Transitions in cast iron technology of the nomads in Mongolia

Metallurgical study of seven cast iron artifacts recovered from sites of the former Xiongnu (BC 3rd to AD 1st), Turk (AD 6th to 8th), Khitan (AD 10th to 12th), and Mongolian empires (AD 12th to 15th) shows that the earlier Xiongnu and Turk artifacts were made of cast iron alloys of near eutectic composition. The later Khitan and Mongol objects had greatly reduced carbon content in the range of ultrahigh carbon steel rather than cast iron, and contained more than 0.5 mass % silicon as an alloying element. Inclusions high in sulfur, phosphorus or silicon are also present. These differences suggest that Mongolia experienced a technical transition a few centuries before the establishment of the Mongolian empire, which is in agreement with some written accounts. The microstructures of the cast iron artifacts are compared with the related archaeological and documentary evidence. The results suggest that the use of fossil coal in smelting and the state policy of controlling iron production were the major factors responsible for the transition.     

Metallurgical Characterization of A Coated Roman Iron Coin By Analytical Investigations

A coated Roman iron coin from Villa Loig in Salzburg, Austria was investigated. The coating is a copper alloy consisting of Cu, Pb, Sn, Zn and negligible amounts of Ag, a variant of gunmetal known as ‘leaded red brass’. The numismatic term for such a coin is subferratus (Latin). From an archaeometallurgical point of view, information about the chemical composition, the microstructure and the manufacturing technique are of interest. To achieve these objectives, different analytical techniques and metallographic examinations were applied. Droplet‐shaped iron inclusions were observed in the red brass coating, while at the grain boundaries, inside the iron core, copper and lead were detected (liquid metal embrittlement). The dendritic microstructure of the coating, the spheroidal‐shaped iron inclusions in the coating and the liquid metal embrittlement show that the iron coin was plated by immersing it in a molten copper alloy. The iron core is a low‐carbon steel with slag stringers, both of which are characteristic of a bloomery iron. Deformation twins (Neumann lines) were observed in the microstructure of the iron core and indicate that the coining was performed after the flan was cooled.     

鲁山望城岗冶铁遗址的冶炼技术初步研究

本文通过对河南鲁山望城岗,台铁遗址出土和采集的冶铁遗物的综合分析,证明该遗址是个集冶炼、铸造和炼钢为一体的大型工场,持续时间较长,具体工艺表现为采用选好的褐铁矿在高炉中炼出生铁,然后铸成器物,存在脱碳制钢的处理工艺,并且在冶炼时可能使用了煤炭作为燃料。     

The Nomad as State Builder: Historical Theory and Material Evidence from Mongolia

Theory on nomadic political complexity has largely been based on twentieth century ethnography and numerous historical accounts of the military confederations of pastoral nomads. Over the past two decades, archaeologists have increasingly used material evidence to evaluate ideas about nomadic polities and have added indigenous and local-scale perspectives to an understanding of nomadic political process in many regions across the Old World. One of these is Mongolia, a major center of nomadic state and empire formation, where archaeologists have recently focused attention on an early regional polity that arose at the end of the first millennium BC and is known as the Xiongnu (also Hsiung-nu) state. This paper synthesizes the latest archaeological research on the Xiongnu state in order to evaluate historical models that explain state emergence among nomads on the far eastern steppe. The material record from Mongolia adds the detail and resolution needed to refine existing explanations for Xiongnu state emergence.      

汉诸侯王陵墓出土铁器的比较

对徐州狮子山西汉楚王陵、永城保安山西汉梁王墓等7座汉王陵出土铁器的种类、材质、制作技术及功能进行了比较研究,探讨了汉代钢铁技术的发展状况、技术特征等问题。狮子山楚王陵5件炒钢制品的发现表明西汉早期(公元前2世纪中叶）已经发明了炒钢技术,是迄今为止最早的;块炼铁、块炼渗碳钢、生铁、铸铁退火、铸铁脱碳钢、炒钢、局部淬火、冷加工等多种钢铁冶炼和热处理工艺在西汉王陵出土铁器中都得到了广泛的应用,表明西汉时期钢铁技术有了较大发展,当时工匠对钢铁性能的认识提高到新的水平。     

