MINERALOGICAL AND PETROLOGICAL INVESTIGATIONS OF EARLY BRONZE AGE COPPER‐SMELTING REMAINS FROM THE KIECHLBERG (TYROL,AUSTRIA)

The prehistoric settlement on the Kiechlberg hilltop is located a few kilometres to the north‐east of Innsbruck, in the Tyrolean Inn Valley. Despite its rather isolated location, a multiphase settlement between the fifth and the second millennium bc was confirmed by archaeological investigations in 2007 and 2008. Metallurgical artefacts, such as copper ore fragments, copper slag and raw copper, as well as finished copper and bronze artefacts, are concentrated mainly in Late Copper Age to Middle Bronze Age layers. The chemical compositions of the slag and raw metals confirm Fe—Zn tetrahedrite–tennantite (fahlore) smelting. The ore was most probably imported from the 30–50 km distant copper ore deposits (mainly fahlore) of Schwaz–Brixlegg, in the Lower Inn Valley. The small amount of slag and the presence of slagged and thermally altered ceramic fragments suggest copper production in small‐scale workshops. Most probably, sulphide‐rich ores were smelted in crucibles in a hearth fire. The process was relatively reducing below the 2Sb + 1.5O₂ → Sb₂O₃ reaction (?8.5 log fO₂ at 1100°C), producing Sb‐rich (>10 wt% Sb in metal) raw copper. Inhomogeneous slag remains containing high amounts of sulphide and metal inclusions suggest a poor separation of the metal, matte (copper sulphide) and silicate/oxide melt during the smelting process.     

LEAD ISOTOPE ANALYSES OF BRONZE AGE COPPER‐BASE ARTEFACTS FROM AL‐MIDAMMAN,YEMEN: TOWARDS THE IDENTIFICATION OF AN INDIGENOUS METAL PRODUCTION AND EXCHANGE SYSTEM IN THE SOUTHERN RED SEA REGION*

The results of the lead isotope analysis (LIA) of 15 copper‐base artefacts from the Bronze Age site of al‐Midamman, Yemen, are reported. The LIA data suggest the existence of an indigenous Bronze Age metal production and exchange system centred on the southern Red Sea region, distinct from those in neighbouring regions of Arabia and the Levant. These preliminary results are highly significant for the archaeology of the region, suggesting that local prehistoric copper extraction sites have thus far gone unrecorded, and highlighting the need for systematic archaeometallurgical fieldwork programmes in the countries surrounding the southern Red Sea.     

COPPER ALLOYS FROM THE ‘ENOT SHUNI CEMETERY AND THE ORIGINS OF BRONZE METALLURGY IN THE EB IV – MB II LEVANT

Tin bronze replaced arsenical copper as the preferred alloy in the Levant for reasons that have long been debated. Found almost exclusively in graves, these two types of copper alloys share nearly identical mechanical properties. The Bronze Age cemetery of ‘Enot Shuni has yielded the first metals ever analysed from an uninterrupted stratigraphic sequence in the Levant, spanning the earliest adoption of tin bronze from the Early Bronze Age (EB) IV through the Middle Bronze Age (MB) II (c. 2300–1530 bc ). SEM–EDS analysis of these artefacts, combined with a compositional meta‐database of all previously published EB IV – MB II alloys, reveals diachronic alloy progression as selected by populations of the Levant. It has long been qualitatively understood that bronze became the primary alloy by the MB II. These results verify this trend and quantify human demand, showing that tin importation increased by 103% and arsenic content decreased by 49% throughout these periods. This shift in technological choice is attributed to cultural reorientation from the Egyptian to Mesopotamian sphere of influence, as well as to tin's appreciable fuel efficiency over pure copper and arsenical copper in light of unprecedented timber shortages.     

