Origin of palaeo‐waters in the Ordovician carbonates in Tahe oilfield,Tarim Basin: constraints from fluid inclusions and Sr,C and O isotopes

Petrographic features, isotopes, and trace elements were determined, and fluid inclusions were analyzed on fracture‐filling, karst‐filling and interparticle calcite cement from the Ordovician carbonates in Tahe oilfield, Tarim basin, NW China. The aim was to assess the origin and evolution of palaeo‐waters in the carbonates. The initial water was seawater diluted by meteoric water, as indicated by bright cathodoluminescence (CL) in low‐temperature calcite. The palaeoseawater was further buried to temperatures from 57 to 110°C, nonluminescent calcite precipitated during the Silurian to middle Devonian. Infiltration of meteoric water of late Devonian age into the carbonate rocks was recorded in the first generation of fracture‐ and karst‐filling dull red CL calcite with temperatures from <50°C to 83°C, low salinities (<9.0 wt%), high Mn contents and high ⁸⁶Sr/⁸⁷Sr ratios from 0.7090 to 0.7099. During the early Permian, ⁸⁷Sr‐rich hydrothermal water may have entered the carbonate rocks, from which precipitated a second generation of fracture‐filling and interparticle calcite and barite cements with salinities greater than 22.4 wt%, and temperatures from 120°C to 180°C. The hydrothermal water may have collected isotopically light CO₂ (possibly of TSR‐origin) during upward migration, resulting in hydrothermal calcite and the present‐day oilfield water having δ¹³C values from ?4.3 to ?13.8‰ and showing negative relationships of ⁸⁷Sr/⁸⁶Sr ratios to δ¹³C and δ¹⁸O values. However, higher temperatures (up to 187°C) and much lower salinities (down to 0.5 wt%) measured from some karst‐filling, giant, nonluminescent calcite crystals may suggest that hydrothermal water was deeply recycled, reduced (Fe‐bearing) meteoric water heated in deeper strata, or water generated from TSR during hydrothermal water activity. Mixing of hydrothermal and local basinal water (or diagenetically altered connate water) with meteoric waters of late Permian age and/or later may have resulted in large variations in salinity of the present oilfield waters with the lowest salinity formation waters in the palaeohighs.     

Rates of retrograde metamorphism and their implications for crustal rheology

The rate of reaction of a natural hornblende garnet granulite with water under a range of mid- to lower crustal conditions has been investigated experimentally. In runs of between 7 and 84 days small but measurable amounts of water were consumed, and sheet silicates (300°C, 300 MPa and 400°C, 400 MPa) and/or secondary actinolite (400°C, 400 MPa and 500°C, 500 MPa) were observed to have grown. When normalized to the surface area of the starting materials, hydration rates were in the range of 2–5 × 10⁻⁸ g m⁻² sec⁻¹. These reaction rates imply that a film of water that infiltrated a planar crack with a half width of 100 μm would be completely consumed within c. 100 years. These results imply that where water infiltrates the crust along faults or underlying shear zones in response to a deformation, it will remain as a free phase for only a finite period of time, which in some cases will be less than the repeat time for major earthquakes in the fault system. Thus, the rheology of fault zones and shear zones is likely to be cyclical, with the zone becoming stronger with time as water is consumed, and then weakened by infiltration of water after each rupture.     

Obsidian hydration dating by infrared spectroscopy: method and calibration

Low temperature (90–190 °C) hydrothermal experiments have been conducted on seven obsidians where composition of the glass varies significantly in the concentration of structural water within the unhydrated bulk material. Infrared transmission spectroscopy was used to track the diffusion of molecular water into the glass surface as a function of time and temperature. Long-term (60–360 days) hydration sequences at 90 °C show a t^0.6 time dependence for the mass uptake of molecular water that forms the hydration layer. The structural water concentration of the unhydrated bulk obsidian is highly correlated with the pre-exponential and activation energy and may be used to estimate the Arrhenius constants. In addition, secondary ion mass spectrometry (SIMS) hydrogen profiling of Napa Glass Mountain obsidian hydrated at 90 °C reveals that the early stages of diffusion exhibit a dynamic behavior that includes a fluctuating hydrogen concentration and a changing diffusion coefficient that slows with time.     

