Production of subterranean resources in the Atacama Desert: 19th and early 20th century mining/water extraction in The Taltal district,northern Chile

The Chilean water model imposed by the Chilean dictatorship in 1981 is broadly known as a radical example of neoliberal water management. Several studies have focused their analyses on this model, and its relation to mining, from a political ecology perspective; however, this has minimized the broader historical context. In this paper, we followed a geohistorical standpoint to gain an extensive understanding of the processes of mining development and the related water extraction in the Atacama Desert. By analyzing different official documents, historical sources and scientific discourses of the 19th and early 20th centuries, we aimed to denaturalize the idea of the Atacama Desert as hyper-arid space, rich in mineral resources. By doing so, from a political ecology perspective, and with a critical approach to territory, we interrogated the mining development in the Taltal district (1840–1920). This exercise led us to understand the Atacama Desert as a socially-produced mining territory, or miningscape, where foreign actors have produced hegemonic discourses and uneven materialities. Here, water, minerals, global markets, scientific knowledge, political and legal discourses, and colonialism have inevitably become interwoven in a territorial long-standing production process. Thus, we propose that the production of miningscapes and waterscapes are entangled process in the Andes mining territories. In turn, this process has enabled the reproduction of the Chilean state, capital accumulation, and the consolidation of a modern project at the expense of local populations and rationalities, which have been invisibilized.     

Fuel Efficiency of Ancient Copper Alloys: Theoretical Melting Thermodynamics of Copper,Tin and Arsenical Copper and Timber Conservation in the Bronze Age Levant*

The melting of pure or alloyed copper, tin and arsenical copper ingots or recycled objects was a drain on the timber and dung fuel resources of many cultures. This paper suggests formulae grounded in thermodynamic principles in an attempt to estimate the energy requirements necessary to melt copper alloys common to both Old and New World cultures, with the goal of identifying consumption and conservation patterns. It has been suggested that tin bronze metallurgy was first adopted in the Levant during the Early Bronze Age (EB) IV, at the onset of the Late Holocene climate episode (c.2300–2000 bc ), becoming the most desired alloy by the Middle Bronze Age (MB) II (2000–1530 bc ) due to the ease of melting tin. To test this hypothesis, the formulae are applied here to all published Levantine EB IV – MB II copper alloys. Fuel conservation rates are proposed based on the thermodynamic formulae. Tin bronze is demonstrably more fuel efficient than pure copper. Due to the inherent difficulties in predicting the behaviour of arsenical copper compounds, it is suggested that melting experiments with representative alloys are conducted to further test and refine these energy relationships.     

Production sequences of ostrich eggshell beads and settlement dynamics in the Geelbek Dunes of the Western Cape, South Africa

The archaeological record attests to the significance of ostrich eggs as a valuable resource for the people of the Later Stone Age. People over a broad geographic range used ostrich eggs to provide nourishment, storage and ornamentation. This paper focuses on the production, use and discard of ostrich eggshell beads recovered from open-air sites in the Geelbek Dunes of the Western Cape, South Africa. We present a comprehensive production chain for analyzing the manufacture of beads and introduce the concept of a heuristic production value for evaluating the degree of completion reflected by an assemblage. The pattern of fabrication and the distribution in size allow for a detailed analysis of the beads that points to specific behavioral patterns involved in their production. This analysis yields information about the duration and intensity of site use, as well as the individual members and cultural affinities of the groups who made the beads. We document the intentional use of fire to blacken the majority of the beads as an aesthetic choice. Combined with the results from AMS radiocarbon dating, the majority of the beads from Geelbek provide insight into the socio-economic identity of their manufacturers: small groups of hunter–gatherers who inhabited and used specific locations on the strandveld near Langebaan Lagoon.     

