The Belgammel Ram,a Hellenistic‐Roman Bronze Proembolion Found off the Coast of Libya: test analysis of function,date and metallurgy,with a digital reference archive

The Belgammel Ram was found off the coast of Libya in 1964, and examined during 2008–9. The following techniques were used: surface non‐contact digitizing using a laser scanner, reflectance transformation imaging using polynomial texture mapping and hemi‐spherical harmonics, digital photogrammetry with dense surface modelling, structured light optical scanning, and X‐ray fluorescence analysis. For internal structure the ram was examined by X‐radiography and 3‐D X‐ray tomography. Metallurgical composition was studied by micro‐drilling and subjecting the samples to scanning electron microscope X‐ray micro‐analysis, micro X‐ray fluorescence and X‐ray backscatter. The lead isotope composition was analysed. The alloy has average percentage composition Cu = 86.9, Sn = 6.3, Pb = 6.6, and Zn = < 0.10. The Belgammel Ram is probably a Hellenistic‐Roman proembolion from a small military vessel or tesseraria. The archived data are at the Faculty of Engineering and Environment, Engineering Sciences, Material Data Centre, University of Southampton ( muvis@soton.ac.uk ).     

Archaeometric Investigation of Medieval Pottery from Excavations at Novo Brdo,Serbia

Medieval pottery from excavations at Novo Brdo, Serbia, an important mining and trading centre during the 14th and 15th centuries, was investigated by a combination of optical microscopy, inductively coupled plasma – optical emission spectrometry, Fourier transform infrared, micro‐Raman and energy‐dispersive X‐ray fluorescence spectroscopy and X‐ray powder diffraction methods in order to determine its composition and firing temperature. The samples investigated were made of medium‐ to coarse‐grained, non‐calcareous clay, by a relatively well‐controlled firing procedure in an oxidizing atmosphere. The firing temperature was estimated to be 850–950°C. The similarity between the chemical composition of the investigated pottery and the local raw clay, combined with the outward appearance and the archaeological findings, indicate domestic production. The pottery is covered with the transparent lead‐rich glaze. Iron and copper were used as colourants.     

The composition of the copper alloys used by the Greek,etruscan and Roman civilisations: 2. The Archaic,Classical and Hellenistic Greeks

This paper is the second dealing with the composition of copper alloys used by the Greeks. About 500 analyses of Archaic, Classical and Hellenistic objects are published here pp. 117–123 together with comments upon the alloys used. The data are arranged chronologically within broad limits and further subdivided typologically. The techniques of sampling and analysis are discussed in depth in the first part of this project (Craddock, 1976).The development of casting technology is one of the principal features of bronze-working during this period. Our knowledge of Greek casting technology comes both from archaeological excavation and from a careful examination of the castings themselves. Evidence from these sources has been brought together here for the first time together with the comments of medieval, renaissance, and modern technical authors to attempt a coherent picture of the way the superb Greek bronzes were produced and adorned.It was during this period that the Greeks started using mercury gilding on copper and bronze; and the techniques and range of gilded metal are discussed.     

Neutron Activation Analysis of Metal Artefacts from the Moche Site,North Coast of Peru

Neutron activation analysis has been used to characterize 60 metal objects from the Moche site, of which four are associated with the Chimú Period, two with the Early Chimú Period and the others with various Moche IV contexts. Different types of utilitarian and non‐utilitarian objects were analysed to identify the metals present, and to investigate their chemical composition and their eventual source. The results clearly indicate the distinction between Chimú and Moche artefacts and confirm the generalized opinion that arsenic bronze was popular after ad 900. They also indicate that gilding copper objects with gold was already a common practice during the Moche era.     

The Evolution of Pre‐Islamic South Arabian Coinage: A Metallurgical Analysis of Coins Excavated In Sumhuram (Khor‐Rori,Sultanate of Oman)

The present paper deals with compositional and microstructural features of 26 pre‐Islamic, South Arabian coins recently unearthed during archaeological excavations. Most of the investigated coins come from Sumhuram (Khor Rori, southern Oman), and were minted by the Hadramawt kingdom (fourth century bc to third century ad ); only a few of them belong to the Himyarite kingdom's coinage (first to fourth centuries ad ). In addition, some coins of both the Hadramawt and the Himyarite kingdoms found at Qani' (B'ir ‘Ali, Republic of Yemen) have been analysed for comparison. Our main focus was to provide new hints towards the comprehension of the chronological evolution in South Arabian coinage in terms of both metal composition and minting techniques. In addition, some melting crucibles found at Sumhuram have been examined in an attempt to make a comparison with the coins’ composition and to test the hypothesis that they were used for minting operations.     

