Ashes to ashes, charcoal to dust: micromorphological evidence for ash-induced disintegration of charcoal in Early Neolithic (LBK) soil features in Elsloo (The Netherlands)

Charcoal and other forms of charred organic material - an important part of the archaeological record - consist of benzenoids. Such components are unstable in basic or alkaline conditions. Since ashes are alkaline, this means that archaeological charcoal may have been disintegrated and lost if they were buried together with ashes, e.g. as in fireplaces. Ash may also cause clay translocation in decalcified loess because of the disaggregating effect of K⁺ ions in the soil solutions. We investigated the interplay of these two processes, using micromorphological samples from the Early Neolithic site at the Joannes Riviusstraat in Elsloo. Evidence for charcoal disintegration was found in the form of cavities in charcoal fragments, most commonly filled in with thick reddish limpid clay coatings. The combination of cavities and clay coatings are evidence for the disintegration of charcoal under the influence of ash. Ash may also have been instrumental in preserving small bone fragments in these decalcified well-drained loess soils. The evidence of ash-induced charcoal disintegration implies that charcoal preservation in the archaeological record is dependent on (1) whether or not is was buried alongside with ashes, and (2) on various soil characteristics that determine that determine how quickly the ash-derived alkalinity and potassium ions are leached.     

The use of reflectance values for the interpretation of natural and anthropogenic charcoal assemblages

Charcoal assemblages occur in both natural and archaeological settings. Cell wall reflectance values of charcoal in polished blocks under oil provide a proxy for temperature of formation. This paper aims to (1) determine whether wildfire charcoals and anthropological charcoals from various pyrotechnical activities can be distinguished using reflectance data and (2) establish if re-charring (i.e. use of charcoal fuel) can be recognised in the archaeological record through analysis of laboratory-produced re-charred charcoals and charcoals from an experimental iron smelt and traditional bronze casting which utilised charcoal fuel. Reflectance frequency data from assemblages representing burning of charcoal, in this case of iron smelting and bronze casting, indicates temperatures from above the mean value of charcoal production (>475°C) up to the maximum temperature reached in the subsequent process (i.e. >475 to >1,100°C). In contrast, wildfire charcoals showed a range of values including material with barely measurable reflectance (minimum values from 0.06% to 0.56%Ro) to maximum reflectance values varying from 1.65%Ro (Tilford) to 3.8%Ro (Zacca). The mean wildfire reflectance indicated temperatures in the range 325–400°C, which can therefore clearly be distinguished from that of the charcoal burning processes. The laboratory-produced re-charred charcoals take on the reflectance value of the highest temperatures experienced; reflectance values were not constrained by the original temperature of formation. High temperatures are most easily achievable by the burning of charcoal fuel, and hence high reflectance charcoals are likely to represent re-charred charcoal. Therefore, this quantitative reflectance method can be used in archaeology to determine the minimum temperature of formation of charcoals in anthropological processes which involve fire, can indicate the likelihood of use of charcoal or wood as fuel and can distinguish between an assemblage of high temperature anthropogenic charcoals and charcoals formed from natural wildfire.     

Preservation of fungi in archaeological charcoal

During the analysis of wood charcoal remains from archaeological sites, it is common to find different microorganisms and different forms of degradation present in the plant tissue. However, one may encounter difficulties when attempting to identify these microorganisms and determine when their attack occurred. This paper focuses on preservation aspects related to the microorganisms in wood and demonstrates the structural changes that take place in different types of decayed wood after it was converted into charcoal. The study seeks to determine whether the microbial attack found in archaeological woods took place before the burning of the wood or after. Burning experiments were conducted using wood that had been decayed by various types of fungi including white-rot, brown-rot, and soft-rot. The laboratory burnt wood samples showed decay patterns that were comparable to those observed in archaeological charcoal samples, indicating that signs of fungal infestation and features of decay can be preserved after burning with micromorphological details of mycelium and cell wall attack evident. This indication may provide important information related to the gathering of deadwood as fuelwood. In addition, examples of decayed wood preserved in archaeological charcoal assemblages are described. Their relationship to the archaeological context and environmental conditions may suggest different interpretative models concerning wood management strategies applied by past societies.     

