Bone diagenesis in the European Holocene II: taphonomic and environmental considerations

We have applied cluster analysis to mercury intrusion porosimetry data from 219 archaeological bones (121 human and 98 animal) and soil chemistry data from 219 accompanying soil samples (1 per bone sample), to investigate the influence of soil chemistry on bone preservation. The samples chosen for the study were obtained from sites ranging in time from the pre-modern to the Mesolithic and were representative of burial environments across Europe (from the Baltic to the Mediterranean). These results represent the single largest database for archaeological bone preservation in the European Holocene to date and demonstrate the potential for large-scale diagenetic studies to help develop long term preservation strategies for our European heritage. Despite the variety of sites and environments, bones could be categorised into only four main diagenetic types. Furthermore, soil chemistry appears to significantly affect only one type of preservation, the pathway characterised by loss of mineral. In neutral to basic soils, taphonomy and in particular the differences between the treatment of human and animal remains, becomes the dominating factor in determining preservation. Using these results, strategies for heritage management of archaeological sites can be suggested; grouping sites into those requiring immediate excavation and those where in situ preservation is viable.     

An X-ray Diffraction (XRD) and X-ray Fluorescence (XRF) investigation in human and animal fossil bones from Holocene to Middle Triassic

We examined by Rietveld refinement of X-ray Diffraction patterns a series of 61 human and animal fossil bones in an age range from present time to Middle Triassic (around 245 Ma). This approach, supplemented by elemental analysis according to X-ray Fluorescence, has permitted to obtain a quantitative evaluation of the mineralogical phases in the specimens, thus allowing to reconstruct the mineralization process involved. Concerning the apatite phase, after adopting a monoclinic geometry for the unit cell, the method permits to determine with fair degree of precision the unit cell volume, which is found to decrease in relatively short geological times as a function of the fluorine substitution process for the hydroxyl group –OH. After excluding the role of a high-temperature fire treatment to the bones, it is found that a certain linear correlation may exist over the geological time scale involved between the age of the specimen and the average crystallite size. This observation permits to use the XRD pattern as an evaluation of the age of the fossil, although the stratigraphic observations, where available, remain as the main reliable source for dating such biomaterials. The uncertainty related to this age estimation may be hardly better than 15–20% in absolute, because of various assumptions involved in the XRD methodology used and in the variability of the burial environment that may be subjected to discontinuous changes over the very long time of deposition.     

Ancient Solomon Islands mtDNA: assessing Holocene settlement and the impact of European contact

Archaeologists, linguists and geneticists generally agree that Near Oceania was subject to two major pulses of human dispersal: a Pleistocene occupation around 40,000 BP and a Late-Holocene migration at 3500 BP commonly associated with the Austronesian expansion out of Taiwan. The latter led to the development of the Lapita cultural complex in the Bismarck Archipelago which resulted in the settlement of Remote Oceania and there are a variety of competing models (express train, slow boat, entangled bank, etc.) used to explain this. Recent genetic studies have focused on this issue, but none of them have taken into consideration the bias possibly introduced by 19th-century historically reported population decline caused by European contact.     

Assessing mussel shell diagenesis in the modern vadose zone at Lyon's Bluff (22OK520), Northeast Mississippi

This study considers the chemical alteration of archaeological freshwater shell above the water table at the Lyon's Bluff site (22OK520), a single-mound and village complex located in east-central Mississippi, and the changes in trace element concentrations between unfired and fired shell. Thin-section petrography, X-ray diffraction, cathodoluminescence, and scanning electron microscopy analyses were conducted on archaeological shell from four natural layers from Unit 20N20W, over a depth of 80 cm and spanning 450 years. ICP–MS analysis also was conducted on a modern freshwater shell subjected to kiln firing. Microscopy results indicate a pristine aragonite crystal structure in the archaeological samples. ICP–MS data show that certain trace elements within the modern shell maintain their concentration after firing at 500 °C. The broader implications are: 1) that diagenetic alteration does not hinder chemical sourcing of shell at Lyon's Bluff, and 2) that certain trace elements are more reliable than others, namely Sr²⁺, Al²⁺, Ba²⁺, and Mn²⁺, when conducting trace element provenance studies on fired-shell temper.     

