THE COMPOSITION OF IRON AGE STRUCK 'BRONZE'COINAGE IN EASTERN ENGLAND

EDXRF was used to analyse the composition of 88 Iron Age copper and copper alloy coins excavated from the site of a pre-Roman shrine and Roman temple at Harlow, Essex. Most of the coins are local to the Essex-Hertfordshire region, with a few of Kentish origin. The earliest struck base metal issues were struck from almost pure copper, but from the late first century BC, their composition shows more variety. Particularly interesting are a group of types belonging to the Romanizing phase of Tasciovanus'coinage, which were struck in brass and possibly represent a distinct denomination. Roman coinage and other metalwork imports from the Roman world presumably provided the initial impetus, and the ultimate source of the brass. However, this experiment was relatively short lived. Cunobelinus, who ruled eastern England during the earlier first century AD, mainly employed bronze to strike his abundant base metal coinage. The products of his Colchester mint reveal a consistently different composition from those struck at his unlocated second mint in the Hertfordshire area, although the precise alloy does vary, sometimes within the same type. This suggests that unlike gold and silver issues, the source and purity of the metal used for minting base metal coinage was not always critical.     

The coinage of ancient Hadramawt The Pre-Islamic coins in the al-Mukallâ Museum

The pre-Islamic coins in the al-Mukallâ Museum come principally from Shabwa, the capital of the kingdom of Hadramawt. The collection consists of 76 coins, three of which could not be identified because of their poor condition. Sixty-seven silver and bronze Hadrami coins; five silver and bronze Himyarite and Sabaean coins; and one gold Roman coin comprise the collection. This material provides a general overview of the coinage of the ancient Hadramawt, permitting us to distinguish the issues of certain individual Hadrami rulers.     

The image of authority in Carolingian coinage: the image of a ruler and Roman imperial tradition

This article examines the influence of Roman imperial symbols of authority on Carolingian coinage. During the brief period of a specific &1squo;renewal' in Carolingian coinage in the 810s, there was an evident turn to the Roman tradition of demonstrating authority. As a result, the image of a peace-making emperor on Roman coins during the late third to early fourth century was employed on Carolingian coins for the purpose of legitimizing the new imperial authority of the Carolingians. This image, however, was not long-lived and gradually disappeared in the 820s to 830s.     

AN ANALYSIS OF SOME THIRD-CENTURY ROMAN COINS FOR SURFACE SILVERING AND SILVER PERCENTAGE OF THEIR ALLOY CONTENT

The silver content within the body and at the surface of 22 Roman ‘bronze’coins dating to a.d. 274–305 was determined by X-ray fluorescence to discover whether these coins were silver dipped and/or issued with a deliberately added amount of silver in their alloy. Results of this analysis indicate that antoniniani and fractional coins of the period 274–294 were probably both silver dipped and minted in an argentiferous alloy. Radiate and laureate fractions issued after 295 do not seem to have had an argentiferous alloy, nor does this analysis provide any evidence that they were silverdipped.     

QUANTITATIVE ANALYSIS OF COPPER-TIN BRONZES BY MEANS OF GLOW DISCHARGE OPTICAL EMISSION SPECTROMETRY

Glow discharge optical emission spectrometry (GDOES) has been used for obtaining calibration curves for copper, tin, lead, silver, antimony, arsenic, zinc and iron from standards including copper-base alloys (Cu 61.33-99.95%) and from bronze Punic coins. The GDOES results were calibrated using atomic absorption spectroscopy with inductively coupled plasma atomization (ICPAAS) to analyse the standards and coins. For all these materials, the results show that via GDOES it is possible to obtain reliable and reproducible calibration curves for copper, tin, lead, zinc and iron with a linear behaviour as a function of the content. The quantitative GDOES and ICPAAS data for the coins have been also compared with those obtained via X-ray fluorescence (XRF) and it is shown that GDOES, ICPAAS and XRF agree well with one another considering that the bronze coins are inhomogeneous to some degree. As an example of GDOES analytical features, a depth concentration profile through a thin bronze patina is shown and briefly discussed.     

