NORTH APULIAN COARSE WARES AND FINE PAINTED WARES: A REAPPRAISAL ACCORDING TO NEW DATA FROM HERDONIA AND CANUSIUM

Late Antique coarse cooking wares and painted fine wares found at Herdonia (second half of the fourth century to mid‐fifth century ad ) and Canusium (late sixth century to early seventh century ad ) have been chemically and mineralogically characterized. A total of 74 samples (40 of coarse ware and 34 of fine painted ware) was investigated through optical microscopy, scanning electron microscopy, X‐ray powder diffraction, inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry, neutron activation analysis and X‐ray fluorescence. A new statistical method, namely the classification tree methodology, was used for the treatment of geochemical data. The characterization of the Herdonia and Canusium assemblages was combined with a review of earlier results obtained for San Giusto and Posta Crusta, in order to get an insight on Late Antique ceramic trades in northern Apulia. It appears possible to reconstruct a production pattern organized at multiple production sites, both rural and urban, that exploited similar raw material deposits, specialized in certain productions, and commercialized products at different geographical scales. Imports from outside northern Apulia may be identified for coarse wares. A likely area of production is difficult to establish; however, the northern Adriatic coast and the area of Greece may be suggested.     

A SCIENTIFIC INVESTIGATION ON THE PROVENANCE AND TECHNOLOGY OF A BLACK‐FIGURE AMPHORA ATTRIBUTED TO THE PRIAM GROUP*

The restoration of a Greek black‐figure amphora provided an opportunity to study the provenance and production technology of the vase. The composition of the ceramic body, determined by inductively coupled plasma optical emission spectroscopy (ICP–OES), matches that of Attic products. Investigation by X‐ray diffraction and reflectance spectroscopy suggests a maximum firing temperature around 900°C and a body re‐oxidation temperature around 800°C, respectively. The morphology and composition of black, red and dark red surface areas were studied by scanning electron microscopy and X‐ray energy‐dispersive analysis; the black areas show the features of a typical well‐vitrified black gloss, while the red areas were most probably obtained by simple burnishing of the body; the dark red additions, on the other hand, are the likely result of a partial re‐oxidation of a clay–ochre mixture.     

BYZANTINE CERAMIC PRODUCTION FROM CUMA (CAMPI FLEGREI,NAPOLI)*

Samples of table and cooking ware, dating back to the Byzantine period of the ancient Greek colony of Cuma, were analysed by optical microscopy, X‐ray diffraction, X‐ray fluorescence and scanning electron microscopy, in order to reconstruct the main technological properties of these manufactures. The comparison of minero‐petrographical data from these samples with those of some kiln wastes allowed us to hypothesize a local manufacture for most of the investigated specimens and to confirm the relative reference groups. A restricted number of samples did not link with the main groups, indicating a regional (or maybe extra‐regional) production, in agreement with the widespread circulation of this high‐medieval ceramic production in southern Italy.     

ANALYTICAL CHARACTERIZATION OF ROMAN PLASTERS OF THE ‘DOMUS FARINI’ IN MODENA*

The paper refers to the analytical characterization of Roman painted plasters dating back to the second century ad . The following techniques were used: optical microscopy (OM), scanning electron microscopy (SEM–EDS), micro‐Raman and Fourier transform infrared spectroscopies (µ‐Raman and FT–IR), X‐ray diffraction (XRPD), colorimetry and thermal analyses (TG/DTA). The investigation analysed the chemical composition and structure of the plasters, the chemical composition of the pigment layers, the use of binders and any chemical alteration of pigments as well as deterioration of the samples. Stratigraphic analysis of plasters allowed identification of their individual components, which proved helpful in finding out more about the mural painting technique employed.     

THE CHARACTERIZATION OF PAINTS AND WATERPROOFING MATERIALS FROM THE SHIPWRECKS FOUND AT THE ARCHAEOLOGICAL SITE OF THE ETRUSCAN AND ROMAN HARBOUR OF PISA (ITALY)*

This work presents the results of a diagnostic survey on the shipwrecks from the archaeological site of the ancient harbour of San Rossore (Pisa, Italy). The original waterproofing, caulking and painting materials were characterized by Fourier transform infrared spectroscopy (FTIR), gas chromatography – mass spectrometry (GC–MS), energy‐dispersive X‐ray microanalysis (EDX) and X‐ray diffraction (XRD). The major constituents of the waterproofing and caulking materials detected on the planks were tricyclic abietanes showing a high degree of aromatization. These compounds are indicative of a pitch obtained from the wood of trees of the Pinaceae family. The analysis of the organic components of the paint samples revealed diterpenoid acids characteristic of Pinaceae resins together with linear long‐chain alcohols and fatty acids, highlighting the presence of beeswax. Noticeably, the characteristic odd carbon number alkanes that are normally present in beeswax were not detected. The EDX and XRD analyses showed that hematite, calcite, cerussite and kaolinite were employed as pigments to paint the ships’ hulls.     