Climate influence on radial increment of oak (Quercus SP.) in central Poland

The study investigates the influence of climate conditions on radial increment of oak, with special concern to the situations when analysed trees formed conspicuously wider or narrower tree-rings. The research material was collected in four locations in central Poland within natural range of pedunculate and sessile oaks. The elaborated residual chronologies were correlated with CRUTS 2.1 climate data. The analyses included thermal and pluvial conditions spanning from April of the year prior to ring formation to September of the current growth year. Special interest was paid to simple water ability index that combined both temperature and precipitation during the vegetation season. Additionally, pointer year analysis was carried out to determine situations when conspicuously smaller or larger increment was formed. Investigated chronologies cover the period of 1927?C1992 (?ochów), 1845?C1992 (P?o??sk), 1868?C1992 (Pu?tusk), and 1796?C1992 (Soko?ów). The analysed oaks from sites in central Poland exhibit growth patterns comparable with those known form previous studies concerning that species, where influence of precipitation (higher and positive) and temperature (negative) have been observed. Extreme growth reactions expressed by negative and positive pointer years turned to present high dependence of analysed oak?? growth on water availability during vegetation season.     

Origin of palaeofluids in a normal fault setting in the Aegean region

The province of Burdur (SW Turkey) is seismically an active region. A structural, geochronological, petrographical, geochemical and fluid inclusion study of extension veins and fault‐related calcite precipitates has been undertaken to reconstruct the palaeofluid flow pattern in this normal fault setting in the Aegean region. A palaeostress analysis and U/Th dating of the precipitates reveals the neotectonic significance of the sampled calcites. Fluid inclusion microthermometry of calcites‐filling extension veins shows final melting temperatures (T_m ice) of 0°C. This indicates pure water, most likely of meteoric origin. The oxygen isotope values (?9.8‰ to ?6.5‰ VPDB) and the carbon isotopic composition (?10.4‰ to ?2.9‰ VPDB) of these calcites also show a near‐surface meteoric origin of the fluid responsible for precipitation. The microstructural characteristics of fault‐related calcites indicate that calcite precipitation was linked with fault activity. Final melting temperature of fault‐related calcites ranges between 0 and ?1.9°C. The oxygen isotope values show a broad range between ?15.0‰ and ?2.2‰ VPDB. Several of these calcites have a δ¹⁸O composition that is higher or lower than the oxygen isotopic composition of meteoric calcites in the area (i.e. between ?10‰ and ?6‰ VPDB). The δ¹³C composition largely falls within the range of the host limestones and reflects a rock‐buffered system. Microthermometry and stable isotopic study indicate a meteoric origin of the fluids with some degree of water–rock interaction or mixing with another fluid. Temperatures deduced from microthermometry and stable isotope analyses indicate precipitation temperatures around 50°C. These higher temperatures and the evidence for water–rock interaction indicate a flow path long enough to equilibrate with the host–rock limestone and to increase the temperature. The combined study of extension vein‐ and fault‐related calcite precipitates enables determining the origin of the fluids responsible for precipitation in a normal fault setting. Meteoric water infiltrated in the limestones to a depth of at least 1 km and underwent water–rock interaction or mixing with a residual fluid. This fluid was, moreover, tapped during fault activity. The extension veins, on the contrary, were passively filled with calcites precipitating from the downwards‐migrating meteoric water.     

