ACKNOWLEDGING FIFTY YEARS OF NEUTRON ACTIVATION ANALYSIS IN ARCHAEOLOGY

Neutron activation analysis has been an important analytical technique for chemical characterization studies of archaeological materials since 1957, and remains one of the best analytical approaches for bulk chemical characterization of archaeological ceramics and other materials. This paper introduces a series of reports that document the history of NAA applied to archaeological materials.     

NEUTRON ACTIVATION ANALYSIS OF ARCHAEOLOGICAL MATERIALS: AN OVERVIEW OF THE ITN NAA LABORATORY,PORTUGAL

Instrumental neutron activation analysis (INAA) has been applied to archaeological samples at the Portuguese Research Reactor (RPI) since 1973, and the number of samples analysed has increased steadily since the mid‐1990s. Archaeometric applications of INAA at RPI include the analysis of archaeological ceramics and the stones used in monumental architecture (menhirs) and other historical monuments. A programme of analysis also exists for measuring the precision of and contributing to the certified values of geochemical reference samples. In addition, the study of interference factors is performed to obtain better accuracy in the determination of concentrations of some elements (e.g., corrections for spectral interferences from uranium fission products in the determination of barium, rare earth elements and zirconium).     

Morphometric Analysis of Camelid Remains from the Alero Deodoro Roca (ADR) Site (Córdoba,Argentina). An Attempt to Characterise Body‐Size Variability in Sierras Pampeanas Australes Region

This paper focuses in the morphometric analyses of Lama guanicoe remains recovered from the hunter–gatherer archaeological site Alero Deodoro Roca, located at Sierras Pampeanas Australes region (Córdoba Argentina), an area that has little information on the body‐size variability of these artiodactyls. Because of the sparse osteometric data in the region, we focused on determining inter‐intraspecific differentiation of wild camelids through corroborated osteometric techniques and multivariate statistical analyses of proximal phalanges. Our results showed a clear interspecific differentiation between modern vicuñas and archaeological specimens. We could also distinguish at least three guanaco size groups (small, medium and large) with the archaeological remains from the late Holocene (3000–3600 bp ) of the site, presenting medium‐size characteristics. Finally this paper aims at establishing a first approach in the characterisation of guanaco body size in the mountainous region of Córdoba. Copyright © 2016 John Wiley & Sons, Ltd.     

Assessing Prehispanic Herding Strategies through Stable Isotope Analysis: A Case Study from the Dry Puna of Argentina

ABSTRACT

The main goal of this work is to study the camelid herding and management strategies employed by the human groups that occupied the Dry Puna of Argentina during the late Holocene. Carbon and nitrogen stable isotope compositions were measured on bone collagen from domesticated South American camelids (llamas: Lama glama) recovered at two archaeological sites (Huirunpure and Chayal Cave). These results were interpreted using an already published data set of δ ¹³C and δ ¹⁵N values measured on bone collagen from modern herds of llamas managed in a traditional way. Our results showed that even though the archaeological sites of Huirunpure and Chayal Cave are located within different settings – at 4020 and 3700?masl respectively – and present different chronologies – 0–650 and 1300–1500 CE respectively – the llamas from both sites exhibit similar δ ¹³C and δ ¹⁵N values. This pattern was explained considering the characteristics of the vegetation communities that grow in the vicinity of both sites as well as the paleoenvironmental records of the Andean highlands. In sum, this work presents and discusses some preliminary results on the study of prehispanic herding practices in the Dry Puna of Argentina during the first 1500 years of the Common Era through stable isotope analysis.     

Ceramic findings from the archaeological site at Aiano-Torraccia di Chiusi (Siena,Italy): a multi-analytical approach

In 2005, the remains of a Roman villa, dating from the early fourth to the sixth centuries ad, were discovered at the archaeological site of Aiano-Torraccia di Chiusi (Siena, Italy). After being abandoned in the sixth century ad, the complex was occupied by a group of Ostrogothic or Lombardic artisans in the period between the sixth and the seventh centuries ad. Many ceramic remains (coarse pottery and red slip ceramics) from the first to the seventh centuries ad have been discovered on this archaeological site. These findings have been analysed using different analytical techniques (optical microscopy (OM), X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope-energy dispersive spectroscopy (SEM-EDS), attenuated total reflection Fourier transform infrared (ATR-FTIR), and micro-Raman in order to characterize the ceramic body, the coating, the temper, and to investigate the compositional relationship between the different kinds of ceramics. The use of different techniques on the same samples yielded information at different scales. OM and SEM-EDS yielded interesting information on the coarse pottery: the analyses performed on some minerals and rock fragments suggest that stone tesserae from the Roman villa (in the form of numerous marble fragments) were used in the production of this pottery. Bulk analyses (XRD and XRF) and subsequent micro-analyses (SEM-EDS, ATR-FTIR, and micro-Raman) of the red slip pottery revealed clear chemical, mineralogical and textural differences: some ceramics (the TCC sample group) typically have a Fe-enriched coating while others (the INGR sample group) present a clear difference in grain size but no chemical or mineralogical differences between the ceramic body and the coating.     

