Comments on Graf, Journal of Archaeological Science 36, 2009 “ “The Good, the Bad, and the Ugly”: evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia”

Here I present a critical evaluation of the analysis conducted by Graf [Graf, K.E., 2009. “The Good, the Bad, and the Ugly”: Evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia. Journal of Archaeological Science 36, 694–707] of the Paleolithic radiocarbon (¹⁴C) dataset for the Upper Paleolithic sites in the Yenisei River basin of Central Siberia. Graf applied a rating system to the corpus of existing ¹⁴C data for the region, and announced some new ¹⁴C dates. The results obtained, however, are highly biased due to several factors, including prejudice concerning the higher accuracy of the AMS technique in ¹⁴C dating and that ¹⁴C dates from the same cultural component should overlap with plus–minus two sigmas; ambiguities with the subdivision of the Lateglacial period; artificially high sample selection criteria; incomplete factual material; and unjustifiable and misleading statements on the ¹⁴C dating of fossil bones and the issue of Last Glacial Maximum human presence in Siberia. As a result, the conclusions made by Graf [Graf, K.E., 2009. “The Good, the Bad, and the Ugly”: Evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia. Journal of Archaeological Science 36, 694–707] are unconvincing. New analysis is necessary in order to improve the quality of treatment of the original data for the Upper Paleolithic ¹⁴C chronology in the Yenisei River basin.     

Dating of modified femora of extinct dwarf Hippopotamus from Southern Madagascar: Implications for constraining human colonization and vertebrate extinction events

Two significant events in the late Holocene history of Madagascar were (a) the arrival of people, and (b) the loss of nearly two dozen species of land vertebrates in the socalled “subfossil extinctions”. The consensus is that the faunal losses occurred shortly subsequent to human arrival, but the timing of these events is poorly constrained. The minimum age for initial human presence on the island may now be set at approximately 2000 bp, on the basis of AMS ¹⁴C dates for human-modified femora of extinct dwarf hippos from SW Madagascar. Assuming that this date also marks the beginning of deleterious human interactions with the subfossil fauna, and assuming that this fauna became completely extinct by 900 bp, the width of the anthropogenic “extinction window” may have been as long as c. 1000 a. This estimate, nearly twice the length of previous ones, is close to the unadjusted minimum for the duration of the terminal Pleistocene extinction event in the Americas. Whether or not this length of time comports with theoretical expectations of a “blitzkrieg” pattern of losses is uncertain, but greater refinement in dating the end of the subfossil extinctions is unlikely to produce radically shorter estimates of duration.     

Lithostratigraphy of Border Cave, KwaZulu, South Africa: a Middle Stone Age sequence beginning c. 195,000 b.p.

Border Cave is well-known for its Middle Stone Age (MSA) sequence and associated hominids, as well as for the earliest demonstrable Later Stone Age (LSA) (c. 38,000 b.p.) strata in southern Africa. Detailed lithostratigraphic and sedimentological study permits identification of 8 Pleistocene sedimentary cycles, including 6 major cold phases and 2 intervening weathering horizons. The 2 youngest cold phases are associated with the LSA and have 8 ¹⁴C dates 38,600-13,300 b.p. By gauging sedimentation rates in finer and coarser sediments, duration of sedimentary breaks, and allowing for differential compaction, the excellent radiocarbon framework provided by 28 available ¹⁴C dates can be extrapolated to the 6 cold intervals and 2 palaeosols that are older than 50,000 b.p. These clearly span oxygenisotope stages 4, 5 and 6, placing the base of the MSA deposits at c. 195,000 b.p., Homo sapiens sapiens at c. 90,000–115,000 b.p. and the sophisticated, microlithic “Howieson's Poort” industry at 95,000 b.p. These results require radical reassessment of the age and nature of the MSA complex and of the earliest evolution of anatomically-modern people.     

