Investigating ancient technology and ceramic composition at Al-Khidr site (Failaka Island,Kuwait): Geochemical analyses of Bronze Age pottery by pXRF and thin-section petrographic analyses

Pottery assemblages from the site of Al-Khidr on Failaka Island, Kuwait, were analysed in order to reconstruct the chemical composition of Bronze Age wares and to build a mineralogical database of Bronze Age pottery dated from Failaka Periods 1–3B (2000–1650 BCE). A total of 145 ceramic sherds from Al-Khidr, as well as reference groups, were analysed by non-destructive portable X-ray fluorescence (pXRF) spectrometry. Preliminarily petrographic thin-section analysis was applied to four samples to reconstruct possible clay paste recipes and to identify raw materials. The results indicate that geochemical analyses can successfully distinguish subgroups within a typological category of ceramic assemblages. The results identified two subgroups within the Al-Khidr typological category: the Dilmun Barbar tradition and the Mesopotamian tradition. Future comparative compositional studies can be conducted to explore other aspects of craft specialisation, such as ceramic technological choices and possibly the influence of sociopolitical units.     

殷墟出土灰陶器的制作与烧制实验研究

本文结合考古实证、史料记载、民族学调查资料、陶器岩相学分析以及复原实验等方法,最大可能地去复原殷墟出土灰陶器的制作与烧制技术。复原实验分两大步:一是灰陶器的制作,大致可分为取土、洗土、制作、阴干、修整等几道工序;二是灰陶器的烧制,大致可分为建窑、装窑、烧窑、还原(加牛粪或水)、出窑等几道程序。复原实验历时2年,比较成功地制作和烧制了200余件灰陶器。经过本次复原实验,我们切实了解了殷墟灰陶器的制作工艺和烧制技术。     

CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF SASANIAN AND EARLY ISLAMIC GLAZED CERAMICS FROM THE DEH LURAN PLAIN,SOUTHWESTERN IRAN*

One hundred and seventy‐five glazed ceramics from Sasanian and Early Islamic period sites located on the Deh Luran Plain in southwestern Iran were examined by instrumental neutron activation analysis for characterizing differences in ceramic pastes and by laser‐ablation inductively coupled plasma mass‐spectrometry for identifying the constituents of the ceramic glazes. The results of the analysis reveal that alkaline‐based glazed ceramics have paste compositions that are distinct from contemporary and later ceramics decorated with alkaline–low‐lead and lead‐based glazes.     

The Faragola Ceramic Collection: Ceramic Production,Consumption and Exchange in Seventh‐Century Apulia

A collection of 30 ceramic samples, 16 of coarse wares and 14 of fine painted wares, have been investigated by optical microscopy, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry and neutron activation analysis. Further samples of clayey sediments, both locally outcropping and found within the settling tank, have been submitted to the same analytical techniques for comparison with the ceramic collection. The results demonstrated that local clayey sediments were used as received for the production of coarse wares. The same raw materials were sieved and/or refined by decantation for the production of fine painted wares, which, in fact, provided results that were perfectly comparable with those for the clayey raw materials found within the settling tank. The Faragola productions were distinguished from the neighbouring Apulian productions according to petrographic features (the presence of leucite‐bearing volcanic rocks and Mn‐rich wads) and their bulk chemical composition.     

A SPECTROSCOPIC INVESTIGATION OF PIGMENT AND CERAMIC SAMPLES FROM COPÁN,HONDURAS*

A combination of micro‐Raman spectroscopy, micro‐infrared spectroscopy and SEM–EDX was employed to characterize decorative pigments on Classic Maya ceramics from Copán, Honduras. Variation in red paint mixtures was correlated with changing ceramic types and improvements in process and firing techniques. We have confirmed the use of specular hematite on Coner ceramics by the difference in intensities of Raman bands. Different compositions of brown paint were correlated with imported and local wares. The carbon‐iron composition of the ceramic type, Surlo Brown, was confirmed. By combining micro‐Raman analysis with micro‐ATR infrared and SEM–EDX, we have achieved a more comprehensive characterization of the paint mixtures. These spectroscopic techniques can be used non‐destructively on raw samples as a rapid confirmation of ceramic type.     

