Electron paramagnetic resonance of mosaic glasses from the Mediterranean area*

Ancient mosaic glass tesserae sampled from archaeological sites located in the Mediterranean area have been analysed by Inductively Coupled Plasma‐Optical Emission Spectroscopy (ICP‐OES). The aim of the research was to understand the role played by 3d transition metals in the optical properties of such samples. In order to better identify the specific effect of the main chromophorous element, modern samples have been prepared in the laboratory by adding to a colourless base frit controlled concentrations of colouring oxides. Samples with compositional and optical properties similar to the ancient ones have been obtained. For all these modern samples, as well as for all the ancient ones, electron paramagnetic resonance (EPR) measurements have been performed. The features of the EPR spectra could be successfully associated with the presence and abundance of the paramagnetic colouring ions (namely iron, manganese and copper) and to their oxidation states. This could be a basic step towards understanding the provenance and chronological attribution of mosaic glass tesserae.     

U-Pb zircon age of the youngest magmatic activity in the High Tatra granites (Central Western Carpathians)

Detailed cathodoluminescence (CL) imaging of zircon crystals, coupled with Laser Ablation Multi-Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) U-Pb zircon dating was used to develop new insights into the evolution of granitoids from the High Tatra Mountains. The zircon U-Pb results show two distinct age groups (350±5 Ma and 337±6 Ma) recorded from cores and rims domains, respectively. Obtained results point that the last magmatic activity in the Tatra granitoid intrusion occurred at ca. 330 Ma. The previously suggested age of 314 Ma reflects rather the hydrothermal activity and Pb-loss, coupled with post-magmatic shearing.     

Roman lead mining in Germany: its origin and development through time deduced from lead isotope provenance studies

High precision lead isotope analysis by Multi Collector Inductively Coupled Plasma Mass Spectrometry was applied to the investigation of more than 240 Roman lead objects from several archaeological sites in Germany, in order to obtain information on the pattern of Roman mining activity and ore processing in the area. Measurements of ore samples from German deposits east (Siegerland, Lahn-Dill, Ems) and west of the Rhine (Eifel, Hunsrueck) were made and supplemented with data from literature to create a data bank of lead isotope ratios of European lead occurrences. Comparing the isotope ratios of lead objects with those from German ore deposits shows that the source of over 85% of the objects is Eifel ore deposits, but that, in the early years, the Romans also imported lead from the Southern Massif Central and later from Britain.     

A pilot compositional analysis of Nasca ceramics from the Kroeber collection

In this paper we report on Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) of a sample of ceramics from Nasca, Peru collected by Alfred Kroeber in the 1920’s and curated at the Field Museum of Natural History in Chicago. The analysis was conducted for two principal reasons: (1) to test the efficacy of LA-ICP-MS when compared to INAA; and (2) to evaluate samples that post-date Early Nasca (where focus has primarily been placed). We show here that LA-ICP-MS is a viable alternative to INAA, present some of the compositional variability in the Kroeber samples, and propose some explanations for this variability.     

Donyatt-type pottery in 17th- and 18th-century Virginia and Maryland

Abstract

Thirty-three examples of pottery matching visually the wares made at the kiln sites of Donyatt, south Somerset, England, have been identified from five sites in Virginia and Maryland, the identifications of two vessels being confirmed by Inductively Coupled Plasma analysis. The paper presents a corpus of the finds identified, draws attention to the good quality of the dating evidence on some sites and offers a guide to the identification of such wares to stimulate further discoveries.     

Sourcing Iron Age softstone artefacts in southeastern Arabia: results from a programme of analysis using Inductively Coupled Plasma-Mass Spectrometry/Optical Emission Spectrometry (ICP-MS/OES)

Iron Age softstone vessels manufactured in southeastern Arabia are widely distributed across that region and in lesser amounts throughout Western Asia. Results from a pilot programme of analysis using Inductively Coupled Plasma Mass Spectrometry/Optical Emission Spectrometry on vessel fragments from two southeast Arabian sites are presented. These results indicate the existence of geochemically distinct groups that are separated by both transition metals and rare earth elements. While this indicates the potential for the application of the provenance postulate in softstone analysis, these promising results need to be further tested by an expanded programme of analysis which includes quarry fragments.     

Roman Glazed Ceramics in the Western Mediterranean: Chemical Characterization by Inductively Coupled Plasma Atomic Emission Spectrometry of Ceramic Bodies

Several objects of Roman lead-glazed ceramic, found inHispania(Spain), were sampled and analysed in order to characterize them to study the spread of glazed ceramic in the western Mediterranean. Chemical analyses were carried out by Inductively Coupled Plasma Atomic Emission Spectrometry.Studies of the chemical composition of the ceramic bodies indicate that ceramics from two different production centres reachedHispaniaduring the Roman period: a non-calcareous fabric, coming from Lyon workshops, and calcareous bodies with bicoloured glazes from another main production centre, which is suggested to be Italy. Other objects, of central Gaulish or eastern origin, have also been found in the western Mediterranean, but only occasionally.     