THE DETERMINATION OF BRICK PROVENANCE AND TECHNOLOGY USING ANALYTICAL TECHNIQUES FROM THE PHYSICAL SCIENCES*†

This work applies established analytical techniques from the physical sciences to Irish brick, in order to gather evidence of ceramic technologies, provenance and sources of raw materials. Petrographic microscopy, X‐ray diffractometry and scanning electron microscopy with an energy‐dispersive X‐ray diffraction attachment were used to study the brick of Rathfarham Castle, Dublin, built c. 1618, where clay brick was introduced in 1771. Local clay was fired in the laboratory and analysed in a similar manner. The petrography of the pointing mortar was studied in order to gather evidence of ceramic provenance. This paper concludes that the brick was hand‐ moulded with a silica‐based, predominantly non‐calcareous clay of glacial origin, gathered locally, including fluxes and a high percentage of non‐plastic material. The mineralogy and petrography of the brick, together with the presence of pebbles and a coarse matrix, suggest that the raw clay was probably gathered from a glacial deposit. The presence of abundant pebbles and colour inhomogeneities suggests a lack of processing of the raw clay. The brick was probably fired in clamps at top firing temperatures ranging from 750°C to above 900°C. Transformation of limestone temper involving the breakdown of calcite and the generation of calcium silicates, and the new formation of plagioclase, high‐temperature quartz, hematite and spinel were revealed. The presence of spinel in ‘hot spots’ indicates that fuel was added to the raw clay in order to assist firing.     

Archaeometric characterisation of coarse and painted fine ware from <Emphasis Type="Italic">Posta Crusta</Emphasis> (Foggia,Italy): technology and provenance

Coarse and painted fine wares from the Late Antique residential complex of Posta Crusta (Lucera, Foggia, Italy) have been here investigated. The ceramic characterisation was our main concern; even so, the provenance and the production technology have been further investigated, focusing on both ceramic bodies and coatings. Optical microscopy, scanning electron microscopy and a set of bulk chemical analyses (inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry, instrumental neutron activation and X-ray fluorescence) were used for the characterisation of 44 samples. Chemical and mineralogical data here obtained were compared with results previously achieved on San Giusto local production, in order to distinguish production areas and identify possible exchanges. As for coarse wares, the characterisation of Posta Crusta pottery shed new light for the reconstruction of the production/distribution framework of this part of northern Apulia. The following trends can be identified: (1) pots from Posta Crusta and San Giusto settlement that can be referred to a single production site, likely located in the nearby territory of one of this two sites; (2) pots from San Giusto kiln exported to Posta Crusta; (3) pots of unknown origin but compatible with the northern Apulian area. Furthermore, it was possible to verify that all Posta Crusta ceramics used the alluvial deposits widely outcropping in northern Apulia as received. As for painted fine wares, Posta Crusta samples enucleated a distinct and homogenous group, including six samples from San Giusto. This result is highly encouraging as it provides the clear evidence of a production group, although it is not possible to refer it to a precise locality. The marine deposits outcropping in northern Apulia can have been surely exploited for raw materials supply. Coatings texture seems to suggest two different ways of application: immersion and painting.     

STUDY ON THE PROVENANCE OF XICUN QINGBAI WARES FROM THE NORTHERN SONG DYNASTY OF CHINA

The Xicun kiln in Guangdong Province was a famous porcelain kiln in the Song Dynasty of China, and for years there has been controversy over the provenance of Xixun Qingbai wares. This paper analyses Qingbai samples from the Xicun, Hutian (Jingdezhen) and Chaozhou (Guangdong Province) kilns by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) and energy‐dispersive X‐ray fluorescence probe (EDXRF). The analytical results indicate that wares with a thin body excavated from the Xicun kiln site were produced in the Hutian kiln, and wares with a thick body were locally fired in Xicun; the contents of trace elements (V, Rb, Ba, Ta, Pb and Th) and the Nb/Ta ratio can be used to discriminate the products from the Xicun and Chaozhou kilns.     