CONTRASTING SUBSISTENCE STRATEGIES IN THE EARLY IRON AGE? – NEW RESULTS FROM THE ALFÖLD PLAIN,HUNGARY, AND THE THRACIAN PLAIN,BULGARIA

Summary. What can students of the past do to establish the predominant land‐use and settlement practices of populations who leave little or no artefactual discard as a testament to their lifeways? The traditional answer, especially in Eastern Europe, is to invoke often exogenous nomadic pastoralists whose dwelling in perpetuo mobile was based on yurts, minimal local ceramic production and high curation levels of wooden and metal containers. Such a lacuna of understanding settlement structure and environmental impacts typifies Early Iron Age (henceforth ‘EIA’) settlements in both Bulgaria and eastern Hungary – a period when the inception of the use of iron in Central and South‐East Europe has a profound effect on the flourishing regional bronze industries of the Late Bronze Age (henceforth ‘LBA’). The methodological proposal in this paper is the high value of palynological research for subsistence strategies and human impacts in any area with a poor settlement record. This proposal is illustrated by two new lowland pollen diagrams – Ezero, south‐east Bulgaria, and Sarló‐hát, north‐east Hungary – which provide new insights into this research question. In the Thracian valley, there is a disjunction between an area of high arable potential, the small size and short‐lived nature of most LBA and EIA settlements and the strong human impact from the LBA and EIA periods in the Ezero diagram. In the Hungarian Plain, the pollen record suggests that, during the LBA–EIA, extensive grazing meadows were established in the alluvial plain, with the inception of woodland clearance on a massive scale from c.800 cal BC, that contradicts the apparent decline in human population in this area. An attempted explanation of these results comprises the exploration of three general positions – the indigenist thesis, the exogenous thesis and the interactionist thesis. Neither of these results fits well with the traditional view of EIA populations as incoming steppe nomadic pastoralists. Instead, this study seeks to explore the tensions between local productivity and the wider exchange networks in which they are entangled.     

‘Guard the Good Deposit’: Technology,Provenance and Dating of Bipyramidal Iron Semi‐Products of the Durrenentzen Deposit (Haut‐Rhin,France)

In the early days of iron metallurgy in Western Europe, the most widespread type of ‘trade iron’ (semi‐product) was bipyramidal in shape. Although they are frequently found, little is known about how they were manufactured and circulated, or even about their age. An interdisciplinary approach was applied to the Durrenentzen deposit (Haut‐Rhin, France), the third‐largest in Europe in terms of artefact quantities, in an attempt to reconstruct the technological, social and economic context that caused them to be abandoned. A morphometric study of the 51 iron bars revealed a high degree of homogeneity, despite variations in detail. Four objects were selected for archaeometric studies. Metallographic analyses show internal differences (quality of the material, nature of the alloys and manufacturing techniques). Chemical analyses also showed different provenances. Finally, radiocarbon analyses of the carbon in steel (iron/carbon alloy) linked this deposit to the early Iron Age. This study provided the first benchmark for more general research, significantly changing perceptions of the economics of iron at the beginning of the Iron Age.     

Internal oxidation of cast iron artifacts from an 18th-century steel cementation furnace

Heavily corroded metal artifacts recovered from the site of an 18th-century steel cementation furnace in Trenton, New Jersey, are cast iron altered by internal oxidation. The progress of the internal oxidation process was followed by comparison with the microstructure of cast iron exposed to high temperature in a wood-burning fireplace. The graphite flake structure of the cast iron allows deep, rapid penetration of oxygen that reacts at the iron–carbon interfaces within the iron to form iron oxides that eventually replace the graphite flakes. Microprobe analyses show that the silicon in the cast iron is converted to knebelite that also serves as the host for phosphorus. Sulfur dispersed in the internal oxidation product and porosity appear to be responsible for rapid rusting of the artifacts. Internal nitriding accompanies the oxidation. The Trenton artifacts are interpreted as grate bars from the fire box of a cementation furnace.     

