Islamic glass in the Christian Kingdom of Alwa: Chemistry of shards from Soba,Nubia, Sudan

Excavations at Soba, the capital of Alwa, between 2019 and 2022 yielded more than 30 glass fragments in addition to a glass cosmetic bottle. An analysis of 30 glass samples has identified glass belonging to a number of compositional groups. The majority of fragments were made of plant ash-soda glass produced in the Middle East (Iran, Iraq) between the 9th and 10th centuries, and in the Eastern Mediterranean (Levant and Egypt) between the mid-10th and mid-12th centuries. Seven fragments were made of mineral–soda-lime glass produced in 9th-century Egypt and three high-lead glasses find analogies in the 9th- to 11th-century glass. Archeological evidence, as well as textual sources, leave no doubt about Alwa’s intense transcultural connections. This article provides the first insight into the chemistry of glass shards from medieval Nubia, and the results of analysis contribute to evidence for long-distance contacts of Soba, the capital of one of the medieval kingdoms of Sahelian Africa.     

Overseas imports on the Blue Nile: Chemical compositional analysis of glass beads from Soba,Nubia

Archaeological evidence as well as textual sources leave no doubt about Alwa's (Alodia's) intense transcultural connections, further corroborated by understudied overseas glass bead imports found there. This paper presents results of an analysis of 23 glass beads from Soba, the most prosperous capital of medieval Nubia. Compositional analyses using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) have identified glass belonging to a number of broad compositional groups. Three samples were made of soda lime low-alumina glass produced in the Middle East (v-Na-Ca) and Egypt (m/v-Na-Ca). The remaining beads were made of two types of mineral–soda high-alumina glass (m-Na-Al) North Indian in origin. The results of this study provide new evidence for the provenance and chronology of glass beads available in medieval Soba and Northeast Africa, and contribute new data to research on trade contacts of that time.     

Glass beads and pendants from Meroitic and Nobadian Lower Nubia,Sudan: Chemical compositional analysis using laser ablation‐inductively coupled plasma‐mass spectrometry

This paper presents a detailed elemental analysis of 64 glass beads and pendants dated to the Meroitic period (first–third centuries ad ) and the Nobadian period (fourth–sixth centuries) from burial sites in the Lower Nubian Nile Valley region. Laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) was used to determine the chemical composition of the glass and to gain knowledge about its origin. Four main glass types were identified: low‐alumina soda‐lime glass, high‐alumina glass, plant‐ash soda‐lime glass, and mixed‐alkali glass. Mineral soda‐lime glass (m‐Na‐Ca) of East Mediterranean/Egyptian provenance is dominant within the low‐alumina glass group from Meroitic and Nobadian periods. Mineral soda high‐alumina glass (m‐Na‐Al) appeared in the Nobadian bead assemblages, and the m‐Na‐Al 1 subtype was produced in Sri Lanka/South India. An initial insight into the origin of the glass beads in Nubia from the first to sixth centuries is described, indicating the first evidence for the presence of Asian objects in Nubia. The data obtained for the bead trade in North‐east Africa in this study has allowed a new light to be shed on the westward flow of Asian glass during a time of intensive maritime trade contacts with the wider Indian Ocean world.     

Like You Need a Hole in the Head: Tool Innovation a Possible Cause of Trephination. A Case from Kerma,Nubia

This paper presents one case from Kerma (ind‐14.1.595 or K317) which was initially reported to have a ‘fatal traumatic wound’ in the front of the skull. The individual has a dime sized, circular hole with no radiating or concentric fracture lines associated with it. It also shows clear evidence of healing along the inside edges of the pathology. This was according to the preliminary, and only, analysis performed when excavated at Kerma (1913–1916), which was most likely performed by a crew member not formerly trained in anthropology, or medical science. Differential diagnosis will be discussed with respect to this lesion actually being a form of traumatic injury, possible remnants of a bony tumour, and trephination, among other diagnoses. Trephination has been identified in ancient Egypt and Nubian studies, though it is a rarity. Although trephination is a possible cause for the present lesion, this example does not fit the morphology of any other examples of the practise from this region or time period. Given that there have been similar borings witnessed on architecture from the Egyptian Old Kingdom, this lesion may suggest implementation of an already present architectural tool for medical purposes among the Kerma Nubians. Copyright © 2011 John Wiley & Sons, Ltd.     