Combining photogrammetry and laser scanning for the recording and modelling of the Late Intermediate Period site of Pinchango Alto,Palpa, Peru

This paper describes the 3D modelling of Pinchango Alto, Peru, based on a combination of image and range data. Digital photogrammetry and laser scanning allow archaeological sites to be recorded efficiently and in detail even under unfavourable conditions. In 2004 we documented Pinchango Alto, a typical site of the hitherto poorly studied Late Intermediate Period on the south coast of Peru, with the aim of conducting spatial archaeological analyses at different scales. The combined use of a mini helicopter and a terrestrial laser scanner, both equipped with a camera, allowed a fast yet accurate recording of the site and its stone architecture. In this paper we describe the research background, the 3D modelling based on different image and range data sets, and the resulting products that will serve as a basis for archaeological analysis.     

Doubts about How the Middle Horizon Collapsed (ca. A.D. 1000) and Other Insights from the Looted Cemeteries of the Lower Ica Valley,South Coast of Peru

This paper presents new information from funerary contexts in the lower Ica Valley, on the south coast of Peru, spanning two millennia from the end of the Early Horizon to the Late Intermediate Period. Although severely looted, these sites can still yield valuable information. We discuss their architecture and material culture in the context of radiocarbon dates. Among other findings, these cast new light on the poorly understood transition from the Middle Horizon to the Late Intermediate Period, for which a paucity of archaeological data from ca. a.d. 1000–1250 has long been taken as evidence of an environmentally- or socially-induced demographic collapse. Yet the data we present here suggest that the basins of the lower Ica Valley were likely occupied continuously over this period, and that the echoes of Wari influence here may have lasted longer than previously thought.     

The Chronology of Settlements with Pre‐Inca and Inca Occupations Superimposed: the Case of Pucará de Tilcara (Humahuaca Gorge,Argentina)

The region of the Central and South Andes was, in about the ninth and 15th centuries ad , the stage for the development of political systems tending towards demographic centralization in villages with defensive structures, known as Pucará. The chronological accuracy for these phenomena still remains uncertain, mainly because it involves intervals of long and superimposed occupations, masked by the Inca domination. Thus, this paper analyses the history of the occupation at Pucará de Tilcara, one of the biggest populated centres of the Humahuaca Gorge (Quebrada de Humahuaca, Argentina). Twenty‐five radiocarbon dates are critically evaluated to judge its reliability. The Bayesian statistics show that all the dated spaces were used on a long‐term basis. The most ancient signs are in the middens and relate at least to the 10th century ad , and the occupation of the housing areas could be calculated to the 13th and 16th centuries. A phase of higher intensity of occupation is observed during the Inca period. This redefinition of this site occupation shows the need to statistically analyse the dates in order to differentiate the phases of occupation.     

Late Holocene climatic fluctuations and soil genesis in southern Patagonia: effects on the archaeological record

Geoarchaeological research conducted at five localities in southern Patagonia and Tierra del Fuego identified a mollisol within late Holocene aeolian and colluvial deposits associated with archaeological material. The mollisol's origin and development are related to an increase in humidity (c. 1000 BP) following an episode of severe drought during the Medieval Warm Period. Corroborating data is supplied from dendroclimatic and pollen studies. A drastic reduction in frequency of artefact distribution recorded at the sites studied corresponds to this pedologic event, suggesting a greater human presence at these sites during earlier, regional-scale arid conditions. However, the paucity of archaeological remains may also be the result of the low resolution of cultural evidence following the pedologic development due to superimposition over previous archaeological deposits.     

Mortality Profiles of Hunter‐Gatherer Societies: A Case Study from the Eastern Pampa–Patagonia Transition (Argentina) During the Final Late Holocene

The objectives of this work are to present a set of methodological procedures to analyse commingled bone assemblages (e.g. secondary burials), in order to build the mortality profile of the Paso Alsina 1 site and discuss the obtained age at death distribution in a context of hunter‐gatherer populations that inhabited the eastern Pampa–Patagonia transition (Argentina) during the Final Late Holocene. The Paso Alsina 1 site is a formal disposal area of inhumations composed by multiple secondary burials dated at ca. 500 ¹⁴C years BP. The site is comprised of a minimum number of 77 individuals, represented by both sexes and all age categories. The mortality profile is characterized by a bimodal pattern with a peak of greater representation of individuals younger than 3 years and another comprising the range between 20 and 34.9 years old. These results are discussed in relation to the paleopathological information available for the site, indicating that individuals suffered mainly disruptions in growth and development by systemic stress. The mortality profile obtained suggests that this skeletal series would not have formed as a result of a catastrophic event. On the contrary, it is an atricional mortality profile, consisting of individuals who died at different times and places and for varied reasons. Later, skeletal remains were grouped into secondary bundles and simultaneously buried at the site. Body manipulation and secondary burials are common in the context of a social reorganization that occurred in the area and in neighbouring regions during the Final Late Holocene. Copyright © 2013 John Wiley & Sons, Ltd.     

