THE HISTORY OF THE LAWRENCE BERKELEY NATIONAL LABORATORY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS PROGRAMME FOR ARCHAEOLOGICAL AND GEOLOGICAL MATERIALS

The Lawrence Berkeley National Laboratory pottery provenance group developed standards and instrumental neutron activation analysis (INAA) methods that are used at many archaeometry laboratories around the world. The background and development of ‘Standard Pottery’ and of methods for INAA are described. Early pottery provenance studies are described, and other research programmes, involving obsidian and magmatic mixing, the origin of the stone used for the Colossi of Memnon, and the ‘Plate of Brass’, are mentioned. Research work by the Laboratory included the discovery of the world‐wide iridium anomaly and extensive subsequent research on what has come to be known as the ‘Asteroid Impact Theory’. Characteristics of the analytical programme for pottery provenance work, including overall aims, precision and accuracy, intercalibration, and irradiation and measurement protocols, are discussed. New research areas developed in the past 15 years, to broaden the usefulness of chemical compositional data for archaeological investigation, and examples of recent work, are described. This research, which makes use of high‐precision X‐ray fluorescence analysis in addition to INAA measurements on sample splits, includes distinguishing the products of different workshops located at the same production site, studies on the significance of the distribution of silver in archaeological pottery and the use of high‐precision chemical compositional data as an aid for making chronological distinctions.     

PLAIN POTTERY AND SOCIAL LANDSCAPES: REINTERPRETING THE SIGNIFICANCE OF CERAMIC PROVENANCE IN THE NEOLITHIC

This paper focuses on plain, stylistically unvaried pottery from three Late Neolithic sites from the Mondego Plateau, Portugal, and investigates ceramic production and exchange among small‐scale prehistoric societies by means of thin‐section petrography and chemical analysis (INAA). The results show that the majority of the pottery was made with widely available, granite‐derived sedimentary clays, but petrographic differences between fabrics indicate collection at multiple locations within these deposits. Variation in chemical composition is consistent with site‐specific sourcing areas, while comparison with data from earlier sites in the Mondego and surrounding mountains suggests that such sources were geographically restricted within the plateau. In contrast, the small percentage of vessels produced with residual clays of metamorphic and intermediate igneous origin, which outcrop over 10 km and 30 km from the archaeological sites, demonstrates that plain pottery did circulate during the Neolithic beyond the funerary sphere. This is the product of the routines of mobility and social networks of Neolithic groups across the wider landscape, which involved the exchange of ‘mundane’ vessels. Finally, the study demonstrates that micro‐regional provenance studies can provide significant insights into prehistoric social landscapes if the data are interrogated beyond simplistic classifications of local and non‐local.     

A Study Of The Firing Technique Of Pottery From Kaman‐Kalehöyük,Turkey, by Synchrotron Radiation‐Induced Fluorescence X‐Ray Absorption Near‐Edge Structure (Xanes) Analysis*

Fe K‐XANES spectra of a series of pottery sherds excavated from the archaeological site of Kaman‐Kalehöyük, Turkey, were measured to reveal the firing technique of the pottery. The analysis disclosed relationships among the chemical form of the iron, the firing conditions and the colour of the pottery. The pottery referred to as ‘Grey Ware’ found at this site was classified into two groups according to the chemical form of the iron. Also, it was revealed that the Iron Age pottery referred to as ‘Cream Ware’ was produced first under reducing conditions, and then fired under oxidizing conditions.     

利用同墓葬出土泥芯、陶器示踪青同器铸造地初探 一以湖北襄樊部分东周墓为例

为研究出土墓葬青铜器铸造地,利用X射线荧光光谱法对湖北襄樊的余岗、沈岗、团山、陈坡四处墓地出土的部分青铜器泥芯、陶片进行测试分析,试验结果与山西侯马、武汉盘龙城遗址进行比较分析。对比研究显示,襄樊地区泥芯与当地墓土、陶片在常量元素上具有高度一致性,而与黄河流域的侯马和长江中下游的盘龙城有明显区别,说明襄樊地区这部分铜器应为本地铸造,暗示江汉流域存在自己特有文化。本项研究工作首次尝试利用同墓葬陶器化学成分探索青铜器铸造地,是泥芯研究青铜器铸造地的重要补充,泥芯和陶器相互配合,为青铜器铸造地研究提供了一种新思路。     