Change in chemical composition of early Islamic glass excavated in Raya,Sinai Peninsula,Egypt: on-site analyses using a portable X-ray fluorescence spectrometer

The Raya port (eighth to 12th centuries) on the Sinai Peninsula, Egypt, was one of the important port cities for the Red Sea trade. We performed on-site analyses of Islamic glass vessels (used in eighth to 11th centuries) mainly from this site in Egypt using a portable XRF spectrometer. The aim of this paper is to contribute to our understanding of the chemical compositions of early Islamic glass vessels by comparing their archaeological date and typology. In the early Islamic period, glass objects were mainly produced from natron as the soda source. Among the natron glass analyzed in this study, glass vessels with low titanium and iron and high strontium contents, which were probably produced in the Syria–Palestine region, were excavated in the eighth century layer. From the ninth century layer, a large number of samples with high levels of calcium, titanium and iron, probably produced in Egypt, were found. It should be noted that a large number of glass vessels with this chemical composition were found at the Raya site, because this type of glass was rarely reported from other Islamic sites. We finally concluded that this type of glass seems to be produced under a fixed recipe, although some samples contain a colorant or decolorized materials.     

Chemical Analyses of Sarmatian Glass Beads from Pokrovka, Russia

The chemical composition of 18 glass beads from Early Sarmatian period burials were determined using electron probe microbeam analysis and energy dispersive X-ray fluorescence. The beads were made from high-magnesia-soda-lime-silica glass, leaded-soda-lime-silica glass, low-magnesia-soda-lime-silica glass and low-magnesia-high-potash glass. Multivariate analysis of the major oxides suggests that there are five distinct glass recipes used to manufacture these beads. These various glass recipes indicate the involvement of the Sarmatians in exchange/trade networks linking the Eastern Mediterranean, the Indian subcontinent, and China.     

The composition of late Romano-British colourless vessel glass: glass production and consumption

One hundred and twenty-eight colourless glass tablewares from settlement contexts throughout the British Isles, dating from the mid-3rd to 4th century AD, were analysed by ICP-AES spectrometry. Three distinct compositional groups were identified based upon the use of different decolourisers and primary raw materials, with possible sub-groups within these. These compositions have distinct, but overlapping chronological ranges, suggesting colourless glass production in at least three, possibly more, centres in the late Roman period. The compositional analysis highlights the high degree to which recycling of glass was taking place during this late period. The chronological distribution of some of these compositions is more restricted within the British assemblages than is observed in other published assemblages from Western Europe. This distinction may indicate different supply patterns of glass to the Western provinces.     

XRF analysis of glass beads from the Mycenaean palace of Nestor at Pylos,Peloponnesus, Greece: new insight into the LBA glass trade

In recent years there has been a growing interest in Mycenaean glass among archaeologists and scientists. Scholars have traditionally thought that all Mycenaean glass was imported either in finished form or as ingots and simply shaped or worked at the Mycenaean sites. Chemical studies of other Mycenaean glass (50 and 43) support the hypothesis that glass was imported into Mycenaean Greece, but there is also indication for glass production in mainland Greece at the palace of Thebes (Nikita and Henderson, 2006). There is no evidence for glass making or working at the Palace of Pylos, yet there is an abundance of glass beads there. The aim of this paper is to identify the technology and source for the glass of these beads and thus to ascertain how Pylos was connected to the broader Mycenaean and Mediterranean economies. The composition of the glasses was determined by means of portable XRF analysis and compared to that of other Late Bronze Age glasses from Egypt, Mesopotamia and mainland Greece. Four blue beads coloured with cobalt and one blue bead coloured with copper have Ti and Zr compositions consistent with an Egyptian origin of manufacture while five other beads show Ti and Zr concentrations consistent with a Mesopotamian origin (Shortland et al., 2007). Based on the dearth of Egyptian and Mesopotamian imports in Pylos, the presented data support the hypothesis that Pylos was receiving via internal Greek trade routes foreign-produced glass, which may have been worked abroad or in Greece.     

The composition of ‘naturally coloured’ late Roman vessel glass from Britain and the implications for models of glass production and supply

Naturally coloured, blue or green are the most common glass colours found in assemblages from the Roman world from the end of the 1st century BC onwards. In the 4th century two different compositions have come to dominate this group, ‘HIMT’ and ‘Levantine 1’ glasses, both of which are now thought to have been produced in the eastern Mediterranean. Using Romano-British glass assemblages from the 4th and 5th centuries, it is shown here that although the two naturally coloured glass types predominate, by far the most common composition in British assemblages is HIMT, although older, earlier blue-green compositions are still present. The earliest date HIMT could be identified in these assemblages is around AD 330, although two distinct compositions can be identified within this group which relate to changes in composition over time. A similar change over time is seen in the Levantine 1 glasses. The reasons for these patterns within the assemblages are explored within the archaeological evidence currently available for glass production and consumption in the Roman world.     

