Portuguese Blue‐on‐Blue 16th–17th Century Pottery

Blue‐on‐blue (‘berettino’) sherds have appeared in numerous production and consumption archaeological excavations in Lisbon and other archaeological sites in Portugal (dated from the mid‐16th century to the beginning of the 17th century). The abundance of this interesting faience led us to compare it with similar pottery from other well‐known production centres in Italy, namely Liguria (Savona and Albisola), Spain (the Triana kilns) and the Low Countries. Differences in the diffraction patterns of the sherds' pastes from the four countries were observed. In most samples, cobalt blue silicate (cobalt olivine) was identified in the dark blue or light blue glazes through the use of micro‐Raman spectroscopy and diffuse reflectance spectra. A remarkable difference in the calcite contents of the Lisbon and Seville pottery sherds was observed, in accordance with previous observations of high calcite contents of Seville ceramics. A comparison was also made for all of the blue‐on‐blue sherds studied here with many other 16th–17th century sherds from Lisbon using bivariate plots of K/Si versus Ca/Si. Lisbon and Seville pottery behave very differently, whereas sherds from Italy and the Low Countries occupy intermediate positions.     

Characterization of Iron age pottery from eastern Turkey by laser- induced breakdown spectroscopy (LIBS)

Selected pottery sherds coming from the Ayanis, Dilkaya and Karagündüz excavations in eastern Turkey and dated from the Early to Middle Iron Age were examined as regards their composition by using laser-induced breakdown spectroscopy (LIBS). The objective of the study was first to investigate the potential of the LIBS technique in the compositional analysis of pottery and further to explore correlations in spectral data, by using chemometrics methods that would possibly enable discrimination among different sherds. This work is part of a broader study aiming to examine clay variability both before and during the Urartian State period and to explore possible relationships and differences among pottery objects from fortresses and settlements or settlements and cemeteries on the basis of the clay composition of sherds. Preliminary results demonstrate that by using the LIBS technique it is possible to analyse pottery sherds in qualitative and semi-quantitative ways, providing information on the clay and slip composition. Furthermore, encouraging results have been obtained by carrying out principal component analysis (PCA) on the LIBS spectra, which suggest that in certain cases, it is possible to directly correlate spectral information with the origin of pottery sherds.     

广东博罗先秦硬陶的XRF和INAA研究

为揭示广东博罗梅花墩、银岗、横岭山三地古陶器的产源、烧造工艺、技术传播和化交流等方面情况,用波长色散X射线荧光分析(WDXRF)、仪器中子活化分析(INAA)同时测量了广东博罗梅花墩、银岗、横岭山等三地点所出38片西周至春秋、战国硬陶中Al、Ba等元素的含量。并用主成分分析分别处理了测量数据。两套数据的分析结果均表明,梅花墩、银岗和横岭山的硬陶原料互不相同,各地点硬陶可能主要是“自烧自用”。数据分析还表明在南方各省区中,广东硬陶具有Al2O3含量偏高这一明显的地区特征。     

A multivariate analysis of pottery from southwestern Cyprus using neutron activation analysis data

Neutron activation analysis is employed to geochemically characterize 129 pottery sherds collected from 38 sites during an archaeological survey of the Paphos District of southwestern Cyprus. Cluster analysis identifies three significant groupings using 26 trace elements and rare earth elements. These compositional groupings appear to reflect differences in the geographical locations of the sherd collection sites and particularly the influence of the surficial geology. In particular, the rocks of the ultramafic Troodos Ophiolite Zone, the Mamonia Complex, and various formations of the Circum Troodos Sedimentary Sequence appear to impart a detectable imprint on the sherds of the study area. Discriminant analysis identifies Ce, Th, Cr, Na, Fe, Hf, Ba and Co as the most significant chemical discriminators between the three compositional groupings and derives two discriminant functions that between them account for 100% of the variance between the groups. Discriminant analysis also confirms that 82% of the sherds classified by cluster analysis are correctly classified. Based on probability measures, the large majority of the sherds (98%) are considered to be local in origin.     