清代云南铜矿垄断经营利润的考察

清政府对云南铜矿实行高度垄断经营的政策,即以低于商品自由贸易市场数倍的价格收购矿铜,又以相对较高的价格将矿铜批发给各铸钱局,通过统购统销来赚取价差,获得了大量垄断利润"铜息"。低价矿铜用于铸钱,极大地降低了铸钱成本,各铸钱局获得了丰厚的"铸息"。不仅如此,各铸钱局利用商品货币市场铜钱价格的高昂,通过出售铜钱或搭放兵饷等途径,最大限度地扩大"铸息"。"铜息"是清政府对云南铜矿实行垄断经营的直接利润,"铸息"是铜矿垄断经营的间接利润,是铜矿垄断利润向铸钱利润的转移。     

Technical Studies on the Bronze Age Metal Artefacts from the Graveyard of Deh Dumen,South‐Western Iran (Third Millennium BC)

During the excavations of the graveyard at the site of Deh Dumen in south‐western Iran, 15 graves from the Early/Middle Bronze Age were uncovered that contained a variety of metallic artefacts. This paper reports on the analysis of nine metal artefacts, including eight broken vessels and a decorative strip that covered the handle of a dagger. The ICP–MS results showed that the bodies of the vessels are made of tin bronze alloy with variable amounts of tin, while the internal piece of the base of one vessel is made from an arsenical copper alloy. Further, the metallic strip is a thin sheet manufactured with partially pure silver. Microanalytical and microstructural information yielded by SEM–EDS revealed elongated Cu–S inclusions and lead globules as various phases formed in bronze solid solution. This study presents some information about the transition from arsenical copper to bronze metallurgy in the third millennium bc in south‐western Iran.     

ROME AND THE EAST. PRODUCTION OF ROMAN PROVINCIAL SILVER COINAGE FOR CAESAREA IN CAPPADOCIA UNDER VESPASIAN, AD 69–79

During the first three centuries AD several eastern provinces of the Roman empire produced silver coinages of specifically local denominations and types. It has been claimed that at certain periods the mint of Rome was employed to strike some of these coinages, rather than the provincial mints to which the coins are traditionally attributed. This claim is based mainly on stylistic observations, but because style is regarded as subjective, some other form of evidence to support these observations is desirable. In this paper three types of coin are submitted to metallurgical analysis: silver denarii struck at Rome; Roman-style provincial silver coinage; and 'local'style provincial silver coinage. The aim is to discover whether the Rome-style and 'local'style coins have different trace element profiles, and whether these might indicate different ore sources or refining techniques. The results are then compared with Roman denarii to see whether there are any similarities between the denarii and the Rome-style provincial silver coins.     

The early roman imperial AES coinage II: Tracing the copper sources by analysis of lead and copper isotopes—copper coins of Augustus and Tiberius*

Lead and copper isotopes of Roman Imperial copper coins (denominations as and quadrans) were analysed by MC–ICP–MS. We concentrated on well‐dated coins minted at the official mint of Rome under the Emperors Augustus and Tiberius (between 16 bc and ad 37). The lead isotope results were compared with published lead isotope data of ore bodies from the Aegaean, Cyprus, Italy and Spain, in order to fingerprint the sources of Roman copper. During the Augustan period the main copper supply, as judged from the copper coins, is from Sardinia and south‐east Spain, with minor contributions from Tuscany. Except for Tuscany, this continued into the Tiberian period, when Cypriot copper also appears. Augustan quadrantes and late Tiberian asses came solely from the Rio Tinto area in south‐west Spain. Copper isotopes were applied here for the first time to systematic archaeometric studies. They are supplementary to lead isotopes and allow further grouping and classification of the copper coins.     

东周青铜复合剑制作技术研究

东周时期,吴越出现了一种奇特的青铜复合剑,剑的中脊和两刃是用两种不同成分的青铜铸接而成。为充分了解青铜复合剑的制作,对上海博物馆馆藏的4把青铜复合剑残剑进行了分析,通过X-射线荧光能谱仪分析残剑的剑刃和剑脊的成分,金相显微镜分析剑刃和剑脊的组织,发现中国古代工匠采用低锡青铜制作韧性好的剑脊,高锡青铜制作强度和硬度高的剑从,通过榫卯结构以铸接法将剑脊与剑从结合成一体,得到刚柔兼具的青铜复合剑。在测试分析的基础上进行模拟实验,先以陶范铸造法铸造出两侧带榫头的青铜剑脊,剑脊的成分采用88％铜、10％锡、2％铅的低锡青铜;然后将青铜剑脊置入铸造剑从的陶范内,两侧的榫头伸入陶范型腔中,剑从的成分采用78％铜、20％锡、2％铅的高锡青铜,当剑从凝固时产生的收缩使剑脊和剑从牢固地结合成整体,再分1次或多次以铸接法铸上剑格、剑茎、剑箍和剑首,成功地复制了青铜复合剑,再现了东周时期青铜复合剑的制作工艺。     

