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1.
A multimethod approach using petrography and strontium (Sr) isotopic analysis was applied to determine the geological source of 17 marble artefacts from the Roman town of Ammaia (Portugal). All samples are calcitic, with dolomite, quartz and muscovite as accessory minerals. The marbles are characteristically medium‐grained with a maximum grain size (MGS) between 0.98 mm and 1.82 mm, have a heteroblastic texture, and have curved to embayed calcite grain boundaries. 87Sr/86Sr values of marble leachates range from 0.708488 to 0.708639. Comparison with Hispanic and Mediterranean marbles suggests the Estremoz Anticline as the most likely source for the Ammaia marble, especially for architectural marble. This hypothesis is supported by the geographical proximity of the Estremoz marble district and the long and expensive overland transport required for other marbles to reach Ammaia.  相似文献   

2.
ABSTRACT

Probably the most important Romanesque artwork in Spain, the Portal of Glory of Santiago de Compostela is essentially made in granite, the most abundant stone in the NW of Iberia, with the only exception of five marble pieces. Different hypothesis on the origin of these marbles have previously been proposed based on visual assessment or by directly assuming a local source. To shed light on their quarry provenance, a multi-analytical study was performed combining polarized-light optical microscopy, cathodoluminescence microscopy, XRPD, SEM-EDS and stable C and O isotopes. The comparison of the results with the available databases reveals the use of marbles from the Estremoz Anticline (Portugal) in the three exquisitely carved columns strategically placed in the central arcade, whereas the other two pieces are local marbles, illustrating a more complex consumption of this noble material than that initially expected.  相似文献   

3.
The present work aims to study surface composition profiles on buried marbles as well as their time evolution. Fifty samples from gravestones, buried for up to 80 years, were analysed by laser‐induced photoluminescence and LA–ICP–MS. The results include profiles of 25Mg, 27Al, 55Mn, 57Fe, 88Sr and organic complexes of calcium, existing in the marble patina. The depth at which 88Sr reaches its bulk value proved to be the best parameter to measure patina thickness. A diffusion model adopted from dissolution studies made on gravestones exposed to the atmosphere was successfully applied to the patina thickness data. The model fails to predict patina thicknesses for ancient excavated objects. However, it seems that ‘Sr alteration depth’ values alone can be used for discriminating ancient from recently buried surfaces.  相似文献   

4.
87Sr/86Sr ratios are presented for white marbles collected from some of the most famous classical quarry areas of the Mediterranean: Carrara, Paros, Naxos, Pentelikon, Dokimeion, Hymettus, Thasos, and Proconnesus. These ratios range from 0.7071 to 0.7092. The ranges of the different quarry areas are notably superimposed; this prevents a common adoption of this parameter in distinguishing the quarry locations for the classification of the provenance of marbles used during classical times for architectural and sculptural artefacts. However some quarry areas show peculiar distributions of their isotopic values, which could help to assign the provenance to an unknown marble artefact.Adding these new data to the scarce number of strontium isotopic compositions measured on white marbles and available in the relevant literature, permits the creation of an initial database of 11 classical quarry locations. This database confirms that the strontium isotope ratio could be used in marble provenance determination, together with petrographic and geochemical methods, as an ancillary technique.  相似文献   

