COPPER AND COPPER ALLOYS IN ANCIENT IRAQ,SYRIA AND PALESTINE: SOME NEW ANALYSES

In a pilot-programme to increase evidence for the history of copper-alloying in ancient Iraq, Syria and Palestine 128 objects in the Ashmolean Museum, Oxford, were tested with a point-source linear X-ray spectrometer for tin, arsenic and antimony. These analyses showed the gradual introduction of tin-copper alloys into Iraq after ca. 2750 b.c. (Early Dynastic IIIA), into Syria a little later and into Palestine by the end of the third millennium b.c. , though numerous artefacts continue to be of copper or arsenical-copper until well into the second millennium b.c. at least. With the appearance of tin-copper alloys the percentage of arsenic in the copper objects noticeably declines indicating that the earlier arsenical-coppers were deliberately produced under controlled conditions.     

AN ANGLO-SAXON DISC BROOCH FROM BLETCHINGDON, OXFORDSHIRE, WITH STYLE II ANIMAL ART

Summary.   The brooch was found in 2003 near Bletchingdon, Oxfordshire. ¹ Its gilt Style II animal ornament and garnet setting indicate that it is a high status dress-fastener, datable to the period AD 575–610. Analysis of its form and ornament suggests that it was a local experiment in the application of a new animal style.     

COPPER AND COPPER ALLOYS IN ANCIENT TURKEY: SOME NEW ANALYSES

This note presents some new analyses for 13 early copper and bronze artefacts from Turkey in the Collection of the Ashmolean Museum, Oxford. They were not included in a small programme of early copper and bronze objects from Iraq, Syria and Palestine (Moorey and Schweizer 1972, Archaeometry 14 (2), 177–198) and conclude this pilot-project.     

COPPER AND COPPER ALLOYS IN THE SOUTHEASTERN ALPS: AN OVERVIEW*

In recent years, several groups of archaeological metal finds from the areas around the southeastern Alps, dated between Bronze Age and Roman times, have been scientifically analysed (by ICP, AAS and/or XRF) within the framework of different projects. The data now available give a fairly good general picture of the evolution and development of metallurgy in this area and seem to indicate that the region played an important role in the exchange of objects and raw materials over many centuries. The significance of some of the metal finds, which are particularly relevant for this research, is discussed.     

ANCIENT EGYPTIAN BLACK‐PATINATED COPPER ALLOYS*

This analytical study aims to investigate ancient Egyptian black‐patinated copper alloys. The study group was selected from the collections of the Egyptian Museum in Cairo and from the Faculty of Archaeology Museum in Cairo University. Examination and analysis were undertaken using optical microscopy (OM), scanning electron microscopy (SEM), energy‐dispersive spectroscopy (EDX), X‐ray diffractometry (XRD), X‐ray fluorescence analysis (XRF) and Fourier transform infrared spectroscopy (FTIR). The analysis results indicated that the black patina contained mainly tenorite (CuO). The study presents evidence of thermal patination and animal glue coating.     

AN ANGLO-SAXON EXECUTION CEMETERY AT WALKINGTON WOLD, YORKSHIRE

Summary.   This paper presents a re-evaluation of a cemetery excavated over 30 years ago at Walkington Wold in east Yorkshire. The cemetery is characterized by careless burial on diverse alignments, and by the fact that most of the skeletons did not have associated crania. The cemetery has been variously described as being the result of an early post-Roman massacre, as providing evidence for a 'Celtic' head cult or as an Anglo-Saxon execution cemetery. In order to resolve the matter, radiocarbon dates were acquired and a re-examination of the skeletal remains was undertaken. It was confirmed that the cemetery was an Anglo-Saxon execution cemetery, the only known example from northern England, and the site is set into its wider context in the paper.     

