fuel. Comparative analysis and interpretation of seed and charcoal evidence thus illustrates the variety of fuel use strategies necessitated by the dynamic and diverse Bronze Age landscapes of the Eastern Mediterranean.     

Going underground: experimental carbonization of fruiting structures under hearths

We show that carbonized fruits and seeds recovered from Middle Stone Age deposits in rock shelters are likely to have been carbonized as part of post-depositional processes. We buried indigenous South African fruits, nuts and seeds at pre-determined depths and distances from the centers of experimental fires. The cold ashes of the hearths and the sand surrounding them were subsequently excavated, using standard archaeological techniques and dry-screening. The fruiting structures from the oxidizing part of the fire were burnt to ashes, whereas those buried in sand under anoxic conditions survived in varying forms. Those buried 5 cm below the center of the fire were carbonized; those buried 10 cm below the center of the fire were dehydrated; and those 5 cm and 10 cm below the surface at the outer edge of the fire were unaffected. Size, moisture or oil content of the original fruit or seed did not appear to influence whether or not carbonization took place. Temperatures recorded 5 cm below the experimental fires suggest that the carbonization occurred at or before a maximum temperature of 328 °C, and also at lower maximum temperatures (152 °C) that were maintained for long periods. Even when the quantities of a particular wood are controlled, open fires may produce variable underground temperatures and the temperatures below ancient hearths would have been equally variable. We suggest that Cyperaceae (sedge) nutlets, the most numerous fruiting structures in the Sibudu Middle Stone Age archaeobotanical assemblage, occur in the shelter as a result of human activity, subsequent burial, and accidental carbonization when hearths were built directly above the buried nutlets.     

Species identification of archaeological dung remains: A critical review of potential methods

Abstract

Dung, macroscopically recognisable as such or not, can more commonly be found in archaeological contexts than is perhaps realised. Up to now, identification of dung to the species which produced it is usually either tenuous, or is not possible. However, species identification can be very informative and is necessary before any further studies can be conducted on the dung, for example on health and hygiene in the past and palaeoecology. This study presents a review of potential methods by which species identifications of archaeological dung can be undertaken. Criteria for identification can be divided into three broad categories: morphometric features of the dung; the content of dung and contextual evidence. Overall, the chances of a precise identification are high; however, a combination of different criteria and techniques will often be necessary to establish a secure identification. Moreover, preservation issues may exclude the application of some criteria while several criteria require more research and the expansion of reference collections of recent material. The overall aim is to move towards standardised methods for species identification of archaeological dung.     

Identifying archaeological wood stack charcoal production sites using geophysical prospection: magnetic characteristics from a modern wood stack charcoal burn site

Charcoal making was a common process in the woodlands of Britain for many centuries. However, historic ‘wood stack’ production sites are difficult to identify. This paper tests the hypothesis that geophysical survey is an appropriate method for the discovery and identification of archaeological charcoal making sites. A traditional wood stack charcoal kiln was constructed in Low Staindale, Dalby Forest, near Pickering, North Yorkshire, to investigate the charcoaling process and the effect of low-temperature carbonisation on the magnetic properties of the soil underlying the kiln. The results from temperature monitoring (within and beneath the charcoal stack) throughout the charcoaling process, geophysical surveys across the charcoal kiln platform, and laboratory analysis of soil and ash samples, are presented. The degree to which the magnetic properties of the ground beneath the charcoal kiln had been enhanced as a consequence of this low-temperature process is discussed. Whilst some magnetic enhancement to the soil beneath the kiln platform was recorded, enhancement appears to be the result of contamination from the wood stack sealing material rather than the effect of heat transfer resulting from the charcoaling process. The results suggest that whilst historic wood stack charcoal production sites are likely to remain an enigmatic and under-reported feature in the archaeological landscape, geophysical prospection does have the potential for identification of these sites.     

An Optimized Approach for Protein Residue Extraction and Identification from Ceramics After Cooking

Extraction of protein residues from archaeological matrices, such as pottery clay, lithics, and grinding stones, has proven to be methodologically challenging. Protein residue analysis is fraught with technical challenges in analytical chemistry. In cooking pottery, protein residues are thought to bind to clay surfaces in vessel walls through a variety of primarily non-covalent interactions. Removal of protein residues requires the disruption of these interactions, and a diverse set of tools has been proposed and applied. Here, we test extraction procedures through varying combinations of physical parameters and solvents to derive an optimal approach yielding efficiencies of recovery from experimental pottery above 60%. The utility of our extraction approach was further validated through liquid chromatography?Cmass spectrometry analysis of experimental residues. We have identified several hurdles to developing a successful study of protein residues from pottery, each of which is surmountable with additional method development in the realm of archaeological chemistry.     