Patterns of Diagenesis in Bone II: Effects of Acetic Acid Treatment and the Removal of Diagenetic CO3

Archaeological bones of varying preservation have been treated with 0·1 M acetic acid in order to investigate the effect on structural and chemical alterations caused by diagenesis. Acetic acid is commonly used as a “cleaning agent” for removing diagenetic carbonate from bone and enamel, in an attempt to recover original, biogenic signals for use in dietary and¹⁴C dating studies.Diagenetic parameters were measured before and after treatment on a range of archaeological bones with good and bad preservation. Histological preservation defined the behaviour of the correlating parameters, where correlation coefficients between carbonate content and crystallinity, microporosity and macroporosity increased significantly after treatment. For histologically well preserved material, acetic acid is effective at returning carbonate content to around that of modern bone. Where bone is extensively damaged by micro-organisms, “loose” diagenetic material can be removed, but a fraction largely composed of hypermineralized bioapatite remains, which, we believe, cannot be reliably used to obtain accurate biological signals.     

Implications of a freshwater radiocarbon reservoir correction for the timing of late Holocene settlement of the Elk Hills,Kern County,California

Uncertainties regarding the magnitude of freshwater radiocarbon reservoir effects can introduce random errors into dates on archaeological freshwater carbonates. As a result, many archaeologists avoid dating freshwater shells unless no other datable materials are available. The chronology of prehistoric occupation of the former Naval Petroleum Reserve No. 1 (NPR-1) at Elk Hills, Kern County, has been established with 50 radiocarbon dates on freshwater mussels (Gonidea and Anodonta sp.). Characterization of any freshwater radiocarbon reservoir effect is crucial for the accurate interpretation of inferred settlement and subsistence changes on the Elk Hills. Paired charcoal and freshwater mussels sampled from closely associated contexts were dated to identify a freshwater reservoir effect. Paired Anodonta and Gonidea sp. shells were dated to investigate interspecific differences in fractionation. Results indicate that a 340 ± 20 ¹⁴C yr correction should be applied to conventional ¹⁴C dates on freshwater carbonates in the Buena Vista Basin before calendar calibration. Evidence of interspecific differences is inconclusive. Dates recalibrated with the reservoir correction indicate that widespread occupation of the Elk Hills is correlated with increasing precipitation towards the end of the Medieval Climatic Anomaly and during the Little Ice Age, suggesting that slough resource exploitation may have been driven by regional population pressure rather than drought-related declines in aquatic productivity.     

Radiocarbon dating and the “old shell” problem: direct dating of artifacts and cultural chronologies in coastal and other aquatic regions

Archaeologists have long recognized the problem of the “old wood” effect in radiocarbon dating charcoal and wood samples, the age of which may be hundreds of years older than their use by humans. Such problems have resulted in significant changes in how most researchers select wood and charcoal samples for ¹⁴C dating, with many now using relatively short-lived carbonized materials for dating. Despite the significant strides made in our understanding of the potential biases of the “old wood” effect, little emphasis has been placed on the possible impacts of dating “old shell” in archaeological deposits. The use of marine shell for ¹⁴C dating is widespread in coastal areas around the world, including a growing emphasis on the dating of individual shell artifacts via Accelerator Mass Spectrometry (AMS). In dating shell artifacts, we have obtained several dates older than associated ¹⁴C dates for short-lived subsistence remains from the same deposits, including great disparities (>10,000 years) and more subtle differences (≥100 years). These discrepancies appear to be due to the use of old shells by humans to make beads and other artifacts, including shells collected from fossil deposits, older archaeological sites, and beaches. The problems caused by the use of old shells to make beads and other artifacts are surmountable through careful sample selection, analysis of multiple ¹⁴C dates on a variety of materials, and proper calibration procedures.     

Palaeoenvironmental and chronological investigations of the Magdalenian sites of Goyet Cave and Trou de Chaleux (Belgium), via stable isotope and radiocarbon analyses of horse skeletal remains