COPPER ALLOYS FROM THE ‘ENOT SHUNI CEMETERY AND THE ORIGINS OF BRONZE METALLURGY IN THE EB IV – MB II LEVANT

Tin bronze replaced arsenical copper as the preferred alloy in the Levant for reasons that have long been debated. Found almost exclusively in graves, these two types of copper alloys share nearly identical mechanical properties. The Bronze Age cemetery of ‘Enot Shuni has yielded the first metals ever analysed from an uninterrupted stratigraphic sequence in the Levant, spanning the earliest adoption of tin bronze from the Early Bronze Age (EB) IV through the Middle Bronze Age (MB) II (c. 2300–1530 bc ). SEM–EDS analysis of these artefacts, combined with a compositional meta‐database of all previously published EB IV – MB II alloys, reveals diachronic alloy progression as selected by populations of the Levant. It has long been qualitatively understood that bronze became the primary alloy by the MB II. These results verify this trend and quantify human demand, showing that tin importation increased by 103% and arsenic content decreased by 49% throughout these periods. This shift in technological choice is attributed to cultural reorientation from the Egyptian to Mesopotamian sphere of influence, as well as to tin's appreciable fuel efficiency over pure copper and arsenical copper in light of unprecedented timber shortages.     

ENERGY DISPERSIVE X-RAY FLUORESCENCE ANALYSIS OF ANCIENT COPPER ALLOYS: EMPIRICAL VALUES FOR PRECISION AND ACCURACY

Energy dispersive X-ray fluorescence (EDXRF) analyses are compared with neutron activation as well as atomic absorption analyses of ancient copper-based alloys in order to examine their accuracy and to estimate realistic values for precision and sensitivity of EDXRF. The results show that it is possible to obtain reliable data of the surface composition of objects non-destructively. Better results for bulk composition are usually obtained with drill samples where the sensitivity of the method is at least competitive with atomic absorption spectroscopy with flame atomization.     

PRE-COLUMBIAN METALLURGY: TECHNOLOGY,MANUFACTURE, AND MICROPROBE ANALYSES OF COPPER BELLS FROM THE GREATER SOUTHWEST*

Twenty-four cast copper crotals (commonly called bells), one 'spilled bell’, one tinkler bell and a number of minerals from locations throughout the Greater Southwest were analysed for their elemental composition by a PIXE nuclear microprobe at Los Alamos National Laboratory, New Mexico, USA. Sixteen bells contained minor and trace amounts of silver, antimony, arsenic, lead, and in some cases tin, strontium, and selenium. Nine bells contained little or no detectable amounts of these elements. This suggests that several workshops throughout the Greater Southwest and Mexico might have manufactured these bells.     

CHEMICAL ANALYSIS OF COPPER ALLOY TRADE METAL FROM A POST-CONTACT HURON SITE IN ONTARIO,CANADA

Fifty-three copper-based metal fragments, recovered from the Robitaille site in southcentral Ontario, were analysed by neutron activation to establish their chemical make-up and to sort them by their trace elemental chemistries. Three different European copper samples, one brassy copper and 48 brass samples with five different chemistries were found. As few as eight trading actions may account for all of the recovered European metal fragments.     

LEAD ISOTOPIC ANALYSIS OF COPPER ORES FROM THE SIERRA EL ARAMO (ASTURIAS,SPAIN)*

This study presents the first ever lead isotope ratio data for copper ore samples (malachite and azurite) from the Sierra El Aramo (Asturias, northwestern Spain). The aim of this study was to supplement information in the existing reference database on the lead isotopic composition of Spanish ores. The Sierra El Aramo is particularly important because, while no data for the Asturian ores have been published so far, this northern province of Spain has played a significant role in terms of copper exploitation and metallurgy since the Copper Age.     

