Characterizing Quartz Artefacts: A Case Study from Manitoba's Northern Boreal Forest

Visual and geochemical analyses of 30 pre‐contact quartz tools from the Churchill River basin of northern Manitoba were used to provisionally assess source provenance based on comparison to local quartz quarry data. The results indicate that tools made from quartz acquired from these quarries were transported and eventually deposited into archaeological sites up to 200 km away. Transport of this quartz, which is of relatively moderate quality, over such distances suggests that stone tool–using hunter–gatherer populations that lived in the Churchill River basin of northern Manitoba were highly mobile. It also indicates that higher‐quality raw materials were unavailable in the immediate area.     

Obsidian provenance for prehistoric complexes in the Amur River basin (Russian Far East)

The sources of high quality volcanic glass (obsidian) for archaeological complexes in the Amur River basin of the Russian Far East have been established, based on geochemical analyses by neutron activation and X-ray fluorescence of both ‘geological’ (primary sources) and ‘archaeological’ (artifacts from the Neolithic and Early Iron Age cultural complexes) specimens. A major obsidian source identified as the Obluchie Plateau, located in the middle course of the Amur River, was found to be responsible for supplying the entire middle and lower parts of the Amur River basin during prehistory. The source has been carefully studied and sampled for the first time. Minor use of three other sources was established for the lower part of the Amur River basin. Obsidian from the Basaltic Plateau source, located in the neighboring Primorye (Maritime) Province, was found at two sites of the Initial Neolithic (dated to ca. 11,000–12,500 BP). At two other sites from the same time period, obsidian from a still unknown source called “Samarga” was established. At the Suchu Island site of the Early Neolithic (dated to ca. 7200–8600 BP), obsidian from the ‘remote’ source of Shirataki (Shirataki-A sub-source) on Hokkaido Island (Japan) was identified. The range of obsidian transport in the Amur River basin was from 50 to 750 km within the basin, and from 550 to 850 km in relation to the ‘remote’ sources at the Basaltic Plateau and Shirataki-A located outside the Amur River valley. The long-distance transport/exchange of obsidian in the Amur River basin in prehistory has now been securely established.     

横岭山商周时期玉器的质地、白化现象和玉料产地研究

为研究广东博罗横岭山商周时期墓地出土玉器的质地、白化现象和玉料产地,对玉料样品进行常规矿物学、红外光谱、X射线粉晶衍射、扫描电镜和拉曼光谱的测试。结果显示,该墓地出土玉器的材质包括石英、水晶、透闪石（软玉）和杂砂岩。其中,透闪石质的玉器呈白色、不透明的外观,被认为和酸性土壤的腐蚀有关;出土的石英质玉器（含水晶器）的包裹体特征及包裹体均一温度显示该墓地出土的石英质玉器（含水晶器）的玉料较可能来自变质石英岩。伟晶岩或高温石英脉,将其与博罗本地、台山地区（近环珠江口地区）的石英及水晶样品进行对比,未有证据显示该墓地出土的石英质玉器（含水晶器）的原料来自上述地区。本研究可为揭示商周时期珠江三角洲地区的先民对自然资源的认识和利用能力以及当时社会的生产力水平、物品交换及贸易路线等方面提供基础科学依据。     

LA-ICP-MS analysis of quartzite from the Upper Gunnison Basin,Colorado

We report the results of LA-ICP-MS analysis of 402 quartzite samples representing 48 collection loci in the Upper Gunnison Basin (UGB), Colorado and determine the extent to which the sources can be geochemically discriminated from one another using this non-destructive technique. The ability to differentiate among the sources would open the door to provenance studies of the quartzite chipped-stone tools and debitage that constitute 95% or more of most of the 3000-plus prehistoric site assemblages documented in the UGB. Our samples represent prehistorically quarried and non-quarried quartzite sources, including outcrop (primary) and gravel (secondary) deposits. The results reveal spatial and chronological trends in quartzite elemental composition that can be exploited for provenance determinations of quartzite artifacts from UGB sites, albeit using an assemblage-based sourcing strategy that differs from the familiar approach of “matching” obsidian artifacts to their statistically likeliest geological source. We offer a preliminary version of a sourcing protocol for UGB quartzite.     

