中国传统灰土灰浆强度增强方法研究

中国传统灰土灰浆中水硬性凝胶材料-水合硅酸钙和水合硅酸铝的形成可以大幅度提高其强度,但在自然条件下生成此类水硬性化合物需要很长时间。本文借鉴现代水泥工艺中利用焙烧黏土材料可提高火山灰活性的原理,从而有效缩短形成水硬性化合物的反应时间,在短时间内大大提高灰浆的强度。以此为出发点,加工制备性能优良的灰浆材料,为传统砌体建筑的保护提供适宜的保护修复材料。     

Rubble Stone Masonry Walls Strengthened by Three-Dimensional Steel Ties and Textile-Reinforced Mortar Render,Under Compression and Shear Loads

This article addresses the results of a structural strengthening solution for rubble stone masonry walls. The strengthening includes inserting three-dimensional steel ties across the thickness of the walls and a 30-mm layer of air-lime and cement mortar render reinforced with glass fiber mesh (textile-reinforced mortar), on both sides of the wall. The strengthening solution was found to be efficient for rehabilitating ancient rubble stone masonry walls due to the “three-dimensional” confinement, provided by the steel wires, by offsetting the low cohesive capacity of the mortar used in the walls and thus improving the mechanical resistance and delaying the collapse mechanisms. This study is part of an experimental research program carried out in Universidade Nova de Lisboa, to evaluate structural strengthening solutions for ancient rubble stone masonry buildings. To this end, three specimens of rubble stone masonry walls without strengthening (unreinforced masonry) and other three, with the mentioned strengthening solution, were subjected to compression and shear load tests. Building materials were also tested in order to characterize physical, chemical and mechanical properties.     

水硬石灰在花山岩画加固保护中的应用研究

水硬石灰兼具石灰和水泥的优点,低收缩、耐盐、适中的抗压和抗折强度、水溶盐含量低,同时与传统的砖石建筑兼容性好,是一种天然、无污染、耐老化的无机材料。本工作针对花山岩画的开裂特点制订出相应的力学参数要求,配制出两种不同的水硬石灰砂浆,并对这两种砂浆的力学性能进行了分析。同时探讨了不同养护条件对水硬石灰砂浆拉拔强度的影响。现场试验结果说明,填补粘结材料可以提供一定的粘结强度,并且具有使用方便,污染小的特点,可用于花山岩画开裂岩体应急保护加固处理。     

Chemical and Microscopic Study of Masonry Mortar in Ancient Pagodas in East China

Ancient mortars played a crucial role in the construction of historical architectures due to their physical and chemical compatibility with traditional building materials such as stones and bricks. Therefore, the analysis and optimization of the ancient mortar formula are significant in the restoration and preservation of historical sites. In this work, 20 mortar samples selected from five ancient stone pagodas in Zhejiang Province, China, were analyzed. The results showed that mud, lime-soil mortar, lime-sand mortar, and lime-gypsum mortar were used as binders in these pagodas. The Ca(OH)₂/aggregate ratio ranging from 0.3 to 2.7 was usually used to prepare lime mortar. Protein and polysaccharide were also found in some samples.     

Archaeometric study of natural hydraulic mortars: the case of the Late Roman Villa dell’Oratorio (Florence,Italy)

This paper shows the results of a multidisciplinary study carried out on the mortars from the Late Roman Villa dell’Oratorio (fourth-sixth ad), an aristocratic mansion built in the lower Valdarno (Florence, Italy). Thirty-one bedding mortar and plaster samples were analysed through optical microscopy, thermogravimetric analysis, X-ray powder diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy for determining the chemical, mineralogical and petrographic characteristics, while their main physical properties were measured by geotechnical procedures. The collected data indicates that the analysed mortars are made up of very fine to coarse river sand aggregate mixed with white to yellowish-white natural hydraulic lime binder mainly consisting of mixtures of prevailing calcite and hydraulic compounds. With regard to the origin of the raw materials, the aggregates were recognized to be selected Arno river sands, and the binders are the burning product of a local marly limestone (ex Alberese). Therefore, the mortars of the Late Roman Villa dell’Oratorio are one of the first uses of natural hydraulic lime in the lower Valdarno.     