Potash - a key raw material of glass batch for Bohemian glasses from 14th-17th centuries?

The aim of this work is to verify or refute hypothesis of existence of basic/universal glass batch: quartz sand: potash: limestone, at a ratio of 2: 1: 1 used in Bohemian glass production since the middle ages onwards and to simulate the preparation of a potassium glass type with the composition used in medieval Bohemia. The chemical composition of Bohemian glass, which incorporated in the proposed glass batch for glassmaking on a laboratory scale, was evaluated by (a) findings directly related to glassmaking (samples from glasswork in Moldava dating back to the 15th century) and (b) information from publications.Experimentally produced glasses for the present paper were prepared from raw materials such as ash, leached ash, potash, limestone and quartz sand. The plant raw materials (spruce, beech and bracken ashes, raw and refined potash) were treated and prepared by methods similar to the production procedures used in the pre-industrial era.The main contrast was found in the CaO/K₂O weight ratio, which was determined in glasses that were characteristic of given periods. While this ratio was often below 1 in glasses of the 15th century, it reached values above 1 in glasses at the turn of the 16th-17th centuries. This result may indicate that the composition of the glass batch had changed.The results of the present study reject the current scholarly work dealing with glass batch composition during the 14th-17th centuries and confirm that glass produced in some Bohemian medieval glassworks could have been melted from a batch that included plant ash, making the use of limestone unnecessary. The traditional suggestion of the exact ratios of raw materials, often cited in historical literature, seems to be impossible. The glassmakers had to react to the variable composition of the raw materials, especially plant ash.     

A geochemical study of Roman to early Byzantine Glass from Sagalassos,South-west Turkey

The finding of glass chunks together with fuel ash slag and kiln fragments related to glass processing strongly suggests local secondary production (working) of glass at Sagalassos (SW Turkey) from imperial to early Byzantine times. Chemical evidence shows that different silica raw materials were used in imperial and early Byzantine times for blue and green glass found locally. Colourless glass shows no clear difference in chemical composition and hence in silica raw materials between late Roman and early Byzantine times. Locally found early Byzantine yellow-green glass and chunks correspond to the previously defined Byzantine HIMT glass type. The chemical composition of the glass chunks found, identical to that of the contemporary glass of the same colour, strongly indicates that these chunks were used for the manufacture of early Byzantine green, colourless and yellow-green glass at Sagalassos.The homogenous lead isotopic composition of the chronological groups of blue glass, suggests the use of two distinct but homogenous silica raw materials for the manufacture of this glass. In view of this homogeneity, it is likely that contemporary blue glass was produced at a single location. The linear trend of the heterogeneous lead isotopic composition of the green and colourless glass is a strong indication of recycling effects in the glass composition. The end members of this trend are formed by the isotopic composition of the blue glass on the one hand, and of the yellow-green (HIMT) glass on the other hand. The heterogeneous lead isotopic composition of the yellow-green glass at Sagalassos is probably the result of recycling of this glass, reflecting mixtures of the original lead isotopic signatures of the broken glass and the original HIMT glass chunks.It should be noted that the two main raw materials for primary glass production (silica and soda) were available on the territory of Sagalassos. Moreover, the lead isotopic composition of quartz pebbles sampled from the artisanal quarter of Sagalassos, is similar to that of the local blue glass.     

Estimates of Historical Tree Densities in the North Lachlan River Catchment,New South Wales,Australia

Vegetation structure and composition during the pre‐ and early‐European period in Australia is often proposed as a benchmark against which to measure the effects of modern landscape management practices. However, little quantifiable information exists for that historical period. One potential source of information is the land survey record, used in this study to provide estimates of tree densities that existed during the period 1870 to 1900 in part of central New South Wales. Estimates were obtained for 23 parishes in the north Lachlan River valley, between the towns of Condobolin and Tottenham. Densities were calculated from portion corner to nearest tree data obtained from historical survey plans, using the plotless, closest individual method. Densities ranged from 6.0 to 31.4 trees per hectare for parishes with enough data points for reliable calculation. These figures would account for trees of a diameter large enough to be blazed with a survey mark. Any smaller trees would be additional and, although no quantitative data existed for this, qualitative evidence suggested that the figures obtained were more likely to be underestimates due to the presence of such small trees. The study area was predominantly covered by woodlands which varied in density across the landscape, in comparison to the modern landscape where much of the native vegetation has been cleared for agriculture. Although the tree density figures should be considered to be indicative rather than precise, they provide quantifiable historical figures for past conditions in an area where the historical record is otherwise sparse. Such information is valuable for interpreting ecological changes brought about by modern land management.     

