Radiocarbon dating: Some practical considerations for the archaeologist

The article is divided into four main sections in each of which a key aspect of radio-carbon dating is discussed with emphasis on the practical implications for users of dates. The four topics which the article attempts to deal with are, in turn, (i) the effect on the radiocarbon timescale of the variations in atmospheric ¹⁴C now known to have occurred in the past and the role of other absorlute dating methods in investigating these, (ii) laboratory measurement of ¹⁴C, (iii) selection of optimum samples for dating and (iv) some of the limitations of the final dates. The theme is essentially that the technical difficulties of radiocarbon measurement in the laboratory have been overcome to the extent that the physical measurements can now be made with high precision, that is to within ±1% or better, as a routine. Thus, it is more important than ever (a) that only reliable samples having very firm associations should be dated and (b) that pretreatment of such samples by the dating laboratory to remove any age contaminants should be completely effective. However, in addition to the recognized statistical limitations, the absolute accuracy of radio-carbon dating is limited by the past ¹⁴C variations. Coupled with the requirements of proper association and pretreatment of samples is the long-term need to establish an overall correlation between radiocarbon and calendar years. At present this is still a matter for final agreement by the laboratories concerned. Meanwhile, when all possible steps have been taken to ensure the reliability of the date messurements, these can strictly only be compared with one another in terms of radiocarbon years bp. In practice this is often too restrictive but any attempts at calibration must be regarded as approximations for the time being. In this article the lower and upper case notation advocated in Antiquity46, 265, for radiocarbon and calendar years respectively has been followed.     

New radiocarbon dating of the transition from the Middle to the Upper Paleolithic in Kebara Cave,Israel

The Middle to Upper Paleolithic transition (MP-UP transition) is considered a major technological and cultural threshold, at the time when modern humans spread “out of Africa”, expanded from the Levant into Europe and possibly into central and northern Asia. The dating of this techno-cultural transition has proved to be extremely difficult because it occurred sometime before 40,000 radiocarbon years before present (¹⁴C years BP), which is close to the end of the effective dating range of radiocarbon. Other dating methods such as Thermoluminescence (TL) or Electron Spin Resonance (ESR) are not sufficiently precise to date the recorded archaeological MP-UP transition in the Levant. Here we report a consistent set of stratified radiocarbon ages on freshly excavated charcoal from Kebara Cave, Mt. Carmel (Israel), that span the late Middle Paleolithic (MP) and Early Upper Paleolithic (EUP) This study applied novel strategies to improve sample preparation techniques and data analysis to obtain high-resolution radiocarbon models. From this study it is proposed that the MP-UP transition for this site can be placed immediately after 45,200 ± 700 ¹⁴C years BP and before 43,600 ± 600 ¹⁴C years BP or from 49/48 to 47/46 radiocarbon calibrated years before present (years Cal BP).     

The Post Medieval Gravellona Toce Boat: an inland watercraft from north‐west Italy assembled using locked dowels

Discovered in 1955, not far from the Roman necropolis of Pedemonte, the Gravellona Toce boat has long been considered evidence of Roman‐period riverine navigation in northern Italy. This initial interpretation, which was not supported by direct dating evidence, has been recently reconsidered on the basis of radiocarbon‐dating and analysis of the timbers retrieved. In this paper, the authors present the results of the recent analysis of the surviving remains which allow the vessel to be interpreted as a post medieval boat built using the traditional bottom‐based construction techniques of the Po Valley region.     

Stable Isotopes,Chronology, and Bayesian Models for the Viking Archaeology of North-East Iceland

This paper reviews the results of a long-term research project that used stable isotope analyses (δ¹³C, δ¹⁵N, δ³⁴S) and Bayesian mixing models to better model the chronology for a presumed Viking Age cemetery at Hofstaðir, near Lake Mývatn in north-east Iceland. δ¹³C and radiocarbon dating indicated that many of the individuals consumed a large amount of marine protein, which results in a marine reservoir effect (MRE), making ages older than expected. In addition to the MRE, geological activity in the region has the potential to introduce massive quantities of radioactive ‘dead’ carbon into the freshwater system, resulting in a very large freshwater reservoir effect (FRE) that can offset radiocarbon ages on the order of a few thousand years. The radiocarbon dates of organisms that derive an unknown proportion of their carbon from both marine and freshwater reservoirs are extremely difficult to ‘correct’, or, more appropriately, model. The research not only highlights the complexities of dealing with multiple reservoirs, but also how important it is to develop models that are temporally and geographically relevant to the site under study. Finally, it shows how this data can be used to inform the development of chronological models for refining the dating for archaeological activity.     