Geochemical fingerprinting of hydraulic fracturing fluids from Qusaiba Hot Shale and formation water from Paleozoic petroleum systems,Saudi Arabia

Provenance studies of produced water are essential to trace flow dynamics and reservoir compartmentalization in petroleum systems and to quantify fluid recovery rates from unconventional fracturing. Produced water from a hydraulically fractured well in the Qusaiba Hot Shale in the Northern Exploration Area, Saudi Arabia, was daily monitored and analyzed for water chemistry, and environmental (δ²H, δ¹³C, δ¹⁸O_H2O, δ¹⁸O_SO4, δ³⁴S_SO4, δ³⁷Cl, ⁸⁷Sr/⁸⁶Sr) and cosmogenic isotopes (³H, ¹⁴C, ³⁶Cl), to differentiate from reference fluids of supply water, fracturing fluids, and formation water from adjacent Paleozoic units. Initially, recovered water is composed of fracturing fluids and subsequently replaced by a homogeneous cut of pristine formation water. Formation water is composed of dominant meteoric water (approximately 84 vol%) and minor fossil evaporated seawater. The young ¹⁴C‐apparent age between 6000 and 6700 years BP and depleted δ¹⁸O/δ²H values for the meteoric component confirm the infiltration of surface water into the Qusaiba Hot Shale interval or adjacent units during the Early Holocene Pluvial Period under cooler and wetter climatic conditions than present, which suggest the presence of a very recent, dynamic hydraulic flow system. ³⁶Cl/Cl ratios between 102 × 10^?15 and 31 × 10^?15 are ambiguous and can be attributed to atmospheric recharge close to the coast, mixing of ³⁶Cl‐enriched Quaternary meteoric recharge with ³⁶Cl‐depleted fossil seawater, and/or hypogene production by U‐Th‐enriched host rock. Produced waters from Qusaiba Hot Shale are within the compositional range of Na‐Cl‐type formation water from Paleozoic reservoir units in northern Saudi Arabia with salinities from 30 000 to 130 000 mg l^?1. As a novel technological approach for exploration wells in Northern Saudi Arabia, multi‐isotopic methods were successfully implemented to quantify flowback volumes from hydraulic fracturing, and to fingerprint pristine formation water or pore water in Paleozoic systems on their provenance, residence time, migration pathways, and secondary alteration processes.     

Hydrogeological insights in antiquity as indicated by Canaanite and Israelite water systems

Hazor, one of the largest fortified city during the Israelite (Iron-Age) period, encompasses a gigantic underground water system within its perimeter, supplying water to thousands of its inhabitants. It is considered as the ultimate example that Iron-Age engineers had mastered the concept of regional groundwater table. However, evaluating the hydrogeological conditions and the degree of success in finding water in Hazor and other contemporary cities, and thereby assess to what extent this concept was known at that time has seldom been done. Resurveying the water system of Hazor indicates that its water chamber was dug along a major strand of the Dead Sea Fault, a boundary between the Arabian and African (Sinai) plates. Hydrological simulations have shown that water ascends into the water chamber, utilizing this strand. Hazor's engineers initially planned to connect the city with the springs at the foot of the mound (tell) through a shaft and tunnel as has been done at other biblical cities, but adjusted their plan when groundwater was encountered within the mound perimeter. This accidental success as well as the failure to reach the aquifer in deep water wells dug in the contemporary cities of Lachish and Beer Sheba, imply limited hydrogeological understanding at the beginning of the first millennium B.C.E.     

Growth responses of sessile oak to climate and hydrological regime in the Zbytka Nature Reserve, Czech Republic

Complex of Nature reservation Zbytka is the rest of various fen vegetation in the northeast part of the Czech Republic. It represents an important spring area which provides high quality potable water for more than 150 000 inhabitants. Waterworks utilization was started in the 1960s and the change of land-use practices has had a strong effect on the ecosystem. Oak chronology has been showing different tree growth trends since the start of the waterworks utilization. Also the occurrences of negative pointer years differ markedly before and after initiation of pumping underground water. Dendroclimatological analyses primarily revealed a close relationship between the temperature and tree growth ?? positive influence of spring and summer temperature. The period 1983?C1992 of maximum artesian water pumping is expressed as higher tree-ring increments, but linear model analyses showed that the growth reaction of oak is not due to simple causality between temperature and under-ground water level. The radial increments reacted positively to the combination of high temperature during the vegetation season and low or, the contrary, high depth of underground water level. No direct relationship was detected between tree growth and fluctuation of underground water level; despite of the results dendrochronological data may be useful in historical ground water modelling studies. Results are also crucial for conflict of interests between nature preservation and potable water supply.     