Trou de Chaleux and Goyet are caves situated less than 30 km apart in Belgium that contain stratified Magdalenian artefacts and butchered faunal remains. Published radiocarbon dates suggest that both sites were contemporaneously occupied during to the Late-glacial interstadial. It has previously been suggested that the Trou de Chaleux Late-glacial faunal remains might be slightly older than those at Goyet Cave, and that Trou de Chaleux has two phases of occupation during the Late-glacial interstadial. However, the limited number of radiocarbon dates currently available makes it impossible to determine whether the sites are truly contemporaneous, and the assessment of their absolute chronologies is complicated by a plateau in the calibration curve. In this paper, bone collagen δ¹³C and δ¹⁵N signatures of horse bones from the two sites are used to reconstruct local palaeoenvironments. We hypothesise that if occupations at the two sites were contemporaneous, the horse collagen δ¹³C and δ¹⁵N isotope signatures from both sites will be similar, since comparable carbon and nitrogen isotopic values would reflect similar diets, ecologies and environments. To provide clear dating parameters, new AMS radiocarbon determinations are also presented. Results show that horse collagen δ¹³C and δ¹⁵N isotope signatures at the two sites are different, indicating that the populations were not subject to similar diets, ecologies and environments. The new radiocarbon dates confirm that the horse bones from Trou de Chaleux date to the Late-glacial interstadial, but they also show that in Goyet Cave Horizons 1 and 2, older horse remains dating to ca. 32?000–27?000 ¹⁴C yr BP are mixed with Late-glacial horse remains. The δ¹⁵N values of the Goyet Cave horse bones radiocarbon dated to the Pleniglacial are substantially higher than those that have Late-glacial radiocarbon dates. Therefore, we now hypothesise that the majority of the horse bones isotopically analysed from Goyet Cave Horizon 1 are Pleniglacial in age. Statistical analysis of the radiocarbon dates indicates that the Late-glacial occupation at the two sites was contemporaneous, and that while there may appear to be two phases of occupation at Trou de Chaleux, this may be an artefact of the radiocarbon calibration curve.     

A Bayesian AMS C chronology of the Classic Maya Center of Uxbenká, Belize

Archaeologists require precise chronologies of cultural change to understand the nature and timing, and causes and effects, of ecological and social transformations. The Uxbenká Archaeological Project (UAP) has made chronology building a main goal, employing epigraphic data, artifact seriation, and high-precision AMS ¹⁴C dating. With more than 60 ¹⁴C dates with measurement errors below ±25 ¹⁴C yr, primarily on single charcoal specimens, Uxbenká may be the most intensively dated Classic Period site in the tropical Maya Lowlands. Here we take the next step, combining this rich chronometric dataset with associated stratigraphic information in OxCal's Bayesian framework to generate a high-resolution chronology of Uxbenká's early development and expansion in southern Belize. We show how archaeologists may take advantage of complex architectural stratigraphy to constrain broad calibrated ranges during the Classic Period, and to estimate dates for observed construction events that can not be directly dated (e.g., clearing/leveling plazas, laying plaster floors, renovating/rebuilding structural elements). Our analysis confirms the antiquity of the ceremonial Stela Plaza (Group A), where first construction is estimated between 60 cal BC and cal AD 220 and is associated with a Pre-Classic structure obscured by later construction and reorientation of the group to a N-S alignment ca. AD 150–310. The analysis also indicates initial leveling and construction at plaza Group B from cal AD 60–310 and Group D from cal AD 20–240, both earlier than previously assumed. Though Late Classic contexts are not as well represented by direct dates, architectural modifications are documented at all three plaza groups after AD 550, including the extensive plastering, laying paving stones, and construction of facades on existing structures. The resulting chronology revises our previous thinking on the mode of settlement and development of Classic Maya society at Uxbenká and indicates specific areas of investigation to elucidate events in the Late and Terminal Classic at the site, including political and social fragmentation and the abandonment of the urban core late in the Classic Period.     

Debates over Palaeolithic chronology – the reliability of C is confirmed

The debate about the complex issues of human development during the Middle to Upper Palaeolithic transition period (45–35 ka BP) has been hampered by concerns about the reliability of the radiocarbon dating method. Large ¹⁴C anomalies were postulated and radiocarbon dating was considered flawed. We show here that these issues are no longer relevant, because the large anomalies are artefacts beyond plausible physical limits for their magnitude. Previous inconsistencies between ¹⁴C radiocarbon datasets have been resolved, and a new radiocarbon calibration curve, IntCal09 (Reimer et al., 2009), was created. Improved procedures for bone collagen extraction and charcoal pre-treatment generally result in older ages, consistent with independently dated time markers.     

