Uranium-series age estimates for rock art in southwest China

We report the first uranium-series age estimates for rock art in China. Calcite bracketing a paint layer was used to constrain the age of a naturalistic outline hunter-gatherer painting in the Jinsha River area of northwest Yunnan Province (southwest China). The rock paintings in this region are unique in style and content compared with other bodies of rock art in China, which are dominated by Neolithic subject matter. The minimum and maximum ages were determined using isochron techniques on multiple samples of calcite from above and beneath the paint layer. A large painted deer head was dated to between 5738 and 2050 years. This painting and underlying flowstone are superimposed on older paintings that suggest the older paintings are at least 3400 years old, if not older than 5738 years. The results indicate for the first time that Jinsha River rock art is older than other forms of rock art in the region and show that rock art likely extends back to at least the transition from the Palaeolithic to Neolithic in this part of China.     

One Colour, (at Least) Two Minerals: A Study of Mulberry Rock Art Pigment and a Mulberry Pigment ‘Quarry’ from the Kimberley,Northern Australia

Distinctive mulberry paintings found in northern Australia, particularly those of the Kimberley region, have been argued to represent some of the oldest surviving rock art on the continent. Significant research efforts continue to focus on resolving the age of these motifs, but comparatively little attention has been given to understanding their physical composition and potential source(s). In a pilot investigation, we conclude that (at least) two mineralogically distinct mulberry pigments occur in Gwion motifs and demonstrate that their major components can be indicatively chemically differentiated, non‐invasively. Characterization of a ‘quarried’ mulberry ochre source demonstrates that these pigments occur locally as natural minerals.     

Digital Technology in Research and Documentation of Hunter-Gatherer Rock Art in South Africa

The use of digital technology to enhance and manipulate photographs of rock paintings affords researchers insights into imagery that was formerly invisible or obscure. Image enhancement and manipulation software have greatly increased the data set available for study. There is a wide range of techniques available in the digital repertoire, depending on the aim of the research. Here, three South African case studies are discussed in which hunter-gatherer rock paintings are enhanced and manipulated to create digital “tracings” using the computer programmes Adobe Lightroom, Adobe Photoshop and DStretch. The results obtained with these simple techniques are presented here, because they might prove useful for rock art research elsewhere in the world. It must be noted, however, that these technological developments do not eliminate the subjective nature of recording and interpreting rock art or the necessity of a theoretical framework in which to understand the imagery.     

THE ORIGIN AND GEOCHEMICAL CHARACTERIZATION OF RED OCHRES FROM THE TITO BUSTILLO AND MONTE CASTILLO CAVES (NORTHERN SPAIN)*

Ochres were the most common source materials for pigments used in Palaeolithic rock art paintings. This work analyses the petrographic and geochemical signatures of different ochre samples from outcrops inside Tito Bustillo Cave and the Monte Castillo Caves using the most common techniques (petrography, XRD, SEM–EDS and ICP–MS) in archaeological pigment characterization studies. The results obtained permit the identification and characterization of the different source ochre types and, furthermore, allow the establishment of mineralogical and geochemical proxies for the study of questions related to ochre characterization, formation processes and provenance.     

Testing recipes: an experimental approach to paint production processes in Levantine rock art (Spain)

Over more than a century, several proposals have been made on the composition and technical features of the pictorial recipes used by Levantine prehistoric painters. In this paper all these proposals are surveyed and tested through systematic experiments to determine the technical affordance of pigments and binders in different pictorial recipes. Experimental results were then used as independent analytical parameters employed as diagnostic criteria to systematically study an archaeological sample of nine sites located in the Maestrazgo region (Spain) and their surroundings. Results reveal that out of 112 experimental recipes, only 16 afforded the production of paintings technically similar to Levantine rock art.     

Revisiting the Parietal Art of Wonderwerk Cave,South Africa

Seen by all who visit Wonderwerk Cave, the rock paintings that adorn its walls have attracted less attention than many other aspects of the site. The paper gives a brief account of their history and significance and of factors that have constrained their study. Graffiti damage and restoration added layers through which researchers would need to delve in order to understand them archaeologically. Pointing to directions for future work, the paper concludes with discussion on a currently debated category of southern African rock art, the “non-entoptic” geometric rock art tradition, to which the Wonderwerk Cave rock paintings would belong. A shift in theoretical focus is advocated for comprehending local contingencies in the formation of rock art “traditions” rather than simply assuming the prior existence of such constructs.     