Coins,Forts and Commercial Exchanges in the Sixth‐ and Early Seventh‐Century Balkans

The nature of settlements in the sixth‐century Balkans is a matter of current debate. Amphorae and hoards of iron implements and weapons have been discussed in relation to this controversy. A key problem is that of the use of coins in an economic environment without any large‐scale agricultural production. While hoards of coins have been analyzed in relation to the presence of the military in the Balkans, single finds of coins remain a category of archaeological evidence commonly neglected in discussions of the sixth‐century economy. The article offers an explanation connected with the quaestura exercitus implemented in 536, and its conclusion is that the small copper denominations discovered on hilltop sites in the Balkans were not obtained on the market (none existed in any of the many hilltop sites known so far), but piggybacked on transports of annona.     

A Preliminary Study on the Loss of Iron and Arsenic in the Re‐Melting of Iron‐Bearing Arsenical Copper

Re‐melting experiments were conducted with specimens made of high‐arsenic copper alloys containing lead, iron and sulphur. The melting treatment at 1000°C in ambient conditions for 5 min was found to cause an almost complete removal of iron and sulphur along with a notable reduction of arsenic levels. Evidence was found that the preferential oxidation of iron and arsenic was responsible for this change in composition. The treatment also brought about perfect dissolution of speiss particles scattered throughout the original specimen, suggesting the possibility of the addition of speiss to molten copper for the production of arsenical copper.     

ARCHAEOMETALLURGICAL CHARACTERIZATION OF HELLENISTIC METAL OBJECTS: THE CONTRIBUTION OF THE BRONZE OBJECTS FROM RISHON LE‐ZION (ISRAEL)*

An archaeometallurgical analysis is presented of 14 bronze artefacts retrieved from an Early Hellenistic–period farmstead in controlled archaeological excavations at Rishon Le‐Zion, Israel, and dated to the first quarter of the third century bce according to coins and pottery vessels. The bronze assemblage includes a needle, pins, spatulas and fibulas. The aims of the research are to determine the composition, microstructure and manufacturing process of these artefacts, and to discover their place of production. This will provide a better understanding of Hellenistic technological abilities and material culture. The examination included optical microscopy, microhardness, SEM including EDS, and XRD. The results show that the collection consists of Cu–Sn binary alloys, with evidence for a controlled alloying process and the absence of recycling. Furthermore, the microstructure of the objects indicates that all artefacts were produced by a cold‐working process. Moreover, the manufacturing process of the rectangular cross‐section fibulas included sophisticated joining techniques of copper and iron.     

Neolithic nomadism in south‐east Arabia — strontium and oxygen isotope ratios in human tooth enamel from al‐Buhais 18 and Umm al‐Quwain 2 in the Emirates of Sharjah and Umm al‐Quwain (UAE)

Human skeletal remains from the Neolithic sites BHS18 in the interior of the Sharjah Emirate and the Neolithic shell midden UAQ2 (Umm al‐Quwain) on the coast of the Persian Gulf (United Arab Emirates, UAE) were analysed for their isotope ratios of strontium (⁸⁷Sr/⁸⁶Sr) and oxygen (¹⁸O/¹⁶O). The results are not in agreement with earlier assumptions about a Neolithic nomadism between inland regions and the south‐eastern coast of the Persian Gulf. Existing evidence of nomadic movements of the people from BHS18 most possibly refers to transhumance within the mountains in the hinterland. The strontium isotope measurements on human skeletons from UAQ2 on the contrary indicate uninterrupted residence of this population on the coast. Nevertheless, evidence was found of individual mobility between inland regions and the coast.     

