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1.
Recent work on infrared stimulated luminescence (IRSL) dating has focussed on finding and testing signals which show less or negligible fading. IRSL signals measured at elevated temperature following IR stimulation at 50°C (post-IR IRSL) have been shown to be much more stable than the low temperature IRSL signal and seem to have considerable potential for dating. For Early Pleistocene samples of both European and Chinese loess natural post-IR IRSL signals lying in the saturation region of the laboratory dose response curve have been observed; this suggests that there is no significant fading in nature. As a contribution to the further testing of post-IR IRSL dating, we have used 18 samples from two Japanese loess profiles for which quartz OSL and tephra ages up to 600 ka provide age control. After a preheat of 320°C (60 s), the polymineral fine grains (4–11 μm) were bleached with IR at 50°C (200 s) and the IRSL was subsequently measured at 290°C for 200 s. In general, the fading uncorrected post-IR IRSL ages agree with both the quartz OSL and the tephra ages. We conclude that the post-IR IRSL signal from these samples does not fade significantly and allows precise and accurate age determinations on these sediments.  相似文献   

2.
Optically stimulated luminescence (OSL) measurements of individual quartz grains are reported for Middle Paleolithic (MP) or Middle Stone Age (MSA) deposits in La Grotte des Contrebandiers, Morocco. Single-grain measurements enable rejection of grains that may lead to under- or over-estimation of age due to malign luminescence properties or remobilisation of grains after burial. We identified the former using a range of experimental procedures and objective rejection criteria. Three post-depositional factors influenced the distribution pattern of equivalent dose (De) values for the remaining single grains: the disintegration of roof spall liberating unbleached, older grains into otherwise well-bleached sediments; the intrusion of a small number of younger grains from the overlying Upper Paleolithic deposits; and small-scale differences in the beta dose received by individual grains. Roof spall contamination was a significant problem, so we characterised the OSL signals and obtained De values for the calcareous sandstone in which the cave is formed, which allowed bedrock-derived grains in the MP/MSA deposits to be identified and rejected prior to age determination. We collected 31 samples from the MP/MSA deposits, and were able to calculate ages for 30 of them. These ages suggest that MP/MSA occupation of Contrebandiers was restricted to the interval between about 120 and 90 ka ago (Marine Isotope Stages 5d to 5b). Weighted mean OSL ages were obtained for samples associated with archaeologically sterile deposits at the base of the excavations (126 ± 9 ka), followed by two phases of the Moroccan Mousterian (122 ± 5 and 115 ± 3 ka), interspersed with archaeologically sterile deposits (112 ± 4 ka). The base and top of the Aterian were dated to 107 ± 4 and 96 ± 4 ka, respectively. Based on the grand weighted mean ages of 116 ± 3 and 103 ± 3 ka for the Moroccan Mousterian and Aterian at Contrebandiers, we suggest that these two industries may be separated by an occupation hiatus of up to 13 ± 3 ka at this site. Our single-grain OSL chronology confirms previous age estimates obtained for Contrebandiers and other sites in the vicinity, but are generally more precise and stratigraphically more coherent, due to the inherent advantages of measuring individual quartz grains and rejecting contaminant and other unsuitable grains before age determination.  相似文献   

3.
A. G. WINTLE 《Archaeometry》2008,50(2):276-312
Luminescence techniques for dating both heated materials (e.g., pottery and burnt stone) and sediments have gone through three phases in the past 50 years. The first 22 years, from 1957 to 1979, were devoted to thermoluminescence (TL) techniques applied to heated material. In the next six years, from 1979 to 1985, it was found that TL dating could be applied to sediments. However, the TL signals of both quartz and feldspar grains observed for modern sediments were small, but were not zero, thus making them useful only for older sediments. A new luminescence signal that was totally zeroed by exposure to sunlight for a relatively short period of time, a few hours or less, was found; this led to the development of optically stimulated luminescence (OSL) dating techniques in 1985. Further developments have continued to the present day. Within the past 22 years, 1999 was also a year with major developments. A reliable procedure for single aliquots of quartz that have a rapidly bleached (‘fast’) OSL component was formalized and an instrument that allowed rapid measurement of equivalent doses for single grains was constructed. These developments have led to OSL becoming a major dating tool in Quaternary geology, at least for the past 100 000 years, and in archaeology, particularly as related to the dispersal of modern humans.  相似文献   

