PHYSICOCHEMICAL COMPOSITIONAL ANALYSIS OF CERAMICS: A CASE STUDY IN KENTING,TAIWAN*

The composition of ceramics does not just reflect the component of some specific, unprocessed, geological, raw material source, but also certain forms of human behaviour involved in its manufacture. The purpose of this research project is to apply the acid‐extraction chemical method, complemented by a thin‐section petrographic study, to the compositional analyses of certain local ceramic collections (mainly from several sites in the southern Taiwan area). The results present the raw materials that the ceramic manufacturers of the two cultural traditions (O‐laun‐pi Phase II and Phase III–IV), which overlapped temporally, used. These materials came from the same sources, but the ceramics were manufactured in different ways. Particularly, the people of O‐laun‐pi Phase III–IV also procured certain materials from either local sources or from somewhere in eastern Taiwan to make their pots. The results also indicate that there might have been a variation in terms of their manufacture among sites of the same cultural tradition.     

1500 Years of Pottery: Neutron Activation Analysis of Northern Chilean Domestic Ceramics from Caleta Vitor and Clay Samples from Nearby Valley,Coast and Highland Contexts

This paper presents the findings arising from neutron activation analysis (NAA) of northern Chilean domestic ceramic samples from Caleta Vitor (n = 38) and clay samples (n = 15) from nearby valley, coast and highland contexts. This study presents the first NAA data set of ceramics spanning a temporal period of 1500 years (c.2000 to c.476 bp ) from the Vitor Valley as well as the first attempt to use NAA to characterize potential clay sources in the region. On the basis of this study, we argue that the majority of domestic ceramics from Caleta Vitor share compositional similarities with clay samples collected from nearby valleys, allowing us to infer that the Caleta Vitor populations primarily procured their clay for domestic ceramics from local sources throughout a 1500‐year period. Thus, despite the fact that there were inter‐regional interactions during this period that included the influence of powerful Andean polities, it would appear that domestic ceramics continued to be produced locally, and by implication it can be argued that such interactions did not substantially affect this sphere of material culture production. Further, the apparent continuities in domestic ceramic production allow us to reflect on local decision‐making processes throughout the cultural phases considered in this research.     

A SPECTROSCOPIC INVESTIGATION OF PIGMENT AND CERAMIC SAMPLES FROM COPÁN,HONDURAS*

A combination of micro‐Raman spectroscopy, micro‐infrared spectroscopy and SEM–EDX was employed to characterize decorative pigments on Classic Maya ceramics from Copán, Honduras. Variation in red paint mixtures was correlated with changing ceramic types and improvements in process and firing techniques. We have confirmed the use of specular hematite on Coner ceramics by the difference in intensities of Raman bands. Different compositions of brown paint were correlated with imported and local wares. The carbon‐iron composition of the ceramic type, Surlo Brown, was confirmed. By combining micro‐Raman analysis with micro‐ATR infrared and SEM–EDX, we have achieved a more comprehensive characterization of the paint mixtures. These spectroscopic techniques can be used non‐destructively on raw samples as a rapid confirmation of ceramic type.     

Ceramics and change: an overview of pottery production techniques in northern South Africa and eastern Zimbabwe during the first and second millennium AD

In southern African Iron Age studies, there are few attempts to systematically apply and include laboratory analyses when studying archaeological ceramic materials. As demonstrated in this paper, such analyses help to understand the technological aspects such as raw materials, manufacturing techniques and vessel function. Combined with vessel shape and decoration as well as ethnographic studies, the results provide new ways to understand local and regional distribution networks of the ceramics craft. Furthermore, laboratory analyses are most useful when studying continuity and changes in the ceramics handicraft over time, which has implications both on cultural and social change as seen in the shift in ceramic production techniques. We use examples from Zimbabwe and South Africa to illustrate these changes and discuss them in a broader social and technological context in Iron Age southern Africa.     

Temporal Patterns in Ceramic Production in the Berbati Valley,Greece

Abstract

This research explores temporal patterns in the procurement of raw materials for ceramic production, based mainly on material recovered in regional survey. The underlying premise is that potters in different cultural phases will preferentially exploit the same geological landscape for the most suitable raw materials, but different materials may be preferred depending upon the potter's technological traditions. A program of petrographic and chemical analyses was carried out on ceramics from the Berbati-Limnes Archaeological Survey, Argolid, Greece. Ceramic fabrics from several cultural phases were studied and compared with patterns of settlement within the valley. The results show that ceramics from regional surveys can be used to identify broad patterns of change in exploitation of the same landscape. In some cases these patterns correlate with changes in settlement and may indicate that different choices in raw material procurement mark the arrival of potters from outside the valley.     