THE ISOTOPIC COMPOSITION OF TIN IN SOME ANCIENT METALS AND THE RECYCLING PROBLEM IN METAL PROVENANCING

A recent suggestion that some ancient metallurgical processes might give rise to large changes (> 0.5%) in the isotopic composition of tin gave hope that it might be possible to identify ancient bronze samples which had undergone recycling and mixing processes. This paper describes a method for the analysis of the isotopic composition of tin by thermal ionization mass spectrometry and applies it to analyse a number of ancient bronzes and tin metal objects from the Bronze Age Mediterranean. No observable isotopic fractionation of tin was found above $0.1% in the ratio¹²² Sn/¹¹⁶. Consequently, either recycling of bronze in the Late Bronze Age Mediterranean was not so common as supposed, or the isotopic composition of tin is not fractionated by anthropogenic metallurgical processes to the extent predicted by the Bradford group.     

EARLY BRONZE AGE TIN PROCESSING AT KESTEL/GÖLTEPE,ANATOLIA

Chemical analysis of statistically significant numbers of samples including minerals, sediments, soil, host rock as well as powdered materials, crucible accretions and metal artefacts revealed information about the distribution of cassiterite at Kestel and the tin smelting processes that took place at Göltepe c. 2600 BC. Using the ancient technique of vanning for the isolation of tin ore (cassiterite), followed by assaying by blowpipe/charcoal block, as well as crucible smelting with a blowpipe, good tin metal suitable for alloying with copper to make bronze was obtained. There is every indication that tin was mined and smelted in the Early Bronze Age at the Kestel/Göltepe sites.     

Technical Studies on the Bronze Age Metal Artefacts from the Graveyard of Deh Dumen,South‐Western Iran (Third Millennium BC)

During the excavations of the graveyard at the site of Deh Dumen in south‐western Iran, 15 graves from the Early/Middle Bronze Age were uncovered that contained a variety of metallic artefacts. This paper reports on the analysis of nine metal artefacts, including eight broken vessels and a decorative strip that covered the handle of a dagger. The ICP–MS results showed that the bodies of the vessels are made of tin bronze alloy with variable amounts of tin, while the internal piece of the base of one vessel is made from an arsenical copper alloy. Further, the metallic strip is a thin sheet manufactured with partially pure silver. Microanalytical and microstructural information yielded by SEM–EDS revealed elongated Cu–S inclusions and lead globules as various phases formed in bronze solid solution. This study presents some information about the transition from arsenical copper to bronze metallurgy in the third millennium bc in south‐western Iran.     

LAND USE IN THE EASTERN ALPS DURING THE BRONZE AGE—AN ARCHAEOBOTANICAL CASE STUDY OF A HILLTOP SETTLEMENT IN THE MONTAFON (WESTERN AUSTRIA)*

Investigations of the oldest prehistoric settlement in the western Austrian county of the Vorarlberg reveal a deeper insight into the colonization of the Alps. The human presence is recorded from the Late Neolithic (c. 3000 cal. bc ) onwards, reflecting farming and possible mining activities. Three distinct settlement phases are recognized palynologically: (1) in the Early and Middle Bronze Ages (c. 1700 cal. bc ), (2) during the Iron Age (c. 500 cal. bc ) and (3) at the beginning of the medieval era (c. cal. ad 800). In addition plant macrofossil analyses of soil samples from the archaeological excavation of the Bronze Age settlement of Friaga indicate a complex subsistence strategy of the Middle Bronze Age settlers, whereby cereals and pulses reveal a balanced diet.     