Golden Biographies: The Production,Curation, Fragmentation and Deposition of the Armorican-Type Rolled-Gold Bead-Like Ornaments found at Pendleton,Lancashire

A rare Chalcolithic rolled-gold bead-like ornament dated to c. 2400–2200 cal. BC was found in association with sherds of early Beaker ware in an Early Bronze Age Collared Urn burial dated to c. 1545–1450 cal. BC. The grave was located at Pendleton, Lancashire. This paper reports on the AMS radiocarbon dates for the burial context along with X-ray composition analysis of the gold ornament, which shows the object had a high platinum content consistent with alluvial, placer, deposits possibly originating in Brittany, France rather than the British Isles. This unparalleled rolled-gold ornament is compared to the corpus of British and French rolled-gold ornaments and contemporary goldwork and a provenance, manufacture and biography of the find is explored. Both curation and fragmentation are considered in the context of a dated Beaker ware assemblage from the local domestic site of Lower Brockholes, Preston, as well as existing corpora of Beaker and Collared Urn ware from the region.     

Classical and Hellenistic black glaze ware in the Mediterranean: A study by epithermal neutron activation analysis

Fifteen chemical elements have been measured quantitatively by epithermal neutron activation analysis in 58 sherds of black glaze pottery found in Carthage/Tunis (23 sherds), the Athenian Agora (9 sherds), Sicily (7 sherds), and several sites in Southern Italy (19 sherds). Detailed statistical analysis of the results clearly distinguishes five separate groups: (a) one of local Carthage/Tunis origin; (b) one of probable Sicilian origin; (c) a large group of Attic origin comprising sherds found at the Athenian Agora and at Carthage/Tunis; and (d) two separate groups from S Italy.     

THERMOLUMINESCENT DATING OF EGYPTIAN PREDYNASTIC POTTERY FROM HEMAMIEH AND QURNA-TARIF

Eight sherds from Hemamieh and two from Qurna-Tarif, both Predynastic settlement sites in the Nile valley, have been dated by the thermoluminescence method (quartz inclusion technique). The results put the Badarian phase at Hemamieh in the sixth and fifth millenium b.c. , and the Gerzean phase in the first half of the fourth millenium b.c. The dates for the village of Qurna-Tarif fall around 4000 b.c.     

古陶瓷科学技术研究在科技考古中的三例应用

利用多元统计分析方法研究了从杭州古中河南段采集的月白釉瓷片,浙江临安天目山地区发现的黑釉瓷片和景德镇历代青花瓷片的胎、釉化学组成和青花色料的变化规律。从而讨论了杭州古中河南段采集的瓷片可能就是凤凰山下万松林附近的修内司官窑制品;指山临安天目山地区新发现的窑群和黑釉瓷才是名副其实的天目窑和天目瓷;发现了元代以及明初洪武和永乐朝青花瓷所用的料可能是来自西域的进口料,而宣德青花瓷所用的色料多数可能是国产的粘土矿。     

Hohokam and Patayan interaction in southwestern Arizona: evidence from ceramic compositional analyses

Ceramic raw material use is one line of evidence for prehistoric territorial boundaries and social interaction. In this paper, we characterize the raw materials used by Hohokam and Patayan potters along the western Hohokam frontier, using data from oxidation analysis, laser-ablation inductively-coupled plasma spectrometry, and petrographic analysis. The sample includes 150 sherds from three sites (AZ Z:1:29[ASM], AZ Z:1:30[ASM], and BMGR-02-F-04) south of Gila Bend, Arizona. Similar Lower Gila River sediments were used for Hohokam and Patayan ceramics during the period A.D. 700–1150. Patayan potters apparently used clay sources from an area dominated by Hohokam settlements, and their ceramics were transported at least 50 km into the desert interior, perhaps representing seasonal movements between the river and the desert.     

THE CHEMICAL ANALYSIS OF ORIENTAL CERAMIC BODY COMPOSITIONS: PART 1: WARES FROM NORTH CHINA*

This paper presents the body analyses of 70 sherds of ceramics made in north China during the Late Tang and Northern Song dynasties (c. AD 80–1200). The major types represented are Ding, Xing and Cizhou-type wares. The analyses were obtained by atomic absorption spectrometry, giving information on nine major and minor constituents. These have been used to differentiate chemically between the major kiln sites in the north, with the aid of multivariate computer analysis. This has demonstrated that there are differing chemical characteristics associated with these kilns, but the study is hampered by the lack of authentic material from controlled excavations of the kiln sites.     