CHARACTERIZING THE DIET OF INDIVIDUALS AT THE NEOLITHIC CHAMBERED TOMB OF HAZLETON NORTH,GLOUCESTERSHIRE, ENGLAND,USING STABLE ISOTOPIC ANALYSIS*

Stable carbon and nitrogen isotope compositions were measured on human and faunal bones, sampled from the Neolithic chambered tomb of Hazleton North, Gloucestershire, UK. The values were used to characterize the diet of the burial community as a whole. Humans were higher in δ¹⁵N by 4.5–5.0‰ relative to animal δ¹⁵N, from which we conclude that, based on currently accepted interpretations of isotopic data, the humans consumed a diet that was very high in meat or animal products (75% by weight of protein). Comparison was also possible between cortical and cancellous femoral collagen, with the results showing no significant difference for the adult humans. The sample of human isotopic values showed little variability, in contrast to that found in the domestic and wild animals from the site (including cattle, pigs, sheep and deer). We suggest that this is due to local environmental differences, rather than to environmental change over time or physiological differences between individual animals, and that this pattern is likely to hold for many other archaeological sites when analysed with sufficient statistical weight.     

EARLY ANGLO-SAXON POTTERY OF THE ‘ILLINGTON-LACKFORD’ TYPE1

Summary. Early Anglo-Saxon pottery of sixth-century date of a distinctive type has been described as the Illington-Lackford type, named after two cemeteries in which large quantities have been recovered in Norfolk and Suffolk respectively. As well as their use as cremation urns, large, but fragmentary, quantities have also also been recovered from the excavated settlement at West Stow. Analytical techniques are applied, especially to the stamped decoration, in an attempt to define more closely the mode and pattern of production.     

SOLDERING WITH GOLD ALLOYS IN ANCIENT SOUTH AMERICA: EXAMINATION OF TWO SMALL GOLD STUDS FROM ECUADOR

This paper presents the results of electron microprobe analysis of two gold studs, and their associated gold alloy solders. from La Tolita in Ecuador. Metallographic and compositional data are presented and the types of solders used are discussed.     

PALAEOCLIMATIC IDENTIFICATION BASED ON AN ISOTOPE STUDY OF TRAVERTINE FROM THE COPPER AGE SITE AT LOS MILLARES,SOUTH-EASTERN SPAIN*

Remains of an aqueduct from the Copper Age settlement of Los Millares have been studied. The isotope results (—7‰ < δ¹⁸O — 5.3‰) show that the aqueduct was used to transport fresh water at room temperature. The results are inconsistent with the aqueduct being used for hot water transport or as a container for water exposed to evaporation processes. Both isotopic and mineralogical results were useful in identifying the origin and use of building materials and also in determining climatic conditions during the time of the settlement occupation.     

THE EFFECTS OF CORROSION AND CONSERVATION TREATMENTS ON NON‐DESTRUCTIVE NEUTRON DIFFRACTION ANALYSIS OF ARCHAEOLOGICAL COPPER ALLOYS: PRELIMINARY RESULTS*

Analysis of residual stress in archaeological copper alloy artefacts by neutron diffraction has considerable potential for the investigation of early fabrication processes. However, residual stresses in metals are known to relax due to conditions similar to those encountered during burial, corrosion and conservation. In this pilot study, we investigate the effects of corrosion and conservation on a small group of replica copper ingots. Although corrosion and light cleaning do indeed cause some relaxation of stresses in the metal, corrosion having the most significant effect, the basic patterns and major features of the stress profiles may still be seen.     

STUDY OF ANCIENT GREEK COPPER COINS FROM NIKOPOLIS (EPIRUS) AND THESSALONIKI (MACEDONIA)

Ancient copper coins from the Greek cities Nikopolis in Epirus and Thessaloniki in Macedonia, minted during Roman imperial times (31 BC to AD 268), were analysed non-destructively by proton induced X-ray emission, after removal of the patina. An intercompar-ison study using different analytical methods was also performed on five coins. Eleven elements were analysed quantitatively on all coins. Statistical analysis of the results was performed for their presentation in the form of dendrograms. Finally, the variations in the concentrations of some individual elements from emperor to emperor were examined.