COPPER ALLOYS FROM THE ‘ENOT SHUNI CEMETERY AND THE ORIGINS OF BRONZE METALLURGY IN THE EB IV – MB II LEVANT

Tin bronze replaced arsenical copper as the preferred alloy in the Levant for reasons that have long been debated. Found almost exclusively in graves, these two types of copper alloys share nearly identical mechanical properties. The Bronze Age cemetery of ‘Enot Shuni has yielded the first metals ever analysed from an uninterrupted stratigraphic sequence in the Levant, spanning the earliest adoption of tin bronze from the Early Bronze Age (EB) IV through the Middle Bronze Age (MB) II (c. 2300–1530 bc ). SEM–EDS analysis of these artefacts, combined with a compositional meta‐database of all previously published EB IV – MB II alloys, reveals diachronic alloy progression as selected by populations of the Levant. It has long been qualitatively understood that bronze became the primary alloy by the MB II. These results verify this trend and quantify human demand, showing that tin importation increased by 103% and arsenic content decreased by 49% throughout these periods. This shift in technological choice is attributed to cultural reorientation from the Egyptian to Mesopotamian sphere of influence, as well as to tin's appreciable fuel efficiency over pure copper and arsenical copper in light of unprecedented timber shortages.     

北宋和南宋青铜钱币对比分析研究

宋代是我国钱币的一个大发展时期,宋代钱币在我国钱币史上占有极其重要的地位.为了解南、北宋钱币的成分、显微结构的差异对铸币保存状况的影响,通过显微镜观察、合金成分分析、显微结构分析,对南宋和北宋各21枚钱币的保存状况进行了对比分析研究,以了解这42枚钱币的锈蚀状况、锈蚀原因,以及成分、显微结构的差异对铸币保存状况的影响.同时在分析研究的过程中,对北宋、南宋钱币的合金成分、铸造工艺进行了对比研究.研究结果表明,南宋钱币的保存状况比北宋的差一些,合金成分及显微结构的差异,是导致保存状况不同的重要原因.这些钱币主要是由铜、锡、铅铸造而成,分析结果进一步证实北宋钱币合金成分比较稳定,成分配比比较科学.而南宋成分数据比较分散,早期铜、锡含量较高,铅含量较低,晚期铜、锡含量较低,铅含量明显增高,合金品质大大降低.本研究可为了解当时的科学技术、社会经济形态进一步提供基本信息.     

AN ELEMENTAL AND LEAD‐ISOTOPIC STUDY ON BRONZE HELMETS FROM ROYAL TOMB NO. 1004 IN YIN RUINS

Lead isotope and element composition analyses were performed by thermal ionization mass spectrometry (TIMS) and inductively coupled plasma optical emission spectroscopy (ICP–OES) on bronze helmets from royal tomb No. 1004 at Yin Ruins, the last capital of China's Shang Dynasty (17th to 11th centuries bc ). The data show that the copper‐based alloy helmets can be divided into two categories: tin bronze and leaded tin bronze; and the lead isotope ratios for both categories are in the range of highly radiogenic lead (HRL). This result offers some important clues to answering questions concerning the provenance of raw metal materials, as well as the chronology of this famous royal tomb.     

Iron Age tin bronze metallurgy at Marlik,Northern Iran: an analytical investigation

The archaeological excavations performed in 1961 and 1962 at the necropolis of Marlik (Gilan District, northern Iran) revealed important archaeological remains dating to Iron Age I and II periods (late second/early first millennium BCE). While the metal collection from Marlik includes various gold, silver and bronze objects and is considered one of the most significant finds of metal objects from the prehistoric Iran, the technological investigations discussed in this paper provide information on tin bronze objects only from Marlik. Both the composition and the microstructure of 25 copper alloy objects have been determined in order to achieve a better understanding of the metallurgical processes used in northern Iran from the second to the first millennium BCE. Experimental analyses were carried out using inductively coupled plasma mass spectrometry (ICP-MS), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS) and optical microscopy. The results demonstrated that the copper-base objects were made of the binary copper–tin alloy with variable tin contents. Other elements such as As, Ni, Pb, Zn and Sb were detected in minor/trace amounts. Variable tin content may be due to the application of an uncontrolled procedure to produce bronze alloy (e.g. co-smelting or cementation). Microscopic observations and microanalyses revealed the presence of numerous copper sulphide inclusions, lead globules and intermetallic phases scattered in the bronze solid solution. The microstructures seen in the bronze objects under study were varied and included worked/annealed or dendritic grain structures.     

“Biblical” bronze coins: new insights into their timing and attribution using copper and lead isotopes

Ancient Judaean bronze coins are important for reconstructing the timing of events, for their cultural information, and for understanding alliances in the Eastern Mediterranean as Roman influence replaced the Hellenic Empires. Isotopic analyses of metals important in archaeology have become increasingly routine using multiple collector–inductively coupled plasma–mass spectrometry. A relatively nondestructive acid swab method for the isotopic analysis of lead (Pb) and copper (Cu) in bronze is described and tested for various isotopic sampling biases. The method is used to examine changes over time in fiduciary metal sources in the Levant during the first centuries bce and ce. The metal sources, timing, and attribution of Judaean “widow's mites” (ca. 80–40?bce) and the bronze coins of Roman governors Valerius Gratus and Pontius Pilate under Tiberius (14–37?ce) are used to illustrate how changes in the isotopes of Pb (widow's mites) and Cu (Roman governors) can be used to elucidate the compositional chronology of archaeological bronzes from this region and period.     

