Taxonomic characterisation of fresh Dipterocarpaceae resins by gas chromatography–mass spectrometry (GC–MS): providing clues for identification of unknown archaeological resins

Plant and particularly non-wood forest products have played an important role in the evolution of human cultures all over the world, as source of food but also of raw substances fulfilling material, spiritual, and medicinal requirements. Plant exudates and particularly dammar resins (Dipterocarpaceae family) were widely used in the past in Asia notably as waterproofing and caulking materials. This study focuses on the GC–MS chemical characterisation of freshly collected dammars and establishes new molecular parameters enabling discrimination between dammars and other types of plant resin, whatever their botanical origin. Such analyses provide clues for a precise identification (taxonomy, occurrence of other material in addition to the resin, alteration state) of unknown resinous material discovered in archaeological contexts. The value of our approach is illustrated by the taxonomic characterisation of two samples collected in jars from the Brunei wreck and a Chinese junk lost more than 40 km off the Sultanate of Brunei during the end of the fifteenth century or the early beginning of the sixteenth century.     

DISTINGUISHING AMBER AND COPAL CLASSES BY PROTON MAGNETIC RESONANCE SPECTROSCOPY

Fossilized resin, or amber, has been examined from 120 worldwide sources by 1D and 2D proton magnetic resonance spectroscopy in solution. These spectra fall into five categories, corresponding to the classes already established by mass spectrometry and carbon‐13 magnetic resonance spectroscopy. The wide availability of this technique provides a straightforward method to classify amber rapidly and inexpensively.     

Underwater Investigation on a Marble Cargo Wreck at Capo Bianco near Isola di Capo Rizzuto,Crotone, Italy

The cargo of marble blocks off Capo Bianco was dated to the Roman period. New sampling and analysis has identified Carrara marble, and also Rosso di Francia and Portargento, which strongly suggests a post‐medieval date. This leads to the suggestion that nearby finds dating between the second half of the 18th century and the first half of the 19th may come from the same ship, perhaps sailing from France and Liguria to deliver stone in southern Italy. This is rare evidence of the post‐medieval marble trade and demonstrates the importance of archaeometric analysis for the interpretation of wrecked cargos. © 2011 The Authors     

A cargo of lead ingots from a shipwreck off Ashkelon,Israel 11th–13th centuries AD

Shipwreck cargo of lead ingots, some marked, discovered off Tel Ashkelon, weighed about four tonnes. C14 analysis of charred wood from an ingot dated it to the 11th–13th centuries AD, Crusader times. Lead isotopic ratios provenanced the ingots to Mont‐Lozère, France. Various aspects of the lead trade are discussed, including: lead sources, extraction, casting, lead in the international maritime trade, weight units in medieval trade, prices, transportation, sale and storage, lead cargo and ballast, reconstruction of the wrecking event, salvage after the vessel was wrecked, Ashkelon as a trading coastal town in the 11th–13th centuries AD, and the possible destination of the cargo.     

A Late Bronze Age Shipwreck with a Metal Cargo from Hishuley Carmel,Israel

A 13th‐century‐BC shipwreck site, Hishuley Carmel, is described and discussed. It provides direct evidence for marine transport of copper and tin along the Israeli coast and may indicate inland and maritime trade‐routes of metals in the Mediterranean. The shipwreck represents a supply‐system providing the demand for bronze in the Levant. Trace‐elements and lead‐isotope analysis suggest that the copper came from Cyprus, similarly to bun and oxhide ingots from Uluburun. The source of the tin cannot yet be ascertained. The medium‐size ship was probably grounded and wrecked during a storm. Some of the cargo may have been salvaged in Antiquity. © 2012 The Authors     

A Late 17th‐Century Trade Cargo from Ponta do Leme Velho,Sal Island,Cape Verde

In 1973, while recovering copper cargo from a 20th‐century ship wrecked off the Ponta do Leme Velho on the south‐east side of Sal Island, Cape Verde, explosives revealed an earlier ship cargo with dozens of Portuguese faience plates and bowls, glass beads and metal objects, including buckles, ammunition and copper manillas. The assemblage, including the ceramics and a marked silver tastevin, provide a site date between 1680 and 1700. The research presented here is a result of collaboration between CPAS and the authors in 2008 to analyse this assemblage in the context of late 17th‐century maritime trade.     