A method for chronological apportioning of ceramic assemblages

Artifact assemblages from long-inhabited sites may include ceramic types and wares from multiple time periods, making temporal comparisons between sites difficult. This is especially problematic in macro-regional data sets compiled from multiple sources with varying degrees of chronological control. We present a method for chronological apportioning of ceramic assemblages that considers site occupation dates, ceramic production dates, and popularity distribution curves. The chronological apportioning can also be adjusted to take into account different population sizes during the site occupation span. Our method is illustrated with ceramic data from late prehispanic sites in the San Pedro Valley and Tonto Basin, Arizona, U.S.A., compiled as part of the Southwest Social Networks Project. The accuracy of the apportioning method is evaluated by comparing apportioned assemblages with those from nearby contemporaneous single component sites.     

PAUL‐LOUIS CYFFLÉ'S (1724–1806) TERRE DE LORRAINE: A TECHNOLOGICAL STUDY

Fragments of four Terre de Lorraine biscuit figurines were subjected to porosity analysis, X‐ray fluorescence analysis, X‐ray diffraction analysis, backscattered‐electron image analysis—coupled with energy dispersive spectrometry—and electron backscatter diffraction analysis to determine the porosity, bulk, major, minor and trace element compositions, and the composition and the proportion of their constituent phases. Cyfflé's Terre de Lorraine wares embrace two distinct types of paste, a calcareous and an aluminous–siliceous one. Both are porous (9–25% water adsorption). The former consists of a mixture of different proportions of ground quartz or calcined flint, ground Pb‐bearing glass and calcium carbonate with a refractory clay. The firing temperature was between 950 and 1050°C. For the latter, Cyfflé mixed ground pure amorphous SiO₂, ground quartz or calcined flint, ground porcelain, ground Na–Ca‐glass and coarse‐grained kaolinite with a fine‐grained kaolinitic clay. The figurines were fired below 1000°C. The result was a porous, hard paste porcelain‐like material. Cyfflé's recipes for both pastes can be calculated from the chemical and the modal analyses.     

The Emergence of Kwahe’e Black-on-white pottery in the Tewa Basin,New Mexico

Despite the importance of ceramic typologies for defining archaeological cultures and making chronological inferences, the ceramic types comprising these typologies are not always well dated. Here, we present an analysis of radiocarbon dates generated from Accelerator Mass Spectrometry of corn remains found in association with Kwahe’e Black-on-white (Kwahe’e B/w) ceramics from the Tewa Basin of the Northern Rio Grande region of New Mexico in the American Southwest. This autochthonous ceramic type is the first in a cohesive lineage of decorated white wares known as the Rio Grande ceramic series. A Bayesian analysis of these dates yielded a 95% probability range of a.d. 975–1023 for the beginning temporal boundary marking the emergence of Kwahe’e B/w. This estimate for the chronological emergence of Kwahe’e B/w is at least 27 years earlier than previously demonstrated and appears to coincide with the initial population increase in the Tewa Basin during the Late Developmental period (a.d. 900–1200), and with the emergence of the Tewa language that is still spoken in the region.     

CHARACTERIZATION OF TAKATORI STONEWARE FROM CHIKUZEN PROVINCE,JAPAN*

This study reports the findings of an examination of stonewares from the Takatori kilns of seventeenth- to nineteenth-century Chikuzen Province, Kyushu, Japan. Scanning electron microscopy and inductively coupled plasma atomic emission spectroscopy were used to determine the mineralogy and chemical compositions of the ceramic bodies. The results of this broad characterization are used to comment on the relationships between these wares and the raw materials used. Despite close similarities in some cases, it is possible to distinguish the wares of many of these kilns from each other and from outwardly similar wares from contemporary kilns in adjacent provinces.     