A technological transition in Mongolia evident in microstructure,chemical composition and radiocarbon age of cast iron artifacts

Metallurgical examination of cast iron objects from the Khitan period (AD 10th–12th) in Mongolia shows that they might be classified into two groups. The first is based on Fe–C alloys of near eutectic composition and the second is based on Fe–C–Si alloys with reduced carbon content and numerous sulfide inclusions. By contrast, all the objects from the succeeding Mongolian empire period (AD 12th–15th) belong to the second group, indicating that a technological transition had occurred during the Khitan period. Accelerator mass spectrometry (AMS) on carbon samples extracted from artifacts in both groups and measurement of alloy compositions suggest that the use of mineral coal in smelting was a major factor for this transition.     

Pre‐Industrial Iron Smelting and Silver Extraction in North‐Eastern Greece: an Archaeometallurgical Approach

In contrast to Western Europe's well‐documented contribution to global industrialization, Eastern Europe has not received adequate attention. This paper addresses this asymmetry by defining a secure socio‐technical framework for the development of metallurgical technology in one of the most important mineralized zones in Eastern Europe, namely the uplands of north‐eastern Greece. The interplay of technological innovation, geography and social process has made this region central in European political history from the Classical and Roman periods up to recent times. Metal procurement has been crucial particularly between the 15th and 19th centuries ad, when armed conflicts escalated across the Balkans and the high inflation throughout Europe increased the demand for raw materials from the East. Field data from north‐eastern Greece and instrumental analysis corroborate the concept of iron extraction during this period from complex ores that were potentially used for their precious metals contents as well. Chemical analysis of slag points to iron bloomery processes, while analysis of respective residues (speiss) reveals significant concentrations of silver and thus testifies to the extraction of precious metals. This study addresses concerns that preoccupy political and technological minds today, and provides a context for understanding the effects of changing attitudes to the environment, social development, consumption and natural resources.     

AN ARCHAEOMETALLURGICAL STUDY OF 13TH‐CENTURY ARROWHEADS AND BOLTS FROM THE CRUSADER CASTLE OF ARSUF/ARSUR

Selected iron arrowheads and bolts retrieved from the destruction layer of the Crusader castle of Arsur/Arsuf, which was taken down by the Mamluk army (headed by Baybars) in late April 1265, were studied. Being the only site within the boundaries of the Latin Kingdom of Jerusalem that has thus far yielded more than 1200 iron arrowheads, an archaeometallurgical characterization was performed. The aim of this research was to study the warfare methods and manufacturing technologies used by the Mamluk and Crusader armies. Examination included optical microscopy, SEM and SEM–EDS, XPS and microhardness tests. Analysis was performed on both the metallic iron and iron oxides. Ferrous wooden ‘fossils’, which were found on and within the bolts, were dendroarchaeologically tested. The microstructure analyses show that the weapons were made of wrought iron. These results are correlated with the function of the weapons. The different microstructures of the arrowheads and the bolts indicate dissimilar manufacturing processes. The graphitization of the ropes on the bolts and the oxide phases on their surfaces both provide evidence of high‐temperature fire. The ropes support the archaeological findings that these devices were used by the Mamluks to set the Crusader castle on fire.     

Unpacking Land Grabs: Subjects,Performances and the State in Ghana's ‘Small‐scale’ Gold Mining Sector

During the 2008 global financial crisis, gold‐backed reserves became a ‘safe haven’ for capital investment, causing gold prices to hit historic highs. Globally, small‐scale gold mining activities proliferated as prices climbed. Along the banks of Ghana's Offin River, abandoned, waterlogged mining pits now stretch for kilometres where agricultural and other land uses recently existed. While small‐scale mining is a right reserved for Ghanaian citizens, many mining sites are foreign‐operated and almost all go unremediated. There is thus a stark tension between Ghanaian minerals laws and environmental regulations and the ongoing transformation of rural landscapes. Based on 112 interviews and long‐term observation in Ghana since 2010, this article untangles the relationships and practices mediating ‘illegal’ foreign mining operations. Shifting subjectivities, performances and practices bring land grabbing into being as state actors weave together legal and extra‐legal domains to facilitate, and profit from, foreign mining. Other officials experience fear and frustration in the face of powerful mining interests, demonstrating the complex workings and conflicts between government actors and agencies. Detailing co‐productions between ‘legal’ and ‘illegal’ domains in official licensing procedures complicates understandings of the state and its role in foreign land grabbing, breaking down the ontological binaries — rational/irrational, official/unofficial — used to uphold an image of state legitimacy and cohesion. Finally, given the spatial extent of small‐scale mining deals and ensuing social and environmental transformations, the authors urge land‐grab scholars not to dismiss the importance of small‐scale deals alongside larger transactions.     