The use of SEM-EDS,PIXE and EDXRF for obsidian provenance studies in the Near East: a case study from Neolithic Çatalhöyük (central Anatolia)

In this paper we evaluate the relative analytical capabilities of SEM-EDS, PIXE and EDXRF for characterizing archaeologically significant Anatolian obsidians on the basis of their elemental compositions. The study involves 54 geological samples from various sources, together with an archaeological case study involving 100 artifacts from Neolithic Çatalhöyük (central Anatolia). With each technique the artifacts formed two compositional groups that correlated with the East Göllü Da? and Nenezi Da? sources. The non-destructive capabilities of these methods are emphasized (albeit with certain analytical limitations in the case of SEM-EDS), suggesting important new techniques for Near Eastern obsidian provenance studies.     

Characteristics of ESR signals and TLCLs of quartz included in various source rocks and sediments in Japan: A clue to sediment provenance

The variation of electron spin resonance (ESR) signal intensities and thermoluminescence colour images (TLCIs) of quartz was investigated in the present study for various rocks and sediments in Japan, to discuss the possibilities of identifying the sediment provenance. The ESR signal intensity of the E₁’ centre in the same grain size in granitic quartz varies from sample to sample, except for that in Quaternary samples of volcanic sediment, which is very low, close to the noise level. It was found that the diagram, ESR intensities of Al versus Ti-Li centre signal intensities, distinguish volcanic from the same grain size in granitic quartz as well as distinguish individual tephra from another. The TLCIs from volcanic quartz and some granitic quartz samples is almost red and that from the rest of granitic and metamudstone quartz is blue as results of TLCIs although the emission intensities are different. Our results suggest that examining the multiple-centre signal intensities of ESR and the TLCIs are effective to identify the source of quartz and to estimate the sediment provenance.     

Defining the provenance of red slipped pottery from Texas and Oklahoma by petrographic methods

Ceramics are among the most important artifacts that archaeologists use to reconstruct patterns of prehistoric trade and exchange. Petrographic analysis of ceramic thin-sections, in addition to providing detailed technological data, enables the identification of sand-tempering agents. These raw materials are potentially important evidence for ceramic provenance, assuming that such common materials themselves would not have been traded. Here we apply methods developed by sedimentary petrographers to the problem of determining the provenance of Red Slipped sherds from late Prehistoric (c. AD 1000–1400) sites in the Caddoan area and contemporaneous Plains Village sites. Modal frequencies of different kinds of quartz, feldspars and lithic grains are used to construct several triangular graphs that reveal compositional patterns indicative of provenance. Sherds from the Plains Village sites exhibit higher frequencies of lithic grains, feldspars and polycrystalline quartz relative to the sherds from sites in eastern Texas and eastern Oklahoma. While anomalous sherds were identified, the longstanding assumption that Red Slipped sherds in Plains Village contexts were traded from the Caddoan area is not supported by these data. These methods have strong application potentials for other, geologically diverse portions of North America.     

Long-distance provenance for obsidian artifacts of Mesoamerica Preclassic and Early Classic periods found in the Los Naranjos Archaeological Park (Honduras)

Los Naranjos is one of the most important pre-Columbian human settlements of Honduras related to the south-easternmost border of the Mayan civilization. Although the archaeological site mostly spans from 850 BC to 1250 AD, the present obsidian study was only focused on the Preclassic and Early Classic periods (Jaral, 800–400 BC and Edén, 400 BC–550 AD) where undamaged blades and/or retouched obsidian flakes are rare. In this way, the INAA analyses of 17 obsidian samples, compared with major-trace elements data of Honduran and Guatemalan obsidian sources, are mostly representative of waste flakes. Lithic artifacts of Los Naranjos such as sandstones, basalts, and quartzites come from local geological outcrops; whereas, obsidian provenance has to be searched from sources which are located within a radius up to 300 km far away. San Luis, La Esperanza, and Güinope obsidian sources are located in Honduras while the three most exploited Highland Guatemalan obsidian outcrops, which have been dominating long-distance trade in the Maya area mostly for the Classic-Postclassic periods, are San Martin de Jilotepeque, El Chayal, and Ixtepeque. An Ixtepeque provenance, for all the investigated obsidian samples of Preclassic and Early Classic periods found in the Los Naranjos Archaeological Park, was established, thus emphasizing a long-distance source (180 km). This also confirms that Ixtepeque represents the most important provenance of the obsidian artifacts found in archaeological sites of Western and Central-Western Honduras. The possible role played by some of the most important rivers of Guatemala and Honduras as waterway networks of transport was finally pointed out. New INAA chemical data from the Honduran obsidian source of La Esperanza (“Los Hoyos”, 4 samples) are also reported in this paper.     