SEM and electrochemical characterization of bronze artifacts from the Francavilla archaeological site

The excavations in the necropolis of the Francavilla Marittima archaeological area, in Calabria, have brought to light the rich burial artifacts and materials, dated between the end of the ninth and sixth centuries BCE. SEM/EDS analysis was conducted on some sections taken from a bronze artifact classifiable as an armilla or fibula fragment. Our aim was to elucidate the nature of the corrosion processes acting on the specimen. SEM investigation detected the segregation of tin towards the outer layer and a depletion of the copper content in the same region. Furthermore, the elemental distribution maps of the sections analyzed evidenced the presence of chloride ions in the border area between the corrosion patina and the metal alloy. Such anion migration of chloride ions into the interior of the alloy leads to a particular variant of the type of corrosion of structure that in the literature has been identified as structure I.A cavity electrode designed for electrochemical measurements of powders was used to perform cyclic voltammetry experiments devoted to explore the activity of the patina covering the surface of the bronze fragment. The surface layer consists mainly of tin and tin oxides; the layer immediately beneath it contains copper oxides. An increase of reactivity was shown in an acidic environment. The activity of the patina is greatly reduced at pH 5 and appears to be zero at neutral pH.     

CHEMICAL COMPOSITIONS OF TEN SEPTIMIUS SEVERUS DENARII

X-ray fluorescence analyses of ten Septimius Severus denarii, all having the catalog number Cohen 777, and all minted in a.d. 196, show the following: (1) copper and silver concentrations in the ten coins cover a rather broad range, (2) lead and gold concentrations correlate with the silver concentrations, (3) no elements, except silver, correlate directly with the copper contents, (4) two coins have very nearly the same compositions, but this could actually be explained by chance, given the precision of the analyses and the range of compositions found for all ten denarii, (5) weights, thicknesses, and diameters of the coins varied over a relatively wide range, but densities varied only slightly. Assuming reasonably homogeneous melts of coinage alloy, X-ray fluorescence (XRF) analyses of many more Severus denarii of a.d. 196 should enable one to deduce several details of the mint operation such as (1) the number of dies in use of C. 777 coins at one time, (2) the overall batch size of coins, and (3) the number of different Severus denarii minted from the same batch of alloy. With improved precision of XRF analyses now possible, it only remains for a source of Severus denarii to be found to enable testing of this hypothesis.     

明代铜镜科学考察

通过对部分明代铜镜的科学分析,了解到明代也使用过与战国汉唐成分相近的合金来铸镜;除了锡汞齐外,此时还使用了铅汞齐和铅锡汞齐来开镜或磨镜。     

铜片除锈强度考察与缓蚀效果分析

在青铜器除锈过程中,既要除去有害锈及其他杂质,又不损伤青铜器原貌,这就需要掌握一定的度。本研究用失重法定量地考察了不同除锈法和不同除锈剂对铜钱的除锈强度。结果表明,物理除锈法与化学除锈法均有明显的失重率。化学除锈中,5%左右的冰醋酸有较高的除锈强度。采用不同组合的BTA缓蚀剂对铜片进行保护,通过Tafel曲线分析其保护效果,以1.5%浓度的BTA与2%H_2O_2的组合液缓蚀效果明显。经盐雾腐蚀试验对此结论进行了验证。     

TIN ISOTOPY—A NEW METHOD FOR SOLVING OLD QUESTIONS

Tin was a vital commodity in times past. In central Europe, the earliest finds of tin‐bronze date to about 2200 bc , while in Greece they are c. 400–500 years earlier. While there is evidence for prehistoric copper mining—for example, in the Alps or mainland Greece, among other places—the provenance of the contemporary tin is still an unsolved problem. This work deals with a new approach for tracing the ancient tin via tin isotope signatures. The tin isotope ratios of 50 tin ores from the Erzgebirge region (D) and 30 tin ores from Cornwall (GB) were measured by MC–ICP–MS. Most ore deposits were found to be quite homogeneous regarding their tin isotope composition, but significant differences were observed between several deposits. This fact may be used to distinguish different tin deposits and thus form the basis for the investigation of the provenance of ancient tin that has been sought for more than a century. Furthermore, the tin‐isotope ratio of the ‘Himmelsscheibe von Nebra’ will be presented: the value fits well with the bulk of investigated tin ores from Cornwall.