PREHISTORIC COPPER PRODUCTION IN THE INN VALLEY (AUSTRIA), AND THE EARLIEST COPPER IN CENTRAL EUROPE*

In recent years archaeological finds and scientific analyses have provided increasing evidence for a very early beginning of copper production in the rich mining area of the Tyrolean Alps. The earliest findings derive from an excavation of a multi‐phase settlement on the Mariahilfbergl in Brixlegg, which revealed evidence that a small amount of fahlores, probably of local provenance, was at least heated if not even smelted there in the Late Neolithic Münchshöfen culture (the second half of the fifth millennium bc ). However, most copper finds of this horizon consist of low‐impurity copper that most probably derives from Majdanpek in Serbia. This long‐distance relationship is corroborated by typological features that link some aspects of the Münchshöfen culture with the Carpathian basin. Thus it is not yet clear if, at Brixlegg, actual copper production took place or, rather, an experimental treatment of the local ores. The typical fahlore composition, with arsenic and antimony in the per cent and silver and bismuth in the per mille ranges, appears in quantity only in the Early Bronze Age. Many thousands of Ösenringe are known from many central European Early Bronze Age sites, with a chemical composition typical of fahlores. At Buchberg near Brixlegg, a fortified settlement with slags from fahlore smelting proves that the local ores were indeed exploited. The lead isotope ratios of Ösenringe from the Gammersham hoard in Bavaria, which consist of fahlore copper, confirm this and suggest that copper mining and production in the Inn Valley reached a first climax during that period. In the Late Bronze Age, copper was produced at an almost industrial level.     

YUGOSLAVIAN TIN DEPOSITS AND THE EARLY BRONZE AGE INDUSTRIES OF THE AEGEAN REGION

Summary. This paper provides a synopsis of those tin sources available to prehistoric communities in Europe and the Near East. Moreover, it is designed to introduce to archaeologists the recent discovery of substantial cassiterite deposits in Yugoslavia, and to discuss their potential and possible exploitation by Early Bronze Age metallurgists in the area around the Aegean.     

LEAD ISOTOPE CHARACTERISTICS OF THE CYPRUS COPPER ORE DEPOSITS APPLIED TO PROVENANCE STUDIES OF COPPER OXHIDE INGOTS

Nearly 200 new lead isotope analyses of sulphidic and oxidized ores from 26 copper mines on Cyprus show that the mines from different geological regions group in five distinctive isotopic groups, each with a substructure, related to the geological history of the ore formation. Comparison of lead isotope compositions of Bronze Age artefacts with these data can in many cases reveal the actual mines from which the copper for particular artefacts was obtained. The particular case of the provenance of the copper for 78 Late Bronze Age copper ‘oxhide ingots’found in Cyprus, Crete, Greece, Sardinia, Turkey and Bulgaria is discussed. The data show that all oxhide ingots so far analysed, dating to the fourteenth century BC and later, were made of copper consistent isotopically with only one mining region in the geographical north of Cyprus, and especially the Apliki mine. The study provides further evidence which supports the validity of the conventional approach to the use of lead isotope analysis for provenancing metals; this evidence is antithetical to recent suggestions of a model for the production of copper oxhide ingots which involved widespread mixing of copper from a number of ore sources throughout the Mediterranean.     

THE SYMBOLIC AND SOCIAL MEANINGS OF THE INTERMEDIATE BRONZE AGE COPPER DAGGERS

Abstract

The transformation of hard, durable natural substances, such as stone or metal, into cultural objects with symbolic value has played an important role in human social development. This paper attempts to understand the symbolic and social meanings of copper daggers during the Intermediate Bronze Age, and the reasons for their widespread use within a burial context. A multidisciplinary approach is taken, combining and processing different areas of research, and employing a range of archaeological and ethnographic parallels. This paper allows also for a more comprehensive understanding of the social organisation during the Intermediate Bronze Age.     

CHEMICAL AND LEAD ISOTOPE ANALYSES OF GREEK LATE NEOLITHIC AND EARLY BRONZE AGE METALS

Results of a combined archaeological and analytical project of Late Neolithic/Early Bronze Age copper, bronze and lead artefacts from four distinct areas of mainland Greece are presented. The aim of the study is to understand better the stages of technological development of each region, their possible ore sources and also to assess any external contribution to or internal evolution of their metallurgy. Interesting results which could challenge the established view of Late Neolithic/Early Bronze Age metallurgy in the Greek mainland are presented.     

Quarterly Statement of Progress

Abstract

This paper reviews the evidence from the Deutsches Bergbau Museum excavations at Barqa el-Hetiye 'House 1', located in the Faynan district of southern Jordan. It presents a re-interpretation of the site and its data and links technological changes in the production of copper that take place at Faynan during the later Early Bronze Age (EBA II–III) to changes in the material culture at Barqa el-Hetiye which suggest influences from the western Levant as a key factor in these developments.     