THE AMBER OF EL DORADO: CLASS IB ARCHAEOLOGICAL AMBERS ASSOCIATED WITH LAGUNA GUATAVITA*

Laguna Guatavita, a crater‐like lake located in central Colombia, was used by pre‐Columbian Muisca people for a variety of socio‐religious ceremonies, many of which involved casting offerings into the lake. Of these, the installation of a new ‘king’ became the basis of the El Dorado myth that was carried back to Europe by 16th century conquistadores. In the present study, beads collected from Laguna Guatavita during a late 19th/early 20th century attempt to recover valuables from the lake bed, have been subjected to geochemical analysis. Results establish that these artefacts have been fabricated from Class Ib amber. Class Ib ambers have not previously been reported in either the geological or archaeological records of Central or South America, and their existence in this context implies that the Muisca people had access to a unique local or regional source of amber, knowledge of which has subsequently been lost.     

琥珀及其作伪

1.琥珀的成因及主要产地琥珀是树脂埋藏地层中日久逐渐石化而成的。树木在遭受昆虫钻咬,或枝干折断时,均会分泌胶质物,以保护创口。分泌的树胶逐渐聚集、凝结,经地质运动深埋土中,或是被海浪冲到岸边,随树木顺河流冲刷而下,最后滞聚于三角洲的浅洼处。     

AMBER FROM THE DOMINICAN REPUBLIC: ANALYSIS BY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

The carbon-13 NMR spectra of amber from several mining sites in the Dominican Republic show considerable variation. In certain cases the differences are sufficiently distinct to serve as a reliable indicator of provenance. The gradations within the resonances of unsaturated carbons may reflect the relative ages of the samples, because fossilization and diagenesis can remove this functionality.     

The 9th‐Century‐AD Belitung Wreck,Indonesia: analysis of a resin lump

The 9th‐century‐AD Belitung wreck was discovered in 1998 in the Java Sea. Construction techniques rapidly confirmed that it was unlike any known Chinese or Southeast Asian vessel. The uncertainty about its origins was resolved in 2008 by timber identifications: it was constructed in the Middle East (probably Oman or Yemen). This paper, on the characterization of a dammar resin lump collected in the vicinity of the wreck, supplies additional evidence confirming the probable re‐stitching of the vessel somewhere in Asia. © 2010 The Authors     

The Effect of Accelerated Alteration on the Discrimination between Baltic and Romanian Amber

Ten geological samples (five from each source—Romanian amber and Baltic amber) in duplicate for five different media (air, water, saline, acid and basic) were subjected to thermal alteration at 80 ± 2°C for 12 weeks, in the dark. The samples were analysed before and after the accelerated alteration experiment by Fourier transform infrared spectroscopy, both in transmittance and reflectance mode, and the acquired spectra were statistically processed by multivariate data analysis, mainly using principal component analysis. The results of the experiment are useful in giving a better picture of how to discriminate between archaeological amber artefacts.     

Local amber in a Palaeolithic context in Cantabrian Spain: the case of La Garma A

It is important to determine the geological sources of Palaeolithic ambers in the south of Europe in order to understand the mobility and interchanges of prehistoric societies. Fourier transform infrared (FTIR) spectroscopy analysis carried out on Upper Palaeolithic ambers from La Garma A cave (Cantabria, Northern Spain) allowed us to identify their source area. Their diagnostic features were found to be similar to the amber obtained in the Lower Cretaceous outcrops close to this archaeological site, and to differ clearly from Baltic amber, which has been generally suggested as the amber found in European prehistoric sites. These results show that the origin of the Gravettian amber found in La Garma A is local and, consequently, a hypothetical contact route is not required to be able to account for the presence of this material in the Iberian Palaeolithic context studied here. For the first time it has been demonstrated that the provenance of an archaeological amber in the Iberian Peninsula is local, with both geographical and spectroscopical evidences. Our study also concludes that the archaeological amber of La Garma A possibly belongs to an araucariacean resin that originated from the coniferous forests which grew in the northeast portion of the Iberian Plate c.110-million years ago.     

CHEMICAL CHARACTERIZATION OF ANCIENT MESOAMERICAN ‘COPAL’ RESINS: PRELIMINARY RESULTS*

So‐called ‘copal’ resins from nine Aztec/Mixtec turquoise mosaics have been subject to analysis by gas chromatography – mass spectrometry to examine their higher terpenoid composition with a view to botanical identification. Botanical specimens and modern commercial ‘copal’ resins were analysed for reference. A range of botanical sources for the resins was identified, including pine, Protium and possibly Bursera. The data reinforce the ambiguity in the use of the term ‘copal’ and demonstrate the need for further work on characterization of ancient Bursera resins.     