4.
Luminescence dating has been applied to volcanogenic outburst flood sediments (Takuma gravel bed) from Aso volcano, Japan, and tephric loess deposits overlying the gravel bed. The poly-mineral fine grains (4–11 μm) from loess deposits were measured with pulsed optically stimulated luminescence (pulsed OSL) and post-IR infrared stimulated luminescence (pIRIR) methods, whereas the Takuma gravel bed containing no quartz, was measured with IRSL and pIRIR methods using sand sized (150–200 μm) plagioclase. The loess deposits date back at least to ~50 ka by consistent IRSL, pIRIR and pulsed OSL ages from the lowermost part of the loess deposits from one section. The ages obtained from the bottom part of the other loess section are not consistent each other. However, we consider that the pIRIR age (72±6 ka) which showed negligible anomalous fading is most reliable, and regard as a preliminary minimum age of the Takuma gravel bed. The equivalent doses (De) for the plagioclase from the Takuma gravel bed have a narrow distribution and the weighted mean of the three samples yield an age of 89±3 ka. This age is in agreement with the last caldera-forming eruption of Aso volcano (~87 ka) and it is likely that the pIRIR signal has not been bleached before the deposition. IRSL dating without applying pIRIR using small aliquots was also conducted, however, the IRSL signal shows no clear evidence of an additional bleaching during the event of outburst flood from the caldera lake.  相似文献   

5.
In the last few decades optically stimulated luminescence (OSL) dating has become an important tool in geochronological studies. The great advantage of the method, i.e. dating the depositional age of sediments directly, can be impaired by incomplete bleaching of grains. This can result in a scattered distribution of equivalent doses (DE), leading to incorrect estimation of the depositional age. Thoroughly tested protocols as well as good data analysis with adequate statistical methods are important to overcome this problem. In this study, samples from young fluvial sand and flood plain deposits from the Elbe River in northern Germany were investigated to compare its depositional ages from different age models with well-known historical dates. Coarse grain quartz (100–200 μm and 150–250 μm) and polymineral fine grains (4–11 μm) were dated using the single aliquot regenerative (SAR) dose protocol. The paleodose (DP) was calculated from the DE data set using different approaches. Results were compared with the development of the Elbe River, which is well-documented by historical records and maps covering the last 1,000 years. Depending on the statistical approach it can be demonstrated that depositional ages significantly differ from the most likely depositional age. For the investigated coarse grain quartz samples all ages calculated from the MAM-3UL, including their uncertainties, are within the historical documented age. Results of the polymineral fine grain samples are overestimating the historically documented depositional age, indicating undetectable incomplete bleaching. This study shows the importance of using an adequate statistical approach to calculate reliable OSL ages from fluvial sediments.  相似文献   

6.
Luminescence properties of two samples taken from sand lenses in proglacial outwash de-posits of a piedmont glacier that reached the Swiss midlands during the Last Glacial Maximum are investigated in detail. Deconvolution of CW-OSL decay curves shows that the fast component dominates the OSL signal of quartz. The chemistry of single feldspar grains, in particular the K content in different grains, is determined using wavelength dispersive spectrometry (electron microprobe), revealing an average 12.9 wt.% K of the grains contributing to the IRSL signal. D e distributions are investigated in order to gain insights into partial bleaching, and agreement is found for quartz OSL and feldspar IR50 and pIRIR225 ages for small aliquots and single grains when applying the Minimum Age Model. These ages are also consistent with independent age control. For one sample, ages determined using the Central Age Model result in highly overestimated ages for both feldspar and quartz.  相似文献   