EXPERIMENTAL EVIDENCE FOR THE PROCESSING OF MARINE ANIMAL PRODUCTS AND OTHER COMMODITIES CONTAINING POLYUNSATURATED FATTY ACIDS IN POTTERY VESSELS*

ω‐(o‐Alkylphenyl)alkanoic acids are known to form in vitro from triunsaturated fatty acids following protracted heating. These compounds have recently been identified in absorbed lipid extracts obtained from archaeological pottery vessels, providing a potentially valuable new class of indicator for the processing of commodities, such as marine oils, which contain high abundances of polyunsaturated fatty acids. Experiments were conducted to assess whether ω‐(o‐alkylphenyl)alkanoic acids form when pure compounds and complex triacylglycerol mixtures are heated with a fired clay. The results demonstrate that ω‐(o‐alkylphenyl)alkanoic acids are only produced following heating of unsaturated fatty acids (tri‐, di‐ and monounsaturated species) or complex unsaturated fatty acyl lipids at around 270°C. Heating saturated fatty acyl lipids does not yield ω‐(o‐alkylphenyl)alkanoic acids. Thus, when searching for evidence for the processing of marine derived animal fats in archaeological pottery vessels, it is essential that: ω‐(o‐alkylphenyl)alkanoic acids of carbon length C₁₈ and C₂₀ should be present, ideally with C₂₂ also detectable (if only in trace abundances), together with at least one of the three isoprenoid fatty acids (phytanic, pristanic or 4,8,12‐tetramethyltridecanoic acid).     

A PROVENANCE STUDY OF POTTERY FROM ARCHAEOLOGICAL SITES NEAR CANOSA,PUGLIA (ITALY)*

Studies have been carried out to assess the provenance of selected pottery excavated at archaeological sites near Canosa, Puglia (Italy). Sixty-six sherds, ranging in date from the mid-seventh century BC to the beginning of the third century BC, were analysed by atomic absorption spectroscopy and 16 elements were determined. The analysis data were subjected to multivariate classification procedures. Tests showed that the majority of the examined sherds came from ancient local kilns; a probable Ionian origin was established for some other sherds, while the rest were of unknown origin.     

Ceramic production,consumption and exchange in the Banda area,Ghana: Insights from compositional analyses

Ceramic production, exchange and consumption in the Banda area, west central Ghana has been affected by historical developments ranging from recent competition with alternative vessels (made of metal and plastic) to political economic upheavals that altered community relationships within and outside the region. In this study, we explore spatial and temporal patterning in pottery production, exchange and consumption using a combination of analytical techniques. Instrumental neutron activation analysis (INAA) of a large sample (491 specimens) of archaeological and ethnographic pottery, clay and temper samples from sites across the Banda area has led to the identification of seven compositional groups whose differential distribution implies shifts in resource selection through the last thousand years. Laser ablation-ICP-MS analysis was used to explore the effects of distinctive tempering agents (crushed slag) on the bulk chemical signature of a subset of Banda ceramics, while petrographic analysis provides insight into the preparation of ceramic fabrics. We integrate insights from these diverse physical studies to investigate the dynamics of pottery production, exchange and consumption over the course of the last millennium in the Banda area and explore potential linkages with broader political economic transformations.     

STATISTICAL ASPECTS OF POTTERY QUANTIFICATION FOR THE DATING OF SOME ARCHAEOLOGICAL CONTEXTS*

This paper describes some statistical analyses of a particular archaeological material (pottery) originating at some sites in the city of Tours. An important part of the archaeological study of pottery is the comparison of ceramic assemblages to establish the absolute dates of contexts. In this paper, a statistical model is built to assess this comparison. The statistical procedure uses classical tools (correspondence analysis, linear regression and resampling methods) in an iterative scheme. Archaeologists may find in the paper a useful set of known statistical methods, while statisticians can learn a method of ‘arranging’ well‐known techniques. No method is new, but their combination is characteristic of this application.     