Chemical characterisation and manufacturing technology of late Roman to early Byzantine glass from Beit Ras/Capitolias,Northern Jordan

The finding of considerable collections of glass artefacts, together with considerable lumps of glass chunks, fuel ash slag and kiln fragments related to glass processing strongly suggests a local secondary production (working) of glass at the Beit Ras/Capitolias archaeological site in northern Jordan from the late Roman to the early Byzantine period. The chemical analysis of ancient glasses can provide important information regarding the manufacturing technology of the glass made during a specific period. The aim of this study is to characterise the chemical and technological aspects of late Roman to early Byzantine glasses excavated from this main archaeological site. Furthermore, the present paper aims to provide incontrovertible evidence that this site must be considered as a major centre for the secondary production of glass during a period between the 3rd and the 6th centuries. For this purpose, a considerable group of raw glass chunks and vessel fragments of different colours and typologies were collected. The results of chemical analyses indicated that the glass did not show a clear difference in chemical composition between late Roman and early Byzantine times. All the glasses (artefacts and chunks) are of the soda-lime-silica type and correspond to the previously defined Levantine I glass group. The chemical composition of the glass chunks, identical to that of contemporary glass of the same colour, strongly suggests that these chunks were used for the manufacture of late Roman to early Byzantine glass at Beit Ras. The observation of technological features indicates that glass chunks were produced in massive tank furnaces in other primary production centres elsewhere, and were meant for local reworking. According to the microscopic examination, it can also be observed that mould-blowing was the main technique used for forming glass.     

A Provenance Study of Early Bronze Age Artefacts Found in Asturias (Spain) by Means of Metal Impurities and Lead,Copper and Antimony Isotopic Compositions

We describe here the first combined isotopic and impurities study on 27 copper artefacts found in the north‐west of Spain. This study follows previous studies on the lead isotopic composition of copper ores in three local mines that were exploited during the Bronze Age. The levels of impurities found were clearly different from ingots and axes, with ingots having much higher levels of impurities. It was not possible to differentiate the origin of the artefacts only by the impurities present. On the other hand, the lead isotopic composition indicated that all artefacts were prepared from local ores, the ‘La Profunda’ mine being the most probable source for most artefacts that carried out a clear radiogenic lead signature. The copper isotopic composition seemed to be able to differentiate artefacts from the ‘El Aramo’ mine from those from the ‘El Milagro’ and ‘La Profunda’ mines. On the other hand, the antimony isotopic signature was not useful for source allocation.     

THE EVOLUTION OF LUSTRE CERAMICS FROM MANISES (VALENCIA,SPAIN) BETWEEN THE 14TH AND 18TH CENTURIES

A set of 33 fragments of lustre‐decorated ceramics uncovered during an archaeological excavation in Manises (Valencia, Spain) have been studied. These ceramics were produced in Manises from the 14th to the 18th century. This well‐dated set of ceramic shards represents the diversity of Manises lustre production and is a complete time sequence of reference for the technological analysis. Texture analysis of the glazes has been carried out by SEM–EDAX, the inner and outer surfaces of the lustre decorations being analysed with non‐destructive ion beams by PIXE and RBS, and also by high‐resolution electron microscopy. The results are compared with other lustre productions and the time trend of the microstructures, glaze and lustre composition is analysed. It is concluded that Sn was used to opacify glazes until the beginning of the 17th century and that changes in the lustre microstructure occurred around ad 1500.     