THE BLACK INLAY DECORATION ON A MYCENAEAN BRONZE DAGGER*

The black inlay decoration with superb marine, hunting and other scenes on Mycenaean bronze daggers and silver cups has often been referred to in the literature as niello—a mixture of sulphides of copper, silver or lead—despite the absence of any systematic analysis of these precious metal artefacts. This paper presents semi-quantitative surface analyses of an example of black inlay on a Mycenaean dagger, now in the Archaeological Museum at Patras in Greece. Using non-destructive X-ray fluorescence spectrometry, it has been established that, contrary to the traditionally-held view, the black inlay is a copper-gold alloy with some silver and possibly small amounts of tin.     

Collapsing Commodities or Lavish Offerings? Understanding Massive Metalwork Deposition at Langton Matravers,Dorset During the Bronze Age–Iron Age Transition

The discovery of 373 intact and broken tin‐bronze socketed axes accompanied by 404 fragments in four pits at Langton Matravers collectively represents one of the largest hoards found to date in prehistoric Britain and Ireland. They were very probably never meant to be used as axes as the very high levels of tin they contain would have made them brittle. Many were poorly finished, with the majority still containing their casting cores. The axes are typologically dated to the Llyn Fawr metalwork phase (c.800–600 BC) and span the Bronze Age/Iron Age transition, when the production, circulation and deposition of bronze appear to have been substantially reduced throughout north‐west Europe. By placing the Langton Matravers hoard(s) in a broader metallurgical, material and archaeological context, existing theories for this phenomenon, such as the preference for iron, a collapse in bronze supply, or the sharp devaluation of a social or ritual ‘bronze standard’, are evaluated. It is proposed that the Langton Matravers axes belong to a short phase in the centuries‐long processes underlying the changing roles of bronze and iron.     

THE PROVENANCE AND PRODUCTION TECHNOLOGY OF BRONZE AGE AND IRON AGE POTTERY FROM TELL MISHRIFEH/QATNA (SYRIA)*

This work deals with the archaeometric study of the Bronze Age and Iron Age pottery from Tell Mishrifeh/Qatna (central‐western Syria), where the complete cycle of ceramic production is well documented. Petrographic, chemical and diffractometric analyses were carried out on both potsherds and a clayey material found in a separation basin within the area of the workshops. Petrographic groups were defined and maximum firing temperatures and redox firing conditions were estimated, providing constraints on identifying the production technology and its evolution with time. The studied potsherds turned out to be locally produced, with only a few cases of possible similarities with those described for other localities along the Orontes Valley, and in a couple of cases with evidence of pottery exchange.     

EARLY BRONZE AGE TROJAN METAL SOURCES AND ANATOLIANS IN THE CYCLADES

Summary. New chemical analyses of EB II copper-alloy artefacts from Troy show that about seventy per cent are of high tin, low arsenic, bronze; the remaining Trojan objects are of arsenical copper but contain no more than 3 per cent of arsenic. Lead-isotope analyses suggest that at this time the Trojans made use of at least five different copper-ore deposits and that at least two of these were not in the immediate vicinity of Troy itself.
At this period tin bronze was unknown in the Early Helladic, Cycladic or Minoan cultures. Low-arsenic tin bronzes do however constitute sixty-nine per cent of the copper-alloy artefacts excavated at the fortified hilltop EC IIIA settlement at Kastri on Syros, but lead-isotope analyses show that the copper in these objects is derived from three different ore deposits which are different from those exploited by the early Cycladic peoples on Amorgos, Paros, Kythnos and Chalandriani on Syros. For Kastri the alloy types are closely similar to and the copper ore sources used are identical with those employed in Troy II; in addition there are good Anatolian parallels for some of the metal types occurring at Kastri. Taken together with evidence from the pottery, the architecture and the nature of the site it seems inescapable that Kastri was a short-lived settlement of Anatolians who lived, perhaps, in somewhat uneasy juxtaposition with their Cycladic neighbours. These Anatolians came most probably from Troy or the Troad since tin bronze was virtually unknown at this period elsewhere in Anatolia, and certainly not in Cilicia, except at the central Anatolian sites of Ahlatlibel, Alishar and Alaca Hüyük.     