RELATIONSHIP BETWEEN THE COLORATION AND THE FIRING TECHNOLOGY USED TO PRODUCE SUSA GLAZED CERAMICS OF THE END OF THE NEOLITHIC PERIOD*

Ancient decorated potteries from Susa (Mesopotamia) dating from 4200 to 3700 bc , were studied in order to determine the origin and the nature of the raw materials used, and to identify the technological processes applied to make the ceramic bodies and their decorations. Bulk compositions were determined by particle induced X‐ray emission (PIXE), while the microstructure and the mineralogical phases were studied using scanning electron microscopy (SEM), energy dispersive X‐ray analyses (EDX) and X‐ray powder diffraction (XRD). The results showed that the raw materials used to elaborate these potteries were similar for all the ceramic bodies (carbonates and iron and magnesium‐rich clays containing sand), and for all the decorations (iron oxides, silica, potassic and alumina sources). The variations of coloration of the ceramics and of their decorations were due to different firing temperatures. The ranges of firing temperatures used by potters were evaluated on the basis of mineral stability domains.     

Application of electron microprobe analysis to identify the origin of ancient pottery production from the Castillo de Huarmey,Peru

A vast amount of ceramics (among other grave goods) were recovered from Castillo de Huarmey, a Wari culture (650–1050 ce ) archaeological site on the north coast of Peru. In order to assess ceramic production area(s) and possible trade, political or cultural interactions with other regions, and to complement earlier petrographic analysis, electron microprobe analysis (EMPA) was conducted following a rarely used methodology in archaeology. The chemical composition of individual minerals in ceramics and sediments samples from the Huarmey Valley was obtained, focusing mainly on amphiboles, feldspars and pyroxenes. The results of the analyses clearly indicate that the majority of the ceramic analysed was made of raw material of local origin.     

Mineralogical analysis and provenancing of ancient ceramics using automated SEM-EDS analysis (QEMSCAN®): a pilot study on LB I pottery from Akrotiri,Thera

A wide range of existing mineralogical and geochemical methodologies such as optical microscopy, X-ray diffraction, manual scanning electron microscopy, ICP-MS and INAA have been utilised in the analysis of ancient ceramics, in attempts to elucidate patterns of regional trade and interaction. However, advances in automated scanning electron microscopy with linked energy dispersive spectrometers (SEM-EDS) have created the potential to offer a seamless combination of textural and mineralogical data based on the acquisition of energy dispersive spectra that has so far been unattainable with existing techniques. In this pilot study on pottery from the Cycladic Bronze Age site of Akrotiri (Thera), we have quantified the mineralogy of the ceramics based on automated SEM-EDS using QEMSCAN^® technology and imaged the textures of the ceramics through compositional mapping. Thirteen samples were analysed and, based upon the automated analysis, four groups of ceramic compositions are defined. These data are consistent with, but also refine, previous traditional petrographic examination of the ceramic samples, and enable the likely provenance of the raw materials used in the ceramic manufacture to be identified. This technique allows the acquisition of fully quantitative data, not only for the larger inclusions within the ceramics but also for the typically finer-grained groundmass/matrix, whilst also providing the overall texture of the ceramic.     

COMPLEMENTARY COMPOSITIONAL ANALYSIS OF FORMATIVE PERIOD CERAMICS FROM THE TEOTIHUACAN VALLEY

During the Classic Period, Teotihuacan was an economic centre of central Mexico, but little is known about the development of this system. This paper presents a pilot study in multi‐method analysis of Formative Period (1500/1400 bc –ad 150) ceramics from the Teotihuacan Valley. Pottery was characterized by instrumental neutron activation analysis, laser ablation inductively coupled plasma mass spectrometry, thermal ionization mass spectrometry and petrography. It appears that most pottery was made from local raw materials that differ from later Postclassic materials. Some inter‐village interaction is suggested by stylistic choices, and one settlement had a group of ceramics made from unequivocally distinct raw materials. The study demonstrates how complementary methods can be used to draw greater anthropological meaning from compositional differences.     

