Neutron activation analysis of fine grey pottery from Conimbriga,Santa Olaia and Tavarede,Portugal

The concentrations of two major elements and thirteen trace elements in 73 selected sherds of fine grey ware from the Iron Age and Roman period, excavated at Conimbriga, Santa Olaia and Tavarede, Portugal, were determined by instrumental neutron activation analysis. These concentrations were used to calculate distance matrices which were then subjected to cluster analysis employing SAHN and k-means methods, as well as to principal components analysis, to group the sherds according to the overall similarity of their compositional characteristics. The results showed that equivalent groupings appeared regardless of the taxonomic method used. Two major clusters were recognized corresponding to two different sites, namely Conimbriga and Santa Olaia, suggesting that the ceramics from these sites were made locally. No significant differences in compositional patterns were observed between iron age and roman sherds from Conimbriga.     

THE UTILIZATION OF TRACE CHEMICAL COMPOSITION TO CORRELATE BRITISH POST-MEDIEVAL POTTERY WITH EUROPEAN KILN SITE MATERIALS

This study uses X-ray fluorescent analysis to compare the trace chemical composition of seventeen pottery sherds excavated from sites in Britain with the trace analyses of twenty four sherds from continental sources. Results indicate that certain elements, notably zirconium, titanium, rubidium, and strontium show little variation within a particular sherd and are consistent among samples from the same source. Certain other elements appear to show wide variation which is possibly attributable to firing conditions, burial or is connected with the glaze. The comparisons of analyses indicate that nine of the seventeen British sherds can be closely correlated with particular continental sources. Tentative correlation is suggested for five sherds. The remaining three sherds clearly do not come from any of the sources investigated.     

CHARACTERIZATION OF SAMIAN WARE SHERDS BY MEANS OF NEUTRON ACTIVATION ANALYSIS

Neutron activation analysis has been employed for the characterization of Samian ware sherds. The analysed samples were classified in ten groups, seven of which belonged to the Arretine production, according to archaeological evidence. By means of high resolution gamma-ray spectroscopy, 22 elements have been identified and analysed. Compositional characterization was looked for by taking counting rate ratios of different nuclides in the samples. The compositional pattern of the sherds was found to be fairly uniform both for each pot and for each group so that, at least in the examined cases, it can be assumed to be characteristic of a given workshop.     

FINE WARE FROM LOCRI EPIZEPHIRI: A PROVENANCE STUDY BY INDUCTIVELY COUPLED PLASMA EMISSION SPECTROSCOPY

Fifty-six sherds of fine ware from Locri Epizephiri were analysed by inductively coupled plasma optical emission spectroscopy (ICPOES) and flame emission spectroscopy (FES). The sherds had been excavated on the archaeological areas of Marasà Sud, Centocamere and San Cono, and represent local and imported products from the seventh to the second century BC. The samples were dissolved by fusion with lithium metaborate and analysed for nine elements (Al, Fe, Ca, Mg, Ti, Mn, Sr, Ba and Cr) by ICPOES, while Na and K were determined by FES. The analytical data were subjected to hierarchical agglomerative clustering and principal components analysis to classify the sherds into compositional groups. The results obtained indicated that Corinthian, Attic and Ionian products or imitations may be classified in a few separate groups, while most local products are found in a unique, large group.     

CAMPANIAN POTTERY FROM ANCIENT BRUTTIUM (SOUTHERN ITALY): SCIENTIFIC ANALYSIS OF LOCAL AND IMPORTED PRODUCTS*

One hundred and fifty-seven sherds of Campanian pottery were analysed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and flame emission spectroscopy (FES). The sherds were found in the course of archaeological excavations carried out at the sites of Sibari, Cosenza, Crotone, Locri, Reggio and Oppido Mamertina in southern Italy (ancient Bruttium, today Calabria). Analyses were carried out on dissolved samples, determining 15 elements per sample (Al, Fe, Ca, Mg, Ti, Mn, Sr, Ba, Cr, Cu, Y, La and Sc by ICP-OES, and Na and K by FES). Analytical data were subject to multivariate statistical treatment by hierarchical cluster analysis and principal components analysis. Results indicated different compositional groups, allowing one to separate suspected imports from Campania, Etruria and Sicily from each other and from likely local products. The latter could be further classified into different groups, comprising imitations of foreign forms as well as original local products.     