The Use of Hunting and Herding Spaces: Stable Isotope Analysis of Late Archaic and Early Formative Camelids in the Tulan Transect (Puna de Atacama,Chile)

We present the results of analysing stable carbon and nitrogen isotopes in camelid remains found at the Late Archaic site TU‐52 (ca. 5000–3800 bp ), the Tarajne Phase site TU‐94 and the Early Formative sites TU‐54, TU‐85 and TU‐122 (ca. 3100–2400 bp ). All of the sites are located in the Puna de Atacama (Northern Chile) along the 14 km Tulan transect, between the head of Tulan ravine (ca. 3000 m.a.s.l.) and the border of the Salar de Atacama (2317 m.a.s.l.). Our aim is to understand how the space was used by hunter‐gatherers and early herders from the beginning of camelid domestication to the consolidation of herding practices. Isotopic analyses were complemented with osteometric data in order to correlate changes in animal size and isotopic values with the initiation of animal husbandry. Isotopic and osteometric results show less variability of δ¹³C and δ¹⁵N values during the Late Archaic and Tarajne Phase, whereas variability is higher during the Early Formative. We postulate that during the latter period, there was more widespread use of hunting and herding spaces along the Tulan ravine, including areas above 3000 m.a.s.l. as result of more consolidated herding practices, while the highlands were used as a complementary space to hold livestock near ritual sites and residential settlements. Copyright © 2017 John Wiley & Sons, Ltd.     

New Data on the Soda Flux Used in the Production of Iznik Glazes and Byzantine Glasses

Previous research has shown that Iznik glazes are characterized by low potash and magnesia contents. It was therefore suggested that the flux used was either a purified plant ash or some unidentified mineral source of soda. More recently, as a result of the detection of small, but significant, amounts of boron and lithium in Byzantine glasses from western Turkey, which also exhibit low potash and magnesia contents, it has been suggested that the source of the flux used was a soda‐rich evaporite associated in some way with the extensive borax deposits in the region. LA–ICP–MS has been used to establish that Iznik glazes also contain similarly small amounts of boron and lithium. The Na/K, Na/Mg, Na/Ca and Na/B ratios for these Iznik glazes are shown to be comparable to the equivalent ratios calculated from published data for waters from a range of Na–HCO₃ type hot springs in western Turkey, with the closest match being to the hot springs around Afyon‐Gazligöl, which is consistent with documentary evidence. It is therefore proposed that the soda‐rich salts produced by evaporating water from these springs to dryness would have provided the flux required for the production of Iznik glazes and high‐boron Byzantine glasses.     

X‐ray Diffraction and SEM Investigation of Wall Paintings Found in the Roman Temple Complex at Horvat Omrit,Israel

In the present study, the fragments of wall painting found in the Roman Temple Complex at Horvat Omrit were analysed for the first time using the non‐destructive techniques of X‐ray diffraction (XRD) and scanning electron microscopy (ESEM) equipped with energy‐dispersive X‐ray spectroscopy (EDS). The application of these methods enabled unambiguous identifications of the pigments and plaster components of the samples. Quantitative information on mineral composition, crystallite size and elemental composition of each studied paint layer and plaster was collected. Based on the results of the XRD and EDS analyses, the green pigment was identified as celadonite. It was revealed that the Egyptian blue pigment does not contain impurities of tin and lead, and this excludes the use of bronze scrap in its synthesis. Comparison of the mineral composition of the paint layers indicates that a wider palette of colours was obtained by mixing the available mineral pigments. The study of cross‐sections of painted specimens revealed the usage of slaked lime for plastering. The obtained results give a new insight into the wall painting technique employed by ancient artists at Horvat Omrit, in northern Israel.     