Tableware in the Hellenistic Tradition from the City of Kampyr Tepe in Ancient Bactria (Uzbekistan)

Slipped and unslipped wares from Kampyr Tepe dated to the Hellenistic–Seleucid and Greco‐Bactrian periods stylistically resemble tableware from the Greek tradition. Since two pottery workshops have been recovered at the site, the aim is to shed light on the provenance and the production and consumption patterns of the tableware, as well as on the degree of technological influence from Hellenistic–Mediterranean traditions. The archaeometric characterization, consisting of thin‐section petrography, XRF, XRD and SEM–EDS analysis, was performed on 44 wares and three unfired locally made pondera, which were used as reference local elemental patterns. The study demonstrated the local origin of most of the wares, which were produced using a similar clay paste, following standardized techniques in modelling and firing, while surface treatments appear to be more diversified.     

Inductively coupled plasma emission spectroscopy and Postclassic Petén slipped pottery: an examination of pottery wares,social identity and trade*

ICP–ES analysis of the clay pastes of Postclassic (c. ad 850–1524) slipped pottery from the central Petén lakes region establishes chemical composition groups that provide information concerning manufacturing traditions and trading patterns. These data demonstrate that manufacturing traditions and trading patterns change throughout the Postclassic period, reflecting possible socio‐political alliances as different ethnic groups migrated to and from the Yucatán peninsula into the central Petén lakes region. The chemical composition groups also demonstrate that some manufacturing traditions imitate those from the Late Classic period and that some clay sources were used throughout the Postclassic period for multiple ceramic groups.     

Cooking Pots and Islamicization in the Early Medieval Vega of Granada (Al‐Andalus,Sixth to Twelfth Centuries)

In this paper we undertake a petrographic analysis of cooking wares in order to explore the relationship between cultural change and issues of production, consumption and distribution of cooking wares, and particularly between political authority and the location of workshops in the early Islamic Vega of Granada, a region in south‐eastern Spain. This work offers the possibility of testing the potential of thin section petrography in combination with a detailed archaeological study and a well‐documented historical background. Examination of both the technology and microprovenance of wares within the Vega has led to a fruitful set of results with an important impact on our understanding of the place of ceramic material culture on both the local and the regional scale.     

INSIGHTS INTO NORTH MESOPOTAMIAN ‘METALLIC WARE’*

With the aim of shedding new light on the still poorly understood North Mesopotamian metallic ware, ceramic and soil samples from Tell Beydar (northeastern Syria, third millennium bc ) were investigated using a range of analytical techniques, including optical microscopy, SR–XRD and SEM–EDX. The objective of this work was to differentiate calcareous metallic ware from non‐calcareous ware without the aid of chemical analyses and to find further validation of the existing hypothesis that the former group is an imitation of the latter. A third group of metallic wares from Tell Beydar is believed to be of non‐local, still regional origin.     

浅谈定窑白瓷铭文

瓷器铭文是在瓷器制造过程中,运用刻划、模印、釉下书写等工艺手段在器物上题写的文字,书体有篆、隶、楷、行、草等。受同时期的文学、艺术、宗教、丧葬礼俗诸方面的巨大影响,中国古代瓷器铭文具有较强的时代特色和资料性,它的内容直接与现实生活中人们的思想观念、风俗习惯以及审美趋向结合,与器物的功用相联系,     

EDXRF对故宫博物院藏宋代官窑瓷器的无损分析

目前对宋代官窑瓷器的科技研究成果主要是在测试南宋老虎洞窑、郊坛下官窑等窑址瓷片基础上取得的,尚缺乏对宋代官窑完整器的科技分析和研究。本文采用荧光能谱仪(EDXRF)在无损情况下对故宫博物院藏35件宋代官窑瓷器青釉的化学组成进行了测试,并结合文献资料,系统地研究了宋代官窑瓷器青釉成分的组成特点及规律,为进一步揭示宋代官窑特征、深入探讨北宋官窑是否存在的问题、研究明清仿官窑以及区分宋官与仿官等问题奠定了基础。     