Preservation potential of charcoal in alkaline environments: an experimental approach and implications for the archaeological record

Charcoalified plant material (usually wood) has been described as being inert with a high preservation potential. Although usually black on both the outside and inside, the physical and chemical properties differ as a function of temperature and time of exposure to a heat source. Post-depositional processes however may exert additional affects on charcoalified material and introduce bias into the archaeological record. This work explores the influence of alkaline conditions, often encountered in the soil environment, on the preservation potential of charcoalified material. Charcoal, experimentally produced at different temperatures, was exposed to a number of solutions of potassium hydroxide and calcium hydroxide with different pHs, to simulate exposure to alkaline soil conditions. Under these conditions chemically mediated physical interactions occur resulting in fragmentation of the charcoal samples into (very) small pieces the size of which depends upon the initial temperature of charcoalification. Moreover further interactions result in a decrease in reflectance relative to samples not exposed to alkaline conditions. Although experimentally driven the potential for physical loss of charcoal from a particular site coupled with the reduction in (expected) reflectance of any resident material, has important implications for any conclusions drawn regarding the archaeological record.     

Dating Ancient Burial Mounds in Denmark – Revealing Problematic Ancient Charcoal

The National Museum of Denmark and the Department of Geography at the University of Copenhagen have collaborated on a project investigating burial mounds near early Medieval churches. The aim was to identify a possible continuity in cult sites across the shift to Christianity in the late Viking Age. Charcoal samples from 18 mounds were radiocarbon dated but the results showed they were far older than expected. Control dating undertaken on burial mounds of known age confirmed that charcoal in the mound fill can at least be up to 3000 years older than the mound itself. As charcoal can survive in the surface soil layer for millennia, in spite of ploughing, bioturbation and frost, it may also dominate the charcoal pool of the grass or heather turfs used in the mound construction. Therefore, the article concludes, charcoal cannot be used to securely date archaeological features built with turfs and it is important to be aware of the possible presence of very old charcoal when selecting material for dating archaeological features, even those which otherwise would be judged unaffected by material from earlier archaeological periods.     

Home Is Where the Hearth Is: Anthracological and Microstratigraphic Analyses of Pleistocene and Holocene Combustion Features,Riwi Cave (Kimberley,Western Australia)

The manipulation of fire is a technological act. The identification of the archaeological signatures of the controlled use of fire has important implications not only for the estimations of the origins and functions of the first fireplaces but also for our understanding of prehistoric technological development and resource use. At Riwi (Kimberley region, Western Australia), excavations over two field seasons have revealed a discontinuous occupation sequence over the past 45 ka, showing numerous, different combustion features interspersed within the deposit. Anthracological and micromorphological investigations at Riwi Cave indicate that the combustion features at the site can be categorised into three types: flat combustion features (type A), dug combustion features (type B) and thick accumulations of mixed combustion residues (type C). These provide evidence for two kinds of combustion practice: (i) fires lit directly on the ground and most likely not re-used and (ii) ground ovens, the latter appearing some 10,000 years after the first evidence for occupation of the site. A comparison of the wood species identified within these combustion features with those from equivalent scattered context levels, enables an exploration of the potential factors influencing wood selection and fire use through time at the site. A detailed understanding of the relationship between wood charcoal remains and archaeological context yields significant information on changes to environmental context and site occupation patterns over time.     

Fire and man in post-glacial woodlands of Eastern England

It has for long been suggested that English early post-glacial woodlands, particularly those dominated by hazel, were a fire-climax vegetation type. This conflicts with the evidence of fire frequency in present-day woodlands. Charcoal and pollen analyses of post-glacial lake sequences in East Anglia, England, suggest that early post-glacial woodlands were not fire-climax types. The pre-5000 BP charcoal record can be best interpreted as a record of intensity of occupation beside lake shores. After 5000 BP, charcoal deposition may reflect increasing use of fire as an agent in land clearance.     