The early roman imperial AES coinage II: Tracing the copper sources by analysis of lead and copper isotopes—copper coins of Augustus and Tiberius*

Lead and copper isotopes of Roman Imperial copper coins (denominations as and quadrans) were analysed by MC–ICP–MS. We concentrated on well‐dated coins minted at the official mint of Rome under the Emperors Augustus and Tiberius (between 16 bc and ad 37). The lead isotope results were compared with published lead isotope data of ore bodies from the Aegaean, Cyprus, Italy and Spain, in order to fingerprint the sources of Roman copper. During the Augustan period the main copper supply, as judged from the copper coins, is from Sardinia and south‐east Spain, with minor contributions from Tuscany. Except for Tuscany, this continued into the Tiberian period, when Cypriot copper also appears. Augustan quadrantes and late Tiberian asses came solely from the Rio Tinto area in south‐west Spain. Copper isotopes were applied here for the first time to systematic archaeometric studies. They are supplementary to lead isotopes and allow further grouping and classification of the copper coins.     

Obsidian Sources in the Regions of Erzurum and Kars (North‐East Turkey): New Data

The obsidian sources on the Erzurum–Kars Plateau have not been extensively surveyed, and their geochemical signatures are still poorly understood. Yet a significant number of artefacts from archaeological sites in Georgia and Armenia have produced chemical compositions that are unrelated to any Turkish or Caucasian source analysed so far. Their origins may lie in these poorly known deposits. The objective of the collaborative project undertaken by the University of Erzurum and the French mission ‘Caucasus’ is to study the sources of obsidian in the Erzurum and Kars regions, in order to shed light on the intensity of exploitation of this material, and to highlight the exchange networks that may have existed between north‐eastern Turkey and the southern Caucasus. The analyses that we have carried out on the samples taken during this exploratory survey have enabled a definite extension of the territory of circulation of this obsidian to western Transcaucasia. The lack of knowledge concerning the diffusion of obsidian from the regions of Erzurum and Kars thus appears for the moment mainly related to insufficient geochemical characterization of the sources, confirming the importance of future surveys.     

Petrographic and Geochemical Investigations on the Pottery Production from Arslantepe–Malatya (Eastern Anatolia) from the Fourth to the Second Millennium BCE: Technological Continuity,Innovation and Cultural Change

The petrographic and geochemical analyses of 130 Late Chalcolithic 3 (LC3, 3800 bce ) to Early Bronze Age IIIB (EBAIIIB, 2000 bce ) ceramics from Arslantepe and the Malatya Plain in the Eastern Anatolian Upper Euphrates have identified critical differences in raw material procurement and paste preparation, reflecting typological, chronological and cultural changes. Based on these differences, distinct modes of production that correspond to phases reflecting significant social, economic and political changes were recognized. In particular, the interruption of the centralization process and the establishment of mobile groups during EBAI (3000–2900 bce ) were accompanied by the exploitation of new sources.     

The Intentional Use of Lead–tin Orange in Indian Islamic Glazes and Its Preliminary Characterization

We describe the historical appearance, composition and texture of a little‐known orange pigment in 17th‐century northern India. The pigment shares similarities with lead–tin yellow type II, but has between 6 and 7 wt% zinc oxide instead of silica as a minor element in its structure, in addition to the dominant lead and tin oxide. The consistency of its occurrence and composition across several important and highly decorated monuments and relatively wide chronological and geographical ranges of use indicate the controlled and intentional production of this pigment. We propose to use the name lead–tin orange for this material, indicating its similarity to lead–tin yellow but highlighting its independent character and distinct colour.     

Inductively coupled plasma emission spectroscopy and Postclassic Petén slipped pottery: an examination of pottery wares,social identity and trade*

ICP–ES analysis of the clay pastes of Postclassic (c. ad 850–1524) slipped pottery from the central Petén lakes region establishes chemical composition groups that provide information concerning manufacturing traditions and trading patterns. These data demonstrate that manufacturing traditions and trading patterns change throughout the Postclassic period, reflecting possible socio‐political alliances as different ethnic groups migrated to and from the Yucatán peninsula into the central Petén lakes region. The chemical composition groups also demonstrate that some manufacturing traditions imitate those from the Late Classic period and that some clay sources were used throughout the Postclassic period for multiple ceramic groups.     