Provenance of Zhangzhou export blue-and-white and its clay source

Trace element compositions of 25 shards of Chinese Late Ming export blue-and-white porcelain from Zhangzhou and Jingdezhen kilns are analysed by Inductively Coupled Plasma Mass Spectrometry. Principle components analysis and REE distribution curves are used to establish method for provenance unknown Chinese export blue-and-white porcelain which may have originated from Zhangzhou or Jingdezhen kilns. By matching the REE distribution curves of Zhangzhou kiln samples and parent rocks of the possible clay sources used to make Zhangzhou blue-and-white, and comparing it with previous results of geological, geochemical and archaeological researches, the clay used for producing Zhangzhou export blue-and-white has been identified as having been collected from the weathered shells of a nearby potassium feldspar miarolitic granite outcrop.     

Can tree-ring chemistry reveal absolute dates for past volcanic eruptions?

Discussion of the significance of volcanically induced impacts on human history, the natural environment, and climate through the Holocene, has frequently stalled because of controversy concerning certain key volcanic eruptions and their precise relationships with the archaeological/environmental record. A major stumbling block in such debates is a failure to obtain precise and accurate dates for many of these key volcanic events. Most existing dates currently float against archaeological, historical, environmental, and climate data. A potential means to resolution lies with tree rings: these can be dated precisely by dendrochronology, are available from a wide range of loci around the world, and can record global climatic influences. It has been suggested that certain growth anomalies in dendrochronological sequences could offer “proxy” absolutely dated records of major, climatically effective, volcanic eruptions. However, this assertion has been widely disputed given the lack of a direct, positive, causal connection. The hypothesis that the required connection may be chemically encoded in individual annual growth rings from dated sequences is explored here both via review of existing literature on dendrochemical techniques, and by LA-ICP-MS chemical analysis of two tree ring sequences. It is concluded that dendrochemistry provides a promising means by which absolute dates may one day be attributed to key volcanic eruptions of pre-modern times.     

Dendroarchaeology of the mid-first millennium AD in Constantinople

The 1st millennium AD was a time of great transition in Europe and the Mediterranean. At the heart of the Byzantine Empire, Constantinople (modern day Istanbul) was a pivotal trade hub for the Aegean region. Establishing a precise and accurate dating framework for the development of this remarkable city and a chronological reference for this critical time period for the Mediterranean region is of great importance to a wide range of scholars. Here we present a new 213 year tree-ring record from 89 oak samples placed in time by dendrochronology and supported by radiocarbon analysis and historical documentation. It represents the middle of the first millennium AD in Constantinople. The tree-ring series are derived from pilings recovered from the extraordinary excavations of the so-called “Theodosian harbor” at Yenikap?, Istanbul, along with timbers from other sites and buildings around the city, including one of the most famous sites on the Istanbul sky-line—Hagia Sophia. They provide potential for new insight into a time period in which earthquakes, the Justinianic plague, and even a possible tsunami struck the city, and during which dramatic changes in climate have been recorded in other paleoenvironmental proxies. The chronology is the first published tree-ring series from the Aegean region to cover the ‘event’ years of AD 536–7 and 542 which are characterized by anomalous growth in other tree-ring series from around the world, but interestingly these event years are not evident in this tree-ring sequence.     

New light on old pumice: the origins of Mediterranean volcanic material from ancient Egypt

This paper presents and discusses the Neutron Activation Analysis (NAA) results newly obtained from pumice pieces found decades ago at the Egyptian sites of Maiyana, Sedment, Kahun, and Amarna – now in the collections of the Ashmolean Museum, Oxford, and the Petrie Museum of Egyptian Archaeology, London – which could be successfully related to several volcanic eruptions in the Mediterranean. The work contributes to the constant accumulation of knowledge concerning the first appearance of pumice from the so-called Minoan eruption of the Santorini volcano. In addition, it unexpectedly sheds more light on the long-distance trade of Mediterranean volcanic material in the Bronze Age world by disclosing another connection between Lipari and the Eastern Mediterranean.     