The Roman Ship 'punta Scifo d' and its Marble Cargo (Crotone,Italy)

In the first three centuries AD, large‐scale building projects, both in Rome and in the western colonies, stimulated the demand for marble from the eastern quarries. The Punta Scifo D shipwreck – discovered in 1986 in the Bay of Scifo, south of Crotone, Italy, and investigated in 2011 and 2013 by a team from the Università Ca' Foscari of Venice – is an important source for the reconstruction of this kind of trade in the Roman Empire. Studies of the cargo, dated to the third century AD, were the basis for the virtual reconstruction of a barge about 40 m long carrying a cargo of almost 340 tons. Petrographic and isotopic analyses demonstrated that it carried three different types of marble: mainly Proconnesian, some Pentelic, and one slab of Dokimean marble. The ship probably departed from the island of Marmara, and stopped at Ephesos, and perhaps also at Piraeus.     

The Port‐Vendres 4 Shipwreck Cargo: evidence of the Roman wine trade in the western Mediterranean

The Port‐Vendres 4 shipwreck is evidence of coastal export trade between Hispania Citerior and Narbonne in 40/30 BC. The cargo is made up of a particular assemblage of Roman wine amphoras (Pascual 1, Dressel 1B and Lamboglia 2) destined for Gallic markets. Archaeological and archaeometric analyses conducted on a selection of the amphoras allowed the provenance of the cargo to be identified as Hispania Citerior and the central‐southern Tyrrhenian coast of Italy. Iluro and/or Baetulo are proposed as the ports of departure, enabling the reconstruction of the trade route and the historical and economic significance of this shipwreck.     

The 4th‐Century‐BC Mazotos Shipwreck,Cyprus: a preliminary report

Since November 2007 an underwater project has been carried out by the Archaeological Research Unit of the University of Cyprus, in collaboration with the Department of Antiquities, at a shipwreck on the south coast, 14 miles south‐west of Larnaca. Its cargo consists mainly of Chian amphoras and has been provisionally dated to the 3rd quarter of the 4th century BC. The good state of preservation of the site gives an opportunity for studying amphora stowage and the wreck‐formation process. Moreover, it can shed new light on sea‐routes and trade between Cyprus and the Aegean during the late Classical period. © 2010 The Author     

Two Early Archaic Shipwrecks at Kekova Adası and Kepçe Burnu,Turkey

During its annual surveys of the Turkish coast in the 1970s and 1980s, the Institute of Nautical Archaeology discovered two early Archaic (7th‐ to early‐6th‐century BC) shipwrecks at Kekova Adas? (Antalya region) and Kepçe Burnu (Mu?la region); Dokuz Eylül University's Institute of Marine Science and Technology is currently involved in survey of the region. The wrecks, marked by a primary cargo of basket‐handle amphoras, indicate exchange between Cyprus and the cities of coastal Asia Minor and Corinth. Such Iron Age internationalism may have been driven by an interest in processed agricultural goods such as olive oil. © 2010 The Authors     

成都光华村街唐墓出土琥珀的红外分析

我国古代先民很早就意识到琥珀的装饰和药用价值,汉代开始从西域引入琥珀,唐代时琥珀已比较常见。我国古代琥珀多为进口琥珀,琥珀产地分析可以反映中外文化交流情况。国内仅对私人琥珀藏品进行过分析,考古出土琥珀的科技分析尚未见报道。本研究通过红外光谱分析,判定成都光华村街低阶官员唐墓出土红色饰品为琥珀;再与若干产地的琥珀开展红外光谱对比,鉴定其产地为波罗的海地区。琥珀经过丝绸之路到达蜀地并为低阶官员所使用,足见唐代琥珀制品的盛行及当时国际贸易文化交流的盛况。     

The Bakau wreck: an early example of Chinese shipping in Southeast Asia

Very few early Chinese shipwrecks have been discovered in Southeast Asia, despite the enormous volume of trade with China. This article describes the surprising hull features of one such wreck, and its diverse ceramic cargo. The Bakau Wreck dates to the early 15th century, and was bound from southern China to Indonesia via a Thai entrepot port.     

SCIENTIFIC INVESTIGATIONS OF ANTIQUE LACQUERS FROM A 17TH‐CENTURY JAPANESE ORNAMENTAL CABINET

A recent restoration of a 17th‐century Japanese lacquer cabinet revealed various later treatments over the original black coating to maintain and preserve the high gloss of the oriental cabinet over the course of time and to meet changing tastes. The comprehensive investigation on a series of coating samples was executed by means of two hyphenated techniques: gas chromatography – mass spectrometry (GC–MS) and pyrolysis combined with GC–MS (Py‐GC–MS). The results showed that the original lacquer is based on urushi and linseed oil, while the past interventions are composed of sandarac, shellac and dammar. Additional microscopic studies proved the multi‐layer structure of the lacquer and the use of different pigments.