楼兰古绿洲的河道变迁及其原因探讨西北历史环境研究

在干旱区,地表径流决定人类居住和生存的空间,是环境变迁的决定因素。楼 兰古绿洲的环境演变及其在４世纪末的最终消失都与塔里木河及孔雀河河水的空间分布密切 相关。石器时代至公元４世纪中叶以前,塔里木河与孔雀河合流,经库鲁克塔格山南麓东流,形 成面积广大的孔雀河三角洲,成为楼兰古绿洲繁荣与发展的基础;４世纪中叶,部分塔里木河水 在营盘附近歧道南流,离开了孔雀河三角洲,楼兰古绿洲开始衰败、萎缩;４世纪末,孔雀河、塔 里木河河水全部南流,孔雀河三角洲水源断绝,楼兰古绿洲衰废、消失。这其中,孔雀河三角洲 的自然地理特征是影响孔雀河河道发生变迁的基础因素;人类引流蓄水的捕鱼活动和屯田所 需河渠管理系统的兴废是影响河道变迁的重要人为因素。４世纪中晚期,塔里木河下游与孔雀 河的改道南流是在自然因素与人为因素的耦合作用下发生的。     

Formation of Fluid Inclusions during Heat Treatment of Barremo‐Bedoulian Flint: Archaeometric Implications

At the end of the fifth millennium bc , the development of a specialized lithic industry in the Chassey societies of south‐eastern France and its dissemination as far as Catalonia and Tuscany attest to important socio‐economic changes in the Mediterranean Neolithic societies. The lithic production was made on barremo‐bedoulian flint that was heat‐treated to improve the sharpness of the tools produced. Microscopic observations of archaeological and geological, heated and unheated barremo‐bedoulian flint samples allowed us to highlight the heat‐induced formation of fluid inclusions. Microthermometry analyses showed that these inclusions contain pure H₂O, most probably resulting from the dehydration of length‐slow (LS) chalcedony and the closure of narrow pores, according to the model proposed by Schmidt et al. ( 2012 ). Our results enable us to estimate the heating temperatures used by Chassey artisans to ≈ 230°C. We also propose the ‘pressure cooker’ model to explain the migration of liquid water in flint nodules heated to 230°C. Then, we discuss the ability of a particular type of flint to be heat‐treated, and hence its value for Neolithic society, which depends on: (1) the amount of LS chalcedony that ensures the water release at relatively low temperature; and (2) on the total volume of porosity available to store the dehydration water.     

Barite–pyrite mineralization of the Wiesbaden thermal spring system, Germany: a 500-kyr record of geochemical evolution

Barite–(pyrite) mineralizations from the thermal springs of Wiesbaden, Rhenish Massif, Germany, have been studied to place constraints on the geochemical evolution of the hydrothermal system in space and time. The thermal springs, characterized by high total dissolved solids (TDS) contents and predominance of NaCl, ascend from aquifers at 3–4 km depth and discharge at a temperature of 65–70°C. The barite–(pyrite) mineralization is found in upflow and discharge zones of the present‐day thermal springs as well as at elevations up to 50 m above the current water table. Hence, this mineralization style constitutes a continuous record of the hydrothermal activity, linking the past evolution with the present state of this geothermal system. The sulphur isotope signatures of the mineralization indicate a continuous decrease of the δ³⁴S of sulphate from +16.9‰ in the oldest barite to +10.1‰ in the present‐day thermal water. The δ³⁴S values of barite closely resemble various recently active thermal springs along the southern margin of the Rhenish Massif and contrast strongly with different regional ground and mineral waters. The mineralogical and isotopic signatures, combined with calculations based on uplift rates and the regional geological history, indicate a minimum activity of the thermal spring system at Wiesbaden of about 500 000 years. This timeframe is considerably larger than conservative models, which estimate the duration of thermal spring systems in continental intraplate settings to last for several 10 000 years. The calculated equilibrium sulphur isotope temperatures of coexisting barite and pyrite range between 65 and 80°C, close to the discharge temperature of the springs, which would indicate apparent equilibrium precipitation. Kinetic modelling of the re‐equilibration of the sulphate–sulphide pair during water ascent shows that this process would require 220 Myr. Therefore, we conclude that pyrite is formed from precursor Fe monosulphide phases, which rapidly precipitate in the near‐surface environment, preserving the isotope fractionation between dissolved sulphate and sulphide established in the deep aquifer. Equilibrium modelling of water–mineral reactions shows slight supersaturation of barite at the discharge temperature. Pyrite is already strongly supersaturated at the temperatures estimated for the aquifer (110°C) and processes in the near‐surface environment are most probably related to contact of the thermal water with atmospheric oxygen, resulting in formation of oxidized intermediate sulphur species and precipitation of Fe monosulphide phases, which subsequently recrystallize to pyrite.     