Weathering of rock art at two sites in the KwaZulu-Natal Drakensberg,southern Africa

Sediments of the Karoo Basin in southern Africa represent one of the world's finest laboratories for investigating sandstone weathering. The natural breakdown of these sandstones, most notably in the Clarens Formation, is destroying much of the indigenous rock art heritage that exists there. In an attempt to elucidate the operative weathering processes, a range of micro-climatic, rock temperature, rock moisture, rock chemistry, and rock property data have been monitored over a 15 year period at two sites in the KwaZulu-Natal Drakensberg. Results suggest that rock moisture regimes and to a lesser extent, rock thermal regimes exert the most damaging influence on San paintings. It is argued that granular disintegration and the enlargement of existing sandstone pores and bedding planes close to the rock surface, facilitate an increasingly dynamic moisture regime, which leads to an accelerating rate of weathering. Recent technological advances in data collection suggest that a re-evaluation of environmental controls may be necessary before weathering, at a scale appropriate to the deterioration of rock art, can be fully understood. The continued existence of indigenous rock art in southern Africa depends on investigations aimed at the development of techniques for its preservation.     

A multi-technique characterization and provenance study of the pigments used in San rock art, South Africa

During the course of a conservation project at the rock shelter known as RSA TYN2 (Eastern Cape, South Africa), a sample of 33 painted fragments that had become detached from the wall were collected. They have been studied using a multi-technique approach (optical microscopy, SEM-EDS, Raman spectroscopy and FTIR), with the aim of achieving a better understanding of their paint stratigraphy, composition, and provenance. The paintings are on a Clarens Formation sandstone and are embedded in calcium sulphates and oxalates. The red pigments show two different ‘hues’, corresponding to two different compositions. The light red is a red ochre, possibly pure, which is probably a degradation product of the Clarens Formation sandstone. The dark red contains more iron oxides and may be a mixture between the red ochre and pure haematite. Because of the presence of crystals which may be identified as augite we suggest this haematite came from the basaltic upper part of the Drakensberg, at least 4 km away from the rock shelter. The black pigments have been identified as carbon black, that is to say, incomplete combustion products of organic compounds, and are radiocarbon dated to between 2120 and 1890 cal BP, making these samples the oldest directly dated South African rock art.     

安徽博物院所藏7幅潘玉良油画矿物色料的组成分析

油画具有色料种类繁多、同一色系的颜料多样及对环境比较敏感等特性,加上颜料自身的风化作用,仅凭肉眼难以分辨。在修复性保护工作之前,对需要补色、补底处原色料的鉴定是一项基础性的工作,以便为修复时色料的选择提供依据。为此,本研究运用X射线衍射(XRD)、X射线荧光(XRF)等方法对7幅安徽博物院收藏的待修复的潘玉良油画矿物色料进行了物相及成分分析,讨论了补色修复时色料选择应注意的问题,以避免因色料粉之间不兼容(起化学反应)而对画作造成的二次伤害。     

红外光谱在传统年画红蓝色料分析中的应用研究

年画是中国特有的民间艺术形式。本研究介绍了传统年画印制所用红蓝色料的发展历史,选取15种中国古代与近现代常用红蓝色料进行红外光谱分析,并归纳总结了标准样品的化学结构与红外谱图特征。在此基础上,利用衰减全反射傅里叶变换红外光谱仪对三幅清末民初时期的传统年画开展无损检测。结果显示三幅年画的红蓝色料均为合成颜料或染料,包括酸性大红G、酸性墨水蓝G、普鲁士蓝等。本研究扩展了红外光谱在书画文物分析检测中的应用范围,为传统年画色料的无损鉴定提供科学依据。     

NON-DESTRUCTIVE ANALYSIS OF CHEMICAL ELEMENTS IN PAINTINGS AND ENAMELS

X-ray fluorescence analysis is a non-destructive method, very useful for qualitative and quantitative determination of chemical elements in paintings, frescoes, enamels, etc. Measurements have been carried out on ancient Persian mural painting allowing the identification of about ten different pigments. Furthermore, many oil paintings have been examined. For example, about thirty regions of different colour tonalities concerning the ‘Deposizione’by Raffaello Sanzio have been analysed; in this way it has been possible to determine the composition of several pigments used by the author and to identify some restored regions. The enamels of a ligneous Egyptian panel have also been studied; the results are in good agreement with those obtained using conventional methods.     