CARBON AND OXYGEN ISOTOPIC RATIOS: A DATA BASE FOR CLASSICAL GREEK AND ROMAN MARBLE

An isotopic data base of δ¹³C and δ¹⁸O analyses of 528 samples collected from 39 classical Greek and Roman quarries of Turkey, Greece, Italy and Tunisia has been accumulated. The discriminative possibilities of the data base vary from quarry to quarry. Most quarries have a distinctive pattern for either or both variables, but some have more than one grouping. The data also overlap for many quarries preventing a unique provenance assignment. If the alternatives are known so that the total pool of possible sources is reduced, the data base can then discriminate and assign a provenance for most classical marble artifacts.     

An empirical evaluation of copper procurement and distribution: elemental analysis of Scioto Valley Hopewell copper

In prehistoric North America, artifacts of copper occupy a position of prominence in the Hopewell societies of Ohio’s Scioto Valley. These artifacts also represent the social contacts and long-distance interactions that brought copper to the Scioto Valley. Yet, our understanding of Hopewell copper acquisition, and the movement of copper artifacts within the social networks of the Scioto Valley and beyond, has been limited due to the limited availability of geochemical data concerning provenance and variability. We begin to develop the foundation for understanding these important social issues by analyzing the elemental variability of Hopewell copper through the use of laser ablation inductively coupled plasma mass spectrometry. We analyze 24 samples from four known copper source regions and 52 samples from 6 prominent sites in the Scioto Valley. Results suggest that a majority of the artifacts are consistent with sources in the Great Lakes, with a plurality classified as Isle Royale. However, 21% of Scioto Hopewell copper artifacts were most consistent with southern Appalachian sources. High elemental variability argues against simple models of copper acquisition and suggests that different social groups had access to a variety of copper sources through varying social networks. Native copper regardless of source seems to have been channeled along similar social and symbolic pathways. Our results suggest that instead of being derived from the struggle to access a specific source, value is derived from the social relationships represented by the copper and the connotation of exotic connection embodied in both style and material.     

Elemental analysis and characterization of ochre sources from Southern Arizona

Iron oxides and other associated minerals (ochre) were widely used in ancient times, however, the use and procurement of these materials is not well understood and there has been little research on the elemental characterization of the material compared to other artifact classes. To assess the possibility of identifying ochre differences between locations, the original potential geological sources should be thoroughly characterized. This paper describes the collection of potential geologic sources of ochre in the Tucson basin of Arizona, sampling of those sources, instrumental neutron activation analysis (INAA), and subsequent multivariate analysis of the data. This paper has several goals, including characterizing geochemical trends within and between ochre sources, identifying the important elements in geochemical characterization of ochre, and establishing a database for further investigations. This preliminary study indicates that the inter- and intra-source variations in geological sources of ochre in the Tucson basin region can be differentiated. Future analysis of iron oxide artifacts will be performed to examine correlations between artifacts and sources and provide a basis for further deductions concerning ancient ochre procurement.     

Ochre fingerprints: Distinguishing among Malawian mineral pigment sources with Homogenized Ochre Chip LA–ICPMS

In this study, we compared the effectiveness of instrumental neutron activation analysis (INAA) of bulk ochre to laser ablation‐inductively coupled plasma mass spectrometry of homogenized ochre chips (HOC LA–ICPMS) at distinguishing among three ochre sources in northern Malawi. Both techniques upheld the Provenance Postulate; however, HOC LA–ICPMS required less sample material than INAA and facilitated fast, inexpensive replicate observations that allowed for more robust statistical analysis. Our results indicated that HOC LA–ICPMS is a maturing technique that will be a valuable option for analysing artefacts that require minimally destructive sampling but are too large to fit into the laser cell for direct ablation. With regard to the statistical procedures used, stepwise canonical discriminant analysis was demonstrated to be a highly effective method for distinguishing among ochre sources, even in the presence of significant intra‐source and intra‐sample heterogeneity. Continued development of the HOC sample preparation technique will expand the range of archaeological ochre artefacts that can be included in provenance studies and prevent bias towards artefacts of convenient‐to‐analyse dimensions.     