Morphometric Analysis of the Yellow Clam (Amarilladesma Mactroides) to Interpret Fragmentary Archaeological Specimens

Mollusks were an important component in the diet of the hunter-gatherer groups that inhabited the coastal zones of South America during the Holocene, as recorded in the littoral shell and archaeological sites distributed from Brazil to Argentina. Although the shells are relatively resistant to physical and chemical agents, they are also fragile and various post-depositional processes affect their integrity. Puente de Fierro is an archaeological site located in the south of Buenos Aires province (Argentina), in which remains of the yellow clam (Amarilladesma mactroides) were recovered totally fragmented. We investigate if a morphometric model based on modern clams could be applied to estimate shell size and individual biomass of archaeological clams. Linear regression models reveal a high correlation between the chondrophore length and the shell length, and therefore, the individual biomass of the yellow clam.     

Trade and the Construction of Bahamian Identity: A Multiscalar Exploration

Using ceramic data, we explore how a multiscalar approach, framed within Giddens' Theory of Structuration, can lead to a more complete understanding of the construction of New World Creole identities. The two scales of analysis serve to inform one another. We draw upon archaeological and historical data from five plantation sites located on three islands of the Bahamas. On the macroscale level, we demonstrate how regional trade networks limited or facilitated access to ceramics and shaped the ways that individual planters used these goods to construct statements about wealth and prestige. A microscale analysis of ceramics recovered from six slave households demonstrates how families with complete market access used ceramics as a means of creating a sense of community identity and mediating tensions within the quarters.     

Identifying the sources of Inka period ceramics from northern Chile: results of a neutron activation study

To examine regional patterns of ceramic production and distribution during the era of Inka domination in northern Chile, we determined the elemental compositions of 157 samples of archaeological ceramics and geological clays from the sites of Catarpe and Turi using instrumental neutron activation analysis. We identified two major and three minor composition groups in the ceramics. The major groups, High Cr and Low Cr, are linked to clays from two broad geological contexts within the region, while the minor Low Na group is made up of ceramics imported from northwestern Argentina. The distribution of the composition groups indicates that, in the Catarpe–Turi region, patterns of ceramic production differed for different vessel types: jars were made from clay and temper acquired near the sites where the jars were used, while bowls were made of material coming from more distant sources. The geographical distribution of the analyzed ceramics indicates that bowls were exchanged between Catarpe and Turi in a pattern more similar to tribute/extraction than to market exchange, with Catarpe being the dominant site. The compositional analysis also demonstrates that Inka-style ceramics were being locally produced at sites in this region during the era of Inka domination.     

The Role of Bubo virginianus magellanicus as Rodent Bone Accumulator in Archaeological Sites: A Case Study for the Atuel River (Mendoza,Argentina)

Micromammalian bone assemblages from modern pellets of the strigiform Bubo virginianus magellanicus, from the upper Atuel River (southern Mendoza, Argentina), were taphonomically analysed. The results allow us to place B. v. magellanicus in the category of intermediate modification (Category 2). This sample has also been compared with results from other members of this genus, in order to classify B. v. magellanicus as a taphonomic agent. The participation of the Bubo species in archaeological accumulations has been documented, but in Argentina, the role of B. v. magellanicus has been reported up to the present. It is partly because of the sequence of one archaeological site in the south of Mendoza Province called Laguna El Sosneado‐3 (LS‐3). However, considering the absence of a current taphonomic model of this owl, this participation was mentioned as a hypothesis. In the current investigation, archaeological and modern samples have been compared. The results indicate that the skeletal element assemblages recovered from LS‐3 were accumulated by strigiform birds. Taphonomical evidence of light modifications on units I and IV indicates that Tyto alba (Category 1) was probably the main species involved in these units, whereas the taphonomical evidence on skeletal element assemblages recovered from units II and III suggests the action of a strigiform with a major category of modification such as B. v. magellanicus. Copyright © 2015 John Wiley & Sons, Ltd.     