The archaeology of radiocarbon accelerator dating

Accelerator mass spectrometry (AMS) allows radiocarbon dating to be carried out by direct counting of¹⁴C atoms, rather than the conventional counting of radioactive disintegrations. The result is that samples up to 1000 times smaller can be handled. The approach was tested in principle by 1977 and for archaeological operation by 1983. More than 2000 samples per year are now being dated worldwide. The machines can now operate to about ± 80 years or better. Dates older than 40,000 years have not yet been achieved, but the ability to use small samples has already had considerable impact on dating the period 10,000–30,000 years ago. Bone is an ideal material for the new technique, since amino acids can normally be isolated and purified from gram-size samples. Studies of the origins of domestication are aided by the dating of individual grains and seeds. Because small samples can be mobile in the soil, careful sample selection strategies and procedures are required. The full impact of the technique can be assessed only through the rapid and comprehensive publication of archaeological results.     

A simple Bayesian approach to tree‐ring dating

Tree‐ring dating involves matching sequences of ring widths from undated timbers to dated sequences known as ‘master’ chronologies. Conventionally, the undated timbers (from a building or woodland) are sequentially matched against one another, using t‐tests to identify the relative offsets with the ‘best’ match, thus producing a ’site’ chronology. A date estimate is obtained when this is matched to a local master chronology of known calendar age. Many tree‐ring sequences in the UK produce rather low t‐values and are thus declared not to have a ‘best’ match to a master chronology. Motivated by this and the routine use of Bayesian statistical methods to provide a probabilistic approach to radiocarbon dating, this paper investigates the practicality of Bayesian dendrochronology. We explore a previously published model for the relationship between ring widths and the underlying climatic signal, implementing it within the Bayesian framework via a simulation‐based approach. Probabilities for a match at each offset are produced, removing the need to identify a single ‘best’ match. The Bayesian model proves successful at matching in both simulated and real examples.     

RADIOCARBON DATING OF MORTARS FROM ANCIENT GREEK PALACES

This study deals with radiocarbon dating of lime mortars which were used as supports for Mycenaean and Minoan paintings. The ¹⁴C dates are. on the whole, compatible with the historical data. and thus show that a large proportion of the Mycenaean surficial coatings can be dated by the radiocarbon method. However. in order to determine the age of the mortars accurately. it is necessary to evaluate the amount of sedimentary carbonate which may have been added to them. It is shown here that the oxygen and carbon isotope compositions of lime mortars are significant indicators that such a mixing actually took place.     

Radiocarbon dating of prehistoric hearths in alpine northern Sweden: problems and possibilities

The chronology of prehistoric Sami settlement sites has previously been established by conventional radiocarbon dating of bulk charcoal samples associated with hearths from sunken hut floors (stállo-foundations). Here we present results of a comprehensive dating exercise of stállo-foundations in the alpine area of northern Scandinavia using Accelerator Mass Spectrometry (AMS) radiocarbon dating of charcoal. Over a 3 km² study area, AMS calibrated ages of hearth charcoal from 22 stállo-foundations across 12 sites securely date these features to between cal. AD 640 and AD 1180. Only small variations in age were found between charcoal samples from different areas of a given hearth. Statistical analysis of all the charcoal AMS radiocarbon dates obtained reveals that 12 stállo-foundations across nine sites are contemporaneous and date to the Viking Period (AD 800–AD 1050). The tightly constrained AMS-based chronology of stállo-foundations contrasts with the existing chronology based on conventional radiocarbon analysis, which places these features within a significantly greater time-frame of between AD 600 and AD 1900, with most dates ranging between AD 800 and AD 1350.This discrepancy is likely to result from the necessity of collecting composite hearth charcoal particles, which may originate from different phases of occupation, in order to achieve the required final carbon content for conventional radiocarbon analysis. We argue that the new AMS-based radiocarbon chronology of stállo-foundations presented here supersedes the existing chronology based on conventional (Gas Proportional counting) radiocarbon analysis and we advocate the use of AMS radiocarbon dating in future hearth investigations.     