Tracing the origins of Eastern European enamelling: Chemical composition of glass and enamels from the Bryansk hoard (south‐western Russia)

The chemical composition of a series of Eastern European enamels from the Bryansk hoard from the third century ad and other sites was studied using scanning electron microscopy with energy‐dispersive spectroscopy (SEM‐EDS) and electron microprobe analysis (EPMA) techniques. Red opaque glass is homogeneous compositionally, suggesting not only common manufacturing traditions but also identical types and sources of raw materials and, consequently, a single origin. The glass is made in the Roman tradition of enamelling, which appeared in the mid‐first century ad , as was the case with orange glass. The difference in the lead content in glass of different colours, which determines the melting temperature, allows the reconstruction of polychrome enamelling techniques.     

Silk Road glass in Xinjiang,China: chemical compositional analysis and interpretation using a high-resolution portable XRF spectrometer

In this paper we explore the major, minor and some trace elements of sixty-five glass beads from eighteen oasis sites both north and south of the Taklamakan Desert, the ancient centre of the Silk Routes linking East and West; the samples date from the Warring States period (475–2211 BCE) to the Tang Dynasty (618–907 CE). Using a high-resolution portable XRF spectrometer, with special attention to issues of surface weathering and sample preparation, we obtained quantitative chemical compositional data that, when combined with archaeological context and the technology of bead manufacture, provide the basis for an understanding of both changes in glass type over time, and possible source areas for the Xinjiang glasses. While glass beads at the early sites (1st c. BCE to 4th c. CE) were coming primarily from Kushan-controlled territories in northern India, Pakistan and Afghanistan, with a small contribution from central China, most of the later glass (4th–10th c. CE) is similar to that produced in the Sasanian Empire at such sites as Veh Ardashir in central Iraq. These changes most likely reflect changing cultural and economic conditions in the Silk Road towns.     

Chemical and lead isotope analysis of some lead-barium glass wares from the Warring States Period,unearthed from Chu tombs in Changde City,Hunan Province,China

In the context of the present study, we have conducted chemical and lead isotope analyses on twelve ancient glass samples unearthed from Chu tombs in Changde City, Hunan Province. The results of the chemical analysis of these samples show that all samples are PbO–BaO–SiO₂ glasses, thus indicating that they are all traditional ancient Chinese glasses. The chemical results also suggest that all Bi wares may either share a common source or were produced according to similar recipes. In turn, the eye beads are different from the Bi wares for their distinct chemical composition. The chemical results indicate that silica, lead-bearing material, barium-bearing material, and sodium/lime-bearing material are the main independent components of the raw materials employed in the production of these glass wares.     

Reflections into Ptolemaic glass: Colorless,white, blue,and green inlays from the workshop of Tebtynis

Inlays range among the most aesthetically pleasing and technically challenging glasses produced in the Ptolemaic period. Despite the central role of this phase in the history of glass technology, little is known about the recipes and the technological knowledge of the Egyptian artisans. This paper will thus focus on the study of the materials from the secondary workshop of Tebtynis (Fayum oasis, Egypt). We report the first multi-methodological study comprising textural, chemical, and mineralogical analyses (optical microscopy, scanning electron microscopy coupled with energy-dispersive system, electron probe microanalysis, and μ-Raman spectroscopy) on a set of 81 colorless, white, blue, and green samples carefully selected among the 800+ glasses from the craft area now stored at the Museo Egizio, Turin (Italy). Our study offers the biggest compositional database of well-dated Ptolemaic glasses currently available in the literature, highlighting some interesting novelties regarding the silica and alkali sources, and the coloring and opacifying techniques employed. The results suggest a specialized craft of traditional origin, but open to innovation and experimentation, as expected from transitional phases.     

Chemical characterisation and manufacturing technology of late Roman to early Byzantine glass from Beit Ras/Capitolias,Northern Jordan

The finding of considerable collections of glass artefacts, together with considerable lumps of glass chunks, fuel ash slag and kiln fragments related to glass processing strongly suggests a local secondary production (working) of glass at the Beit Ras/Capitolias archaeological site in northern Jordan from the late Roman to the early Byzantine period. The chemical analysis of ancient glasses can provide important information regarding the manufacturing technology of the glass made during a specific period. The aim of this study is to characterise the chemical and technological aspects of late Roman to early Byzantine glasses excavated from this main archaeological site. Furthermore, the present paper aims to provide incontrovertible evidence that this site must be considered as a major centre for the secondary production of glass during a period between the 3rd and the 6th centuries. For this purpose, a considerable group of raw glass chunks and vessel fragments of different colours and typologies were collected. The results of chemical analyses indicated that the glass did not show a clear difference in chemical composition between late Roman and early Byzantine times. All the glasses (artefacts and chunks) are of the soda-lime-silica type and correspond to the previously defined Levantine I glass group. The chemical composition of the glass chunks, identical to that of contemporary glass of the same colour, strongly suggests that these chunks were used for the manufacture of late Roman to early Byzantine glass at Beit Ras. The observation of technological features indicates that glass chunks were produced in massive tank furnaces in other primary production centres elsewhere, and were meant for local reworking. According to the microscopic examination, it can also be observed that mould-blowing was the main technique used for forming glass.     