Historical Archaeology: An Outlook from the Argentinean Pampas

This paper ponders a number of theoretical and methodological aspects concerning historical archaeology and resulting from an analysis of their development and integration with disciplines such as history, ethnohistory, and anthropology. Special attention is paid to how these are involved in the research of documentary evidence and how the different approaches have an influence on a given case. The authors' viewpoint in the matter is explained and reported on the basis of the fleldwork they conducted at an archaeological site: a midnineteenth-century fortlet located in the center of Province of Buenos Aires, Argentina.     

THE DISCOVERY OF ANOMALOUSLY HIGH SILVER ABUNDANCES IN POTTERY FROM EARLY ROMAN EXCAVATION CONTEXTS IN JERUSALEM*

This is the first study on the differential distribution and concentrations of silver in ceramics recovered from archaeological excavations. The chemical compositions of 1174 pottery vessels from 38 Roman‐period sites in Israel have been determined. Unusually high and variable abundances of silver were discovered in pottery samples of all vessel types and chemical compositions from four distinct archaeological contexts dating to late first century bce to 70 ce Jerusalem. The large majority of the Jerusalem vessels could be distinguished by their silver abundances from all analysed pottery pieces recovered at rural sites outside Jerusalem, even when the pottery types and chemical compositions, except for silver, of pottery found within and outside Jerusalem were indistinguishable. The evidence is suggestive of a human origin for the high and variable silver abundances, and dispersion of the silver by aqueous transport. The differential silver concentrations found in excavated pottery from Jerusalem and other urban and rural sites suggest that attention to the distribution of silver in pottery from excavated contexts may be helpful for evaluating the nature and function of archaeological remains and patterns of urban contamination.     

ceraDAT—PROTOTYPE OF A WEB‐BASED RELATIONAL DATABASE FOR ARCHAEOLOGICAL CERAMICS

The prototype of a relational database for archaeological ceramics is presented. At this stage, the ceraDAT database contains the elemental compositions of several thousand ceramic artefacts from the Eastern Mediterranean, analysed by neutron activation analysis (NAA) at different laboratories. The data have been calibrated on the basis of the analytical routine and can be accessed via a web application. Apart from the elemental compositions, the database contains reference patterns of specific sites, metadata concerning archaeological information, the geographical distribution, literature references and former statistical evaluations. Due to the database design, the structure can be extended in future towards petrographical and mineralogical information.     

ARCHAEOLOGICAL AND CHEMICAL RESEARCH ON SEDIMENTS AND CERAMICS AT POLIDEPORTIVO (SPAIN): AN INTEGRATED APPROACH*

This paper proposes a preliminary approach to the integration of archaeological evidence and various chemical analyses (phosphorus and lipid) on sediments and ceramics. Phosphorus and organic matter analyses are, thus, used for the study of sediments, and lipid analyses for pottery from structure 19 of the Late Neolithic—Early Copper site known as ‘Polideportivo’, Martos, southern Spain. The results of both types of analysis point to a predominantly domestic function for this structure.     

The HMS Swift shipwreck: The development of underwater heritage protection in Argentina

Abstract

The aim of this article is to evaluate, with a critical perspective, the legal framework for heritage protection in Argentina, viewing it within an international context and focusing on the HMS Swift shipwreck – sunk in Puerto Deseado (Santa Cruz province) in 1770 – as a case study. Moreover, some initial proposals for a management plan are presented as a first step in thinking about the challenges of preserving underwater sites in Argentinian Patagonia.

Through this analysis some interesting points are outlined, including the reasons that make the Swift shipwreck a leading case in Argentina. It is the first interdisciplinary underwater archaeology project in the country comprising archaeologists who are also divers; it is supported by national authorities; and it is the first project of its kind to give underwater archaeologists experience in dealing with archaeological research and preservation in an environment of multiple conflicting interests.

The international relevance of the Swift case relies on the nature of underwater cultural heritage as an international resource. The project's history is located in an international setting, derived from ihternational trade and communication, in which many ships and their contents have been lost far from their origin or destination. At a national level the Swift is a wreck with significant historical and cultural value. It is in a unique state of preservation and its location near to the shore makes it highly accessible. Locally,HMS Swift will be relevant when Puerto Deseado's community starts to recognise it as a significant part of their own heritage and local people become involved in the preservation of the wreck.     