郑韩故城出土青铜器的矿料来源初步分析

基于富集在铜料中而保留其母矿信息的元素可以用于示踪青铜器的矿料来源,为了解郑韩故城青铜器的矿料来源,利用ICP-AES方法对郑韩故城出土东周时期青铜器的微量元素进行了检测。结果显示,21个青铜器样品微量元素特征具有相对一致性,推测可能具有相同的原料来源。与小双桥遗址出土青铜器的微量元素特征进行对比,二者存在明显的差异,说明从商代中期到春秋战国时期,这一地区的原料来源发生了改变。研究结果可为研究东周时期这一地区铜业发展状况提供线索。     

何郢遗址出土青铜器铜矿料来源的初步研究

本文利用地球化学示踪的方法对何郢遗址出土青铜器的铜矿料来源进行了初步研究.采用ICP-AES测试了样品的微量元素,根据元素的地球化学亲和性,探索其在冶炼过程中的化学行为和再分配规律,从而选出对铜绿山和皖南的铜陵、南陵铜矿具有指示意义的特征元素,作为判断其铜料输出路线的综合判别标志.结合文献和地质资料,可初步认为何郢遗址青铜器的铜矿料来自滁县.     

Melian obsidian in NW Turkey: Evidence for early Neolithic trade

Abstract

Archaeological investigations carried out at the Early Neolithic coastal site of Co?kuntepe in northwestern Turkey yielded an assemblage of 110 obsidian artifacts displaying the macroscopic characteristics of the well-known obsidian deposits on the Cycladic island of Melos. Analysis of three samples from this homogeneous obsidian assemblage using both X-Ray Fluorescence and Laser Ablation High Resolution Inductively Coupled Plasma Mass Spectrometry confirmed that these artifacts were derived from Melos. The presence of these Melian obsidian artifacts at Co?kuntepe, along with a few pieces with central Anatolian macroscopic characteristics, is intriguing because intensive production of tools made of local flint was also identified at the site through the analysis of surface scatters. This finding raises the question of the status of obsidian and associated procurement systems. The presence of obsidian can be also used to argue that certain coastal villages acted as nodes of exchange for Aegean seafarers at times in the late 7th millennium B.C.     

Chemical characterization of some potsherd pavements from parts of Yorubaland in southwestern Nigeria

Several samples of potsherd pavement were recovered during excavation and archaeological reconnaissance of six sites, along the trade and migration route of the Yoruba of southwestern Nigeria. A significant feature of these pavements is the similarity to Ife in design which consists of a herringbone design, with a ritual pot embedded in their middle. Microscopic analysis of samples shows the presence of high proportions of non-plastic grains, mainly quartz, micas, minor plagioclases, and traces of ferruginous grains, tourmaline and amphibole, interpreted as being produced by low temperature firing. Major, trace and rare earth elements' composition of 21 samples of sherds was determined using Inductively Coupled Plasma (ICP-MS) technique. The chemistry of the potsherd samples is generally similar to regolith derived from granitic rocks, which are abundant in the area. Principal component analysis (PCA) was used to reduce the number of variables and model-based cluster analysis was used to find clusters in the PCA scores. Model-based clustering found one major cluster in the data set, which corresponds to the local weathered granitic/pegmatitic raw materials near the sites. Our work shows that the technology for the manufacture of these pavements might have originated from Ile-Ife, but the production was geologically controlled.     

Tree-ring based temperature reconstruction for the west Qinling Mountains (China): linkages to the High Asia,solar activity and Pacific-Atlantic Ocean

We developed a Faxon fir (Abies faxoniana) tree-ring width chronology at the timberline in the western Qinling Mountains, China. Herein February–July mean temperature was reconstructed for Zhouqu in the western Qinling Mountains back to AD 1650 based on the standard chronology. The climate/tree-growth model accounts for 43.5% of the instrumental temperature variance during the period 1972–2006. Spatial correlation analyses with the gridded temperature data shows that the temperature reconstruction captures regional climatic variations over central and southeast China, and strong teleconnections with the nearby High Asia. There is a good agreement with cold and warm periods previously estimated from tree-rings in Nepal, India and southwest China. The temperature re-construction indicates that there was pronounced cooling in Zhouqu during the Maunder Minimum (late 1600s to early 1700s). The cold period (1813–1827) of the temperature reconstruction coincide with the volcanic eruptions. Significant spectral peaks are found at 56.9, 22.3, 11.4, 2.9, 2.8, 2.6, 2.2 and 2.0 years. The spatial correlation patterns between our temperature reconstruction and SSTs of the Atlantic and Pacific Oceans suggest a connection between regional temperature variations and the atmospheric circulations. It is thus revealed that the chronology has enough potential to reconstruct the climatic variability further into the past.     