Alkali extraction of archaeological and geological charcoal: evidence for diagenetic degradation and formation of humic acids

Charcoal forms a crucial source of archaeological and palaeoenvironmental data, providing a record of cultural activities, past climatic conditions and a means of chronological control via radiocarbon (¹⁴C) dating. Key to this is the perceived resistance of charcoal to post-depositional alteration, however recent research has highlighted the possibility for alteration and degradation of charcoal in the environment. An important aspect of such diagenesis is the potential for addition of exogenous “humic acids’ (HAs), to affect the accuracy of archaeological and palaeoenvironmental reconstructions based upon chemical analyses of HA-containing charcoal. However the release of significant quantities of HA from apparently pristine charcoals raises the question whether some HA could be derived via diagenetic alteration of charcoal itself. Here we address this question through comparison of freshly produced charcoal with samples from archaeological and geological sites exposed to environmental conditions for millennia using elemental (C/H/O) and isotopic (δ¹³C) measurements, Fourier Transform Infrared Spectroscopy (FTIR) and proton Liquid-State Nuclear Magnetic Resonance (¹H NMR). The results of analyses show that the presence of highly carboxylated and aromatic alkali-extractable HA in charcoal from depositional environments can often be attributable to the effects of post-depositional processes, and that these substances can represent the products of post-depositional diagenetic alteration in charcoal.     

Cooked Bones? Method and Practice for Identifying Bones Treated at Low Temperature

Is it possible to determine low‐temperature cooking in archaeological bones? The indirect exposure of bones to fire at low temperature (≤ 100 °C), linked to cooking, produces macroscopic modifications on these bones. These modifications have not been clearly or systematically described previously. Instead, physicochemical changes at nanometric level are only now beginning to be understood. In this paper, our principle aim is to explore new methods and techniques that correlate macroscopic features such as smoothness or light transparency with physicochemical characterization results that could aid towards detecting cooked bones in the archaeological record. This study then selected 11 archaeological samples, both human and non‐human. Bones were considered to be thermally treated or not, on the basis of macroscopic criteria. Complementary characterization techniques were used to study morphology (scanning electron microscopy and small angle X‐ray scattering), structure (X‐ray diffraction and transmission electron microscopy), local composition (energy‐dispersive X‐ray spectroscopy) and texture (gas adsorption). Indeed, fractal dimension, particle size, crystalline percentage or specific surface area may well explain some of the macroscopically observed modifications on these samples. The possibility that such apparent modifications may also be due to diagenesis is also considered. From an archaeological point of view, the results are promising. Our characterization of human and non‐human bones demonstrates that physicochemical techniques are complementary and provide good criteria against which to distinguish boiled from un‐boiled archaeological samples. Copyright © 2013 John Wiley & Sons, Ltd.     

Environment,cooking strategies and containers

This paper is an exercise in theory building that explores container form, function, and distribution. Using ethnographic data, environmental reconstructions, and archaeological information, containers are examined within the framework of the container complex, the group of containers used within a system. The results reveal a robust patterning between stone boiling and direct fire boiling and environmental thresholds. It also shows that container fabric used in these cooking strategies patterns by environmental variables. The results are models of the distribution of cooking strategies and the container fabrics used for cooking that can then be applied to the archaeological record.     

Geoarchaeological perspectives on paleolandscapes and regional subsurface archaeology

This paper explores geoarchaeological approaches to regional-scale research in dynamic landscapes. Landscape element, a spatial concept from landscape ecology, and the archaeological notion of place are integrated with geomorphological models of landscape evolution. A distributional or non-site approach to the subsurface archaeological record is argued to be most consist with a dynamic view of landscapes. Regional geomorphological studies are shown to be crucial, given the volume of sediment that needs to be searched, in developing efficient subsurface sampling strategies. Various subsurface recovery techniques are reviewed, including the potential use of microartifacts to increase the effectiveness of small bulk samples in sampling the buried archaeological record.     

Application of lipid biomarker analysis to evaluate the function of ‘slab-lined pits’ in Arctic Norway