广东博罗先秦硬陶的XRF和INAA研究

为揭示广东博罗梅花墩、银岗、横岭山三地古陶器的产源、烧造工艺、技术传播和化交流等方面情况,用波长色散X射线荧光分析(WDXRF)、仪器中子活化分析(INAA)同时测量了广东博罗梅花墩、银岗、横岭山等三地点所出38片西周至春秋、战国硬陶中Al、Ba等元素的含量。并用主成分分析分别处理了测量数据。两套数据的分析结果均表明,梅花墩、银岗和横岭山的硬陶原料互不相同,各地点硬陶可能主要是“自烧自用”。数据分析还表明在南方各省区中,广东硬陶具有Al2O3含量偏高这一明显的地区特征。     

Classical and Hellenistic black glaze ware in the Mediterranean: A study by epithermal neutron activation analysis

Fifteen chemical elements have been measured quantitatively by epithermal neutron activation analysis in 58 sherds of black glaze pottery found in Carthage/Tunis (23 sherds), the Athenian Agora (9 sherds), Sicily (7 sherds), and several sites in Southern Italy (19 sherds). Detailed statistical analysis of the results clearly distinguishes five separate groups: (a) one of local Carthage/Tunis origin; (b) one of probable Sicilian origin; (c) a large group of Attic origin comprising sherds found at the Athenian Agora and at Carthage/Tunis; and (d) two separate groups from S Italy.     

Defining the provenance of red slipped pottery from Texas and Oklahoma by petrographic methods

Ceramics are among the most important artifacts that archaeologists use to reconstruct patterns of prehistoric trade and exchange. Petrographic analysis of ceramic thin-sections, in addition to providing detailed technological data, enables the identification of sand-tempering agents. These raw materials are potentially important evidence for ceramic provenance, assuming that such common materials themselves would not have been traded. Here we apply methods developed by sedimentary petrographers to the problem of determining the provenance of Red Slipped sherds from late Prehistoric (c. AD 1000–1400) sites in the Caddoan area and contemporaneous Plains Village sites. Modal frequencies of different kinds of quartz, feldspars and lithic grains are used to construct several triangular graphs that reveal compositional patterns indicative of provenance. Sherds from the Plains Village sites exhibit higher frequencies of lithic grains, feldspars and polycrystalline quartz relative to the sherds from sites in eastern Texas and eastern Oklahoma. While anomalous sherds were identified, the longstanding assumption that Red Slipped sherds in Plains Village contexts were traded from the Caddoan area is not supported by these data. These methods have strong application potentials for other, geologically diverse portions of North America.     

A SCIENTIFIC STUDY OF TRADITIONAL KOREAN CELADONS AND THEIR MODERN DEVELOPMENTS

Eighty sherds from nine different kiln sites representing a wide geographic distribution and a long time span of Korean celadon culture are analysed for macroscopic and compositional characteristics. Additionally chemical and mineral compositions of six unglazed sherds are compared with those of some modern raw materials. Unusually high values of alumina in the earliest Kangjin pieces of the middle ninth and early tenth century (I¹) could represent a significant technological innovation at the end of this period at this most important celadon production centre. Similarity in chemical and mineral compositions between unglazed sherds and some raw materials such as Kangjin clay and pottery stone show the possibility that many of the celadons were made from these types of raw materials as found in nature without additives and only after mechanical refining.     

X-ray fluorescence analysis of late Roman and Sassanian silver plate

About 200 analyses have been made on late Roman and Sassanian silver objects using energy-dispersive X-ray fluorescence. This has shown that the main feature of the composition of the silver throughout the period and across the geographical area studied was towards high fineness (average silver percentage about 95%). Compositional differences are found between Roman and Sassanian silversmiths' products for the elements copper and lead. Much of the material analysed came from hoards, and using a statistical technique on the analytical data (Discriminant Analysis) broad compositional differences between hoards were found to emerge. The use of different compositions of silver for different joined parts of a single object are discussed.     