Effect of natural polymers from cissus glauca roxb on the mechanical and durability properties of hydraulic lime mortar

The tradition of using lime as a binder has been in practice over the centuries and is cited in the architectural feats of all kinds of civilizations. Besides the basic ingredients of lime, sand and water, organic admixtures were also mixed into the mortars to modify fresh and hardened state properties as well as to enhance its durability. The motivation of the present study was to develop a replacement of synthetic admixtures by the bio-admixtures. The plant extract of Cissus glauca Roxb (CGR) which is being used in ancient temples and monuments in Kerala has been tested as admixture in varying concentrations and fermentation periods in lime mortar mix. The admixture is polysaccharide rich and a moisturizing agent.

Tests were conducted to measure changes in microstructure of the mortar; fresh state properties such as setting time and workability, mechanical properties such as compressive strength and flexural strength. Also, physical characteristics of admixture modified mortars such as bulk density, porosity and water absorption were also determined. Morphological analysis using SEM with EDX, mineralogical analysis using XRD and organic analysis adopting FT- IR have been done to validate the results of mechanical and physical tests. Capillary water and salt absorption by suction and resistance to salt crystallization cycles were measured as an indicator of durability properties.

The admixture modified mortar resulted in increased mechanical properties and reduced water absorption. It also limits the capillary rise of water and salt intrusion through the hydrophobic nature. The admixture modified mortar have also offered better resistance against the damaging action of deteriorating salts such as sodium chloride and sodium sulphate crystallization cycles. Polysaccharides and proteins in the plant extract interact with the calcium hydroxide of slaked lime and forms complexes. Hence the, natural polymer has increased the durability of hydraulic lime mortars used for repair and it could be a natural alternative to synthetic admixture.     

Characterization of Hydraulic Lime Mortar Containing Opuntia ficus-indica as a Bio-Admixture for Restoration Applications

Many successful and long lasting structures that contain lime mortars are hydraulic in nature. Organic admixtures are added to lime mortar mix to modify their fresh and hardened state properties. The present work proposes plant extract as bio-admixture for repair mortar towards the protection of heritage structures. The effect of cactus extract on the properties of hydraulic lime mortar is studied. Mortar´s composition is selected with respect to the composition of historic mortars and modern restoration practice. Cactus extract was added to the lime sand mixture with varying concentrations (25%, 50%, 75%, and 100%) and with different fermentation periods of 0, 1, and 2 days The consistency and workability of modified mortar, mechanical behavior, water absorption, porosity, and water/salt absorption through capillary rise, salt crystallization have been studied. Micro structural properties of the resulting mortar have been evaluated by XRD and FT-IR to identify their mineralogical composition and morphology by SEM-EDX. It is observed that addition of 75% cactus extract with 1-day fermentation produces maximum positive effect on the strength and durability properties of lime mortar. It improves the mechanical characteristics, limits water and salt absorption by capillarity into mortar and also show resistance to salt crystallization cycles.     

On the Sexagenary Cycle of the Tibetans

This study examines Zuozhuan narrative accounts that conclude with evaluations ascribed to the “Gentleman” (junzi 君子). The Zuozhuan is one of the earliest extant Chinese works of narrative history, and in the past many scholars assumed that narrative accounts formed its core, dismissing subjective evaluations of those accounts, such as the Gentleman's comments, as secondary, later additions. This study demonstrates that narrative account plus Gentleman judgment function together as a unit, contending that these units were likely introduced into the Zuozhuan as such. It further proposes that the perception that the Gentleman's concluding comments were later, independent additions was likely influenced by the practice of capping narrative accounts with quotations borrowed from other sources, and furthermore, suggests that this perception may have led compilers on occasion to insert material between the narrative accounts and the Gentleman's evaluations of them.     