New age constraints for hominid footprints found on Jeju Island,South Korea

In 2004 numerous hominid footprints, along with diverse animal footprints, were found in the Late Quaternary strata of Jeju Island, South Korea. However, the age of the sediments in which the footprints were found is still controversial. Previous age estimates included radiocarbon ages of ca. 15,000 yr BP (Late Pleistocene) and quartz optically stimulated luminescence ages of ca. 7000 yr BP (mid-Holocene). In this study we report on 11 AMS ¹⁴C dating results from a new set of samples collected from the footprint-bearing strata and from associated sediments. Despite some variations and age reversal, all samples collected from the footprint-bearing strata yielded ¹⁴C ages of late Pleistocene. These ages are comparable with previous radiocarbon dating results. Furthermore, the presence of the proboscidean footprints attributable to woolly mammoths in the footprint-bearing strata supports the radiocarbon dating results. Based on the new radiocarbon dates and the presence of the alleged mammoth footprints, the age of the hominid footprints found at Jeju Island is thought to be late Pleistocene (about 19,000–25,000 cal yr BP). Therefore, this is the second discovery of hominid footprints dated to the Pleistocene age in Asia, and the first to be discovered in Korea.     

Debates over Palaeolithic chronology – the reliability of C is confirmed

The debate about the complex issues of human development during the Middle to Upper Palaeolithic transition period (45–35 ka BP) has been hampered by concerns about the reliability of the radiocarbon dating method. Large ¹⁴C anomalies were postulated and radiocarbon dating was considered flawed. We show here that these issues are no longer relevant, because the large anomalies are artefacts beyond plausible physical limits for their magnitude. Previous inconsistencies between ¹⁴C radiocarbon datasets have been resolved, and a new radiocarbon calibration curve, IntCal09 (Reimer et al., 2009), was created. Improved procedures for bone collagen extraction and charcoal pre-treatment generally result in older ages, consistent with independently dated time markers.     

Investigation of palaeodiet in the North Caucasus (South Russia) Bronze Age using stable isotope analysis and AMS dating of human and animal bones

This paper addresses the question of human palaeodietary adaptation in the Eneolithic and Early Bronze Age periods of the North Caucasus (South Russia) using stable isotope analysis. One of the key questions is the presence of fish in the diet. AMS radiocarbon dating of archaeological bone collagen has also been carried out to investigate potential radiocarbon reservoir effects in human skeletal material as a result of an aquatic diet. A fish component has previously been suggested in the diet of Iron Age and Bronze Age humans across Eurasia by isotopic research and radiocarbon dating of contemporaneous human and animal bones. In the North Caucasus however, isotopic data is scant. This study presents a new set of stable isotopic data from several Early Bronze Age sites, mainly belonging to the Maikop culture of the North Caucasus. The results show that the diversity in climate and environment across the northern Caucasus may be a causal factor for the patterns observed in the stable isotope values of terrestrial herbivores. This affects the isotopic values of the humans consuming them. The differences in δ¹⁵N and δ¹³C ranges of both humans and fauna were found to correlate strongly with geography and climate; the most enriched isotopic values are found in the dry steppe areas to the north. Overall, a relatively high enrichment in δ¹⁵N values of humans compared to local terrestrial herbivores and carnivores was observed. This indicates that aquatic resources were probably part of the Bronze Age diet in the region although the extent of this needs further investigation. The dramatic effect of environmental factors on isotopic values in the Early Bronze Age of the North Caucasus illustrates how confident conclusions cannot be drawn on the basis of a small number of samples from widely differing regions and time periods. Radiocarbon dating can provide a useful tool for identifying dietary derived reservoir ages in humans, potentially caused by a fish diet. With two possible exceptions, the nine human–animal bone pair dated as part of this study showed no consistent indication for a consistent reservoir effect.     

Comments on Graf, Journal of Archaeological Science 36, 2009 “ “The Good, the Bad, and the Ugly”: evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia”

Here I present a critical evaluation of the analysis conducted by Graf [Graf, K.E., 2009. “The Good, the Bad, and the Ugly”: Evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia. Journal of Archaeological Science 36, 694–707] of the Paleolithic radiocarbon (¹⁴C) dataset for the Upper Paleolithic sites in the Yenisei River basin of Central Siberia. Graf applied a rating system to the corpus of existing ¹⁴C data for the region, and announced some new ¹⁴C dates. The results obtained, however, are highly biased due to several factors, including prejudice concerning the higher accuracy of the AMS technique in ¹⁴C dating and that ¹⁴C dates from the same cultural component should overlap with plus–minus two sigmas; ambiguities with the subdivision of the Lateglacial period; artificially high sample selection criteria; incomplete factual material; and unjustifiable and misleading statements on the ¹⁴C dating of fossil bones and the issue of Last Glacial Maximum human presence in Siberia. As a result, the conclusions made by Graf [Graf, K.E., 2009. “The Good, the Bad, and the Ugly”: Evaluating the radiocarbon chronology of the middle and late Upper Paleolithic in the Enisei River valley, south-central Siberia. Journal of Archaeological Science 36, 694–707] are unconvincing. New analysis is necessary in order to improve the quality of treatment of the original data for the Upper Paleolithic ¹⁴C chronology in the Yenisei River basin.     