宜昌路家河遗址夏商时期陶釜研究

本文从宜昌路家河遗址最多最典型的炊器陶釜入手,主要运用统计学的方法,通过分析陶釜在数量、器形、容量、纹饰等方面的变化,总结本区夏商时期考古学文化的特点,进而探讨不同时期陶釜在发展、交流与演变,来源与去向等方面的一些问题。     

INSTRUMENTAL NEUTRON ACTIVATION BASED PROVENANCE STUDIES AT THE HEBREW UNIVERSITY OF JERUSALEM,WITH A CASE STUDY ON MYCENAEAN POTTERY FROM CYPRUS

A neutron activation programme aimed at archaeological provenance research operated at The Hebrew University of Jerusalem between the years 1974 and 1997. The history and accomplishments of that laboratory are presented. Endeavours to preserve unpublished results are described. Results on Cypriote pottery are presented.     

Technological Choices in Hand‐Made Indigenous Pottery from Western Mallorca (Balearic Islands,Spain) (C.1200–75 bc): An Archaeometric Approach

This paper addresses the technological choices observed in Mallorca (Spain) for the production of hand‐made pottery during the Late Bronze and Iron Age. We have conducted a diachronic analysis of the ceramic assemblages recovered from two archaeological sites placed in the same territory by means of X‐ray fluorescence and optical microscopy by thin‐section analysis. The archaeometric characterization of the hand‐made vessels allows us to establish several compositional groups related to the use of different raw materials and certain paste recipes associated with the archaeological sites and periods considered. Thus, this study evidences different productive strategies in each site and across time in the same geographical area.     

THERMOLUMINESCENT DATING OF COLOMBIAN POTTERY IN THE YOTOCO STYLE

Two contexts from the Colombian sites, Yotoco Ferry and Moralba, had been linked by archaeological similarities in pottery style, and dated by association with ware from other sites at circaa.d. 1000. However, radiocarbon dating of those contexts set Moralba at circa 800 b.c. , some 2000 yr older than Yotoco Ferry. Thermoluminescent dating of pottery from Yotoco Ferry dated it at circaa.d. 900, and pottery from Moralba was dated at circaa.d. 870. In addition a metal-smelting pottery crucible, thought to be prehispanic, was studied by thermoluminescence and dated, on the contrary, at less than 120 yr old.     

ALTERATION PROCESSES OF POTTERY IN LAGOON‐LIKE ENVIRONMENTS

Post‐depositional processes in pottery can give rise to chemical and mineralogical alterations, the extent of which is closely related not only to the microstructure and composition of the potsherds, but also to the chemical–physical conditions of the burial environment. The present paper describes the characterization of post‐depositional alterations and identification of processes involving pottery buried in lagoon‐like environments. A set of various types of Roman transport amphorae and African Red Slip ware (ARS), collected from two archaeological sites characterized by a lagoon‐like depositional environment and showing evident changes in the original colours, was analysed by a combination of microstructural, mineralogical and microchemical approaches. The formation of pyrite after hematite, jarosite after pyrite and microstructural substitution features are interpreted here in terms of the chemico‐physical conditions of the burial environment and their evolution in time.     

The Latest Objects from Silchester,Hants

THIS paper brings together for the first time a selection of medieval glass and pottery distilling-vessels from British sites. A discussion on the technical aspects of distilling by F. Greenaway (Part I) is followed by a report on two important groups of glass and pottery distilling-apparatus from Selborne and Pontefract priories of the middle and late 15th century respectively (Part II). Part III discusses pottery distilling-vessels from other finds in Britain. Two types of pottery alembic are distinguished and their use in association with bases of either furnace or bowl type is suggested; industrial bottles connected with distilling are also briefly considered. The survey has brought much information to light but has also left many problems unanswered. Coordination of documentary research into techniques, archaeological recognition of vessels, and the chemical analysis of residues is necessary before firm decisions can be made about the uses of the vessels and the types of unit required for specific operations. It is hoped that this paper will stimulate further work in this field.     