Investigating the production provenance of iron artifacts with multivariate methods

The quest for suitable data, data treatments and statistical methods for identifying the provenance of iron artifacts has led to a variety of analytical strategies. Researchers working on the problem have been slow to develop or adopt the use of multivariate statistical techniques, despite their successful implementation in other archaeomaterials sourcing frameworks. This paper explores the analytical potential of a comprehensive multivariate statistical strategy for identifying the primary production origins of bloomery iron artifacts using bulk chemical analyses of bloomery smelting slag and slag inclusions in iron artifacts. This strategy includes a multivariate model for identifying distinct slag inclusion types introduced during smelting and refining. Principal component analysis and linear discriminant analysis are then applied to smelting slag training sets to create multivariate provenance fields, the chemical distributions of which are defined by kernel density estimation. Single and multi-group evaluation methods are examined. Appropriate data transformations are discussed to facilitate the projection of the chemistry of “unknown” slag inclusions into the multidimensional space generated by the smelting slag groups of known provenance. The efficacy of this strategy is demonstrated through its application to a previously examined data set derived from three iron production experiments and a published archaeological example. Results indicate that an appropriately designed multivariate strategy can be an effective tool for evaluating provenance hypotheses for bloomery iron artifacts.     

RAPID CHEMICAL CHARACTERIZATION OF OBSIDIAN ARTIFACTS BY ELECTRON MICROPROBE ANALYSIS

The potential of the electron microprobe to analyse chemically obsidian artifacts for source provenance studies is demonstrated using artifacts from four archaeological sites in Kenya.     

Non-destructive Provenancing of Ground-Edged Mafic Artifacts: A Holocene Case Study from the Sydney Basin,Australia

Ground-edged artifacts were an important part of the Australian Aboriginal toolkit. They had practical day-to-day uses, but some had symbolic and social values that led to their movement across great distances. Australian provenance studies document long-distance Aboriginal exchange systems extending over hundreds of kilometers. The size and complexity of exchange systems and social networks were contingent upon resources and the productivity of a region's environment. Along the fertile, well-watered lands east of the Great Dividing Range, movement of objects may have been geographically more circumscribed than in drier areas to the west. One hundred and twenty-one mafic, ground-edged artifacts from the New South Wales (NSW) Central Coast and 368 geological specimens from potential sources were non-destructively analyzed by portable X-Ray fluorescence spectrometry. Results indicate the existence of a well-used basalt source within the region at Peats Ridge-Popran Creek as well as multiple local and non-local sources up to 430?km from Mangrove Mountain on the NSW Central Coast.     

FOUNDATIONS OF THE CADES POND CULTURE IN NORTH-CENTRAL FLORIDA: THE RIVER STYX SITE (8AL458)

The River Styx site was an important Middle Woodland ceremonial center in north-central Florida that included a horseshoe-shaped earthen embankment, a burial mound containing only cremations, and diverse nonlocal artifacts. The site was recorded more than forty years ago but a report was never written. This article presents a summary of excavation results at River Styx and analysis of the pottery assemblage based on archived notes and collections at the Florida Museum of Natural History. From the pottery assemblage, 24 vessel lots, consisting of mostly partially reconstructed vessels, are described in terms of form, surface treatment, and mineralogical constituents characterized by petrographic analysis. The provenance of each vessel is inferred, and more than half of the analyzed assemblage is judged to be nonlocal.     

Source provenance of obsidian artifacts from the Early Stone Age (ESA) site of Melka Konture,Ethiopia

The source provenance of 10 Early Stone Age artifacts from the localities in Melka Konture has been determined by EDXRF. Results show that the early to mid-Pleistocene makers of the artifacts derived the raw material from a source located in their proximity, supporting the previously proposed short distance transport of raw material for the time period.     