‘Old wood’ effect in radiocarbon dating of prehistoric cremated bones?

Numerous reports of successful radiocarbon dating of cremated bones have emerged during the last decade. The success of radiocarbon dating cremated bones depends on the temperature during burning and the degree of recrystallisation of the inorganic bone matrix. During cremation bones undergo major morphological and mineralogical changes which have raised some interesting questions and discussion on the origin of the carbon source in archaeologically cremated bones. Recent laboratory experiments reveal that the properties of the combustion atmosphere play a significant role regarding the source carbon in cremated bones. Thus radiocarbon dating cremated bones is potentially dating the wood used for the cremation fire. Here we compare a high precision radiocarbon dated human bone with an associated dendrochronological age from an oak coffin. We find that the age discrepancy between the dendrochronological age and the cremated bone of 73 ± 26 ¹⁴C yr is best accounted for by the so called ‘old wood’ effect.     

A lake fortress,a floating chronology,and an atmospheric anomaly: the surprising results of a radiocarbon wiggle-match from Āraiši,Latvia

An Iron Age timber settlement which, in view of the defensive structures uncovered, is described as a lake fortress, on an island in Lake ārai?i, north-eastern Latvia, was excavated in 1965–69 and 1975–79 by teams led by Jānis Apals, who distinguished five construction phases. Dendrochronological analysis produced a c. 100-year floating chronology for Norway spruce (Picea abies (L.) Karst.) timbers from the earliest phase. A ¹⁴C wiggle-match was undertaken to obtain an absolute date range for the final year of the floating chronology, and thus for the construction of the settlement. Ten blocks of wood from one timber, each comprising 6-11 years and collectively spanning the whole 93-year tree-ring series, were dated by AMS. Using the IntCal13 calibration data, there is a 95% probability that the felling date of this timber falls in the range 775–784 cal AD. It appears, however, that the AD 775 spike in the atmospheric ¹⁴C level occurred within the 6-year span of the last sample. On this basis, we can narrow the date of construction to 776–780 cal AD. This date is significantly earlier than those reported in previous publications.     

Implications of a freshwater radiocarbon reservoir correction for the timing of late Holocene settlement of the Elk Hills,Kern County,California

Uncertainties regarding the magnitude of freshwater radiocarbon reservoir effects can introduce random errors into dates on archaeological freshwater carbonates. As a result, many archaeologists avoid dating freshwater shells unless no other datable materials are available. The chronology of prehistoric occupation of the former Naval Petroleum Reserve No. 1 (NPR-1) at Elk Hills, Kern County, has been established with 50 radiocarbon dates on freshwater mussels (Gonidea and Anodonta sp.). Characterization of any freshwater radiocarbon reservoir effect is crucial for the accurate interpretation of inferred settlement and subsistence changes on the Elk Hills. Paired charcoal and freshwater mussels sampled from closely associated contexts were dated to identify a freshwater reservoir effect. Paired Anodonta and Gonidea sp. shells were dated to investigate interspecific differences in fractionation. Results indicate that a 340 ± 20 ¹⁴C yr correction should be applied to conventional ¹⁴C dates on freshwater carbonates in the Buena Vista Basin before calendar calibration. Evidence of interspecific differences is inconclusive. Dates recalibrated with the reservoir correction indicate that widespread occupation of the Elk Hills is correlated with increasing precipitation towards the end of the Medieval Climatic Anomaly and during the Little Ice Age, suggesting that slough resource exploitation may have been driven by regional population pressure rather than drought-related declines in aquatic productivity.     