7.
Optically stimulated luminescence (OSL) dating of heated/fired materials of archaeological importance from various parts of India was attempted. A single-aliquot regenerative-dose (SAR) procedure was used for palaeodose determination in the quartz grains extracted from the heated materials using the luminescence produced by blue light stimulation. In most pottery samples, the palaeodose obtained using SAR-OSL is ∼6% lower than the palaeodose measured using thermoluminescence (TL) method. Broadly, there is good agreement between the SAR-OSL and TL ages of the artefacts and their archaeologically expected ages. The results suggest that routine dating of heated/fired materials using the SAR-OSL procedure is more practicable, especially when the TL sensitivity of the quartz grains is poor and availability of datable material is limited.  相似文献   

8.
This paper presents a series of new single-grain optically stimulated luminescence (OSL) ages for the Still Bay at Blombos Cave, South Africa, and compares them to previously published OSL, thermoluminescence (TL) and electron-spin resonance (ESR) ages for this site. Details are provided about the measurement and analytical procedures, including a discussion of the characteristics of the OSL signals of individual quartz grains. This forms the basis for further investigations into the sensitivity of the equivalent dose (De) estimates to a range of different analytical approaches, including changes in the size of the test dose, the choice of signal integration interval, the subtraction of an appropriate background, and isolation of the most light-sensitive (‘fast’) component of quartz OSL. We also report the results of an inter-operator test of De determination using seven new samples from Blombos Cave, and demonstrate the reproducibility of results obtained for two samples that had been dated previously at another laboratory and were measured and analysed again in this study. Together, these tests validate the robustness of the Blombos Cave single-grain OSL age estimates to a variety of alternative OSL dating procedures. We have incorporated, for the first time, these ages for Blombos Cave into a data set of all single-grain OSL ages for Still Bay and Howieson's Poort sites across southern Africa, and have used a statistical model to re-evaluate the timing and duration of the Still Bay industry. We calculate the most plausible start and end dates of the Still Bay as 72.2 ka and 71.3 ka, respectively – amounting to a duration of 0.9 ka – and estimate (with conventional 95% confidence) that this industry began no earlier than 75.5 ka, ended no later than 67.8 ka and lasted no longer than 6.6 ka.  相似文献   

9.
Well constrained numerical ages of alluvial fan sediments are key to understanding the chronology of alluvial episodes and tectonic activity at the front of the Andean Precordillera. We tested the application of radiocarbon and optically stimulated luminescence (OSL) dating in the distal part of an alluvial fan five kilometers north of Mendoza. For OSL dating a large number of aliquots (n > 70) — each composed of ∼50 quartz grains — were measured in order to obtain reliable burial ages despite scattered dose distributions. Owing to a feldspar contamination in all samples, an infrared stimulation was inserted before each OSL measurement, which reduced the feldspar OSL signal successfully. By using the minimum age model we obtained stratigraphically consistent burial ages of alluvial deposits in a depth profile. The uppermost ∼1 m of sediment is composed of debris flow deposits buried 770±76 years ago. Three plant remnants used for radiocarbon dating from the same layer, however, yielded ages younger than 350 years, which are interpreted to underestimate the depositional age. Underneath the debris flow, a major unconformity cuts a series of distal alluvial fan sediments with interstratified floodplain deposits, which are composed of sandy and calciterich silt layers, respectively. Three samples from this unit which were distributed over one meter of sediment thickness yielded statistically concordant OSL ages of 12.3±1.2 ka, 12.3±1.2 ka, and 11.7±1.1 ka. The deposition of these sediments during the latest Pleistocene coincides with a phase of cool and humid climate, which occurred before the alluvial fan propagated farther into the foreland. The overlying debris flow sediments are associated with alluvial fan incision during the arid Late Holocene.  相似文献   