A rapid INAA method to characterize Egyptian ceramics

A rapid cost-effective instrumental neutron activation analysis method has been developed to characterize Egyptian ceramics. Using this approach, it is possible for one person to take representative samplings from 25 sherds, analyse them and tabulate the data within an 8 h working day. This in turn means that successive analytical samplings of available materials may be made on the basis of the suite of sherds already analysed. The efficacy of such an analytical procedure has been tested using a large number of sherds from the collection of the Egyptian Department of the Royal Ontario Museum. The results indicate that elements producing short-lived isotopes may be used to differentiate sherds made from Nile alluvium from sherds formed from chemically different clay sources and from mixtures of Nile alluvium and clays or other materials.     

THERMOLUMINESCENT DATING OF BAKED CLAY BALLS OF THE POVERTY POINT CULTURE

Seven sites in Mississippi, Louisiana and Arkansas have been dated. For six sites (Terral Lewis, Poverty Point, Jaketown, Teoc Creek, Shoe Bayou, and Claiborne) the results are not inconsistent with contemporaneity; excluding Claiborne the average date is 1000 b.c. , with an error limit in absolute terms of ± 200 years. The seventh site (Loggy Bayou), in which sherds and balls were found in association, gave a date some fifteen hundred years more recent.     

THE UTILIZATION OF TRACE CHEMICAL COMPOSITION TO CORRELATE BRITISH POST-MEDIEVAL POTTERY WITH EUROPEAN KILN SITE MATERIALS

This study uses X-ray fluorescent analysis to compare the trace chemical composition of seventeen pottery sherds excavated from sites in Britain with the trace analyses of twenty four sherds from continental sources. Results indicate that certain elements, notably zirconium, titanium, rubidium, and strontium show little variation within a particular sherd and are consistent among samples from the same source. Certain other elements appear to show wide variation which is possibly attributable to firing conditions, burial or is connected with the glaze. The comparisons of analyses indicate that nine of the seventeen British sherds can be closely correlated with particular continental sources. Tentative correlation is suggested for five sherds. The remaining three sherds clearly do not come from any of the sources investigated.     

Ancient Egyptian Pottery from the Subsurface Floodplain of the Saqqara–Memphis Area: Its Mineralogical and Geochemical Implications*

Potsherds recovered from the Saqqara–Memphis floodplain in Egypt, dated according to their typology and radiocarbon dating of the included sediments, are analysed geochemically and mineralogically to identify source materials and fabrication characteristics. Pottery layers were identified and potsherds were recovered from several settlement levels. Sherd typology was used to identify sherds from four periods (the Old and New Kingdoms, and from the Late Period to the Ptolemaic). The Pharaonic pieces were found at depths of between 8 and 12 m and the later material was between 6 and 3 m. Chemical analyses of the potsherds revealed three main source materials: local Nile silt, marl clay and mixed Nile silt–marl. Two marl clay types were recognized: marl clay from Upper Cretaceous marine sediment and another one from Late Pliocene deltaic sediments. The mineralogical composition of the pottery samples shows that the estimated firing temperature was about 850–900°C. No consistent differences in sherd mineralogy and geochemistry were found according to pottery types, so that the ancient Egyptian potters used essentially the same materials throughout the Pharaonic period. However, this initial study has revealed the existence of extensive pottery‐rich occupation sites buried within the Nile floodplain deposits between Memphis and Saqqara.     

Neutron activation analysis of fine grey pottery from Conimbriga,Santa Olaia and Tavarede,Portugal

The concentrations of two major elements and thirteen trace elements in 73 selected sherds of fine grey ware from the Iron Age and Roman period, excavated at Conimbriga, Santa Olaia and Tavarede, Portugal, were determined by instrumental neutron activation analysis. These concentrations were used to calculate distance matrices which were then subjected to cluster analysis employing SAHN and k-means methods, as well as to principal components analysis, to group the sherds according to the overall similarity of their compositional characteristics. The results showed that equivalent groupings appeared regardless of the taxonomic method used. Two major clusters were recognized corresponding to two different sites, namely Conimbriga and Santa Olaia, suggesting that the ceramics from these sites were made locally. No significant differences in compositional patterns were observed between iron age and roman sherds from Conimbriga.     