Preliminary archaeometric study of the Neolithic pottery from the “Le Grottelline” site (Spinazzola, Italy)

The archaeological site of “Le Grottelline”, in the territory of Spinazzola, province of Bari (southern Italy), which dates back to the Early Neolithic Age, is located in the Bradanic Trough. Abundant ceramic material was recovered, which mainly belongs to the Culture of “Archaic-Impressed Pottery” and appears similar to that found in other Neolithic sites of the Murge area. The archaeologists recognized four ceramic classes: coarse, semi-depurated, depurated, and figulina. Fine ceramics can be red paint decorated. Aim of this work was a preliminary archaeometric characterization of the ceramic material from “Le Grottelline” in order to have information about the use of local raw materials and to address subsequent studies aimed to verify the relationships among the Neolithic cultures of the Murge area. The present study evidenced two typologies of ceramic body, characterized by calcium-rich and calcium-poor pastes, respectively, and two single samples. For the two groups of ceramics, a manufacture with local raw materials is assumed by using two types of clay: carbonate clays from “Subapennine Clays” formation and residual carbonate-free clays such as the well-known “red earths”. These two ceramic typologies are very similar to those reported for the near Neolithic site of Ciccotto, and it also located in the Bradanic Trough. For the two single samples, on the contrary, a manufacturing with “Alluvial Clays” and a provenance from the site of Pulo di Molfetta are supposed. The red painted decorations are aluminum- and iron-rich, while the content of calcium can be very different.     

The Source Provenance of Bronze Age and Roman pottery from Cyprus

Archaeological interpretations of ancient economies have been strengthened by chemical analyses of ceramics, which provide the clearest evidence for economic activity, and comprise both the objects of exchange and its means. Pottery is often manufactured from local materials, but its compositional diversity typically prevents significant patterns of resource utilization from being identified. Centrally located and positioned on traditional shipping routes, Cyprus maintained ties with and supplied a variety of distinctive ceramic products to the major commercial centres in the eastern Mediterranean throughout Antiquity. We analysed two Cypriot .ne wares and a variety of utilitarian pottery, as well as samples of extant Cypriot clays to determine source provenance. These chemical analyses provide an objective indication of the origins of ancient (Bronze Age and Roman) ceramics manufactured on Cyprus. The distribution of the probable clay sources and the links between pottery style and the material environment also afford a perspective on the spatial organization of large‐scale pottery production on the island. Compositional analysis provides the means to assemble geographies of pottery production and to unravel the interregional system of exchange that operated in Antiquity, but the ability to accomplish these tasks is predicated on systematic analyses of ceramic products and raw materials that are found far beyond the bounds of individual archaeological sites.     

INCISED SLIPWARE PRODUCTION AT CASTELFIORENTINO (FLORENCE): THE ‘VIA BERTINI’ SITE (15TH–17TH CENTURIES)*

This study deals with the physical–chemical and mineralogical–petrographic investigations (OM, SEM–EDS, EPMA, ICP, XRpD, Mössbauer and IR) conducted on first‐ and second‐firing wasters belonging to two types of incised slipware (sgraffito), manufactured at Castelfiorentino between the late 15th and the early 17th centuries. Raw materials, colouring agents and firing products were analysed in order to establish the production technology of the ceramic coatings, by means of detailed microtextural and chemical investigations. The pottery underwent two firing processes: the firing of the white slip‐coated ceramic body and a further firing after application of the glaze. The homogeneity of the raw materials, white slip and glaze is remarkable, and demonstrates the use of well‐established recipes with a constant supply of raw materials from the same places. Highly efficient kiln management during both firings is revealed by body–glaze interface reactions.     