10.
Archaeosediments are deposits with a direct or indirect anthropogenic component. They provide useful information about past human activities and interaction with the environment. When other materials, such as pottery, are present in archaeosediment layers, the combination of TL ages from pottery and OSL ages from sediments can provide complete data about the occupation and evolution of an archaeological setting. In Mesopotamia, tells are mounds formed by the debris of human occupation and the accumulation of muddy sediments mainly due to the decomposition of mud bricks in ancient towns. Many other materials such as pottery fragments, bones and charcoal can be found in the sediment layers. The combination of OSL, TL and radiocarbon ages can be very useful in the case of the Bronze Age Period in Syria, allowing the occupation sequence of such archaeological sites to be reconstructed. Tell Qubr Abu al-’Atiq, is located on the left bank of the Middle Euphrates River (Syria). The archaeological artefacts found in the sediment layers (pottery) collected during excavations in two areas of the site, indicated the occupation of the tell during the Early and Late Bronze Age by typological pottery classification. The radiocarbon ages of charcoal indicate that human occupation fits the archaeological hypothesis, providing an older and maximum occupation period between 2800 and 2300 BC and a younger period between 1400 and 900 BC. OSL dating of sediments shows ages younger than charcoal, while TL ages of pottery are generally older than sediment and charcoal ages. This can be explained as the different materials correspond to different events. The charcoal and pottery correspond to occupation periods, while sediments correspond to the further destruction of the site.  相似文献   

11.
Micro-fabric characteristics and optically stimulated luminescence (OSL) dating results are presented to discuss the controlling agents and timing of beachrock cementation on the fresh-water Iznik Lake shoreline. The beachrocks are made up of grain-supported polygenic conglomerate containing 20.42% carbonate with encrusted grains, basically as micrite coatings, isopachous aragonite rims, cryptocrystalline void fills and meniscus bridges. The optical ages of twelve samples yielded ages that range from 4.226±0.569 ka on the lowermost beds to 0.706±0.081 on the uppermost. This is the first report of precipitation of marine-like cements in Iznik Lake. The abundant aragonite-dominated cement is likely indicative of precipitation-prone dry evaporative conditions from the climatic optimum to the last millennia.  相似文献   

12.
Using a set of modern/young (0 to about 200 years old) dust samples collected from the Chinese Loess Plateau the bleachability of IRSL measured at 50°C (IR50) and post-IR50 elevated temperature IRSL (measured at 225°C and at 290°C) is investigated by measuring the apparent (residual) doses recorded by these signals. Doses recorded by quartz OSL are used as a reference. Allowing for differences in dose rates it seems that both IRSL and post-IR IRSL signals yield residual doses that are significantly larger than the doses measured in quartz. These residual doses can be largely explained by thermal transfer caused by preheating. Nevertheless, we advise against the use of a low temperature preheat (<200°C) with IR50 to date loess samples because, as has been reported before, the signal appears to be thermally unstable. In general, we conclude that it may not be advisable to apply post-IR IRSL dating to Chinese loess samples where residuals of up to ∼20 Gy are a significant fraction of the total dose. However, these residuals quickly become unimportant when dating older samples, and this is the age range in which post-IR IRSL dating is likely to be most useful.  相似文献   

13.
Different post-IR Infrared Stimulated Luminescence (IRSL) approaches are applied to sediments from a Holocene coastal foredune sequence on Ruhnu Island in the eastern Baltic Sea. The comparison of D e-values and ages determined by the different approaches is complimented by fading and bleaching experiments. The fading experiments imply strong fading of IRSL (50°C) signals and no fading of any of the post-IR IRSL signals, but this is not confirmed by the determined D e-values. In fact, post-IR IRSL (150°C) D e-values agree within errors with those calculated for IRSL (50°C). From the bleaching experiments it is inferred that the higher values observed for post-IR IRSL at more elevated stimulation temperatures (225°C/290°C) are likely related to either thermal transfer and/or slow-to-bleach components within the signal. For the dating of the Holocene foredune sequence of Ruhnu Island, the post-IR IRSL (150°C) approach is preferred and these agree with the limited independent age control available from radiocarbon dating. Accordingly, the sequence formed between ca. 7.0 ka and 2.5 ka ago.  相似文献   

14.
The site of Vértesszöllös has yielded a pebble-tool industry, a fragment of the cranium of a primitive form of Homo sapiens, and a vertebrate fauna indicative of the Biharian faunal stage. We have analyzed the travertines under- and overlying the hominid-bearing marl. All the samples are significantly contaminated with detritus, so that calculated U-series disequilibrium ages provide upper limits to the true age. The individual samples, when corrected for a possible initial 230Th/232Th ratio of 1·5, give an average age of 211 ± 13 Ky. By fitting the data to a model consisting of a mixture of authigenic and detrital components, we obtain an age of 162 ?62+73 Ky. The travertines appear to have been deposited over a span of about 40,000 years centred at about 185 ± 25 Ky bp. This places their deposition near the beginning of isotope stage 6, much younger than has been generally believed.  相似文献   