Thermoluminescence (TL) dating of ancient Syrian pottery from six different archaeological sites

Syrian archaeological pottery sherds were collected for TL dating from six different archaeological sites named Al-Shermanieh, Tell Serah, Der Al-Hajar (south of Damascus), Tell Al-Shekdakah, Tell Al-Souwirieh (east of Damascus) and Khurbet Al-Kulieh (south west of Damascus). The samples were prepared by fine grain technique and the annual dose for each sample (pottery sherds and soil sample) was measured using an alpha spectrometer system for uranium and thorium contribution as well as with atomic absorption spectrometry for the potassium contents. The mean ages were found to be 5500 ± 150 years, 2950 ± 50 years, 1200 ± 50 years, 1300 ± 150 years, 3300 ± 100 years and 3400 ± 200 years for the examined pottery from the sites Al-Shermanieh, Tell Serah, Der Al-Hajar, Tell Al-Shekdakah, Tell Al-Souwirieh and Khurbet Al-Kulieh, respectively. The results were in good agreement with the ages estimated by archaeologists except for one sample which belongs to Der Al-Hjar site.     

Defining the provenance of red slipped pottery from Texas and Oklahoma by petrographic methods

Ceramics are among the most important artifacts that archaeologists use to reconstruct patterns of prehistoric trade and exchange. Petrographic analysis of ceramic thin-sections, in addition to providing detailed technological data, enables the identification of sand-tempering agents. These raw materials are potentially important evidence for ceramic provenance, assuming that such common materials themselves would not have been traded. Here we apply methods developed by sedimentary petrographers to the problem of determining the provenance of Red Slipped sherds from late Prehistoric (c. AD 1000–1400) sites in the Caddoan area and contemporaneous Plains Village sites. Modal frequencies of different kinds of quartz, feldspars and lithic grains are used to construct several triangular graphs that reveal compositional patterns indicative of provenance. Sherds from the Plains Village sites exhibit higher frequencies of lithic grains, feldspars and polycrystalline quartz relative to the sherds from sites in eastern Texas and eastern Oklahoma. While anomalous sherds were identified, the longstanding assumption that Red Slipped sherds in Plains Village contexts were traded from the Caddoan area is not supported by these data. These methods have strong application potentials for other, geologically diverse portions of North America.     

A STUDY OF ANCIENT CHINESE PORCELAIN WARES OF THE SONG‐YUAN DYNASTIES FROM CIZHOU AND DING KILNS WITH ENERGY DISPERSIVE X‐RAY FLUORESCENCE*

Multi‐variable statistical analysis based on energy dispersive X‐ray fluorescence measurements on both porcelain body and glaze is employed to give clear and consistent classification of porcelain sherds from northern China of different styles from the Song‐Yuan dynasties (Ding and Cizhou styles), and also from the Sui‐Tang dynasties (Xing style). However, the observed separation is less clear for Cizhou style sherds produced at neighbouring kiln sites. Imitation Ding porcelain samples produced by ancient Cizhou potters are also analysed.     

Technological investigation of the decorative coatings on Yangshao pottery from Henan,China

Yangshao pottery sherds dated to c. 4200 bc from two archaeological sites in Henan province, China, were examined to determine the technological aspects of their decoration. The selected samples comprised plain and painted pottery, some of which have a white background slip and black or red decoration on the surface. Various analytical techniques including SEM/EDS, XRD and FTIR were applied in the study. Observations show that some pieces were wheel‐thrown. The refinement of the body fabric varies. Surface finishing includes simple burnishing, slipping and brushing. The black decoration on the surface is manganese black. The white background layer is kaolinitic clay slip. No organic binders or decorations were detected. The results of these analyses will help our understanding of the production steps involved in the craft production of Yangshao pottery.