ALUMINA AND CALCIUM OXIDE CONTENT OF GLASS FOUND IN WESTERN AND NORTHERN EUROPE, FIRST TO NINTH CENTURIES

Summary. The glass of Gallo-roman origin and that considered as coming from the several centuries after the disintegration of the Roman empire has much the same composition in examples found in northern and western Europe. The components calcium oxide and alumina (CaO and Al₂O₃) increase or decrease together. Compositional variation between different samples from this geographic area are not much greater than those at a single site of manufacture. Contamination during the manufacture process is unlikely to account for the CaO and Al₂O₃ contents in glass from this period according to analyses of glass adhering to crucibles or fusion pots. CaO and Al₂O₃ were apparently added intentionally to the glass composition. A slight tendency to an increase in these oxides is accompanied by a decrease in Na₂O content which might be due to a loss through volatilization during re-workings. Such a trend is apparent in the eighth to ninth century samples. The remarkably constant composition of glass found in a wide area for objects produced over a long period of time suggests that a limited number of production sites existed for either the raw materials or the confection of raw glass which was fashioned at various other sites.     

Mid‐Holocene Development of Mangrove Communities Featuring Rhizophoraceae and Geomorphic Change in the Richmond River Estuary,New South Wales,Australia

This paper describes the hitherto unreported occurrence of mid‐Holocene mangrove deposits in the Richmond River estuary, southeastern Australia, thereby providing evidence for changes in the distribution and composition of mangrove communities within a subtropical estuarine system during the Holocene. Stratigraphic, radiocarbon and palynological evidence indicates that widespread development of mangrove communities took place in the upstream reaches of the Richmond River estuary during the period 7000 to 6000 years BP. These communities maintained their habitat through substrate aggradation under the conditions of a moderate sea‐level rise, in contrast to other estuaries within the region, which generally experienced the submergence of intertidal substrates. Mangrove species belonging to the family Rhizophoraceae, most likely Bruguiera gymnorrhiza and Rhizophora stylosa, dominated these communities, in strong contrast to contemporary communities, which are dominated by Avicennia marina. Moreover, these mid‐Holocene communities were located a considerable distance upstream of the contemporary occurrences of Rhizophoraceae species within the estuary. The changes in the spatial distribution and composition of mangrove communities parallel the large‐scale evolution of the estuary driven by sea‐level variation. Shallow, buried Pleistocene terraces probably contributed to the regionally unique aggradational response of the mangrove communities and their substrates to a sea‐level rise during mid‐Holocene times.     

Determining the provenance of black limestone artifacts using petrography,isotopes and EPR techniques: the case of the monument of Bocco

This paper investigates the provenance of the black limestone of the monument known as Bocco, named after the king of Mauretania who presented Silla with this work as a sign of his submission to the power of Rome. A multi-method approach, comprising petrographic observations, carbon and oxygen isotope composition and electron paramagnetic resonance (EPR) spectra characteristics, was used for this purpose. The monument is part of a reconstruction of a rectangular base (approx. 8 × 2 m) which is likely to have served as the base for a bronze statuary group and is currently composed of six blocks of limestone whose exterior is engraved with a fine frieze. The results of the different analyses were compared with the data of a published database of the most important black limestone quarries exploited during Roman times in the Mediterranean area. The petrographic and physico-chemical parameters did not prove to be very effective in determining the provenance of the black limestone of Bocco; the isotopes result even raised some uncertainty as to whether all six blocks came from the same quarry, though this doubt was dispelled by the EPR data and, above all, by the evident petrographic similarity between them. Differences in the isotopic composition of the various blocks may be due to an in situ rock alteration process caused by interaction with an aqueous fluid. It was, however, impossible to determine with certainty the origin of the material of the stone artifact using the database available; it is possible that the black limestone of Bocco came from an ancient quarry that is likely to be located in north western Africa but has not yet been uncovered. An alternative hypothesis, according to which the limestone used for the monument of Bocco came from the ancient quarry of Ain el Ksir, one of the Tunisian quarries present in the database, is also discussed.     

EXAMINING CHILDHOOD DIETS AT KAMINALJUYU,GUATEMALA, THROUGH STABLE ISOTOPIC ANALYSIS OF SEQUENTIAL ENAMEL MICROSAMPLES*

Stable carbon and oxygen isotope ratios of tooth enamel provide a means to examine nutritional changes during childhood. To date, such studies have used large enamel samples, often spanning the developmental period of the tooth. This paper reports the results of small samples drilled from first molars and premolars of human teeth from Kaminaljuyu, a Classic period city in highland Guatemala. Carbon isotopes show considerable increase between cuspal and cervical enamel for both teeth, indicating an increase in maize consumption during childhood. Oxygen isotope trends are more variable, and suggest some seasonal fluctuation. While the oxygen isotope data confirm the identification of foreign skeletons among the samples, they illustrate a need for caution when sampling teeth due to variable δ¹⁸O composition of enamel within a tooth.     