Reviews

Book reviewed in this article:
Roman amphoras: A review article
Shipwrecks and archaeology: the unharvested sea. P eter T hrockmorton
Ships and seamanship in the ancient world. L ionel C asson
Ships of the Pharaohs. B jorn L andstrom
Skind eller Træ (Skin or Wood). Author in Smand og Fisker. Skib og Wærf , Roskilde, 1970, pp. 213–39, 13 figs. O le C rumlin -P edersen
Die Bremen Haose-Kogge. Fund, Konservierung, Forschung. H. A bel et al .
Skonnerten Fulton af Marstal. O le C rumlin -P edersen
Boats and boatmen of Pakistan. B asil G reenhill
Fishbourne. A Roman palace and its gardens. B arry C unliffe
Archaeology under water. G eorge F. B ass
Nautical archaeology. A handbook. B ill S t . J ohn W ilkes
Conservation in field archaeology. E lizabeth A. D owman     

Measurements of noctilucent cloud heights: a bench mark for changes in the mesosphere

Recent studies of noctilucent clouds indicate a secular increase in their frequency of occurrence which may be associated with changes either in the water vapour concentration or in the mean temperature of the mesopause. Noctilucent clouds are expected to be seen very close to the level where the relative humidity is 100% and changes in temperature of the mesosphere or in its water vapour content might be expected to alter the height at which the clouds occur. Comparison of our height measurements with those obtained over the past 100 yr shows that the suggested changes since 1885 in temperature (a decrease of approximately 7°C) and water vapour mixing ratio (an increase of approximately 1.7 ppmv) have not been sufficient to affect the height of the clouds by an observable amount. Future height measurements of noctilucent clouds may provide a practical indicator of changes taking place in the mesosphere which could be associated with global-scale alterations of the lower atmosphere.     

洞庭湖变迁的历史过程再探讨

关于洞庭湖的历史变迁过程问题,学术界一直没有取得共识。本文认为,今洞庭湖地区在先秦两汉时期尚处于河网沼泽平原阶段,没有形成大型湖泊;进入魏晋南朝隋唐时期,今洞庭湖地区的湖泊水体得到快速扩展;唐后期至清前期,今洞庭湖地区的湖泊水体面积处于全盛阶段;自清中期以来,随着长江来沙量的日益增加,湖泊进入明显的萎缩阶段。历史时期洞庭湖的形成与变迁主要取决于洞庭湖区的沉降速度和长江干流的来沙量。     

Stress‐induced temperature variations in groundwater of the Monferrato area (north‐western Italy)

Although characterized by low seismicity, the Monferrato area of north‐western Italy was affected by earthquakes, of magnitude M5.1 and M4.8, in 2000 and 2001. At the same time, marked changes were recorded in water temperature and chemistry in several wells within the epicentral area. In May 2004, an automatic network for the continuous monitoring of groundwater was installed in selected wells to study the phenomenon. Here, we report on data collected during a 3‐year period of groundwater monitoring. During the first year, episodes of water heating (by up to 20°C) were observed in one monitored well. The temporal analysis of the seismic activity recorded in the area revealed as almost all seismic events occurred during the period of elevated water temperatures. The similar timing of earthquakes and groundwater‐temperature anomalies suggests that both may be triggered by the same processes acting in the crust.     