The production and technology of glazed ceramics from the middle ages,found in the saepinum territory (Italy): a multimethodic approach*

A collection of ceramics from the Middle Ages found in Altilia and Terravecchia (the Saepinum area, Campobasso, Italy) were characterized by using different mineralogical analyses to investigate their provenance and production techniques. The body ceramic was investigated using Rietveld phase analysis of X‐ray powder diffraction patterns, X‐ray fluorescence spectrometry and scanning electron microscopy. The chemical compositions of the coatings were measured by scanning electron microscopy and their mineralogical compositions were determined using a particular technique of X‐ray small‐angle scattering (SAS) optimized for studies of thin films. Moreover, the material used for decoration was studied using micro‐Raman spectroscopy. The archaeometric results confirmed the distinction into two different ceramic classes, already individuated from archaeological analysis: the Altilia objects belong to the protomajolica class, whereas the objects from Terravecchia are RMR (ramina‐manganese‐red) ceramics. A comparison between the chemical and mineralogical compositions of good‐quality ceramic objects and those of waste products indicated local production of the ceramics. A sharp distinction was found in the chemical composition of the coatings: the Altilia products have tin‐opacified lead glazes, while the Terravecchia ones have transparent high‐lead glazes. Among the Altilia products, the unsuccessful process that produced a large quantity of discarded materials was attributed to the high lead content of the glazes. In fact, the principal advantage of the high lead content was to make the preparation and application of the glaze suspension easier, but the risk of reduction of lead oxide to metallic lead was greatly increased. Using micro‐Raman spectroscopy, the following minerals were identified as pigments: pyrolusite for the dark colour, malachite for green, lepidocrocite for yellow and hematite for red.     

STUDYING TECHNOLOGICAL PRACTICES AT A LOCAL LEVEL: NEUTRON ACTIVATION AND PETROGRAPHIC ANALYSES OF EARLY CERAMIC PERIOD POTTERY IN CENTRAL CHILE*

We discuss neutron activation and petrographic analyses of domestic ceramics and some raw materials from five archaeological sites in the Valdivia de Paine locality, in Central Chile. During the time period studied, the area was occupied by small‐scale horticultural groups with disperse and sedentary or semi‐sedentary settlement patterns. The analyses indicate that diverse local raw material sources were used in pottery production, and shared by members of different co‐residential units and between different cultural groups. The data indicate as many similarities as differences among the technological practices of pottery‐producing groups who lived in spatial proximity. The results have implications for the understanding of pottery‐producing communities at a local level, as well as small‐scale groups in general.     

Residential Mobility and Ceramic Exchange: Ethnography and Archaeological Implications

After the appearance of agriculture and subsequent increasing population densities and agricultural intensification, some mobile hunters, foragers, and part-time horticulturalists often obtained ceramic vessels from nearby villages. Mobile groups are firmly embedded within regional patterns of interaction and exchange. Certain regional interaction patterns encourage use of vessels made by a sedentary neighbor, and the factors that would discourage it are less significant than previously believed. The vessels made by neighboring agriculturalists may often be as well suited to the tasks and settlement pattern of mobile groups as vessels made by the mobile groups themselves. Given the probable frequency with which mobile groups discarded ceramics made by a neighboring group, archaeologists should consider this scenario when interpreting ceramic frequencies in remote small sites, where some ceramics may be far from the villages in which they were apparently made. Using an archaeological case study from the Western Papaguería of the US Southwest, I propose using vessel techno-function, along with other data, to place individual sites within a broader settlement system. The settlement system, rather than diagnostic ceramic types, may be most useful for assigning these sites to particular cultural traditions and for understanding patterns of landscape use.     

IBERIAN CERAMIC PRODUCTION FROM BASTI (BAZA,SPAIN): FIRST GEOCHEMICAL,MINERALOGICAL AND TEXTURAL CHARACTERIZATION

Ceramic fragments from the archaeological excavation of the Iberian–Roman city of Basti (Spain) were studied from a geochemical point of view and by applying a statistical tool to X‐ray fluorescence data to discover similarities between ceramic materials. The analysis of these samples was completed by performing a mineralogical analysis, textural observation, and by characterizing the porous system and the colour of the pieces. Our results enabled us to identify the source area of the clayey raw material in the surroundings of Basti and to estimate the firing temperature of the ceramics. Differences in the chemistry were confirmed by characteristics of the pastes and the mineralogical composition of the pieces. Some samples show black cores, which would suggest the presence of organic matter in the raw material and fast firing of the ceramics. The main types of temper were quartz grains and gneiss fragments, although carbonate grains were also identified. Our evidence suggests that most of the samples were well fired. New silicate phases were found to be present in several samples. The mercury intrusion porosimetry verified and confirmed the firing temperature of non‐carbonated samples. Colorimetry showed that the colour of the ceramics varied according to the amount of CaO that they contained.     