GLAZED CERAMIC MANUFACTURING IN SOUTHERN TUSCANY (ITALY): EVIDENCE OF TECHNOLOGICAL CONTINUITY THROUGHOUT THE MEDIEVAL PERIOD (10TH–14TH CENTURIES)*

Archaeometric investigation allowed the characterization of two important classes of ceramics: ‘vetrina sparsa’ and ‘invetriata grezza’. Their archaeological peculiarity makes them particularly suited for tracing the evolution of glaze manufacturing in southern Tuscany throughout the medieval period (10th–14th centuries). These ceramics were found in different sites of historical importance, and also from a mining perspective. Local copper, lead, zinc and iron mineralizations supported the growth of several settlements in the vicinity of the mines. The many castles and different archaeological finds (ceramics, glazed ceramic, slag etc.) attest to the intense mineral exploitation of the area from at least the first millennium bc up to the modern period. In light of these geological and archaeological characteristics, archaeometric investigation was intended to provide insight into ancient technical knowledge of ceramic glazing and to determine the source area for raw materials in the medieval period (10th–14th centuries). Ceramic bodies were analysed through OM, XRDp, SEM–EDS and XRF, while coatings were investigated through SEM–EDS. Mineralogical, petrographic and chemical analyses revealed slightly different preparation and firing processes for the two classes of ceramics. These data suggest the continuity through the centuries of the ‘vetrina sparsa’ and ‘invetriata grezza’ production technology. The mineralogical phases, such as monazite, xenotime, zircon, barite, Ti oxide, ilmenite, titanite, tourmaline and ilvaite, and the lithic (intrusive and volcanic) fragments detected within the ceramic bodies suggest a source area in the vicinity of the Campiglia mining district. Lastly, the presence of Cu–Zn–Pb (Ag) and Fe sulphide mineralizations (materials used to produce glaze) in the area supports the hypothesis of local manufacture.     

The pre-Hispanic ceramic technology of South American hunter–gatherers (Paraná River Delta, Argentina): a preliminary archaeometric study

This work presents the preliminary results of studies conducted on pre-Hispanic pottery produced by the South American hunter–gatherer communities that inhabited the Paraná River lowlands during the Late Holocene. The data generated allow advancement of knowledge and discussion regarding the ceramic technologies employed by these groups, which have to date received little archaeological study. Specifically, technological and formal-functional analyses have been performed on a ceramic assemblage from the site of Cerro Puesto Acosta, located in the upper region of delta formed by this high-volume South American river in northeastern Argentina. Both macroscopic and microscopic aspects of these ceramics have been studied using archaeometric techniques (petrographic analysis). The patterns revealed by these analyses suggest the implementation of technological choices oriented towards the creation of vessels especially suitable for the processing, cooking, and serving of foods, which indicates the economic importance of these artifacts in allowing maximum advantage to be taken of the area’s available resources.     

Magnetic Sourcing of Obsidians in Southern South America: Some Successes and Doubts

Sourcing of archaeological obsidians is of great importance in unravelling the cultural, social and economic development of many ancient societies. Use of magnetic properties of obsidian fragments has been reported as a cheap, fast and versatile tool for these purposes. One hundred and seventy-six obsidians from archaeological sites and sources in Argentina and southern Chile were analysed magnetically using the weight-normalized intensity of JNRM (Intensity of Natural Remanent Magnetization), the intensity of JSIRM (Intensity of Saturation of Isothermal Remanent Magnetization) at 0·35 T and the bulk susceptibility. The method allowed identification of at least two different sources for archaeological materials found respectively to the north and south of the Lago Argentino, in SW Santa Cruz province, Argentina. Comparison of values from most samples in south and central Santa Cruz with those from a known source may lead to the interpretation that most of them belong to that source. In contrast, a critical analysis of the resolution of this using a larger than usual number of samples from three well distant obsidian sources in Argentina showed that two of the sources showed an almost complete overlapping of these three parameters, and all displayed a very large dispersion of values. This different result indicates that the magnetic sourcing of obsidians may not always have the resolution previously portrayed, but is applicable in certain localities.     

Determining Olmec maize use through bulk stable carbon isotope analysis

Bulk stable carbon isotope analysis on absorbed organic residues in ceramics can be an effective method for discerning patterns of maize use when the ceramics come from relatively uniform archaeological contexts. The bulk stable carbon isotope method is faster and less costly than the more commonly used compound-specific stable carbon isotope analysis. Moreover, the bulk stable carbon isotope method can determine the presence of C4 plant carbon in samples in which organic compounds have degraded. Bulk stable carbon isotope analysis was used to discern patterns of maize (Zea mays mays) use among a sample of 24 ceramic sherds from an Early Franco Period feasting deposit (ca. cal 650 B.C.) at the Olmec site of San Andrés, La Venta, Tabasco, Mexico. A comparison of the δ 13C results of different categories of ceramics showed that proportionally more maize was used in luxury beverage service wares than in utilitarian vessels, suggesting that maize-based beverages were prominent in this probable elite feasting episode.