CHEMICAL CHARACTERIZATION AND STATISTICAL MULTIVARIATE ANALYSIS OF ANCIENT POTTERY FROM MESSINA,CATANIA, LENTINI AND SIRACUSA (SICILY)*

This paper presents the chemical characterization of 79 fragments of Archaic and Hellenistic fine‐grained pottery from archaeological sites in Messina, Catania, Lentini and Siracusa (Sicily). The sherds were classified as ‘calcidian’, ‘banded’, ‘unvarnished’ and ‘black varnished’ pottery. The major and trace elements identified by X‐ray fluorescence (XRF) were statistically elaborated using the method proposed by J. Aitchinson in 1986 for the analysis of compositional data. From cluster analyses using element/SiO₂ log‐ratios, it was possible to group the pottery found in Catania, Lentini and Siracusa into highly linked clusters. Conversely, the Messina pottery was divided into two clearly distinct groups. With the aim of identifying any possible mineralogical differences between the two Messina groups, Fourier transform infrared (FT–IR) absorption measurements were made, showing only quantitative differences in plagioclase and muscovite. The specific groups of pottery with restricted chemical compositions are considered to be of local production, also on the basis of archaeological and petrographic evidence.     

Sourcing ceramics with portable XRF spectrometers? A comparison with INAA using Mimbres pottery from the American Southwest

Seventy-five intact Mimbres and Jornada pottery sherds from the American Southwest were analyzed by portable XRF and instrumental neutron activation analysis (INAA). Examination of the data demonstrates that INAA and portable XRF results for elements common to both analyses can be used to construct similar compositional groups. When individual compositional groups are compared to one another, it is apparent that unambiguous separation of compositional groups is challenging by portable XRF given (1) the limited number of key discriminating elements that can be measured relative to INAA, and (2) the relative analytical precision and accuracy of portable XRF for measurements of intact heterogeneous ceramics. We conclude that sourcing intact ceramics by portable XRF is challenging and that bulk analytical measurements, such as INAA, remain a better approach for sourcing archaeological pottery.     

THE DATING OF ANCIENT CHINESE CELADON BY INAA AND PATTERN RECOGNITION METHODS*

In 2005, sherds of a special type of ancient Longquan celadon ware were excavated at Maojiawan, in the city of Beijing, China. Although archaeologists agree that these sherds were fired in the period between the Yuan and Ming Dynasties, their specific date is unclear. In order to solve this problem, five other groups of ancient Longquan celadon sherds of known date were selected as reference samples. The elemental body composition of all the sherds was determined by Instrumental Neutron Activation Analysis (INAA). Using the same principles as in provenance research, pattern recognition methods were used to build classification functions to specify the date of the unknown sherds. After analysing the experimental data by discriminant analysis, three classification functions were built. All the unknown sherds were classified as Ming Dynasty. This prediction is well in accordance with the fact that these sherds are similar to other Longquan Ming celadon, and so they should be fired in the same dynasty. This also verified the judgement of the Beijing Institute of Cultural Relics.     

Preliminary Provenance Research on Chinese Neolithic Pottery: Huating (Xinyi County) and Three Yellow River Valley Sites

Instrumental neutron activation analysis (INAA) was applied to sherds from the important site of Huating and, for comparison, several Neolithic sites in the valley of the Yellow River. We hoped to compare the compositions of two stylistically different ceramics found at Huating, and to evaluate the degree of compositional clustering and inter‐site resolution that could be expected in an area that is noted for its extensive, and possibly very homogeneous, loess deposits. In addition, pottery sherds from Huating have been examined by microscopic petrography. All of these results will provide needed input in the planning of research towards the formation of a Neolithic/Shang Dynasty ceramic database for future use in archaeological research in China.     

A PROVENANCE STUDY OF POTTERY FROM ARCHAEOLOGICAL SITES NEAR CANOSA,PUGLIA (ITALY)*

Studies have been carried out to assess the provenance of selected pottery excavated at archaeological sites near Canosa, Puglia (Italy). Sixty-six sherds, ranging in date from the mid-seventh century BC to the beginning of the third century BC, were analysed by atomic absorption spectroscopy and 16 elements were determined. The analysis data were subjected to multivariate classification procedures. Tests showed that the majority of the examined sherds came from ancient local kilns; a probable Ionian origin was established for some other sherds, while the rest were of unknown origin.     