5.
This study explores the feasibility of using strontium isotope (87Sr/86Sr) analyses of enamel from domestic dogs (Canis familiaris) to investigate networks of exchange in the prehistoric Circum‐Caribbean. Dog teeth were obtained from burial and domestic contexts from two prehistoric sites (Anse à la Gourde and Morel) on Grande‐Terre, Guadeloupe (Lesser Antilles). Strontium isotope results were compared with local biosphere 87Sr/86Sr data at the scale of the site, island and archipelago. The isotope results indicate both local and nonlocal origins with three dogs (30%) identified as nonlocal (one from Anse à la Gourde and two from Morel). The variance in 87Sr/86Sr ratios of the nonlocal dog teeth is consistent with diverse multiple origins external to the island of Grande‐Terre but consistent with origins from other islands of the Lesser Antilles. The diverse origins of the nonlocal dog samples indicate that the prehistoric circulation of dogs occurred at multiple scales from regional to long distance. Significantly, the 87Sr/86Sr ratios of some of the dog teeth are comparable with values of nonlocal humans at Anse à la Gourde determined in previous studies. It is possible that these comparable 87Sr/86Sr ratios result from similar natal origins, for example if individuals were migrating to Guadeloupe with dogs. The results of this study contribute to an ongoing regional investigation of the economic, social and political roles of animals and animal remains and the multiscalar networks of prehistoric mobility and exchange in the Circum‐Caribbean region. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

6.
While the use of radiogenic strontium isotope values to examine paleomobility is increasingly common in the Andes, and beyond, many questions about baseline variability remain. To better understand baseline radiogenic strontium isotope compositions in the Andes, we present new 87Sr/86Sr values from Peruvian soil samples. Modern soil samples were collected from agricultural fields from the following areas in central and southern Peru: Arequipa, Atico, Camaná, Chala, Cusco, Ica, Ilo, Lima, Mejía, Moquegua, Nazca, Ocoña, Palpa, Pisco, Puno, Tacna, and Yauca. Samples were partially dissolved to better approximate the bioavailable strontium. Radiogenic strontium isotope values from the partially dissolved soil samples range from 87Sr/86Sr?=?0.70202 to 0.71894 and, for all soil samples, have a mean of 87Sr/86Sr?=?0.70773?±?0.00166 (1σ, n?=?114). In general, the 87Sr/86Sr values measured for soil samples collected from modern agricultural fields reflect the expected 87Sr/86Sr values based on bedrock geology. Comparing our new soil data with published radiogenic strontium isotope data for bedrock, soil, water, and faunal samples provides constraints on the regions in the Andes that can, and cannot, be distinguished through radiogenic strontium isotope analysis.  相似文献   

7.
This paper presents a pilot study of strontium (Sr) isotope ratios from Iron Age horse tooth enamel samples. It compares 87Sr/86Sr ratios from horse teeth to estimates for local ranges of biologically available strontium, to investigate whether horses were being bred at the sites where their remains were discovered. A horse from Middle Iron Age Rooksdown, Hampshire, was not bred at the site but, rather, came from as far away as Wales, Scotland or continental Europe. Horse teeth from Middle Iron Age Bury Hill, Hampshire, returned 87Sr/86Sr values typical of local chalkland.  相似文献   

8.
The value of strontium isotope analysis in identifying immigrants at numerous archaeological sites and regional areas has been demonstrated by several researchers, usually by comparing 87Sr/86Sr values of human tooth enamel and/or bone with the local strontium isotope signature determined by faunal and environmental samples. This paper examines the feasibility of using 87Sr/86Sr ratios to investigate residential mobility in the Nile Valley region, specifically at the New Kingdom period (∼1050–1400 BC) archaeological site of Tombos (ancient Nubia). Archaeological and textual information regarding this period indicates that immigrant Egyptians and local native Nubians were likely interacting at this site during a period of Egyptian colonial occupation. The results of this study suggest that non-local individuals may be distinguished from locals using 87Sr/86Sr values and that colonial agents in the Tombos population were probably both local native Nubians and immigrants.  相似文献   