苏家村遗址烧土样品的过火温度研究

烧土制品作为最早的人工建筑材料,使人类的居住环境得到了根本性的改善。然而,学界关于烧土建筑的成因存在人为烘烤处理、缘自火焚、废弃习俗等多种观点。通过科技手段研究烧土制品的过火温度,有助于科学分析烧土建筑的成因,探讨与之相关的建筑工艺,丰富史前建筑史研究。磁学研究表明,考古遗址中的土壤及其他沉积物在受热后新生成了磁铁矿、磁赤铁矿等强磁性矿物导致磁性显著增强,且矿物成分和磁性几乎不会再发生变化;但当重烧的温度接近或大于原始烧成温度时,样品中原始矿物的破坏或新矿物的生成,会引起矿物磁性的改变。基于这一原理,实验室内分析受热黏土的磁化率随再加热温度的变化特征,可反映烧土制品的过火温度。苏家村遗址是大汶口文化晚期至龙山文化中期早段一处重要的聚落遗址,遗址中第5层为厚约20～40 cm的红烧土层且覆盖整个遗址,推测为房屋倒塌造成的建筑垃圾堆积层或人为堆积层,出土大量烧土块。本研究利用X射线衍射分析法、X射线荧光光谱分析法和磁化率法等对苏家村遗址出土的烧土样品开展了组成及构造特征和样品的过火温度的综合分析。结果表明,苏家村遗址烧土样品中的白灰层中人为地添加了白色陶土原料,土层中有意地添加了植物残骸作...     

Land use in prehistoric malta. A re-examination of the maltese 'cart ruts'

Summary. This paper explores the manufacture and function of the so‐called ‘cart ruts’ within the harsh environment of Malta and proposes that they were deliberately constructed in order to push the boundaries of available arable land and are better identified as field furrows. Using comparative ethnographic evidence as well as archaeological data from European contexts, it is argued that the driving force, which necessitated their manufacture in Malta, lay in socio‐economic pressures. It is argued that the ruts are of high antiquity, products of Temple Period intensification and marginalism in land use.     

Ethnographic Clay Sourcing Practices: Insights for Archaeological Assemblage Interpretations

This paper uses examples of ethnographic clay sourcing strategies from coastal and central Kenyan communities (Digo, Jomvu, Chonyi, Tigania and Mbeere), and potsherds from the Manda archaeological site in Kenya (seventh-fourteenth centuries AD), to illustrate archaeological clay variability and discuss cultural and social behaviour which may contribute to paste inconsistences in an archaeological assemblage. I demonstrate that while function and environmental constraints influence the potters’ decision in the selection of clay sources/treatment, the choice may also be influenced by other factors such as aesthetics, which are dependent on the values of the customer, and in some cases, societal taboos. I also argue that clay sources are not always indicators of production centres, and that heterogeneity and homogeneity in paste composition could imply production centres and customer homesteads respectively.     

Is vitrification in charcoal a result of high temperature burning of wood?

The term ‘vitrified’ is used to describe the glassy appearance of some charcoals recovered in the archaeological record. It has been generally considered that this phenomenon is a result of wood being subjected to high temperatures similar to the role of temperature in the formation of glass and pottery. Charcoals displaying characteristics of vitrification from three distinct archaeological contexts were analysed using reflectance microscopy to determine their temperature of formation. Charcoal was also generated in laboratory charring experiments at temperatures of 900–1100 °C for durations of 1, 6, 12 and 24 h to determine if subjection to high temperature led to vitrification. None of the laboratory-produced charcoals displayed characteristics of vitrification. Mean random reflectance of the vitrified archaeological fragments indicated temperature of formation from 310 to 530 °C. A charring experiment was also conducted, at 500 °C for 6 h, using green wood with some bark attached, and added sugars, but no evidence of vitrification was seen. Therefore vitrified charcoals do not result from high temperature charring or primarily from the use of green wood.