Characterization of Iron age pottery from eastern Turkey by laser- induced breakdown spectroscopy (LIBS)

Selected pottery sherds coming from the Ayanis, Dilkaya and Karagündüz excavations in eastern Turkey and dated from the Early to Middle Iron Age were examined as regards their composition by using laser-induced breakdown spectroscopy (LIBS). The objective of the study was first to investigate the potential of the LIBS technique in the compositional analysis of pottery and further to explore correlations in spectral data, by using chemometrics methods that would possibly enable discrimination among different sherds. This work is part of a broader study aiming to examine clay variability both before and during the Urartian State period and to explore possible relationships and differences among pottery objects from fortresses and settlements or settlements and cemeteries on the basis of the clay composition of sherds. Preliminary results demonstrate that by using the LIBS technique it is possible to analyse pottery sherds in qualitative and semi-quantitative ways, providing information on the clay and slip composition. Furthermore, encouraging results have been obtained by carrying out principal component analysis (PCA) on the LIBS spectra, which suggest that in certain cases, it is possible to directly correlate spectral information with the origin of pottery sherds.     

ROMAN POTTERY FROM AUGUSTA PRAETORIA (AOSTA,ITALY): A PROVENANCE STUDY

Forty-five sherds of Roman pottery, 21 terrae sigillutae and 24 common wares excavated in Augusta Praeroria, were analysed for 12 elements by atomic absorption and emission spectroscopy. Hierarchical agglomerative cluster analysis, principal component analysis, and non-linear mapping were performed on the analytical data in order to classify the objects in groups which could account for different provenances; soft independent modelling of class analogy (SIMCA) and K nearest neighbours (KNN) were used for solving doubtful assignments. The classification results indicate that local productions of terra sigillatu can be easily distinguished from the imported ones, and that common wares have compositional patterns which differ from those of both local and imported terrae sigillatue.     

IDENTIFICATION OF POST‐DEPOSITIONAL CHEMICAL ALTERATION OF CERAMICS FROM THE NORTH COAST OF PAPUA NEW GUINEA (SANDUAN PROVINCE) BY TIME‐OF‐FLIGHT–LASER ABLATION–INDUCTIVELY COUPLED PLASMA–MASS SPECTROMETRY (TOF–LA–ICP–MS)*

The measured chemical composition of archaeological ceramics can result from a variety of geological, cultural and taphonomic factors. In the present study, we evaluate the likelihood that elevated barium concentrations in ceramics from the archaeological site of Wom/Aiser, located on the northern coast of Papua New Guinea, result from post‐depositional enrichment. Using time‐of‐flight–laser ablation–inductively coupled plasma–mass spectrometry, we mapped chemical compositional profiles across cut sections of ceramic sherds from four archaeological sites, all previously chemically characterized. We identify the formation of pronounced concentration gradients in samples from Wom/Aiser relative to sherds with low barium concentrations, consistent with post‐burial uptake.     

'Ubaid and ED pottery from five sites at' Ain as-Sayh, Saudi Arabia

This paper presents an analysis of sherds, collected from five archaeological sites at'Ain as-Sayh in Saudi Arabia. The original material has not been available to the author. Consequently, the analysis is based on drawings, photos, and notes provided by H. A. McClure, one of the researchers who collected the material in the field. The sherds may be divided into two groups: one dated to the'Ubaid period, and one dated roughly to the third millennium BC. In the paper the sherds are typologized and compared with material from other sites. A dating of the'Ain as-Sayh sites is attempted with reference to the distribution of pottery-types on the sites, geomorphological information, and a set of mutually consistent radiocarbon dates.     

A LYONS BRANCH OF THE POTTERY-MAKING FIRM OF ATEIUS OF AREZZO

Fifty-one waster sherds of Terra Sigillata (～20-0 b.c. ) from Arezzo, Italy and Lyons, France have been chemically analysed for twenty-eight elements by neutron activation and seven by X-ray fluorescence. Most of the elemental abundances were measured with high precision and cross-comparisons of the two techniques of measurement (and sample preparation) give added insight as to their relative precision, the calibration differences and the extent to which volatile materials such as carbonate or water influence the results. The sherds from Arezzo formed a homogeneous and distinctive chemical group while all but two of those from Lyons were classified into three such groups. Two of the Lyons groups (MML A and MML B) were from Montée de La Muette and one was from Loyasse. Four additional sherds from houses excavated in Strasbourg and one from Lyons, all of which bore the signature of the famous Anetine pottery-making firm of Ateius, were also analyzed by the same techniques. These signed sherds all had the same composition pattern and it closely matched one of those from Montée de La Muette (MML A) in Lyons. It is therefore suggested that these five sherds bearing the Ateius signature were made in the general vicinity of Lyons and were part of the output of an as yet unknown Gallic branch of the firm of Ateius.