殷墟卜辞中的鸟

中国古代的民族有鸟崇拜的习俗。《左传.昭公十七年》记载郯子论古代官制,云:我高祖少挚之立也,凤鸟适至,故纪于鸟,为鸟师而鸟名。凤鸟氏,历正也,玄鸟氏,司分者也,伯赵氏,司至者也,青鸟氏,司启者也,丹鸟氏,司闭者也。祝鸠氏,司徒也,睢鸠氏,司马也,鸠氏,司空也,爽鸠氏,司寇也,鹘鸠氏,司事也。五鸠,鸠民者也,五雉为五工正,利器用,正度量,事民者也。     

Palaeoenvironmental reconstruction of La Olla,a Holocene archaeological site in the Pampean coast (Argentina)

The evolution of littoral palaeoenvironments in the southern Pampas region of Argentina towards the end of the early Holocene and the beginning of the mid Holocene is discussed, and the formation processes of the archaeological site of La Olla are analysed. This site is located in the intertidal zone of the present beach and is remarkably well-preserved. The human occupation at the site has been dated at between 7400 and 6480 yrs BP, and is interpreted as a place for the processing and consumption of the southern fur seal (Arctocephalus australis) and southern sea-lion (Otaria flavescens). It is concluded that biostabilization by microbial mats of the sedimentary structures and archaeological remains that developed and are present on the tidal flat prevented their erosion by wind, turbulence currents and waves. This is what has permitted the exceptional preservation of the site. On the basis of the analyses of one of the sectors of the site it can be concluded that the sedimentary succession of the La Olla site is the result of the coastal environmental changes during the early–mid Holocene in the pre-maximum transgressive episode. During this interval a tidal flat developed on the Pleistocene abrasion platform. Human occupation occurred during the formation of mixohaline marsh, an upper intertidal–lower supratidal zone ecosystem.     

论殷墟甲骨文中的兼语句

本全面探讨了殷墟甲骨兼语句的句型问题。根据语句中兼语之后句子成分的不同,同时也根据兼语在语句中位置的不同（前置或后置）,把甲骨兼语句分成8种句式。每种句式内又根据句子成分隐现的差异,分成不同的句型（共有112种句型）。章指出了现代常见的兼语句句型对使令动词为“呼”的兼语句和使令动词为“令”的兼语句的区别也做了探讨。     

Bison Bone Fragmentation and Survivorship: a Comparative Method

Zooarchaeologists usually describe a bone fragment as a particular portion or segment using terminology based on skeletal orientation (e.g. proximal, anterior, lateral). A more precise understanding of bone fragmentation can be achieved by naming portions for discrete anatomical features and defined zones. Since the anatomical features are the diagnostic criteria for identifying and orienting bones, each specimen normally has at least one such portion, and a complete element contains all of them. This recording method facilitates study of the relationship between survivorship and volume density, and it enhances inter-site comparisons. The method employs the minimum number of elements (MNE) and minimum animal units (MAU) across a site-wide aggregate. Although illustrated here with an analysis of bison bones, the method can be adapted for the study of other taxa as well as for inter-species comparisons.     

Mobility in Central European Late Eneolithic and Early Bronze Age: tibial cross-sectional geometry

An absence of settlement features during the Central European Corded Ware period (Late Eneolithic, 2900–2300 BC) has been interpreted as a reflection of mobile pastoral subsistence. Recent analyses of the Late Eneolithic archeological context reveal that the Late Eneolithic exhibit evidence of sedentary agricultural activities similar to the Early Bronze Age. Since the archeological analyses are not clear cut, we tested mobility pattern differences between the Late Eneolithic and Early Bronze Age using biomechanical analysis of the tibial midshaft cross-sections. The total sample of the 130 tibiae representing five archaeological cultures was used. The results of the tibial midshaft geometry do not support the hypothesis about different mobility in the Late Eneolithic and Early Bronze Age. This conclusion is supported by nonsignificant differences between the Corded Ware females and the Early Bronze Age females. Higher absolute values for the Corded Ware males should be explained either by stochastic variation or by differing amounts of physical demands despite a generally similar pattern of subsistence of the Late Eneolithic and Early Bronze Age. One of the Early Bronze Age samples, the Wieselburger group, is an exception because the individuals show both reduced overall size and bending resistance of the tibial parameters not only in comparison with the Late Eneolithic but also to the rest of the Early Bronze Age. The results suggest that the behavioral processes which affected the tibial midshaft biology operated during the Late Eneolithic and Early Bronze Age as a mosaic across time and between/within cultures.     