New radiocarbon dating of the transition from the Middle to the Upper Paleolithic in Kebara Cave,Israel

The Middle to Upper Paleolithic transition (MP-UP transition) is considered a major technological and cultural threshold, at the time when modern humans spread “out of Africa”, expanded from the Levant into Europe and possibly into central and northern Asia. The dating of this techno-cultural transition has proved to be extremely difficult because it occurred sometime before 40,000 radiocarbon years before present (¹⁴C years BP), which is close to the end of the effective dating range of radiocarbon. Other dating methods such as Thermoluminescence (TL) or Electron Spin Resonance (ESR) are not sufficiently precise to date the recorded archaeological MP-UP transition in the Levant. Here we report a consistent set of stratified radiocarbon ages on freshly excavated charcoal from Kebara Cave, Mt. Carmel (Israel), that span the late Middle Paleolithic (MP) and Early Upper Paleolithic (EUP) This study applied novel strategies to improve sample preparation techniques and data analysis to obtain high-resolution radiocarbon models. From this study it is proposed that the MP-UP transition for this site can be placed immediately after 45,200 ± 700 ¹⁴C years BP and before 43,600 ± 600 ¹⁴C years BP or from 49/48 to 47/46 radiocarbon calibrated years before present (years Cal BP).     

New age constraints for hominid footprints found on Jeju Island,South Korea

In 2004 numerous hominid footprints, along with diverse animal footprints, were found in the Late Quaternary strata of Jeju Island, South Korea. However, the age of the sediments in which the footprints were found is still controversial. Previous age estimates included radiocarbon ages of ca. 15,000 yr BP (Late Pleistocene) and quartz optically stimulated luminescence ages of ca. 7000 yr BP (mid-Holocene). In this study we report on 11 AMS ¹⁴C dating results from a new set of samples collected from the footprint-bearing strata and from associated sediments. Despite some variations and age reversal, all samples collected from the footprint-bearing strata yielded ¹⁴C ages of late Pleistocene. These ages are comparable with previous radiocarbon dating results. Furthermore, the presence of the proboscidean footprints attributable to woolly mammoths in the footprint-bearing strata supports the radiocarbon dating results. Based on the new radiocarbon dates and the presence of the alleged mammoth footprints, the age of the hominid footprints found at Jeju Island is thought to be late Pleistocene (about 19,000–25,000 cal yr BP). Therefore, this is the second discovery of hominid footprints dated to the Pleistocene age in Asia, and the first to be discovered in Korea.     

A bayesian approach to wiggle-matching

“Wiggle-matching” is a technique developed to provide calendar dates for a series of samples of known deposition rate using the now well-established high-precision radiocarbon calibration curve. In this paper we describe how the technique may be formulated within the Bayesian framework for statistical analysis and thereby permit the incorporation of uncertainties regarding the deposition rate. The methodology is illustrated by two archaeological examples.     

Variability in the marine radiocarbon reservoir effect in Muscat (Sultanate of Oman) during the 4th millennium BC: reflection of taphonomy or environment?

Radiocarbon (¹⁴C) dating of archaeological coastal sites in arid areas is challenging because of the relative rarity of datable terrestrial artefacts. Marine artefacts provide an abundant source of carbon, which is technically easy to date but radiocarbon dates need to be corrected for local variations from the global average marine ¹⁴C reservoir age (ΔR). In archaeological sites, this is usually done by the comparison of the ¹⁴C age measured between coeval pairs of terrestrial and marine samples that have no inbuilt age. Here, we present the results of a study that aims to determine the local ¹⁴C marine reservoir effect (MRE) along the Eastern coast of the Arabic Peninsula during the 4th millennium BC, a period of important cultural, demographic and social changes in this region. Previous estimates of the MRE based on associated shells and charcoal vary by about 400 ¹⁴C yr and this is a serious limitation to the establishment of a precise chronology in the area based on marine material. In order to maximize the chances to obtain contemporaneous terrestrial–marine pairs for a new assessment of the MRE in this region we dated charcoal, shells, fish and turtle bones as well as human bones found in three recently and carefully excavated graves from Ra’s al-Hamra RH5. A large variability was found between charcoals (up to 240 ¹⁴C yr) and marine specimens (up to 785 ¹⁴C yr) present in the same grave. This variability was attributed to inbuilt ages, diagenesis and possibly environmental factors although taphonomic processes cannot be excluded. We discarded the oldest charcoals and used the ¹⁴C ages obtained on human apatite as a cut-off value to remove the marine outliers. Two out of the three graves provided terrestrial and marine assemblages which did not differ statistically and were used to calculate an average MRE of 645 ± 40 ¹⁴C yr (ΔR = 255 ± 55 ¹⁴C yr). This value is consistent with previous estimates based on the ¹⁴C dating of marine sediments off Pakistan and suggests stability of the MRE in the Arabian Sea since the 4^th millennium BC.     