9.
As part of a preliminary geological characterization programme to assess the feasibility of an underground laboratory in granitic rock, a series of 17 deep boreholes (maximum depth, 900 m) was drilled by ANDRA in the Vienne district, France. A salinity gradient was demonstrated in the granitic waters with concentrations varying from approximately 1 g L?1 at 150 m depth at the top of the basement (beneath the sedimentary cover) to 10 g L?1 in the deeper part (from 400 to 600 m depth). Sr and B isotope ratios were measured in order to better understand the origin of the salinity and to evaluate the degree of water–rock interaction in the system. The results obtained were compared to those of mineral spring waters emerging from the granitic basement in the Massif Central. Evidence in support of a significant marine contribution include: (i) the Cl–Br investigations agree with a marine origin for the saline groundwaters without evolution from seawater; (ii) the 87Sr/86Sr ratio of the Vienne deep groundwaters (0.7078–0.7084) is in agreement with a palaeo‐seawater isotopic signature; (iii) measured δ11B values for the deepest brine samples are enriched in 11B (up to 36.1‰) relative to the granitic springs. The combined use of δ11B, Cl, B, Br, Sr contents and 87Sr/86Sr ratios makes it possible to define and quantify a mixing model between marine and crustal end‐members in order to explain the origin of the deep saline groundwaters in the Vienne granitic rocks.  相似文献   

10.
Stable strontium isotopes have been used to identify the skeletons of migrants in several recent archaeological studies, in which local 87Sr/86Sr values have been inferred through statistical parameters of human 87Sr/86Sr data, or by reference to local fauna or other environmental samples. This paper compares these approaches using data from the ancient Maya city of Tikal, Guatemala. The skeletons of eight migrants from distant geological zones are readily apparent among the 83 Tikal skeletons sampled. Three additional non-local skeletons can be eliminated to obtain a normally distributed “local” Tikal sample. The mean of this sample is higher than the available data for local fauna and for lime that may have been used to treat maize at Tikal. It is possible that imported sea salt with a high 87Sr/86Sr ratio could account for this elevated mean for Tikal humans. Modeling demonstrates that dietary 87Sr/86Sr may be raised to the level found at Tikal by a daily intake of only 6 g of sea salt.  相似文献   

11.
N. HERZ 《Archaeometry》1992,34(2):185-194
Two stable isotopic data bases for ?13C and ?18O values of marble have been accumulated: (1) 590 analyses from 42 Classical quarries of Greece, western Turkey, Tunisia, and Carrara, Italy, and (2) potential Early Bronze Age (EBA) marble sources in the central Cyclades, comprising 192 analyses from 16 sites on the islands of Paros, Naxos, Ios, and Keros. The data bases include the most important marble occurrences in the eastern Mediterranean and so can be used to source artefacts of any age. Neolithic artefacts found at Franchthi Cave, where no marble occurs locally, have been attributed to the Peloponnese and the Cyclades, direct evidence for early trade. In the Cycladic EBA, Naxos and Keros were the principal marble sources for the abundant artefacts found at Keros. The commercial marble trade in Archaic Greece began in the central Cyclades where the tradition apparently went back some 5000 years, to the Neolithic. Classical Greece and especially Rome expanded the number and locations of commercial marble sources throughout the Mediterranean.  相似文献   

12.
C. HILGERS  S. SINDERN 《Geofluids》2005,5(4):239-250
The source of fluid‐forming veins is of great importance in order to understand the hydraulic system acting in the earth's crust. The study of syntectonic antitaxial veins is one of the few methods by which the opening history can be deduced from rocks, and thus these veins are of primary importance in determining rock kinematics. Antitaxial veins were taken from black shales in two different tectonic settings in the Helvetic Alps, Switzerland, and the Taconic Appalachians, New York State. These syntectonic extension veins are regularly spaced and are oriented sub‐normal to bedding. The vein microstructure displays a symmetry around the median line in the centre of the vein, and a symmetry in cathodoluminescence banding parallel to the vein–wall interface, which suggests transport along bedding‐parallel dissolution planes from both vein‐walls. Antitaxial veins nucleated in transgranular fractures, but evidence for ongoing multiple crack‐seal increments is lacking; rather, veins grew continuously keeping close contact to the vein‐wall. Radiogenic 87Sr/86Sr ratios are higher in the surrounding matrix than in the vein, and higher than the corresponding seawater data in all samples. Variations are small and calcite in both the vein and the host rock were derived from the same source of fluid in the Helvetic samples. Mass balance of Sr suggests that the amount of calcite is too small in the surrounding host rock to be derived locally. Stable oxygen compositions are heavier in the host rock than in the veins, with overall low variation in both δ18O and δ13C values in the Mesozoic Helvetic samples. Data point to a rock‐buffered system, the precipitate most likely derived from an external source. The lower Palaeozoic Appalachian veins have lesser δ18O values than the host rock, similar to the Helvetic veins. Radiogenic 87Sr/86Sr data and a large heterogeneity in stable isotope values indicate an open system. Microstructural and isotopic evidence suggests that the antitaxial veins were formed by pervasive fluid flow, with the solute at least partly derived from an external source.  相似文献   