Fluid inclusion and isotopic constraints on the origin of ore‐forming fluid of the Jinman–Liancheng vein Cu deposit in the Lanping Basin,western Yunnan,China

Extensive quartz–carbonate–Cu sulfide veins occur in clastic rocks and are spatially related to Paleocene granites in the western border of the Lanping Basin, western Yunnan, China. Abundant aqueous‐carbonic fluid inclusions occur in these veins but their origin is debated. In the Jinman–Liancheng deposit, individual primary inclusion groups contain either exclusively liquid‐rich inclusions (Gl), or coexisting liquid‐rich and vapor‐rich inclusions (Glv). Microthermometry and estimate of CO₂ content indicate that type Gl inclusions either have homogenization temperatures (Th) 238–263°C and contain c. 3.9–5.5 mole % CO₂, or have Th 178–222°C and contain c. 1.6–3.2 mole % CO₂. Type Glv inclusions are thought to represent samples of fluid unmixing that occurred at 183–218°C. At that time, the liquid phase in the unmixing fluid may contain c. 2.0–3.3 mole % CO₂. As such, the correlation of CO₂ content with Th for type Gl inclusions is thought to be caused by fluid unmixing with decreasing temperature and subsequent CO₂ escape. δ¹⁸O and δD values of the parent water mainly fall in the field below that of primary magmatic water, indicative of fluid derivation from degassed (in open system) magmatic water, with no contributions from basinal or meteoric water. Initial Sr isotopic compositions of hydrothermal carbonates suggest that the fluid was magmatic, probably derived from the Paleogene granites. δ¹³C_PDB values (?4‰ to ?7‰) of the hydrothermal carbonates and δ³⁴S_V‐CDT values of sulfides (mainly ?11‰ to +5‰) indicate that the carbon and sulfur can be derived from (degassed) magma and/or nonmagmatic sources. The CO₂‐rich and magmatic‐water‐derived fluid at Jinman–Liancheng differs from the CO₂‐poor and basinally derived fluid in sediment‐hosted stratiform Cu (SSC) deposits, which suggests that there are no genetic linkages between the vein Cu and SSC deposits in the Lanping Basin.     

Chemical and isotopic signatures of Na/HCO3/CO2‐rich geofluids,North Portugal

Geochemical and isotopic studies have been undertaken to assess the origin of CO₂‐rich waters issuing in the northern part of Portugal. These solutions are hot (76°C) to cold (17°C) Na–HCO₃ mineral waters. The δ²H and δ¹⁸O signatures of the mineral waters reflect the influence of altitude on meteoric recharge. The lack of an ¹⁸O‐shift indicates there has been no high temperature water–rock interaction at depth, corroborating the results of several chemical geothermometers (reservoir temperature of about 120°C). The low ¹⁴C activity (up to 9.9 pmC) measured in some of the cold CO₂‐rich mineral waters (total dissolved inorganic carbon) is incompatible with the presence of ³H (from 1.7 to 4.1 TU) in those waters, which indicates relatively short subsurface circulation times. The δ¹³C values of CO₂ gas and dissolved inorganic carbon range between ?6‰ and ?1‰ versus Vienna‐Peedee Belemnite, indicating that the total carbon in the recharge waters is being diluted by larger quantities of CO₂ (¹⁴C‐free) introduced from deep‐seated (upper mantle) sources, masking the ¹⁴C‐dating values. The differences in the ⁸⁷Sr/⁸⁶Sr ratios of the studied thermal and mineral waters seem to be caused by water–rock interaction with different granitic rocks. Chlorine isotope signatures (?0.4‰ < δ³⁷Cl < +0.4‰ versus standard mean ocean chloride) indicate that Cl in these waters could be derived from mixing of a small amount of igneous Cl from leaching of granitic rocks.     