Electron backscatter diffraction investigation of length‐fast chalcedony in agate: implications for agate genesis and growth mechanisms

Agates of volcanic origin contain a range of silica minerals, with chalcedony and quartz arranged in concentric bands. Although agates are abundant worldwide, little is known about the genesis of their characteristic banding patterns. Current hypotheses suggest the bands result either from precipitation from convecting siliceous hydrothermal influxes or by in situ crystallization of a silica gel. This study combines the use of a variety of analytical techniques, including electron backscatter diffraction (EBSD), cathodoluminescence (CL), and Fourier transform infrared (FT‐IR) spectroscopy, to characterize the silica minerals present and investigate their spatial and crystallographic relationships in the banding arrangement. Microstructural and spectroscopic observations reveal that chalcedony bands are composed of amorphous silica that also contains nanocrystalline and later‐formed microcrystalline quartz. Nano‐ and microcrystalline quartz grew with a‐axes perpendicular to the growth substrate, typical of length‐fast chalcedony. The bands formed as a result of discrete influxes of silica‐rich fluid. Within these individual bands, there is a sequence of minerals: chalcedony‐A (with amorphous silica and nanocrystalline quartz) → chalcedony‐MQ (with microcrystalline quartz) → quartz. This sequence is reflected in the degree of crystallinity, crystal orientations and water content and is analogous to a diagenetic cycle; the initial chalcedony portion of the band commences with amorphous silica with nanocrystalline quartz followed by fibrous microcrystalline quartz crystals; chalcedony then grades into larger equiaxial mesoquartz crystals. This paragenetic sequence suggests a viable model for the growth of chalcedony in agates.     

Joint controlled fluid flow patterns and iron mass transfer in Jurassic Navajo Sandstone,Southern Utah,USA

The Jurassic Navajo Sandstone of Grand Staircase Escalante National Monument (GSENM), Utah, exhibits a broad range of iron oxide/oxyhydroxide concretionary geometries that record a complex paragenetic history of the reservoir. The concretionary geometries are as follows: (i) common macroconcretions (>5 mm in diameter), (ii) ubiquitous microconcretions (<5 mm in diameter), (iii) localized iron oxide/oxyhydroxide‐lined northeast‐striking joints, and (iv) loopy asymmetrical mineralization and banded precipitation patterns (Liesegang bands) associated with the joints. Spheroidal concretion geometries typically indicate diffusive mass transfer, whereas asymmetrical mineralization represents advective directional flow. Liesegang bands parallel to asymmetrical mineralization denote a diffusive mass transfer component perpendicular to the principal flow direction. Careful study of concretionary geometries and their cross‐cutting relationships establishes a relative timing of precipitation and mobilization events. Macroconcretions formed post‐Laramide (<55 Ma), prior to and independent of the Miocene joints. The joints provided conduits for later oxidizing fluids that precipitated iron oxide/oxyhydroxide lining on the joint faces. Advective mass transfer overprinted the area with preferentially cemented flow lines (asymmetrical mineralization) less than 10 Ma, coincident with development of a hydraulic low to the southeast of the region (Colorado River downcutting). Certain trace elements are genetically tied to concretion formation, and evaluation of trace elements establishes precursor mineral phases. Enriched uranium concentrations in concretions (relative to the host rock) and low/undetectable sulfur concentrations in both host rock and concretions suggest that iron oxyhydroxide was a primary precipitate rather than a reduced iron mineral (i.e., pyrite or siderite) that later oxidized. Enrichment of Ni and As in concretions functions as fingerprints for diagenetic concretion formation when determining genesis of ambiguous iron oxide/oxyhydroxide spherules such as the remotely sensed ‘blueberries’ on Mars. Similarities between Mars and Utah spherules such as geometry, in situ spacing and volumetric density suggest that Mars spherules precipitated via a geochemically self‐organized nucleation pattern in diffusive chemical reaction fronts.     