13.
A collection of 31 glass fragments, dated to the 3rd to 7th century AD and excavated in Veh Ardašīr, (modern Iraq), were analysed for their Sr and Nd isotopic compositions with the aim of deepening our knowledge on glass circulating within central Mesopotamia during Sasanian times and to highlight the merits of isotope ratios for the definition of the production scenery. Based on the elemental composition of the samples, two groups related to the exploitation of different plant ashes were previously distinguished, and also a change in the silica source in the course of the 4th century AD emerged. The determination of isotopic distributions of Sr and Nd offers a deeper insight. The 87Sr/86Sr isotope ratio, together with the Sr elemental concentration, confirms this use of different plant ashes, and permits one to distinguish distinct glass batches, although the isotopic Sr signature does not allow us to highlight evidences of different provenances for the samples of different composition. Moreover, the 143Nd/144Nd isotope ratio suggests the use of sands belonging to a common geological area, and also allows the identification of a set of samples that were possibly produced exploiting a further different sand source. As a whole, Sr and Nd isotope ratio values for the samples considered, i.e. 87Sr/86Sr = 0.70833 to 0.70916 and ?Nd = −8.69 to −4.98, differ from the published isotopic data on middle Eastern glass samples and can therefore define a characteristic Sr–Nd signature for plant-ash Sasanian glass excavated in Veh Ardašīr.  相似文献   

14.
This paper uses strontium isotope (87Sr/86Sr), oxygen isotope (δ18O) and Ba/Sr trace element data in archaeological tooth enamel samples to investigate migration and mobility at the Late Lapita site of SAC, Watom Island in the Bismarck Archipelago. Previous archaeological models have identified Lapita mobility at a community level using obsidian distribution patterns and changes in ceramic design, whereas isotope and trace element data can potentially reconstruct prehistoric mobility on an individual level. Human and pig teeth were sampled from SAC and a selection of human teeth were included from the Late–Post Lapita site of Lifafaesing, Tanga Islands as a geographic/geological comparison.The results indicate that there is a large amount of isotopic variation in the Bismarck Archipelago which is useful for identifying non-local individuals and possibly determining their origins. One human individual and several pigs were suggested as coming from elsewhere in the region. Three potentially separate locations were identified for the non-local pigs. It is argued, using the data from SAC, that Late Lapita communities in the Bismarck Archipelago were more mobile than previously assumed. The potential for identifying individual migrants in a Lapita context are discussed in terms of assessing the more subtle aspects of Lapita society in the Southwest Pacific Islands.  相似文献   

15.
87Sr/86Sr ratios have been determined for glasses from four production sites, dated to between the sixth and the 11th centuries, in the Eastern Mediterranean region. On the basis of elemental analyses, the glasses at each location are believed to have been melted from different raw materials. Two glass groups, from Bet Eli‘ezer and Bet She‘an, in Israel, are believed to have been based upon mixtures of Levantine coastal sands and natron, and have 87Sr/86Sr ratios close to 0.7090, plus high elemental strontium, confirming a high concentration of modern marine shell (87Sr/86Sr ~ 0.7092) in the raw materials. The isotopic compositions of these two groups of glasses differ slightly, however, probably reflecting a varying ratio of limestone to shell because the sands that were utilized were from different coastal locations. Natron‐based glasses from a workshop at Tel el Ashmunein, Middle Egypt, have 87Sr/86Sr values of 0.70794–0.70798, and low elemental strontium, consistent with the use of limestone or limestone‐rich sand in the batch. High‐magnesia glasses based on plant ash, from Banias, Israel, have 87Sr/86Sr values of 0.70772–0.70780, probably reflecting the isotopic composition of the soils that were parental to the plants that were ashed to make the glass. Strontium and its isotopes offer an approach to identifying both the raw materials and the origins of ancient glasses, and are a potentially powerful tool in their interpretation.  相似文献   