Fluid chemistry in the Solitaire and Dodo hydrothermal fields of the Central Indian Ridge

Fluid chemistry and microbial community patterns in chimney habitats were investigated in two hydrothermal fields located at the Central Indian Ridge. Endmember hydrothermal fluid of the Solitaire field, located ~3 km away from the spreading center, was characterized by moderately high temperature (307°C), Cl depletion (489 mm ), mildly acidic pH (≥4.40), and low metal concentrations (Fe ≤ 105 μm and Mn = 78 μm ). Chloride depletion indicates that the subseafloor source fluid had undergone phase separation at temperatures higher than ~390°C while the metal depletion was likely attributable to fluid alteration occurring at a venting temperature of around 307°C. These different temperature conditions suggested from fluid chemistry might be associated with an off‐spreading center location of the field that allows subseafloor fluid cooling prior to seafloor discharge. The microbial community in the chimney habitat seemed comparable to previously known patterns in typical basalt‐hosted hydrothermal systems. Endmember hydrothermal fluid of the Dodo field, standing on center of the spreading axis, was characterized by high H₂ concentration of 2.7 mm . The H₂ enrichment was likely attributable to fresh basalt–fluid interaction, as suggested by the nondeformed sheet lava flow expansion around the vents. Thermodynamic calculation of the reducing pyrite–pyrrhotite–magnetite (PPM) redox buffer indeed reproduced the H₂ enrichment. The quantitative cultivation test revealed that the microbial community associated with the hydrothermal fluid hosted abundant populations of (hyper)thermophilic hydrogenotrophic chemolithoautotrophs such as methanogens. The function of subseafloor hydrogenotrophic methanogenic populations dwelling around the H₂‐enriched hydrothermal fluid flows was also inferred from the ¹³C‐ and D‐depleted signature of CH₄ in the collected fluids. It was observed that the hydrothermal activity of the Dodo field had ceased until 2013.     

Savoury Recipes and the Colour of the Tlatelcomila Human Bones

Bones from Tlatelcomila (Tetelpan, México D.F.) were characterized by several complementary physical and chemical techniques, such as X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, atomic force microscopy, energy‐dispersive spectroscopy and ultraviolet spectroscopy, to determine whether they were boiled or grilled. The usual correlation between thermal treatment and colour is revisited in terms of microscopic structure, morphology and texture. At temperatures less than 100°C, it is shown that colour depends not only on temperature or diagenesis but also on the cooking procedure; that is, on the presence of spice dyestuffs such as axiote (Bixa orellana) or chilli (Capsicum).     

The Composition and Microstructural Variation of the Bronze Age Metal Ornaments from Lower Silesia (South‐West Poland): Chemical Analytical and Archaeological Aspects

Metal ornaments from Únětice (Mierczyce, Tomice, Jordanów and Opatowice) and Urnfield culture (Szprotawa, ?arek and Wroc?aw ?erniki) sites in south‐west Poland are made of bronze of varying composition, with the exception of the early Bronze Age Przec?awice site, where the copper items are found in graves from stages III/IV. The combined XRF and electron microprobe study of 37 ornaments (mostly pins) shows that those excavated from Únětice culture graves usually consist of cored dendrites, plus a Sb‐rich phase in some. The copper objects from Przec?awice correspond in composition to the East Alpine Copper or to the Ösenring copper and were produced from fahlore. Those from the Urnfield culture sites consist of homogeneous bronze. The Únětice culture ornaments were produced with little control of the effect of varying bronze composition on its microstructure. The results of XRF analyses of heterogeneous metal artefacts vary depending on the proportion of phases in the analysed site, and should be combined with micrometre‐scale analytical data and microstructural information yielded by electron microprobe methods. The same refers to deeply weathered or corroded objects made of homogeneous metal, which contain irregularly dispersed decomposition products.