A STATISTICAL APPROACH TO THE CALIBRATION OF FLOATING TREE-RING CHRONOLOGIES USING RADIOCARBON DATES

The bristlecone pine tree-ring calibration of radiocarbon dates, while necessitating changes of up to 700 years in Holocene chronology before 1000 b.c. , offers possibilities of very accurate dating when ¹⁴C determinations from floating tree-ring chronologies are utilized. A statistical approach assuming linear regression is developed and used to position the floating tree-ring chronologies at Swiss neolithic sites, using radiocarbon dates published by Ferguson, Huber and Suess and by Suess. The statistical method gives objective estimated dates with estimates of error related, in a consistent and explicit manner, to the inherent inaccuracies of the radiocarbon dates. Most of the method may readily be tested by standard statistical procedures. For the particular cases considered the assumptions of linearity and parallelism are investigated, and the precision of the estimated dates is comparable with that claimed by Suess and his co-workers. A precise calibration is thus possible without utilizing the short-term fluctuations in the Suess calibration curve. The analysis, while avoiding some assumptions of Suess and his collaborators, offers an explicit procedure for establishing controlled teleconnections with the Ferguson dendrochronology, and supports their emphasis on the importance of radiocarbon dates from floating tree-ring sequences for the construction of precise prehistoric chronologies.     

Radiocarbon dating: Some practical considerations for the archaeologist

The article is divided into four main sections in each of which a key aspect of radio-carbon dating is discussed with emphasis on the practical implications for users of dates. The four topics which the article attempts to deal with are, in turn, (i) the effect on the radiocarbon timescale of the variations in atmospheric ¹⁴C now known to have occurred in the past and the role of other absorlute dating methods in investigating these, (ii) laboratory measurement of ¹⁴C, (iii) selection of optimum samples for dating and (iv) some of the limitations of the final dates. The theme is essentially that the technical difficulties of radiocarbon measurement in the laboratory have been overcome to the extent that the physical measurements can now be made with high precision, that is to within ±1% or better, as a routine. Thus, it is more important than ever (a) that only reliable samples having very firm associations should be dated and (b) that pretreatment of such samples by the dating laboratory to remove any age contaminants should be completely effective. However, in addition to the recognized statistical limitations, the absolute accuracy of radio-carbon dating is limited by the past ¹⁴C variations. Coupled with the requirements of proper association and pretreatment of samples is the long-term need to establish an overall correlation between radiocarbon and calendar years. At present this is still a matter for final agreement by the laboratories concerned. Meanwhile, when all possible steps have been taken to ensure the reliability of the date messurements, these can strictly only be compared with one another in terms of radiocarbon years bp. In practice this is often too restrictive but any attempts at calibration must be regarded as approximations for the time being. In this article the lower and upper case notation advocated in Antiquity46, 265, for radiocarbon and calendar years respectively has been followed.     