Long-term clay raw material selection and use in the region of Classical/Hellenistic to Early Byzantine Sagalassos (SW Turkey)

A provenance study was carried out on coarse ceramics from the Classical/Hellenistic to Mid-Byzantine city of Sagalassos, SW Turkey. The ceramics were sampled from the excavations of the city, and clay raw materials were sampled throughout its ancient territory. Used techniques were optical microscopy and electron microprobe analysis on thin sections, geochemical analysis (fusion ICP/MS and mineralogical analysis (X-ray diffraction). The geochemical/mineralogical diversity in the ceramics is not as wide as for the clay raw materials. It seems that even at the restricted scale of this study, the resources were limited to the area around the ancient site. The differences between the ceramics are likely due to the use of different ophiolitic clay bodies being exploited for their production.     

Two unique Byzantine immured lead-glazed relief ceramic icons and related tiles from the church of St Basil in Arta,Greece: investigation and interpretation of materials and techniques

St Basil’s late Byzantine church in Arta (NW Greece) is unique among other surviving churches of the same era as a result of two glazed relief ceramic icons and arrays of square glazed tiles that decorate its external wall. The latter decorative items were carefully examined by means of analytical techniques in order to reveal the materials and techniques used for their manufacture and thus interpret their connection to the contemporary Byzantine and Italian ceramics. Analytical results indicate that lead plus quartz suspensions were employed for the fabrication of the majority of the glazes in the spirit of recipes for Italian Archaic majolica pottery, and thus they are differentiated from the common contemporary Byzantine products. Nonetheless, the raw materials used in the Arta area ceramics deviate substantially from those used in the Italian products and, possibly, a local (NW Greece) production is reflected. The unexpected rather rich variety of raw materials and/or techniques that underlies the visual uniformity of the glazed material in consideration might reflect selection of the best products generated upon experimentation with various contemporary technical alternatives. Finally, the decorative arrangement of the glazed items that we see today might reflect a way to circumventing original objections to the ceramic icon innovation.     

A Comparative Study of the Early High‐Fired Ceramic Shards from Dongtiaoxi,Zhejiang (China)

There is a generally accepted view that there is an obvious distinction between proto‐porcelain and stamped stoneware. However, some early shards unearthed from the Dongtiaoxi region (northern Zhejiang) inspire people to rediscuss the relationship between them, because it is difficult to identify them as proto‐porcelain or stamped stoneware. In this work, we have collected samples from three of the earliest kiln sites (Piaoshan, Beijiashan and Nanshan) in the Dongtiaoxi region. We have analysed the chemical composition, firing temperature and phase composition of the samples. Comparing samples from the three kiln sites, we find that, from Piaoshan and Beijiashan to Nanshan, there has been progression in the manufacturing technology. The Shang proto‐porcelain and the stamped stoneware from Nanshan have similar raw materials, firing temperatures and body phase compositions—and they have obviously different decorative appearances, such as glazing or stamping. For ceramics from Piaoshan and Beijiashan, there is no clear distinction between glazed and unglazed samples. We believe that in the Dongtiaoxi region, the difference in the decoration between proto‐porcelain and stoneware became obvious up to the time of the Nanshan production but that, subsequently, two different paths for the development of high‐fired ceramics began to diverge.     

French Decorative Ceramics Mass‐Produced During and After the 17th Century: Chemical Analyses of the Glazes

Chemical analyses of a group of Pb silicate–glazed decorative objets d'art showing scenes of the French royal family (Louis XIII and Henri IV), and biblical and classical figures, have been analysed and compared with other similar heritage ceramics and with the rustiques figulines of Bernard Palissy (1510–90) and his followers and imitators. In particular, non‐destructive ion‐beam chemical analyses (PIXE and PIGE) have been performed on 11 ceramic artefacts from the Cleveland Museum of Art (CMA) and a like number from several French museums; results for 13 objects are described in detail in this paper. SEM–EDX has been performed on chips (‘microsamples’) taken from small unobtrusive defective regions on the CMA ceramics. The results of the ion‐beam and SEM–EDX techniques are in good agreement. All the decorative ceramics included uniform non‐opacified glazes. None of these objects can be of 16th century production; all must date from the 17th to the 19th centuries.