Testing the ‘Laacher See hypothesis’: a health hazard perspective

It has recently been suggested that the Laacher See volcanic eruption, which occurred around 13,000 years ago, initiated significant demographic fluctuations along the northern periphery of Late Glacial human settlement and that these led to a number of material culture transformations. The origins of the Southern Scandinavian Bromme culture and the northeastern European Perstunian culture as well as the temporary abandonment of Central European regions have been linked to this eruption. However, it remains unclear precisely which aspects of the eruption stimulated Late Glacial foragers to abandon their traditional ways of life. Paradoxically, the culture–historical impact of the eruption appears greater further away from the eruptive centre. Here, we investigate one potential middle-range link between the Laacher See eruption and Late Glacial fauna and foragers: tephra as a health hazard. We use laser-diffraction particle-size analysis to quantitatively investigate tephra from one site with a secure Late Glacial archaeological deposit. In addition, we use values previously reported in the literature and a predictive model to calculate the hazard potential along a transect of two of the three major Laacher See tephra fans. Our results show that the Laacher See tephra may have posed a potential health hazard and that its hazard potential may have increased with distance from the vent. To our knowledge this is the only study that attempts to quantify the changing grain-size composition of tephra fall-out longitudinally in this way, at least with regard to a prehistoric eruption. We close by discussing, more speculatively, other possible health-pertinent effects of the Laacher See eruption and suggest ways in which future work can further evaluate the impact of this eruption on Late Glacial populations.     

Geochemical characterisation of north Asian glazed stonewares: a comparative analysis of NAA,ICP-OES and non-destructive pXRF

The analytical performance of non-destructive portable X-ray fluorescence (pXRF) is compared with that of Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) and Neutron Activation Analysis (NAA) for the elemental characterisation of a group of glazed stonewares from North-East Asia. As a non-destructive technique pXRF is potentially well suited to the elemental analysis of high value archaeological and museum collections but has yet to be critically evaluated for the analysis of archaeological stonewares. In this study we use multivariate evaluation to compare results from non-destructive pXRF in relation to ICP-OES and NAA analysis for the same group of samples. We conclude that, although pXRF is comparatively limited to a small number of major, minor and trace elements, these are sufficient to identify the same compositional groups as high dimensional ICP-OES and NAA datasets for this assemblage.     

Geoarchaeological tsunami deposits at Palaikastro (Crete) and the Late Minoan IA eruption of Santorini

The explosive eruption at Santorini in the Aegean Sea during the second millennium BCE was the largest Holocene volcanic upheaval in the Eastern Mediterranean region. The eruption was disastrous for the Minoan settlements at Santorini, but the effect on human society in the neighbouring islands and regions is still clouded in uncertainty. Tsunami generation was suggested, but comparatively little evidence was found. The lack of firm tsunami traces is particularly puzzling in Crete with its coastal settlements of the Late Minoan IA period, during which the Santorini eruption occurred. Here, we report the discovery of extensive geoarchaeological tsunami deposits at Palaikastro in north-eastern Crete. These deposits are characterized by a mixture of geological materials, including volcanic Santorini ash, and archaeological settlement debris. Various tsunami signatures were identified: (1) erosional contact with the underlying strata, (2) volcanic ash intraclasts in the lower part of the deposit, (3) reworked building stone material in the lower part of the deposit, (4) individual marine shells, (5) marine micro-fauna, (6) imbrication of rounded beach pebbles, settlement debris, ceramic sherds and even bones, (7) multi-modal chaotic composition. Late Minoan human settlement activities at Palaikastro provided architectural and stratigraphic frameworks in space and time that recorded and preserved tsunami evidence as geoarchaeological deposits. Such stratigraphic resolution and preservation may not occur in the natural landscape. Volcanic ash transported by wind from Santorini south-east to Crete preceded the tsunami. Geological, archaeological and radiocarbon dating criteria all converge, indicating that the tsunami deposits are coeval with the Minoan Santorini eruption. Field evidence suggests that tsunami waves at Palaikastro were at least 9 m high. Inverse tsunami modeling was attempted, based on these newly discovered tsunamigenic deposits. The initial wave in the generation region at Santorini that best fits the stratigraphic data is a wave with +35 to −15 m initial amplitude and a crest length of about 15 km.     

AD536 – BACK TO NATURE?

A spate of archaeological, historical and scientific publications have recently argued that the dust veil from a volcanic eruption (or series of eruptions) caused climatic change, which ‘forced’ significant historical transformations in the middle of the sixth century AD. In this paper, I situate this phenomenon within a more general return to environmental determinism in archaeological explanation, a return which itself needs to be understood in the context both of contemporary fears about the devastation to be unleashed by the climatic change we have made, and of the rise of precise measurement in environmental and archaeological science. I do not doubt the reality of the climatic change reconstructed for AD536/546 but, given the coarseness of the dating of the historical transformations, I do question the causal connections drawn between the former and the latter. I suggest that for many archaeologists, the AD536 event (and similar phenomena) functions much as written texts once did – as both the framework for analysis and as the explanation of historical process.