15.
Although radiocarbon (14C) dating, uranium-series dating, and optically stimulated luminescence (OSL) dating have been conducted for Upper Palaeolithic sites in the Nihewan Basin, northern China, there is room for constructing a detailed chronological framework. In this study, loess sediments collected from two Upper Palaeolithic sites, Youfang site and Hutouliang site, were dated using the single-aliquot regenerative-dose (SAR) OSL protocol. OSL measurements for palaeodoses estimation used fine-grained quartz samples extracted from loess. OSL dating results were obtained as 10–17 ka. These OSL ages were consistent with the related stratigraphy of Palaeolithic sites, archaeological evidence and independent 14C ages.  相似文献   

16.
New radiometric data are reported from the recent excavation of the type locality of the Early Upper Palaeolithic entity of the Bohunician. Recently obtained radiocarbon (14C) data on charcoal are compared with new Optically Stimulated Luminescence (OSL) dating of sediment. OSL ages were determined on sediment from the archaeological occupation at Brno-Bohunice, as well as from the over- and underlying loessic sediments. Multiple techniques were applied, which all gave congruent results. While a dual protocol (post IR-OSL) failed the quality criteria tests, ages were obtained by Multiple-Aliquot-Additive-Dose (MAAD) on polymineral material and Single-Aliquot-Regeneration (SAR) on fine grain quartz extract as well as on polymineral material. Fading tests show significant loss of Infrared Stimulated Luminescence (IRSL) after storage for 3 and 12 months for one sample, but little or no fading for others. The resulting (uncorrected) age estimates are smaller than those on quartz by OSL methods. The latter are considered to be more reliable estimates of the sedimentation age of these deposits. The measured OSL doses do not show a simple distribution and the lowest 5% was used for age calculation to represent the most likely sedimentation age. The quartz from the loess overlying the archaeological layer is OSL dated to 30.9 ± 3.1 ka, while the sediment for the paleosol which contains the archaeological layer gave an age of 58.7 ± 5.8 ka. The attribution of this paleosol to the Hengelo interstadial is therefore questionable. However, if the Hengelo interstadial is correlated with the Dansgaard/Oeschger (D/O) event 12, statistical agreement within 2-σ is achieved. The OSL result for the archaeological layer is in accordance with a weighted average TL date on heated flint artifacts of 48.2 ± 1.9 ka from this layer as well as calibrated radiocarbon data (CalPal Hulu 2007) from nearby locations. However, radiocarbon data on charcoal samples obtained during excavation at Brno-Bohunice 2002 provide age estimates between 30 and 40 ka 14C-years, which translate to approximately (33) 35–44 ka on the calendric time scale according to the Hulu 2007 model. For the underlying loess a depositional age of 104.3 ± 10.6 ka was obtained by OSL. The presented OSL ages indicate that a simple correlation of soil sequences between sites within a region has to be verified by chronometric dating.  相似文献   

17.
A new measurement protocol has been tested on K-feldspars from Whanganui Inlet and Parengarenga Harbour, New Zealand. A Single Aliquot Regenerative (SAR) dose protocol, using two successive infrared (IR) stimulations (post-IR IR SAR protocol) is setup for these young (<1000 years) coastal sediments. Significant anomalous fading (g 2days =7 %/decade) is observed using the conventional IR signal measured at 50°C. In contrast, the fading rate of the IR signal measured at elevated temperature (150°C) after the IR stimulation at 50°C (a post-IR IR signal) is not significant (g 2days ≤ 1 %/decade). Surprisingly low residual infrared stimulated luminescence (IRSL) signals were observed for a surface sample, suggesting that accurate ages as young as ∼50 years can be obtained for these recent deposits. IRSL ages ranging between 48±6 years and 1050±50 years are obtained from six samples, indicating that sediment accumulation has occurred at the two sites during the last millennia, despite a falling trend in relative sea-level in Whanganui Inlet and a stable relative sea-level at Parengarenga Harbour.  相似文献   