Late horizon silver,copper, and tin from Machu Picchu,Peru

Analyses of silver–copper alloy artifacts from Machu Picchu show silver contents ranging from 24 to 81%. The tin present, ranging up to 3%, originated with the copper, perhaps from admixture of recycled bronze. The presence of 0.4–0.9% lead in the silver-rich phase indicates use of silver prepared by cupellation. All the objects had been forged after casting, some extensively. All have surface enhancement of the silver arising from depletion of the copper-rich phase. Some of the tin found at the site contains inclusions of hardhead (FeSn₂) and of a nickel–arsenic–copper compound. Forming trials with duplicate silver–copper alloys show that intermediate anneals at temperatures between 500 and 600 °C facilitate making thin sheet artifacts. Mechanical tests show that the most commonly used alloys, containing 25–30% silver, are particularly well adapted to forging because of their uniform work hardening during plastic deformation. Annealing of the laboratory-made alloys in air followed by boiling in salty weak acid creates a silver-rich surface layer comparable to that found in the artifacts. Depletion forms a dense silver surface on the alloy containing more silver than the eutectic composition, but a porous surface layer on the 25% silver alloys.     

Characterization and textural analysis of Middle Bronze Age Transdanubian inlaid wares of the Encrusted Pottery Culture,Hungary: a preliminary study

Inlaid ceramics belonging to the Encrusted Pottery Culture and dated to the Middle Bronze Age (2000–1500 BC) are highly distinctive vessels with complex decorative motifs found in large numbers in the Transdanubia region of Hungary. Despite this considerable corpus of material there has been little systematic investigation of the composition of the inlays. Micro-analysis of Transdanubian inlaid wares by X-ray diffraction (XRD), micro-Fourier transform infrared microscopy (FT-IR), and scanning electron microscopy (SEM) provides new compositional, structural and textural information on the inlays. In contrast to common statements in the literature regarding the materials used to make inlays, these new data show that the majority of inlays are composed of hydroxyapatite (bone) that was previously ashed, although some of the inlays are composed of calcium carbonate. Additional compositional and textural variation in the bone inlays suggests that bone material from different skeletal elements and/or of different age may have been used, and that contrasting recipes for inlay preparation were employed during fabrication. These results suggest that the production of inlaid vessels of the Encrusted Pottery Culture was more complex than has hitherto been thought.     

越王勾践剑菱形纹饰技术再讨论——与董亚巍、周卫荣、王昌燧先生商榷兼谈科技考古方法问题

本文简介了已完成科学检测与模拟试验的东周青铜剑菱形暗格纹的成分、组织与形成工艺,认为金属膏剂涂层加热扩散工艺是东周时期唯一的、完全可能实现的、使青铜表面富锡和细晶化的表面装饰工艺;认为菱形纹饰呈黑色是特定埋藏条件下形成的;解释了越王勾践剑未见铭文错金的原因。并就此与董亚巍、周卫荣、王昌燧等先生进行商榷。     

宝鸡益门出土玉器分析研究

使用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)对陕西宝鸡益门出土的玉器残块的显微结构、元素和物相组成进行了分析研究。结果表明,益门二号墓出土玉器分析样品属单斜闪石类型中的透闪石系,其透闪石含量在85%以上。出土玉器样品应归属为青玉种类,玉料较好,属中上水平的玉料。根据我国玉器文化的历史和和田玉的矿物特征,益门二号墓出土玉器分析样品类似于和田玉矿物。     

Iron isotope analysis of red and black pigments on pottery in Nasca,Peru

The Nasca culture of the south coast of Peru developed during the first millennium ad and is known internationally for its elaborately decorated polychrome pots. Despite decades of iconographic analysis, little is known about the more technological aspects of Nasca pigment production and application. We present results from a pilot study on iron isotopes as a potential line of inquiry into the differences between red and black pigments in Nasca pigments. As well, we conduct a small firing experiment to examine potential changes in isotope composition. Our analyses show three significant results. First, firing does not change the isotopic ratios of Fe in pigments. Second, red and black pigments show differences in their iron isotope composition, which relate to differences in the minerals used to make the different colors. Third, naturally available hematite samples show greater isotopic variation than pigment samples, suggesting that people selected a limited range of iron oxides to produce pigments.