Geochemical and mineralogical analysis of stone anchors from west coast of India: provenance study using thin sections,XRF and SEM-EDS

Stone anchors have been recovered along the Indian coast as a part of the maritime archaeological studies at the National Institute of Oceanography (NIO), Goa. Study of stone anchors provides clues to understand the ancient maritime trade contacts of India with other countries. These anchors resemble those found in the Mediterranean Sea, Persian Gulf and Red Sea Coast. Underwater explorations at Bet Dwarka, Dwarka, Goa, Visawada and Somnath have yielded stone anchors of widely varying shapes, sizes and weights ranging between 16 and 410 kg. Sixteen (10 Indo-Arabian, 4 Ringstone and 2 Single hole type) of the total of 269 stone anchors have been studied to determine provenance of rock through petrographic analysis using thin section studies, X-ray Fluorescence (XRF), and Scanning Electron Microscope – Energy Dispersive Spectrometer (SEM-EDS).     

An archaeometric contribution to the characterization of Renaissance maiolica from Urbino and a comparison with coeval maiolica from Pesaro (the Marches,central Italy)

The results of an archaeometric trial study performed on an important finding of Renaissance maiolica (mid‐15th to early 16th century) from the Ducal Palace of Urbino are presented. Mineralogical–petrographic data (XRD, OP, SEM–EDS) and chemical characterization (ICP/AES–MS: major and trace elements) of both ceramic bodies and glazes were compared with similar data provided on coeval maiolica found in archaeological excavations in Pesaro, now stored in the city's Municipal Museum, in order to verify an origin of the potteries from common (Pesaro) or different (Pesaro and Urbino) production centres. The results indicate that ceramic bodies were produced with quite similar illitic–calcareous clays, most probably taken from the same local Pliocene Formation. Similarities were also found concerning the glaze's glass (silica–lead), colourants (cobalt, copper and manganese) and pigments (lead antimonate and cassiterite).     

Obsidian from Pulo di Molfetta (Bari,Southern Italy): provenance from Lipari and first recognition of a Neolithic sample from Monte Arci (Sardinia)

Twenty-four obsidian artefacts of the Neolithic Age were found at the large karstic doline of Molfetta (near Bari) along the Southern Italian Adriatic coast. Non-destructive chemical analyses of the glass, by SEM-EDS, allowed their source rock regions to be determined. Twenty-three of the studied artefacts had been traded from the island of Lipari. Only one sample had a glass composition and microphenocrysts (biotite, pyroxene and feldspar) that indicate provenance from the Monte Arci area of Sardinia, in particular from the Perdas Urias (SC) outcrops. The attribution of this artefact to Sardinia enlarges the geographical pattern of Monte Arci obsidian exploitation and distribution from island to Southern Italy during the Middle to Late Neolithic.     

Sentinel Butte: neutron activation analysis of White River Group chert from a primary source and artifacts from a Clovis cache in North Dakota,USA

Instrumental neutron activation analysis (INAA) was used to characterize the chemical composition of chert from a primary source in western North Dakota. Known as Sentinel Butte, this source is part of the Eocene-age White River Group (WRG), a widespread geological formation on the central and northern Plains. INAA results demonstrate that it is chemically distinct from other known chert-bearing WRG. Further, analysis of three bifaces from the nearby Beach Clovis cache site demonstrates that they are made of chert from Sentinel Butte, and most likely the other 55 White River Group Silicate (WRGS) bifaces in the cache are as well. Although Clovis caches typically are dominated by materials transported hundreds of kilometers, it is argued that the advance manufacture and caching of bifaces even a short distance from a source may be a highly effective tactic to reduce gearing up time and hence search costs associated with the pursuit of mobile game at the close of the Pleistocene.     

The use of SEM-EDS,PIXE and EDXRF for obsidian provenance studies in the Near East: a case study from Neolithic Çatalhöyük (central Anatolia)

In this paper we evaluate the relative analytical capabilities of SEM-EDS, PIXE and EDXRF for characterizing archaeologically significant Anatolian obsidians on the basis of their elemental compositions. The study involves 54 geological samples from various sources, together with an archaeological case study involving 100 artifacts from Neolithic Çatalhöyük (central Anatolia). With each technique the artifacts formed two compositional groups that correlated with the East Göllü Da? and Nenezi Da? sources. The non-destructive capabilities of these methods are emphasized (albeit with certain analytical limitations in the case of SEM-EDS), suggesting important new techniques for Near Eastern obsidian provenance studies.