A MICRO‐RAMAN AND INTERNAL MICROSTRATIGRAPHIC STUDY OF CERAMIC SHERDS FROM THE KILNS OF THE MEDICI CASTLE AT CAFAGGIOLO*

Nine representative sherds from the old (14th–16th century) kilns at the Castle of Cafaggiolo in Tuscany have been analysed by means of internal microstratigraphic analyses and micro‐Raman spectroscopy and classified as follows: six engobed and glazed fragments, of which three are covered with an opaque white, decorated layer, one is marbleized, and two are engobed. The surface of the two engobed sherds, fragments of unfinished products, indicates that at least two firing processes were used. Two samples show characteristics of Byzantine pottery, and three of them can be classified as Islamic ware or maiolica, whilst the other one displays intermediate characteristics. The variety of ceramic wares indicates the presence of craftsmen with differing expertise, and suggests that part of their work was dedicated to experimentation on new ceramic production techniques.     

Ceramic Production in the Kur River Basin (Fars,Iran) During the Middle to Late Second Millennium bce: A Geochemical and Technological Characterization

A total of 119 middle to late second millennium bce pottery samples from six sites in the Kur River Basin (Fars, Iran) were examined to characterize these ceramics and reconstruct their manufacturing technology and the origin of the primary materials. For this, a combined study of handheld XRF and thin‐section petrography was performed. The geochemical signatures of these ceramics were defined and interpreted in their archaeological and geological framework, resulting in the determination of different production processes and clay types used for four ceramic wares (Middle Elamite, Qaleh, Shogha and Taimuran) and the identification of possible outcrops used for Shogha–Taimuran production.     

MINERALOGICAL ANALYSES OF CERAMIC MATERIALS FROM QUINUA,DEPARTMENT OF AYACUCHO,PERU

Mineralogical analyses of clays, tempers and paints from contemporary sources in the vicinity of Quinua, Peru, were carried out by means of X-ray diffraction, microscopic examination and physical separation. The data indicates that (1) there is a substantial amount of mineralogical variability in these materials, (2) the differences between the clays and tempers consist of the differences between the relative amounts of plastics and non-plastics present in each of these kinds of materials, (3) the paints contain a mineral known for its superior spreading qualities. The study concludes that (1) the region had the ceramic resources to support a tradition of several polychrome styles like those made during the Peruvian Middle Horizon (a.d. 600–800), (2) ancient pastes made in the region had a great deal of mineralogical variability, (3) archaeologists should redefine their notion of ‘temper’, and (4) modern mineralogical differences between pastes tempered by the potter and those not tempered by the potter can also apply to ancient pastes of the region.     

北宋海外贸易陶瓷之考察

北宋是海外陶瓷贸易相对平缓的一段时期,但贸易活动并未中断。北宋早中期,贸易陶瓷在五代宋初基础上渐进发展,越窑青釉瓷和景德镇窑青白釉瓷构成了稳定组合。北宋中期晚段是贸易陶瓷的转变期,闽广地区以外销为主的窑场迅速兴起并占据了海外市场的主体。其中广州、潮州、泉州窑场主要面向东南亚及西印度洋地区,福州窑场主要面向日本。北宋末期,闽南、广西窑场青白釉瓷繁盛,龙泉窑青釉瓷崛起,潮州、漳州产品亦见于日本。此时,东西方贸易陶瓷品类组合都趋于复杂化。     

Understanding ceramic variability: an archaeometrical interpretation of the Classical and Hellenistic ceramics at Düzen Tepe and Sagalassos (Southwest Turkey)

Within the aim of contributing to the artisanal craft history at Sagalassos (SW-Turkey), an archaeometric programme including thin section analysis, ICP-MS and multivariate statistics was developed to define the variability on a provenance and/or technological scale of the Classical/Hellenistic ceramic assemblage of Sagalassos and Düzen Tepe. The obtained data were used to evaluate the extent and variation of local pottery production. Petrographic and geochemical analysis as a grouping technique proves to be conditional for documenting the variation in ceramic wares present on both archaeological sites. Elemental evidence supports local production activities between Classical and Hellenistic times, documenting a deliberate change in treatment of raw materials during the Late Hellenistic period in function of ware groups.