Bone preservation in human remains from the Terme del Sarno at Pompeii using light microscopy and scanning electron microscopy

Archaeological bone can show marked and complex alterations depending on the environment in which it was buried. In this study, the state of preservation of 27 femurs recovered from the archaeological site of Pompeii was evaluated by light microscopy and scanning electron microscopy. Most of the bone samples, prepared by the grinding method, showed good histological preservation, although they were characterized by microfissures (microcracking). Nine bone samples showed different states of histological preservation, including worst preservation (two femurs), due to diagenetic processes. Cryostat bone sections stained with thionin or 4′,6′-diamidino-phenylindole (DAPI) revealed the persistence of DNA within some osteocyte lacunae. Scanning electron microscopy analysis showed that ultrastructural characters, such as lamellae and collagen fibres, are recognizable only in unaltered bone. Our results reveal that most Pompeian samples are well preserved since they have a bone microstructure virtually indistinguishable from that of fresh bone. In methodological terms, although each of the various morphological methods used contributes information, histological and histochemical analyses are the most informative for studying the preservation state of bone and allow for rapid essential screening of archaeological bone.     

Stable isotope reconstructions of shellfish harvesting seasonality in an estuarine environment: implications for Late Holocene San Francisco Bay settlement patterns

Seasonality estimates based on stable isotope analyses of shellfish remains has been an important thrust of settlement pattern reconstruction, allowing researchers to place people on the landscape at points in space at different times of the year. In exposed coastal settings seasonality reconstructions are typically dependent on annual changes in water temperature. This paper has two goals. First, we continue development of a method for determining shellfish harvest seasonality in estuarine environments where annual salinity changes, not temperature, drive isotopic variation. Second, we contribute to settlement pattern studies by showing how small and large sites can be linked into a single system by examining different site types and shellfish species. Our case study focuses on the Late Prehistoric period of the San Francisco Peninsula, includes a large shellmound (CA-SMA-6) and an ephemeral camp (CA-SFR-171), and examines clam (Macoma spp.) and mussel (Mytilus spp.) harvesting. In this case, data support a fission-fusion settlement pattern, with periods of dispersal during late winter through early summer and aggregation in late summer through early winter.     

Secular variations in seawater chemistry as a control on the chemistry of basinal brines: test of the hypothesis

The hypothesis that basinal brines inherited their major ion chemistries and elevated salinities from evaporated paleoseawaters is tested by comparing the compositions of basinal brines in Silurian (Michigan basin, Illinois basin, Appalachian basin in eastern Ohio) and Jurassic/Cretaceous (Central Mississippi Salt Dome basin, Arkansas shelf, and south‐central Texas) host rocks, when the world oceans were ‘CaCl₂ seas’, with those from Permian and Pennsylvanian rocks (Palo Duro basin, Central Basin Platform, and Delaware basin, Texas and New Mexico) when the world oceans were ‘MgSO₄ seas’. Basinal brines examined are assumed to have originally formed from evaporation of the same seawaters that produced major evaporites. Sulfate, Mg and K levels in basinal brines are below the concentrations expected from evaporation of seawater of any type, which emphasizes the importance of diagenetic mineral–brine interactions in controlling basinal brine chemistry. There are no major differences in SO₄, Mg and K concentrations between basinal brines hosted by rocks originally formed during ages when the world oceans were MgSO₄ seas versus CaCl₂ seas. Basinal brines in Pennsylvanian–Permian rocks are compositionally distinct (relatively high Na and low Ca) from basinal brines in Silurian, Jurassic and Cretaceous host rocks, which may reflect original differences in seawater chemistry. Basinal brines enriched in Ca and depleted in Na relative to evaporated seawater of any type have traditionally been interpreted to form by albitization of plagioclase feldspar. A new explanation for Ca enrichment and Na depletion of basinal brines is the mixing of evaporated CaCl₂‐type seawater with more dilute water. Some basinal brines are similar in major ion composition to evaporated seawater of a particular age, for example basinal brines in the Cretaceous Edwards Group carbonates, Texas, where dolomitization is the only reaction required to convert evaporated Mesozoic CaCl₂ seawater into Edwards Group brine.     