Gas chromatography–mass spectrometry (GC–MS) and bulk carbon isotope determinations have been performed on samples (‘cemented organic residues’, charcoal, sediment and fire-cracked rock) excavated from 12 slab-lined pits from various locations in Arctic Norway to test the premise that these archaeological features were used for the extraction of oil from the blubber of marine mammals, such as seal, whale and walrus. A wide range of lipid compound classes were detected especially in the cemented organic residues and in the charcoal samples. The presence of long-chain unsaturated and isoprenoid fatty acids together with oxidation and thermal alteration products of unsaturated acids such as dicarboxylic acids, dihydroxyfatty acids and ω-(o-alkylphenyl)alkanoic acids suggests that these features were used for marine oil extraction at elevated temperatures. Notably the location of the hydroxyl groups in the dihydroxyfatty acids provides a record of the positional isomer of the precursor fatty acid and allows confirmation that 11-docosenoic (cetoleic) acid, the most abundant C_22:1 isomer in marine oil, was a major component of the original lipid. Further information was provided by the presence of long-chain fatty acyl moieties in surviving triacylglycerols and the presence of cholesterol. A fungal metabolite, mycose (trehalose), was found in all samples apart from a fire-cracked rock and points to microbiological activity in the pits. Bulk isotope analysis conducted on the ‘cemented organic residues’ is consistent with modern reference samples of blubber and oil from seal and whale. These data provide clear analytical evidence of the function of slab-lined pits in the archaeological record and suggest widespread exploitation of marine mammals for producing oil for heating, lighting and myriad other uses in the past.     

The black layer of Middle Palaeolithic combustion structures. Interpretation and archaeostratigraphic implications

Certain aspects of the formation processes of simple, flat archaeological combustion structures such as those present in the Middle Palaeolithic record remain unexplained. Such kind of combustion structures are commonly affected by postdepositional agents and often, their only distinct, well preserved component is a thin black lens on the ground. Hence, understanding the nature of this black lens is essential towards archaeological interpretation. From an interdisciplinary microstratigraphic approach, we present a case study in which for an entire experimental series of flat combustion structures the black layer represents the fire-altered topsoil on which the fire was made. Parallel analysis of archaeological Middle Palaeolithic combustion structures from the site of El Salt (Alicante, Spain) reveal similar patterns, leading to significant implications for archaeological interpretation. In the light of these results, special attention must be paid to the formation processes of flat Middle Palaeolithic combustion features, as black layers and the material contained in them are not necessarily linked with combustion but with preceding activities or events. In such cases, black layers represent intact remnants of occupation surfaces, concealing significant behavioural and palaeoenvironmental information relevant to the reconstruction of Middle Palaeolithic societies.     

The Role of Fire in the Life of an Adhesive

The use of fire is essential for the preparation of hafting adhesives; both are suggested to be a proxy for distinguishing the technological expertise and complex cognition among Palaeolithic populations. While use of fire has been argued to exist from about 1.0 Ma onwards, evidence for adhesives in the Palaeolithic record is rare and fragmented. In spite of the close link between fire places and adhesives, no study has ever focussed on examining the impact of heat on adhesive deposition and preservation. This paper discusses the results of a combustion experiment that was undertaken to understand the impact of heat exposure on hafting adhesives. The results have significant implications for archaeological interpretations. Deposition in or near a fire proves to severely impact the types of residues that preserve on a stone tool. The vertically transferred heat is responsible for the loss of adhesives but also for the incidental production of adhesives and their deposition on stone tools. It can be hypothesised that the rare survival of adhesives on archaeological stone tools might not only be the result of direct contact with the fire but also the result of degradation due to heat from overlying fireplaces. If we are to improve our understanding of the preservation of adhesives, it is important to unstand the taphonomic processes that affect these adhesives, in particular heat alteration.     

Middle pleistocene adaptations in Central Europe

The biological evolution documented in the fossil and archaeological record of Central Europe between about 700,000 and 100,000 years ago reflects the transition fromHomo erectus to the earliestHomo sapiens. These populations created different types of industries, ranging from assemblages of small artifacts and industries with simple pebble tools to standardized units such as the Evolved Acheulean and the Early Mousterian. The industries of the Last Interglacial (Taubachian) show some regression in technological standardization and a reappearance of small artifacts. Other aspects of cultural adaptation (settlements, dwellings, hunting activity, symbolic and aesthetic expressions) are also summarized. It is suggested that the impact of climate and climatic changes on human settlement and behavior was greater in Central Europe (where two glaciations advanced from both north and south) than in the Mediterranean and Western Europe. The general trend of cultural veolution was toward greater technological and social complexity, but its course was not unilinear.     