Radiocarbon pottery dating: the chemical compounds of organic fractions, the reliability of 14C dates (preliminary results)

In recent times, a large number of radiocarbon dates appeared for the Southern Neolithic on the basis of pottery dating because other organic matter has practically not been preserved. There are two organic fractions of pottery useful for dating: food residues and carbon from the pottery matrix itself. Food residues are often dated, but this material is not always preserved and is prone to being removed during the cleaning of the pottery. The clay mass of the pottery contains carbon, often directly visible upon breaking of the pottery. The article focusses on determining the chemical composition of the organic fractions in the pottery and the origin of the carbon. For this aim we used the nuclear magnetic resonance (NMR) method to identify the chemical compounds in the food residue and in the pottery matrix. As an example we used pottery from the Neolithic sites: Zamost??e (Central Russia) and the Varfolomeevskay sites (Southern European Russia, Low Volga region) from archaeological collections. The results obtained demonstrate that the food residue and the pottery matrix contain practically the same organic compounds, even if the relative abundances of various compounds are different in these materials. The origin of the carbon from pottery is discussed.     

RQ-MODE PRINCIPAL COMPONENTS ANALYSIS OF CERAMIC COMPOSITIONAL DATA*

RQ-mode principal components analysis (PCA) is a means for calculating variable and object loadings on the same axes, so that elements can be displayed along with data points on a single diagram. The biplots resulting from RQ-mode PCA preserve both Euclidean relations among the objects and variance-covariance structure. When used with data on the chemical composition of archaeological pottery, such biplots facilitate recognizing compositional subgroups and determining the chemical basis of group separation. RQ-mode PCA is illustrated in this paper with neutron activation data on Mesoamerican Plumbate pottery.     

CYPRIOT BYZANTINE GLAZED POTTERY: A STUDY OF THE PAPHOS WORKSHOPS

Twenty‐five samples of Byzantine glazed pottery from two archaeological sites between Limassol and Paphos region (Cyprus), dated between the 12th and 15th century ad were studied using micro X‐ray fluorescence spectroscopy, scanning electron microscopy and X‐ray diffraction analysis. It was found that all the glazes contain lead, following the main manufacturing process of medieval pottery in the Mediterranean territory, while some of them contain tin, possibly for better opacity. Furthermore, it is shown that copper, iron and cobalt with nickel are responsible for the decoration colours. Finally, the application of principal component analysis revealed significant differentiation for some of the samples.     

Ceramics, Ethnohistory, and Ethnography: Locating Meaning in Southern African Iron Age Ceramic Assemblages

For ceramics to be relevant in the Southern African Iron Age, archaeologists must broaden their theoretical base to include social and other contexts when interpreting material culture items such as pottery. Pottery remains critical in understanding cultural dynamics in the region for the past two millennia, but current usage is narrow in scope. Using ethnohistorical data and archaeological examples from South Africa and Zimbabwe, we argue that pottery provides valuable information on the region's Iron Age, if archaeologists address the social meaning of ceramic assemblages. Ceramic production among rural communities provides the basis on which a wide range of social issues are discussed and used to critique pottery recovered from archaeology. Ethnography suggests that ceramic assemblages are context specific, and archaeologists are cautioned against making generic statements on the basis of similarities of vessel shape and decoration motif.     

NEUTRON ACTIVATION ANALYSIS OF BIRD BOWLS AND RELATED ARCHAIC CERAMICS FROM MILETUS

In this paper we present the results of a chemical investigation by neutron activation analysis of sherds of different kinds of bird kotylai, bird bowls and related wares excavated in Kalabaktepe, a hill of the ancient city of Miletus. A new archaeological classification of this well-known group of Archaic ceramics of eastern Greece is presented. A number of kiln wasters of misfired vessels from Kalabaktepe revealed a characteristic local pattern. This pattern helped to clarify the provenance of some of the bird bowls classified archaeologically as of orientalizing type: they have been made in Miletus. But bird kotylai and bird bowls in the 'standard fabric’as well as other archaeologically related vessels show a different chemical pattern of unknown provenance.     

河曲坪头遗址龙山时期陶器及其制陶原料的化学成分分析

为了对山西省忻州市河曲坪头遗址出土的龙山时期的陶器以及制陶原料中的粘土原料的种类和来源进行相关探讨,利用ICP-OES对出土的陶器、坯料,以及遗址附近采集的土样进行了化学成分测试,并使用SPSS软件对分析结果进行了降维处理和主成分分析。结果显示:坪头遗址不同质地的陶器陶土原料相同,只是在钙含量方面存在细微差异。制作陶器所用的粘土原料很可能取自附近的红色古土壤层。该遗址是古人在当地制作陶器的一个场所。