Rock Art Conservation and Tourism

Rock art conservation has developed hand-in-hand with the increased pace of tourism, yet the two activities tend to remain in opposing camps. Policies and guidelines have been developed for cultural heritage and cultural tourism and there is a widely accepted range of principles in place, but a theory of sustainable rock art tourism is only in its infancy. To mature, the discipline needs research into the interaction of key elements that affect the long-term conservation of frequently visited rock paintings and engravings in their original setting, as well as consideration of social and economic factors that drive tourism and the public interest in rock art.     

Rock surface luminescence dating of prehistoric rock art from central Iberia

Rock art paintings are notoriously difficult to date numerically. Recently, luminescence dating has been shown to provide reliable rock surface burial ages in various archaeological settings. Here we use the cross-cutting relationship between a fallen rock and two paintings of the Iberian Levantine (older) and Schematic (younger) styles to constrain the age of the paintings by dating the rockfall event using rock surface luminescence dating. Infrared-stimulated luminescence (IRSL) signals as a function of depth into the buried face of the talus border indicate that the IRSL signal measured at 50°C (IR₅₀) was sufficiently reset to a depth of about 1.6 mm prior to burial. An uncorrected IR₅₀ age of 1.6 ± 0.2 ka was calculated for the rockfall event by dividing the surface equivalent dose (D_e) by the total dose rate. This age was corrected using both conventional and field-to-laboratory saturation approaches to yield indistinguishable ages of 2.7 ± 0.5 and 2.9 ± 0.3 ka, respectively. Since the panel with Schematic art was first available to the artist after the rockfall, we conclude the Schematic rock art at Villar del Humo is younger than ~2.9 ka. The Levantine rock art was painted on a panel constrained by the talus boulder before detachment, and so it is likely to be older than ~2.9 ka.     

Acoustics and Levantine rock art: auditory perceptions in La Valltorta Gorge (Spain)

This article explores the relevance of acoustics as a factor for in the production and active use of Levantine rock art in Spain. The renowned rock art area of La Valltorta Gorge serves as a case study. Two experiments are described; the first assessed whether the sites with the most painted motifs had better acoustics than those with fewer motifs. The second tested which areas in La Valltorta Gorge had better acoustics and whether there was a difference between the acoustics of the decorated area and the contiguous sectors of the Gorge where no paintings have been found. In both experiments different sounds and pitches were used. The results suggest a strong relationship between the painted areas and the sonority of the place, with the major sites generally having provided the best results, with the exception of the sonority when facing the rock art panels. It is suggested that La Valltorta Gorge was chosen to be decorated with a view to increasing the perceptual impact of the rituals that may have been held at rock art sites due to the amplification caused by the echoing and resonance.     

First absolute dating of Andean hunter-gatherer rock art paintings from North Central Chile

We report the first absolute dating for rock paintings by Andean hunter-gatherer groups. Analysis by Raman spectrometry of remains of black paintings from the center-north of Chile (30° lat. S) allows for the identification of carbon as the raw material. Radiocarbon dating situates these paintings between 1623–1431 BCE and 80–240 ACE, dates that are supported by other lines of independent evidence. These results are consistent with proposals that suggest the appearance and popularization of rock art in various places in the Andes for the temporal transect of 3000–1000 BCE. Finally, these new datings are added to the scant corpus of absolute dates for rock art that exist in South America.     

Mid-Holocene age obtained for nested diamond pattern petroglyph in the Billasurgam Cave complex,Kurnool District,southern India

India has one of the world's largest and most significant bodies of rock paintings and engravings, yet not a single rock art site or image has been directly and accurately dated using radiometric techniques. Here we report on results from the Billasurgam Cave complex near Kurnool in southern India. Although this cave complex has been investigated archaeologically since the late 1800s, it was not until 2008 that a large petroglyph, consisting of the remains of three nested diamond designs on a stalactite, was noted. In order to determine if this petroglyph had been made recently, flowstone was sampled from on top of and below the engraving. Radiocarbon dating revealed a mid-Holocene age of about 5000 cal BP for the petroglyph, but we cannot rule out the possibility that the engraving is several centuries younger. Similar nested diamond designs at some rock painting sites and on a chert core elsewhere in India have been assumed to be Mesolithic. Our result is consistent with this hypothesis, although we note that it also consistent with the creation of the petroglyph in the early Neolithic. We conclude that the Billasurgam engraved diamond design was probably made by Mesolithic foragers of the Kurnool region and is the oldest surviving form of rock art yet directly dated in southern India.     