The application of forensic fire investigation techniques in the archaeological record

This paper seeks to assist in defining a role for a suite of adapted techniques of analysis and interpretation that are drawn primarily from the methods of contemporary forensic fire investigation. In so doing, the paper identifies a general paucity of literature providing detailed discussions of structural fires preserved in the archaeological record. In addition the paper provides a generalised account of the manner in which structural fires (most especially compartment fires, defined later) will tend to burn and which tools can assist in the interpretation of fire dynamics, the identification of points of origin of fire within buildings, and the response of building materials to burning. Ultimately, such an approach can improve understanding of past structures, and also provide an interpretative avenue for understanding human response to fire and the risk of structural fire in the past.     

Where are the dead of medieval battles? A preliminary survey

Abstract

Only a handful of mass graves from late medieval battles in Western Europe have been subject to large scale excavation to modern standards. The principal reason is that these, and indeed even early modern battlefield graves, have proven extremely elusive, most being identified by chance. Despite a few successes, no combination of prospecting techniques yet provides a consistently effective method of locating such small archaeological features set almost anywhere within a site covering many square kilometres. But this important resource should be explored and conserved for, as Towton has shown, much can be learnt through modern excavation and analysis of the remains. While this paper does consider the existing archaeological record, its primary focus and the starting point for almost any search for mass graves on a battlefield, has to be the documentary record. Using this evidence one must debate the number who actually died, how they were interred and commemorated and whether this varied according to status or allegiance, and where on the battlefield the graves might lie. One must also consider how often we will need to look further afield for the dead, for it is unclear how often the desire for appropriate Christian burial meant some or even most were interred in, or later moved to, consecrated ground.     

Feasting at Poverty Point with Poverty Point Objects

ABSTRACT

Attempts to account for the impressive and unusual archaeological record of the World Heritage site of Poverty Point have often faltered. The vast and diverse set of artifacts, the spectacular and well-designed earthworks, and the millions of baked-clay objects known as Poverty Point Objects are all distinctive and anomalous features of the site. This paper argues that the archaeological record of Poverty Point can best be explained as the product of periodic, ritualized feasting events. Drawing on diverse archaeological and anthropological studies of feasting I demonstrate that it is a useful research framework for understanding the site’s content because many of the archaeological signatures of feasting are present at Poverty Point. I argue furthermore that Poverty Point Objects were an integral component of this culture of feasting and offer hypotheses on their role in the feasts.     

Early Holocene land snail exploitation in northern spain: the case of La Fragua cave

Abstract

The question of the anthropic or natural origin of land snail deposits within the archaeological record is the subject of debate all over the world. In the Cantabrian region of northern Spain land snail middens are routinely identified in the early Holocene archaeological record. La Fragua Cave (Cantabria, Spain), which contains an early Holocene layer dated to 9600±140 BP (10,932±196 cal BP), offers the opportunity to address this debate through the examination of Cepaea nemoralis (Linnaeus) land snails recovered in direct association with mammal bones, charcoal, lithic artefacts and other materials. It is therefore believed that their presence at the site is clearly anthropic in origin. In addition, the exploitation patterns indicate an occasional collection and consumption of land snails, which confirms the complementary character of these resources in the diet of hunter-gatherers in Cantabrian Spain during the Pleistocene-Holocene transition.     

Spatial and temporal variety of prehistoric human settlement and its influencing factors in the upper Yellow River valley,Qinghai Province,China

We report an investigation of forty-two prehistoric sites in the upper Yellow River valley located in Guide, Jianzha, Hualong, Xunha and Minhe, Qinghai Province, China, including forty-four new radiocarbon dates from twenty-four sites, review published archaeological surveys and radiocarbon dates, analyze landform features and discuss the reasons for spatial and temporal variety of regional prehistoric human settlement. Our results suggest that people occupied the upper Yellow River valley during the early Holocene, but a continuous archaeological record begins only after about 5500 Cal yr BP. Thereafter, the intensity of prehistoric human settlement in the area is varied. Neolithic human settlement spread northwestward to high altitude areas of the upper Yellow River valley during early-mid Majiayao and Qijia periods, but moved southeastward to lower locations in the area during late Majiayao period. During the Bronze period, two coeval archaeological cultures, the Kayue and Xindian, occupied the upper Yellow River Region. Kayue archaeological sites are numerous and widely distributed in the high areas of the upper Yellow River, while Xindian sites are restricted to the lowest basin of the region. Variation in site density and location are likely the result of changing paleoclimate and technology.