18.
Thermoluminescence (TL) dating of pottery and infrared stimulated luminescence (IRSL) dating of sediments from early Neolithic layers at the Jiahu site, Henan Province, east-central China, have been achieved. The pottery TL ages range from 6800 (±450) to 8900 (±640) years and the sediment IRSL ages from 6750 (±760) to 8860 (±870) years confirming former 14C data. Both TL and IRSL ages agree well with each other. They reinforce the very early existence of a fully developed Neolithic civilization in central China, starting already in the first half of the 7th millennium BC and lasting about 2100 years. From these layers finds of bone flutes and Chinese characters have already been reported [X. Li, G. Harbottle, J. Zhang, C. Wang, The earliest writing? Sign use in the seventh millennium BC at Jiahu, Henan Province, China, Antiquity 77 (2003) 31–44; J. Zhang, G. Harbottle, C. Wang, Z. Kong, Oldest playable musical instruments found at Jiahu early Neolithic site in China, Nature 401 (1999) 366–368.] The Jiahu pottery of the 7th millennium BC belongs to the earliest in China and elsewhere.  相似文献   

19.
The Ramat Saharonim site, located in the central Negev desert, Israel, consists of four shrines in a shallow valley and 30 tumuli, aligned on two cuesta cliffs on the valley's sides. Previous assessments based on site surveys suggested a general chronological span from Late Neolithic period (ca. 5000–5500 BC) through the Early Bronze Age (third millennium BC). Excavations in one shrine and three tumuli revealed a well-constructed double wall at the shrine and seven primary adult burials in the three tumuli. Quartz from sediment samples post-dating the construction of the burials and shrine was dated by optically stimulated luminescence (OSL) using the single aliquot regenerative dose (SAR) protocol, and charcoal and leather samples were dated by 14C. The OSL results for a burial in one tumulus are 7500 ± 700 to 6000 ± 600 years. In a second tumulus, OSL ages of 2000 ± 200–1800 ± 170 years and a 14C age on leather of 390–200 BC (2340–2150 cal BP) imply that this burial is Nabatean and that the site was used also in the Hellenistic period. Two 14C ages on charcoal from the shrine give an age between 5280 and 4710 BC (7230–6660 cal BP). OSL single aliquot ages for sediment from the shrine are highly scattered and far too old (60,000 to 12,000 years). The unlikely old ages are due to insufficient resetting of the OSL signal of some of the quartz grains when sand was blown onto the site. Indeed, single grain measurements for six samples of sediment postdating the shrine show a very large range of grain ages, but with a distinct young population in all samples. Ages calculated from these young populations average 5400 ± 800, in better consistence with the 14C dates and confirming our supposition that only some of the transported grains were reset at the time of deposition. The combined OSL and 14C dating shows that the shrines and tumuli are contemporaneous and attributes the complex to the Late Neolithic. This has clear ramifications for our understanding of the period and the rise of desert pastoral societies.  相似文献   

20.
Quartz has been the main mineral used for optically stimulated luminescence (OSL) dating of sediments over the last decade. The quartz OSL signal, however, has been shown to saturate at relatively low doses of ~200–400 Gy, making it difficult to be used for dating beyond about 200 thou-sand years (ka), unless the environmental dose rate is low. The infrared stimulated luminescence (IRSL) from feldspars has been shown to continue to grow to higher dose levels than quartz OSL. The application of IRSL dating of feldspars, however, has long been hampered by the anomalous fading effect. Recent progress in understanding anomalous fading of the infrared stimulated luminescence (IRSL) signals in potassium-feldspar has led to the development of post-IR IRSL (pIRIR) protocols and also a multiple elevated temperature (MET) stimulation (MET-pIRIR) protocol. These procedures have raised the prospect of isolating a non-fading IRSL component for dating Quaternary deposits containing feldspars. In this study, we review the recent progress made on (1) overcoming anomalous fading of feldspar, and (2) the development of pIRIR dating techniques for feldspar. The potential and problems associated with these methods are discussed.  相似文献   

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