MULTIANALYTICAL STUDY OF PALAEOLITHIC REINDEER ANTLER. DISCOVERY OF ANTLER TRACES IN LASCAUX PIGMENTS BY TEM*

Palaeolithic and modern reindeer antler were analysed using complementary techniques to evaluate the conservation state of bone material. X‐ray diffraction, FT‐IR spectroscopy, scanning electron microscopy (SEM–EDX) and transmission electron microscopy (TEM–EDX) as well as proton induced X‐ray and γ‐ray emission (PIXE–PIGE) at the particle accelerator AGLAE, C2RMF were applied. This study enabled us to define the chemical and structural features of ancient antler at the micro‐ and nanometre scale and compare them to those of other bone materials such as bone and ivory. Antler is richer in its organic fraction compared to bone and ivory. Its mineral fraction, carbonated hydroxylapatite, shows very specific crystal shapes at the nanometre scale. This specific property allowed us to recognize antler traces in pigment samples originating from rock art paintings in the Lascaux cave, Dordogne, southwestern France, Magdalenian period. Therefore, TEM–EDX is the technique of choice for characterizing antler traces in complex mixtures. In the paint material of Lascaux, antler seems most likely to be a pollutant introduced either by stirring the pigments in water with a piece of antler or by carving antler artefacts next to the preparation of paint material. However, it could eventually be used as a marker of paintings that were created contemporaneously.     

Designing Digital Recording for Volunteers in Rock Art Surveys,Management Plans and Public Outreach in the Cederberg,South Africa

The rock art survey and recording project described in this paper was designed for volunteers and heritage professionals involved in locating and mapping the position of rock art and other archaeological sites in the field, recording basic details for conservation and management, and making these details accessible in digital format for researchers who might want to undertake further investigation. An OpenDataKit (ODK) App with a digital site recording form was designed for mobile phones to be used in the field and to send data directly to the digital inventory of the South African Heritage Resources Information System (SAHRIS). The inventory has accumulated over 3000 sites with Later Stone Age rock paintings in the mountainous terrain of the Cederberg, a region that includes properties in the serial Cape Floral Region World Heritage Site in the Western Cape Province. More than a third of these rock art sites have been added to the database since 2007 by the members of the South African Archaeological Society. The information forms the basis for rock art management plans that are given to property owners to guide them in maintaining the value of the rock art. Interpretation of the information has raised awareness of the significance of the rock art in its historical and landscape setting with a trail and information boards. Local residents and CapeNature staff, who have received training in rock art monitoring and tourist guiding, play a key role in implementing the management plans for CapeNature properties, and monitoring individual sites and trails. The broader international context of volunteer programmes for archaeological site recording suggests that this type of programme has the potential to raise awareness of rock art beyond books and visits to museums and public lectures.     

Characterization and origin of black and red Magdalenian pigments from Grottes de la Garenne (Vallée moyenne de la Creuse-France): a mineralogical and geochemical approach of the study of prehistorical paintings

Pigments sampled from wall paintings and from crayons taken on the floor, at the Grottes de la Garenne (Saint-Marcel – Indre, France) have been analyzed and characterized by infrared spectroscopy, Raman micro-spectroscopy, X-ray diffraction, ICP/MS and analytical TEM. The red pigment used for the wall paintings is mainly composed by hematite, clays, carbon matter and carbonates. Results on the red pigments show that the compositions of the paintings are similar to that of some crayons. Regarding these analyses, their origin is compatible with local siderolithic facieses. Analysis of black pigments shows that they are made of cryptomelane, pyrolusite, clays, carbonates and carbon matter. It shows also that paintings and some crayons compositions are compatible. On the contrary of red pigments, the origin of black pigments is probably allochtonous. Indeed, the traces of thallium detected in cryptomelane, the cerium anomaly and the absence of iron are not compatible with local facieses or other sites from the French Massif Central.