A SCIENTIFIC INVESTIGATION ON THE PROVENANCE AND TECHNOLOGY OF A BLACK‐FIGURE AMPHORA ATTRIBUTED TO THE PRIAM GROUP*

The restoration of a Greek black‐figure amphora provided an opportunity to study the provenance and production technology of the vase. The composition of the ceramic body, determined by inductively coupled plasma optical emission spectroscopy (ICP–OES), matches that of Attic products. Investigation by X‐ray diffraction and reflectance spectroscopy suggests a maximum firing temperature around 900°C and a body re‐oxidation temperature around 800°C, respectively. The morphology and composition of black, red and dark red surface areas were studied by scanning electron microscopy and X‐ray energy‐dispersive analysis; the black areas show the features of a typical well‐vitrified black gloss, while the red areas were most probably obtained by simple burnishing of the body; the dark red additions, on the other hand, are the likely result of a partial re‐oxidation of a clay–ochre mixture.     

The Location of the Cement Industry of Eastern Siberia Within the Long-Term Future

The present location of the East Siberian cement industry is irrational because it does not correspond to the location of its markets, depends heavily on raw-material hauls from other parts of the country, and does not supply the cement types needed within the East Siberian region. Because of a shortage of natural cement materials within the region, it is proposed that cement production be based on the utilization of by-products of other industries, such as alumina production.     

缅甸蒲甘佛塔表面灰浆成分研究——以苏拉牟尼佛塔为例

本研究以缅甸蒲甘苏拉牟尼佛塔为研究对象,使用光学显微镜、扫描电镜、能谱分析仪、X射线衍射仪和显微红外光谱仪等科学仪器,对佛塔后期修复灰浆、外墙灰浆和壁画地仗的主要组成成分进行了深入研究。通过有机添加物、钙含量和泥沙质量比试验,详细探究了灰浆的制作工艺。结合试验结果和当地走访调查,揭示了缅甸蒲甘灰塑的传统工艺和材料。研究结果显示,苏拉牟尼佛塔灰浆主要由石灰、砂砾和泥组成,同时含有淀粉和蛋白质等有机添加剂。缅甸蒲甘地区的佛塔灰浆与我国传统的复合灰浆在制作工艺上存在相似之处,但也呈现明显区别。通过对灰浆制作工艺和材料的研究,有助于理解缅甸文化的独特之处,促进跨文化交流,并为佛塔的修复和技术研究提供重要参考资料。     

Unstabilized and stabilized compressed earth blocks with partial incorporation of recycled aggregates

This article aims to characterize the physical, mechanical, and water-resistant behavior of unstabilized and stabilized compressed earth blocks (CEB) produced with partial incorporation of recycled fine aggregates from construction debris. The objective was to produce an alternative-earth construction material with lower embodied energy. To this end, different types of common CEB were covered, namely: unstabilized CEB; stabilized CEB with 8% cement; stabilized CEB with 4% cement and 4% lime. CEB were characterized in terms of density, thermal conductivity, compressive and tensile strength, water absorption, permeability, and resistance to water erosion from drip and spray tests. The influence of moisture content was also analyzed. Lime stabilization had little effect on the early age mechanical and durability behavior of CEB. Design coefficients are suggested for common cement-stabilized CEB under different environmental conditions. A minimum of 4% cement content was sufficient to produce water-resistant CEB with partial incorporation of recycled aggregates.     

以糯米灰浆为代表的中国传统有机-无机复合灰浆研究进展和新发现

在中国数千年的建筑实践中,已发现许多具有中国特色的创造,其中以糯米灰浆为代表的中国传统有机-无机复合灰浆就是其中的一类。本文综述了自2007年以来相关研究的进展,包括：针对传统灰浆中有机残留物的化学检测和免疫分析技术的创新发展;全国252处古建筑遗址的1149个灰浆样品的检测结果及解读;糯米灰浆和桐油灰浆等传统胶凝材料固化作用机理及效果的实验验证;糯米灰浆研究成果对世界的影响及在世界复合材料历史上的地位;最近在新石器时代“白灰面”中新发现的有机添加物及相关溯源;传统糯米灰浆的改良研究及在文物保护工程中的应用情况等。这一系列的探索性研究不仅可为古建筑保护提供材料和技术,也为弘扬中华文明提供了鲜活的案例。     