Book Reviews

Books reviewed in this article:
The lie of the land Paul Carter
The lie of the land: migrant workers and the California landscape Don Mitchell
The way the world works. World hegemony to world impasse Peter J Taylor
The cinematic city David B Clarke (ed.)
Space and social theory: interpreting modernity and postmodernity Georges Benko and Ulf Strohmayer (eds)
Reconstructing Quaternary environments (second edition) J J Lowe and M J C Walker
Sediment and water quality in river catchments Ian Foster, Angela Gurnell and Bruce Webb (eds)
Regions of risk: a geographical introduction to disasters Kenneth Hewitt
Environmental and social impact assessment C J Barrow
Sustainability: a systems approach Anthony M H Clayton and Nicholas J Radcliffe
Artificial intelligence in geography Stan Openshaw and Christine Openshaw     

Numerical modeling of the origin of calcite mineralization in the Refugio‐Carneros fault,Santa Barbara Basin,California

Many faults in active and exhumed hydrocarbon‐generating basins are characterized by thick deposits of carbonate fault cement of limited vertical and horizontal extent. Based on fluid inclusion and stable isotope characteristics, these deposits have been attributed to upward flow of formation water and hydrocarbons. The present study sought to test this hypothesis by using numerical reactive transport modeling to investigate the origin of calcite cements in the Refugio‐Carneros fault located on the northern flank of the Santa Barbara Basin of southern California. Previous research has shown this calcite to have low δ¹³C values of about ?40 to ?30‰PDB, suggesting that methane‐rich fluids ascended the fault and contributed carbon for the mineralization. Fluid inclusion homogenization temperatures of 80–125°C in the calcite indicate that the fluids also transported significant quantities of heat. Fluid inclusion salinities ranging from fresh water to seawater values and the proximity of the Refugio‐Carneros fault to a zone of groundwater recharge in the Santa Ynez Mountains suggest that calcite precipitation in the fault may have been induced by the oxidation of methane‐rich basinal fluids by infiltrating meteoric fluids descending steeply dipping sedimentary layers on the northern basin flank. This oxidation could have occurred via at least two different mixing scenarios. In the first, overpressures in the central part of the basin may have driven methane‐rich formation waters derived from the Monterey Formation northward toward the basin flanks where they mixed with meteoric water descending from the Santa Ynez Mountains and diverted upward through the Refugio‐Carneros fault. In the second scenario, methane‐rich fluids sourced from deeper Paleogene sediments would have been driven upward by overpressures generated in the fault zones because of deformation, pressure solution, and flow, and released during fault rupture, ultimately mixing with meteoric water at shallow depth. The models in the present study were designed to test this second scenario, and show that in order for the observed fluid inclusion temperatures to be reached within 200 m of the surface, moderate overpressures and high permeabilities were required in the fault zone. Sudden release of overpressure may have been triggered by earthquakes and led to transient pulses of accelerated fluid flow and heat transport along faults, most likely on the order of tens to hundreds of years in duration. While the models also showed that methane‐rich fluids ascending the Refugio‐Carneros fault could be oxidized by meteoric water traversing the Vaqueros Sandstone to form calcite, they raised doubts about whether the length of time and the number of fault pulses needed for mineralization by the fault overpressuring mechanism were too high given existing geologic constraints.     

Sasanian period drop-tower gristmills on the Deh Luran Plain,southwestern Iran

Abstract

The nature of the Deh Luran gristmill system is described, and archaeological and ethnohistorical observations provide insights into ancient rural technology, economics, and socio-politics. Optically Scanned Luminescence, ceramics, and other archaeological associations, date the Deh Luran gristmills to the Sasanian period (A.D. 225–700). A Middle East/Mediterranean origin as early as 250 B.C. is suggested for the drop-tower side-shot water wheel technology used.

The Deh Luran gristmill technology was well adapted to the topography and limited, variable water supply. Currently farmed lands, and their productivity, are found to be far less than projected grain surpluses for an expanding Sasanian Empire in Deh Luran. Population estimates based on gristmill productivity contradict those from archaeological data. Data suggest that Deh Luran, and similar rural areas, were relatively autonomous.