OSL dating as an alternative tool for age determination of relic charcoal kilns

Chronometric studies of charcoal production remains are largely based on ¹⁴C-dating of associated charcoal. Owing to intrinsic limitations, however, this method provides no meaningful time resolution for post-1650 CE features. We investigate the potential of optically stimulated luminescence (OSL) dating of heated sandy sediments as an alternative and complementary tool for dating charcoal kiln remains. Seven samples from five relic charcoal kilns and 11 complementary samples from the underlying sandy substrate are used. Through a range of procedural tests, we demonstrate that the single-aliquot, regenerative-dose procedure in combination with OSL signals from quartz allows determining equivalent doses both accurately and precisely. For four of the five investigated kilns, OSL ages are consistent with independent age information from ¹⁴C-dating and written sources. Especially for post-1650 CE features, the precision can be significantly better than that of ¹⁴C-dating, and we highlight the potential of OSL dating for distinguishing, relatively, between charcoal production phases with an unprecedented time resolution. We conclude that the approach is a promising alternative to ¹⁴C.     

Pollen analytical investigations at Crosby Warren, Lincolnshire, in the Vicinity of the iron age and Romano-British settlement of Dragonby

Open-cast ironstone mining at Crosby Warren, near Scunthorpe, Lincolnshire exposed an extensive section through “cover sand” deposits. revealing buried podzol soils and peat layers. Stratigraphic studies, pollen analysis and radiocarbon dating have been carried out on three representative profiles. From these investigations it would appear that the “cover sands” in this area were stabilized under mixed oak woodland by c. 300 BC. After c. 100 BC woodland clearance and farming activities have been distinguished. Local alterations in land-use may be linked with cultural developments at the nearby Iron Age and Romano-British settlement of Dragonby. It is suggested that the impact of man upon the vegetation during Iron Age and Romano-British times probably facilitated podzolization and sand blowing.     

Dating the Ramat Saharonim Late Neolithic desert cult site

The Ramat Saharonim site, located in the central Negev desert, Israel, consists of four shrines in a shallow valley and 30 tumuli, aligned on two cuesta cliffs on the valley's sides. Previous assessments based on site surveys suggested a general chronological span from Late Neolithic period (ca. 5000–5500 BC) through the Early Bronze Age (third millennium BC). Excavations in one shrine and three tumuli revealed a well-constructed double wall at the shrine and seven primary adult burials in the three tumuli. Quartz from sediment samples post-dating the construction of the burials and shrine was dated by optically stimulated luminescence (OSL) using the single aliquot regenerative dose (SAR) protocol, and charcoal and leather samples were dated by ¹⁴C. The OSL results for a burial in one tumulus are 7500 ± 700 to 6000 ± 600 years. In a second tumulus, OSL ages of 2000 ± 200–1800 ± 170 years and a ¹⁴C age on leather of 390–200 BC (2340–2150 cal BP) imply that this burial is Nabatean and that the site was used also in the Hellenistic period. Two ¹⁴C ages on charcoal from the shrine give an age between 5280 and 4710 BC (7230–6660 cal BP). OSL single aliquot ages for sediment from the shrine are highly scattered and far too old (60,000 to 12,000 years). The unlikely old ages are due to insufficient resetting of the OSL signal of some of the quartz grains when sand was blown onto the site. Indeed, single grain measurements for six samples of sediment postdating the shrine show a very large range of grain ages, but with a distinct young population in all samples. Ages calculated from these young populations average 5400 ± 800, in better consistence with the ¹⁴C dates and confirming our supposition that only some of the transported grains were reset at the time of deposition. The combined OSL and ¹⁴C dating shows that the shrines and tumuli are contemporaneous and attributes the complex to the Late Neolithic. This has clear ramifications for our understanding of the period and the rise of desert pastoral societies.     

Lichenometric constraints on the age of the Huashan Grottoes, East China

Lichenometry is a method of dating that has been widely used in glaciated areas for determining the minimum age of exposure of a geomorphic landform during the late Holocene. This paper presents a regional calibration data set of lichen thallus sizes versus rock surface ages for the Huashan area, East China, based on measurements of yellow-green Rhizocarpon lichens on the known-age substrates at eight sites. An empirical relationship between thallus sizes and rock surface ages was established using both the traditional regression and the Bayesian approaches. Using the Bayesian calibration, the minimum age of the Huashan Grottoes was dated from 450 ± 60 to 330 ± 60 years ago, corresponding to the late Ming Dynasty (AD 1477–1632). These dates are generally consistent with those predicted from the regression-based linear growth curve. Our results suggest that applications of this technique can be safely extended to the non-glaciated areas.