U-series dating of soda straw stalactites from excavated deposits: method development and application to Blanche Cave, Naracoorte, South Australia

This study aimed to further test the method, reported by St Pierre et al. (2009), to develop robust chronologies of deposits in limestone caves through U/Th (Uranium/Thorium or U-Series) dating of soda straw stalactites. The chronology of fossil bearing deposits at Blanche Cave was further constrained with thermal ionisation mass spectrometry (TIMS) U/Th dating of 17 additional soda straw stalactite samples, and results were compared to recalibrated ¹⁴C ages of charcoal. The results support the assertion that soda straw stalactites can provide ages close to the time of sediment deposition and may be used as reliable chronological markers, particularly for periods reaching or beyond the radiocarbon dating limit. The application of an enhanced cleaning technique facilitated the reduction of detrital Th in samples, significantly increasing age accuracy and precision. Additionally U/Th age accuracy and precision was increased through the application of site-specific measured U/Th ratios to correct for the detrital ²³⁰Th component in samples.     

Pre-screening techniques for identification of samples suitable for radiocarbon dating of poorly preserved bones

Under certain environmental conditions, post-depositional diagenetic loss of bone collagen can severely reduce the number of bones from a particular archaeological site that are suitable for stable isotopic analysis or radiocarbon dating. This study examined nearly 300 bones from 12 archaeological sites across southern England known to yield poor or variable preservation to try to identify one, or more, pre-screening technique(s) that would indicate suitable collagen preservation for radiocarbon dating. The most reliable method was shown to be the percent nitrogen (%N) of whole bone powder, which has an 84% chance of successfully predicting whether or not a bone will yield sufficient (i.e. >1% weight) collagen for dating.     

RADIOCARBON DATING: REVOLUTIONS IN UNDERSTANDING*

Radiocarbon dating has undergone a number of ‘revolutions’ in the past 50 years. This is in part because it is a field in continuous development, but perhaps more because of its profound impact on archaeology and the nature of interdisciplinary research. In order to understand the use of radiocarbon as a dating tool, it is necessary to understand the life cycle of radiocarbon, from its production in the upper atmosphere, through its sequestration in reservoirs and samples and its final decay. Different elements in this life cycle lead to complications, or subtleties that need to be understood if we wish to develop high‐resolution chronologies. Most of the changes that have influenced radiocarbon dating are revolutions in understanding of the natural world in disparate academic disciplines. More than ever, it is necessary for users of radiocarbon to understand and engage with the science that underlies the method.     

The Dramatic Abandonment of a Late-Antique Settlement in the South Caucasus: The First Archaeological Findings from Qaratəpə, Bərdə Rayon,Azerbaijan

This paper presents the first results of a new project investigating the provincial structure of the eastern Caucasus region in the late Antique and early Islamic periods. Excavations at the newly discovered rural archaeological site of Qarat?p? have so far revealed two phases of use: a burial ground dating to the 12th century a.d. and an unusually large earthen structure burnt in a catastrophic fire. Owing to the rapid abandonment of this building, whole ceramic and glass vessels were recovered from the fill of one of the rooms. The presence of charred seeds and roof timbers allowed for the acquisition of radiocarbon dates for the construction and abandonment of the building, placing the latter at the end of the 6th century a.d. These findings reveal crucial clues as to the transformation of the rural zone prior to the expansion of Islam, and a unique material assemblage dating from this period.     

RADIOCARBON DATING ARCHAEOLOGICAL SAMPLES IN THE EASTERN MEDITERRANEAN, 1730 TO 1480 BC: FURTHER EXPLORING THE ATMOSPHERIC RADIOCARBON CALIBRATION RECORD AND THE ARCHAEOLOGICAL IMPLICATIONS*

The East Mediterranean Radiocarbon (Inter‐)Comparison Project (EMRCP) has measured time series of radiocarbon ages for known age samples of German oak (GeO) and for samples from the near‐absolutely placed Gordion juniper dendrochronology from central Anatolia. In this paper, we review the data for the calendar years from 1730 to 1480 bc , relevant in particular to controversy and debate concerning the absolute date of the Minoan eruption of the Santorini (Thera) volcano. We consider the issue of the radiocarbon (¹⁴C) dating of the Santorini eruption, and the problem of how this relates to the archaeological record and historical chronology of Egypt in light of the ¹⁴C data. We find that these ¹⁴C data, and other recent radiocarbon work, provide good grounds to be confident in the possibility of a robust radiocarbon‐based chronology for the eastern Mediterranean. In contrast, as the radiocarbon case becomes stronger, questions must be asked about some archaeological dating: in particular, at the site of Tell el‐Dab‘a in the Nile Delta of Egypt.