Qadhat—a comparative study of ancient and new lime mortar from the Marib province/Yemen

Qadhat is the name for a lime mortar in Southern Arabia. Its usage has a long tradition. This work describes physical and mineralogical properties of ancient, historical and new samples, which seem to have been produced the same way. XRD, thin sections and SEM analyses show the similarity of the material. It consists of aggregates of volcanic material that are rich in volcanic glass and lime as binder. The production process includes several hours of crushing the material, which produces fine-grained splinters of aggregates in the binder matrix and gives the mortar a high stability. A weathering test with sodium sulphate on different samples confirms that the stability of this mortar is the result of the production process.     

World Heritage policy on reconstruction: from exceptional case to conservation treatment

Abstract

International heritage doctrine and the Operational Guidelines (OG) for the Implementation of the World Heritage (WH) Convention discourage the reconstruction of cultural heritage. Only ‘exceptional circumstances’ justify this practice, namely armed conflicts and natural disasters. The UNESCO WH Committee recently expressed its support for the reconstruction of damaged WH properties in view of such circumstances and requested the development of new guidance to address this timely issue (Decisions: 39 COM 7 and 40 COM 7). Guidelines will be prepared and provided to the Committee accordingly (Decision: 41 COM 7). We can therefore foresee revisions and additions to Paragraph 86, which is currently the only guideline in the OG, deemed ‘inadequate’ by the Committee. This research paper brings into focus the status of reconstruction in WH policy formulation and takes a normative position. Drawing on document analysis and the most up-to-date studies, I argue that its status should formally shift from exceptional case ruled out a priori to conservation treatment ruled in. I encourage a fruitful international exchange of ideas among a broad interdisciplinary readership to contribute to policy-making. Readers who dispute my position, no less than those who support it, may come to see reconstruction in a different light.     

A Multidisciplinary Approach for the Archaeometric Study of Pozzolanic Aggregate in Roman Mortars: The Case of Villa dei Quintili (Rome,Italy)

This contribution focuses on the study of historical mortars from a Roman archaeological site known as Villa dei Quintili, a monumental villa located in the south‐eastern part of Rome (Italy). The study was carried out on 38 mortar samples, collected from several edifices within the complex. A multi‐analytical approach, including polarized optical microscopy, scanning electron microscopy coupled with energy‐dispersive system and laser ablation inductively coupled plasma mass spectrometry, was used to analyse the pozzolanic material used for the preparation of mortars. Data obtained on both major and trace elements were compared with the compositions of Pozzolana Rossa, Pozzolana Nera and Pozzolanella samples from the Alban Hills volcanic district, collected from a historic quarry nearby, as well as with literature data. The results of such a multidisciplinary approach allowed us to recognize the use of all three pozzolan types for the aggregate fraction of examined mortars from the Villa dei Quintili.     

Firing Techniques of the Impasti from the Protohistoric Site of Concordia Sagittaria (Venice)

⁵⁷Fe Mössbauer spectroscopy provided relevant information on the firing techniques employed in manufacturing concotto and coarse pottery, two types of fired clay mixtures (impasti) of the protohistoric settlement site of Concordia Sagittaria. The firing techniques of Concordia were reconstructed by comparing the Mössbauer patterns of the artefacts with those of the local raw clays fired in the laboratory. The concotto was produced in kilns by firing clay mixtures under oxidizing conditions at 700–1000°C, or at lower temperatures in the open air. The firing of these clay mixtures containing mainly ground pieces of waste pottery, resulted in hard and variously coloured construction materials, particularly suitable for humid environments. In turn, the coarse pottery was produced by firing clay mixtures more homogeneous than those used for the artefacts of concotto. The firing of coarse pottery was performed under reducing conditions at about 900°C with a final exposure to air by opening the hot kiln. Light and agreeable coarse pottery, with a red surface on the grey-black core, was obtained when the effective temperature of air was higher than 500°C.     