Development of quartz cathodoluminescence for the geological grouping of archaeological ceramics: firing effects and data analysis

Cathodoluminescence (CL) spectrometry reveals genetic crystallographic and chemical characteristics of quartz grains specific to the thermodynamic conditions in which they crystallised and their mineralisation history. These genetic characteristics have been used successfully to determine the provenance of sediments. Geological sediments are the raw material for archaeological ceramics which means quartz CL has a potential application in ceramic provenance studies, particularly for fine wares and fabrics in which quartz is the only identifiable inclusion.     

A Paleolithic Cache at Tolbor (Northern Mongolia)*

This study presents analyses of a unique assemblage of lithic artifacts, 57 large flakes, discovered in the Ikh Tulberiin Gol River valley of Northern Mongolia. The assemblage represents the first Paleolithic cache ever discovered in Mongolia and is an isolated find, not directly associated with a habitation or logistic activity site. Results of use-wear analysis suggest most of the flakes were unused, with only a few minimally used for processing wood. GIS analyses of the local landscape indicate that the placement of the artifacts was likely symbolic, rather than utilitarian or for storage, lying in an east-west linear viewshed of the primary mountain pass to an adjacent river basin. Based on the context of the discovery as an isolated find and technical-typological features of the artifacts, the assemblage is interpreted as a cache of tool blanks that was purposefully and symbolically positioned on the landscape relative to the primary mountain pass by Upper Paleolithic hunter-gatherers.     

SOURCES FOR VALLEY-FILL ALLUVIAL SEDIMENTS: BELLA COOLA RIVER BASIN, BRITISH COLUMBIA

Changes in the grain-size distribution and the lithologi-cal I mineralogical properties of sandy-gravel sediments are used to discriminate between sources for the alluvial valley-fill of Bella Coola River, coastal British Columbia. Spatially variable bedrock sources, ranging from highly resistant quartz monzonites to easily weathered basalts, yield sediments that reflect parent rock characteristics. Local increases in the D₉₅ fraction of bulk gravel samples and the D₅₀ fraction of sand samples can be related to inputs from steeper, heavily glaciated tributaries, or those underlain by fractured basalts of the Fraser Plateau. Where there are similarities in the grain-size properties of the source and the sampled deposit, however, grain-size information alone cannot be used to discriminate between sources. The lithology of Bella Coola alluvium shows a close correspondence with the general distribution of rock types in the basin, suggesting proportional contributions from most tributary sources over the long term. However, sand samples from the floodplain have a mostly volcanic affinity, indicating the dominance of sediment derived from headwater tributaries underlain by this rock type. Admixture of plutonic source sediments is evident in lower Bella Coola River adjacent to alluvial fans, heavily glaciated tributary creeks or rock walls comprised mainly of quartz monzonite. Les changements dans la granulometrie et les proprietes lithologiques et mineralogiques des sediments de gravel sablonneux servent d differencier les sources des depéts alluviaux de la Riviere Bella Coola sur la céte de la Colombie-Britannique. La variation spatiale des sources fondamentales donnent des sediments qui refletent les caracteristiques de la roche-mbe variant des quartz rnonzonites très résistants aux basaltes superficiellement altérés par les agents atmospheriques. Les augmentations locales dans la fraction D₉₅ des echantillons de gravel et la fraction D₅₀ des echantillons de sable peuvent être reliees la contribution des tributaires aux pentes plus escarpees et fortement glaciaires ou ceux qui traversent les basaltes fractures du Plateau Fraser. Cependant, quand il y a des similitudes dans la granulometrie de la source et le dépôt-échantillon, l'information granulometrique seule ne peut pas 6tre employee pour differencier les sources. La lithologie des alluvions de Bella Coola montre une correspondance avec la distribution générale des types de roches dans le bassin, suggérant des contributions proportionnelles des sources tributaires a long terme. Cependant, les échantillons de sable des plaines sujettes à inondations ont en grande part une affinité volcanique, indiquant que la dominance du sédiment provient des tributaires qui traversent ce type de roche. Une addition de sediments de sources plutonique est evidente dans le bas de la Riviere Bella Coola adjacent aux eventails alluviaux, aux ruisseaux tributaires affect& par une forte glaciation, ou aux murs de roches qui comprennent principalement des quartz monzonites.