THE ‘FRYING PANS’ OF THE EARLY BRONZE AGE AEGEAN: AN EXPERIMENTAL APPROACH TO THEIR POSSIBLE USE AS LIQUID MIRRORS*

The so‐called ‘frying pans’ are peculiar vessels, most of them made of terracotta, flat and shallow, usually decorated on the outside part and dated to the Early Bronze Age. They were unearthed mostly in the Cyclades, in Crete and on the Helladic mainland. There are also a few artefacts made of stone and of bronze, from the Cyclades and Asia Minor, respectively. The intended purpose of these objects is disputed. Several interpretations exist for their function, the earliest one being that of liquid mirror vessels. We investigated the mirror hypothesis experimentally, by testing trays with attributes similar to those of the original ‘frying pans’, filled with a series of liquids familiar to the people of the time and the place where those vessels were made. The criterion employed was the contrast of mirror images. We conclude that, provided that some minimal prerequisites are met, the ‘frying pans’ are quite appropriate as liquid mirror vessels.     

ANALYSIS OF LATE BRONZE AGE GLASS AXES FROM NIPPUR—A NEW COBALT COLOURANT

A multidisciplinary study of a unique group of Late Bronze Age (LBA) ceremonial glass axe heads and other artefacts shows that these are the first significant group of glasses coloured with cobalt to be identified from the Near East. The axes were excavated from the site of Nippur, in present‐day Iraq. Several are incised with the names of three kings, which dates the material to the 14th–13th centuries bc . Analysis by laser ablation inductively coupled plasma mass spectrometry (LA–ICPMS) indicates that the glass had high magnesia (MgO) and potash (K₂O) associated with a plant‐ash flux and was coloured blue by copper or a combination of copper and cobalt. These glasses are similar, but not identical, in major element composition to blue‐coloured glasses manufactured in ancient Egypt and elsewhere in Mesopotamia in the same period. However, the Nippur cobalt‐ and copper‐coloured glasses exhibit significantly different trace elemental compositions compared to Egyptian glass coloured with cobalt, showing that the ancient Near Eastern glassmakers had clearly identified and utilized a distinctive cobalt ore source for the colouring of this glass. Since it was previously thought that the only cobalt ores exploited in the LBA were exclusively of Egyptian origin, this new finding provides new insights on the origins of glass and how it was traded during the Bronze Age period.     

Fuel Efficiency of Ancient Copper Alloys: Theoretical Melting Thermodynamics of Copper,Tin and Arsenical Copper and Timber Conservation in the Bronze Age Levant*

The melting of pure or alloyed copper, tin and arsenical copper ingots or recycled objects was a drain on the timber and dung fuel resources of many cultures. This paper suggests formulae grounded in thermodynamic principles in an attempt to estimate the energy requirements necessary to melt copper alloys common to both Old and New World cultures, with the goal of identifying consumption and conservation patterns. It has been suggested that tin bronze metallurgy was first adopted in the Levant during the Early Bronze Age (EB) IV, at the onset of the Late Holocene climate episode (c.2300–2000 bc ), becoming the most desired alloy by the Middle Bronze Age (MB) II (2000–1530 bc ) due to the ease of melting tin. To test this hypothesis, the formulae are applied here to all published Levantine EB IV – MB II copper alloys. Fuel conservation rates are proposed based on the thermodynamic formulae. Tin bronze is demonstrably more fuel efficient than pure copper. Due to the inherent difficulties in predicting the behaviour of arsenical copper compounds, it is suggested that melting experiments with representative alloys are conducted to further test and refine these energy relationships.