Characterization of ancient building lime mortars of Anhui province,China: A multi-analytical approach

The characterization of lime mortars has become of primary importance in order to obtain information about the raw ingredients and building technology of ancient masonry structures. Five different samples from Anhui province, China, representing two types of lime mortar-based materials: joint mortars between the bricks of the city wall and lime mortar sealing a tomb coffin, were collected for analysis. Archaeological information about the samples was reported and studies into the microtextural features and mineralogical compositions of those mortars were performed via a multi-analytical approach. The joint lime mortars between the bricks of city walls, including Mingzhongdu city wall, Mingzhongdu Xihua gate foundation, Zhengyangguan city wall and She county city wall, were found to be aerial lime mortars. The lime mortar from Nanling Tieguai Song dynasty tomb was analysed and found to be a pozzolanic mortar consisting of lime, clay, sand and cocciopesto-like materials. The analytical results serve as a critical reference for the maintenance and restoration of ancient city walls in Anhui province, and as a starting point for searching for ancient Chinese pozzolanic mortars and technology for making those mortars.     

THE DETERMINATION OF BRICK PROVENANCE AND TECHNOLOGY USING ANALYTICAL TECHNIQUES FROM THE PHYSICAL SCIENCES*†

This work applies established analytical techniques from the physical sciences to Irish brick, in order to gather evidence of ceramic technologies, provenance and sources of raw materials. Petrographic microscopy, X‐ray diffractometry and scanning electron microscopy with an energy‐dispersive X‐ray diffraction attachment were used to study the brick of Rathfarham Castle, Dublin, built c. 1618, where clay brick was introduced in 1771. Local clay was fired in the laboratory and analysed in a similar manner. The petrography of the pointing mortar was studied in order to gather evidence of ceramic provenance. This paper concludes that the brick was hand‐ moulded with a silica‐based, predominantly non‐calcareous clay of glacial origin, gathered locally, including fluxes and a high percentage of non‐plastic material. The mineralogy and petrography of the brick, together with the presence of pebbles and a coarse matrix, suggest that the raw clay was probably gathered from a glacial deposit. The presence of abundant pebbles and colour inhomogeneities suggests a lack of processing of the raw clay. The brick was probably fired in clamps at top firing temperatures ranging from 750°C to above 900°C. Transformation of limestone temper involving the breakdown of calcite and the generation of calcium silicates, and the new formation of plagioclase, high‐temperature quartz, hematite and spinel were revealed. The presence of spinel in ‘hot spots’ indicates that fuel was added to the raw clay in order to assist firing.     

Cementation and the hydromechanical behavior of siliciclastic aquifers and reservoirs

Progressive cementation and lithification significantly influence the mechanical and hydrologic properties of granular porous media through elastic stiffening and permeability reduction. We use published data that quantify the effect of grain‐bridging cement distribution in granular porous media at the grain scale to investigate the influence of variable cement content on the competing roles of hydrologic and mechanical effects on fluid flow and deformation at the reservoir scale. The impact of quartz overgrowths in natural samples was quantified using a bond‐to‐grain ratio, allowing a geologically meaningful interpretation of percent cement in conceptual models of quartz cementation. An increase in the bond‐to‐grain ratio from 1 to 2.2 (~1–15% cement by volume) results in a 1.4‐fold increase in Young's modulus and an ~1000‐fold decrease in permeability. The hydromechanical properties of a suite of variably cemented natural samples are used as input into two‐dimensional, kilometre‐scale, axially symmetric poroelastic models of an isotropic confined aquifer. Models isolating the hydrologic and mechanical effects of cementation indicate that the hydrologic properties dominate the overall mechanical response, controlling both the volume and magnitude of deformation. Incorporation of changes in hydrologic properties due to cementation is therefore essential to capturing the first‐order physics of coupled aquifer behavior.