16.
Contrasting lifestyles are recorded by the isotope composition of Bronze Age Beaker people (c. 2500–2000 bc ) from three burial sites (Boscombe Down, Normanton Down and the ditch around Stonehenge) at or near to the Stonehenge monument in Wiltshire, southern England. Seven individuals (three adults, a sub‐adult, two juveniles and an infant) were recovered from a single grave at Boscombe Down. Strontium and oxygen isotope analysis of tooth enamel from two teeth (a premolar and third molar) from each of three of the adults in this grave (referred to as Boscombe Bowmen) show that they had all shared a pattern of mobility and migration during their lives. The three adult males spent their early childhood (as represented by data from the premolar teeth) in an area with a radiogenic 87Sr/86Sr isotope signature of around 0.7135. They each then moved, during early adolescence (as represented by the third molar results), to a less radiogenic area, where they acquired an 87Sr/86Sr signature of around 0.7112. This implies that they must then have travelled to the Stonehenge area of Wiltshire at a later time in their lives. Wales provides the closest area with rocks that supply suitable 87Sr/86Sr ratios and δ18O isotope compositions for these individuals, although other areas of Palaeozoic rock, such as Scotland and parts of Europe, cannot be ruled out. Enamel from the two juveniles from the Boscombe Down burial yields 87Sr/86Sr ratios of 0.7098 and 0.7099, and strontium concentrations for both of 55 ppm. The very close match of the data for the two juveniles supports the possibility that they were raised in the same environment. The difference in strontium isotope data between the juveniles and three adult males described above shows that the children did not come from the same homeland as the adults with whom they share a grave. The two adult males from the single burials at Normanton Down, and from Stonehenge itself, had static lifestyles and show no evidence of migration, in contrast to the Boscombe Bowmen. Their oxygen and strontium data are consistent with a childhood in the Stonehenge area.  相似文献   

17.
Strontium (Sr) isotope ratios (87Sr/86Sr) measured in human skeletal material can increase one's understanding of the residential behaviour and resource-acquisition strategies of past populations. The paper maps bioavailable 87Sr/86Sr variation in 183 plant and soil samples across Cambodia. Bioavailable 87Sr/86Sr, as measured in plants, differs significantly between four major geological units. The data set will support future investigations of skeletal material from Cambodian archaeological sites. Baseline 87Sr/86Sr data should be applied judiciously to skeletal populations, and in concert with other lines of evidence, to identify potential geographical outliers rather than to ascribe specific locations from which individuals may have moved.  相似文献   

18.
In archaeology, strontium isotope analysis is developing into an efficient scientific technique for tracing the movement of prehistoric humans and animals. Determining the local bioavailable 87Sr/86Sr ratio range is the key to distinguishing whether the human or animal is indigenous to the local area. It has been shown that the 87Sr/86Sr ratio in the enamel of pigs can be an excellent sample to determine the range of local strontium isotope ratio at the site. However, pigs may not be all local at the site, and there is no special study on whether pigs’ different ages and tooth types impact the local strontium isotope characteristics. In this paper, the tooth enamel of 19 pigs from the Zaoshugounao site for strontium isotope ratio (87Sr/86Sr) by multicollector–inductively coupled plasma mass spectrometry. There were no significant differences in 87Sr/86Sr ratios of local pigs at different months and different molar types, which did not affect the determination of the local strontium isotope standard. Based on the local strontium isotope ratio range (0.711056–0.711476), we found that five pigs were non-local. The Jing and Wei river basins (in Guanzhong basin) and northern Shaanxi are likely sources of non-pigs.  相似文献   