Zooarchaeological Evidence for Domestic Rituals in the Iron Age Communities of North‐Eastern Iberia (Present‐Day Catalonia) (Sixth–Second Century BC)

Many socio‐economic changes occurred in southern Europe during the first millennium BC. In north‐eastern Iberia societies evolved from the small‐scale local groups of the Late Bronze Age to the more complex societies of the Iron Age. Together with a diversity of material changes (detected in pottery, agricultural techniques, architecture, etc.), a new ritual manifestation is attested in the Ancient Iberian Period (about 550 BC), lasting until some time after the Roman conquest. This consisted of sheep and goats (among other species) being carefully deposited below the floors of some domestic buildings. In this article the characteristics of these associated bone groups are described and their significance is discussed.     

Evidence of Soldering Technology on Pre‐Columbian Gold Pendants from Western and North‐Western Colombia

Microscopic examination and analysis (metallography, X‐radiography, SEM–EDS, pXRF and μ‐XRF) of a group of stylistically linked gold alloy pendants from western and north‐western Colombia confirms the use of a highly unusual manufacturing technique for the region. While the Darién pendants were made using lost‐wax casting by a diverse group of cultures from southern Colombia through Costa Rica, only one subset of pendants produced in the Gran‐Zenú region (the Caribbean lowlands of northern Colombia) and the Chocó region (the Pacific area of western Colombia) in the Early Period (ad 0–900) was found to be manufactured by hammering of gold sheet and fine wires followed by hard soldering of components to produce true filigree. Similarities in features between the stylistically related cast and hammered pendants suggest that the hammered pendants may have served as a prototype for the cast versions. Other possible instances of hard soldering in the region are also presented.     

Early use and production of iron in the northern Shaanxi: A perspective on iron objects excavated from the Yuejiazhuang cemetery site

Yuejiazhuang is a cemetery site of Qin people in the Northern Shaanxi, China, and it is dated to the mid-late Warring States Period. Ninety-two iron objects were excavated from the Yuejiazhuang cemetery site, which provide an opportunity to understand the use and production of iron in the Northern Shaanxi. The metallurgical and statistical study has revealed that bloomery iron, cast iron, and steel made from cast iron were adopted in the Northern Shaanxi during the mid-late Warring States Period. In the meanwhile, cast iron and steel made from cast iron became dominant in the Northern Shaanxi.     

The implication of the metallurgical traditions associated with Chinese style wagons from the royal Xiongnu tomb at Golmod 2 in Mongolia

Lavishly decorated wagons excavated from royal Xiongnu burials are generally regarded as tribute items from China offered to Xiongnu elites, symbolizing important political and economic interactions between the Xiongnu state (209 BC–155 AD) and the Han dynasty (206 BC–220 AD). This theory views such vehicles as having no relation to indigenous Xiongnu craftsmanship. Furthermore, specialized products delivered to the northern nomadic peoples from the Han state are often cited in support of the notion of Xiongnu dependency on foreign states for technological and political development. Expecting to find evidence of China’s traditional iron and bronze technology, we examined a number of key metallic components of these wagons excavated from the royal Xiongnu burial at Golmod 2 in central Mongolia, radiocarbon dated to 109 BC–AD 75. Surprisingly, the iron metallurgy in question was based primarily on the bloomery process while low tin bronze and arsenical copper alloys dominated the pertinent bronze production. These respective technological traditions are typical of Xiongnu manufacture but significantly different from traditional Han metallurgy. We interpret this evidence as suggesting the need for a more balanced evaluation of foreign influence on the rise and development of the Xiongnu state.