Hunter–gatherer foraging ranges, migrations, and travel in the middle Holocene Baikal region of Siberia: Insights from carbon and nitrogen stable isotope signatures

Foraging ranges, migrations, and travel among Middle Holocene hunter–gatherers in the Baikal region of Siberia are examined based on carbon and nitrogen stable isotope signatures obtained from 350 human and 203 faunal bone samples. The human materials represent Early Neolithic (8000–6800 cal BP), Late Neolithic (6000–5000 cal BP), and Early Bronze Age periods (∼5000–4000 cal BP) and come from the following four smaller areas of the broader region: the Angara and upper Lena valleys, Little Sea of Baikal’s northwest coast, and southwest Baikal. Forager diets from each area occupy their own distinct position within the stable isotope spectrum. This suggests that foraging ranges were not as large as expected given the distances involved and the lack of geographic obstacles between the micro-regions. All examined individuals followed a similar subsistence strategy: harvesting game and local fishes, and on Lake Baikal also the seal, and to a more limited extent, plant foods. Although well established in their home areas, exchange networks with the other micro-regions appear asymmetrical both in time and direction: more travel and contacts between some micro-regions and less between others. The Angara valley seems to be the only area with the possibility of a temporal change in the foraging strategy from more fishing during the Early Neolithic to more ungulate hunting during the Late Neolithic–Early Bronze Age. However, the shift in stable isotope values suggesting this change can be viewed also as evidence of climate change affecting primary productivity of the Baikal–Angara freshwater system.     

Lapita subsistence strategies and food consumption patterns in the community of Teouma (Efate,Vanuatu)

The subsistence strategies of the Lapita populations (3100–2800 BP), the first colonisers of the pristine environments of the islands of Eastern Melanesia and Western Polynesia, have been a matter of ongoing debate for decades. Opinions have ranged between the two extremes of Lapita colonisers being either characterised as highly mobile foragers to fully horticultural communities. To further address the question, this paper presents stable carbon and nitrogen isotopic data obtained from analyses of human and animal collagen samples from the site of Teouma (Efate, Vanuatu) dated to between c. 3000–2500 BP. The isotopic signatures obtained from 28 samples (23 human and 5 animal), interpreted in combination with isotopic information from several coastal and insular environments, suggest a diet primarily made up of terrestrially derived animal protein with lesser contributions from vegetable produce and inshore marine species. Comparisons linking the isotopic data gleaned from the Teouma individuals and Lapita subsistence patterns reconstructed through archaeozoological and archaeobotanical remains support the hypothesis of a mixed economy, that included terrestrial foraging, inshore marine exploitation and a low level of food production for at least some of the earliest Lapita colonists in Vanuatu.     

Dietary patterns during the late prehistoric/historic period in Cikobia island (Fiji): insights from stable isotopes and dental pathologies

The dietary patterns of eight adults and one child interred in the Korotuku burial mound (Cikobia, northern Fiji), dated from the late prehistoric/historic period (around AD 1850), have been investigated using carbon and nitrogen stable isotope signatures and dental and oral pathologies. Bone collagen isotopic compositions showed that (1) males and females had similar diets in terms of terrestrial C₃ resources and marine fish components and proportions; (2) the proportion of marine fish comprised around 25% of the protein fraction of the diet, and the proportion of vegetal food was high; and (3) one canid that was also studied had a different diet, probably rich in shellfish. Oral and dental examinations of the humans evidenced (1) a low level of dental macrowear, (2) a high rate of carious lesions—interproximal and cervical—of about 15%, and (3) a low amount of abscessing, as well as the presence of alveolar bone recession and calculus in most of the adults. This evidence suggests a diet relying mainly on vegetal food with very limited shellfish consumption. When viewed in the light of ethnohistoric information, this pattern suggests a particular sociocultural behaviour, including food selection, since the analyses of the canid remains indicate that more diversified food resources were available than those consumed by the humans. Overall observations suggest that the deceased in the Korotuku burial mound might be members of an elite living on the island, thus pointing to possible social stratification in the late prehistoric/historic Cikobia community.