19.
In this paper, we investigate the potential use of oxygen and strontium isotope ratios (δ18Op and 87Sr/86Sr) measured in archaeological fish enamel as provenance indicators. δ18Op and 87Sr/86Sr were measured in a suite of archaeological carp remains recovered from the Anatolian townsite of Sagalassos dated to the Early Byzantine period (AD 450–650) and compared to that of modern fish, river and lake waters from the Anatolian region. We used sequential leaches in weak acetic acid to remove diagenetic Sr from fossil tooth enamel, monitoring the effectiveness of this approach by measuring the Sr/Ca ratios of the leachates via an isotope dilution thermal ionization mass spectrometry method (ID-TIMS). δ18Op values mostly excluded a riverine origin. 87Sr/86Sr ratios of one fish overlapped with the 87Sr/86Sr signatures of two lakes in the Anatolian region, and at least one lake (Gölcük) could be removed as a candidate owing to a very distinctive 87Sr/86Sr signature not found in any of the fish remains. Most of the tooth samples analyzed could not be assigned a precise geographical origin since the 87Sr/86Sr ratios measured in enamel did not match that of any of the local lakes selected as potential origin. This result suggests that carp may have originated from lakes that have not yet been sampled, although this conclusion is not supported by other archaeological evidence. Alternatively, the lack of correspondence between lakes and fish Sr isotope ratios highlights several possible sources of uncertainties including spatial heterogeneity in 87Sr/86Sr ratio within a lake, the contribution of dietary strontium to the 87Sr/86Sr ratio of fish tooth enamel, and post-mortem alteration of the tooth Sr isotope signal during fossilization. In spite of the high precision of the strontium isotope analyses and the wide range of variation in the surface waters of the Anatolian lakes and rivers, this method may remain limited to distinguishing between lakes situated in regions of bedrock of very distinct age and geology until these sources of uncertainty are more fully investigated.  相似文献   

20.
This paper presents the results of strontium (Sr) isotope analysis of modern and archaeological animal remains and modern plant samples from the Caribbean region. The goal is to assess if patterns of human mobility can be determined from the archaeological record in an archipelagic setting. The range of variability and spatial distribution of biologically available strontium isotope signatures is reported and data evaluated to determine if sufficient heterogeneity exists to permit the identification of mobility despite the presence of potentially large contributions of marine strontium in island and coastal ecosystems. The (is)landscape is divided into several sub-regions based on the age and lithology of underlying geology and the variability of 87Sr/86Sr ratios is reported as; mean 87Sr/86Sr ± 2 standard deviations, number of samples: 1) Volcanic and Intrusive rocks (0.7077 ± 0.0019; n = 162); 2) Cretaceous–Miocene Limestone (0.7085 ± 0.0009; n = 50); 3) Pliocene–Quaternary Limestone (0.7091 ± 0.0004; n = 54); 4) Sedimentary Deposits (0.7094 ± 0.0015; n = 16); 5) Metamorphic Deposits (0.7104 ± 0.0014; n = 6). There are substantial differences between expected 87Sr/86Sr values based on associated geology and measured 87Sr/86Sr in flora and fauna samples. These differences emphasize the importance of focusing on bioavailable strontium, as opposed to geological proxies, for estimations of Sr isotope ranges, especially in archipelagic environments. While some overlap exists between the 87Sr/86Sr ranges of certain sub-regions, other sub-regions possessed limited variation and could be distinguished based on strontium isotope data. This spatial patterning of biologically available strontium indicates that strontium isotope analyses can be successfully applied to the archaeological study of human mobility within the Caribbean region.  相似文献   

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