Archaeometric Investigation of Medieval Pottery from Excavations at Novo Brdo,Serbia

Medieval pottery from excavations at Novo Brdo, Serbia, an important mining and trading centre during the 14th and 15th centuries, was investigated by a combination of optical microscopy, inductively coupled plasma – optical emission spectrometry, Fourier transform infrared, micro‐Raman and energy‐dispersive X‐ray fluorescence spectroscopy and X‐ray powder diffraction methods in order to determine its composition and firing temperature. The samples investigated were made of medium‐ to coarse‐grained, non‐calcareous clay, by a relatively well‐controlled firing procedure in an oxidizing atmosphere. The firing temperature was estimated to be 850–950°C. The similarity between the chemical composition of the investigated pottery and the local raw clay, combined with the outward appearance and the archaeological findings, indicate domestic production. The pottery is covered with the transparent lead‐rich glaze. Iron and copper were used as colourants.     

CHARACTERIZATION OF PLASTERS FROM PTOLEMAIC BATHS: NEW EXCAVATIONS NEAR THE KARNAK TEMPLE COMPLEX,UPPER EGYPT*

The aim of the present work is to characterize plasters from Ptolemaic baths recently discovered in front of the Karnak temple complex, by the excavations of an Egyptian–French team. The characterization was carried out by means of optical microscopy (OM), scanning electron microscopy (SEM) equipped with an energy‐dispersive X‐ray detector (EDS), X‐ray diffraction analysis (XRD) and Fourier transform infrared spectroscopy (FT–IR). The results allowed the identification of the chemical composition and structure of these plasters. In addition, samples of red, yellow, black and white pigments were examined and identified. The results helped in providing an image concerning some materials used during the Ptolemaic era in ancient Egypt.     

MINERALOGICAL INVESTIGATIONS OF MEDIEVAL BRICK SAMPLES FROM BÉKÉS COUNTY (SE HUNGARY)

Brick samples from nine archaeological sites representing seven contemporary medieval settlements in Békés County (SE Hungary) were analysed by quantitative X‐ray powder diffraction, optical microscopic, scanning electron microscopic and coupled thermal analytical – evolved gas analytical methods. The aims of this study were to give a mineralogical–petrographical characterization of the brick samples, to gain possible information on the raw clay and the admixed materials, and to determine the firing techniques applied in medieval southeastern Hungary. The mineralogical composition of the samples suggests that the locally extracted clay was mixed with fluvial sand and wheat (Triticum monococcum L.) chaff. The moulded bricks were fired in clamps. The different degrees of calcite consumption suggest that the firing temperature ranged from ～750°C to ～950°C. Moreover, the well‐developed reaction coronas on calcite grains indicate long firing times, lasting perhaps several days.     

CHARACTERIZATION OF LATE CHALCOLITHIC MICRO‐BEADS FROM ÇAMLIBEL TARLASI,NORTH‐CENTRAL ANATOLIA

Micro‐bead manufacture is geographically widespread from the fifth millennium bc . Previous studies of comparable micro‐beads from sites in the Indus Valley region and the Near East suggest that many of these beads were formed from synthetic enstatite. Characterization of micro‐beads from the Late Chalcolithic site of Çaml?bel Tarlas? was carried out by optical microscopy (OM), scanning electron microscopy (SEM) and microanalysis with energy‐dispersive X‐ray spectroscopy (EDS), and X‐ray diffraction analysis (XRD). The chemical composition of the micro‐beads analysed indicated that they were made from three distinctive materials; namely, bulk talc (i.e., synthetic enstatite precursor), apatite and mineral‐rich clay pastes.     

MINERO‐PETROGRAPHIC STUDY OF COOKING WARE AND POMPEIAN RED WARE (ROSSO POMPEIANO) FROM CUMA (SOUTHERN ITALY)

Excavations carried out in Cuma by the Centre Jean Bérard archaeologists have uncovered a large quantity of pottery. This study is focused on cooking ware and on internal red‐slip cookware, also known as Pompeian Red Ware (Rosso Pompeiano), dated from the first century bc to the first century ad . A comparison with the minero‐petrographic composition of beach sands collected along the Bay of Naples coastline highlights the provenance of the temper from the Somma‐Vesuvius area, marked by leucite‐bearing scoriae and garnet. Petrochemical analyses allow us to distinguish two main groups of pottery characterized by different technological options based on the amount of temper and on the type of clay. X‐ray diffraction and scanning electron microscope data demonstrate improved accuracy in the production of Rosso Pompeiano, especially with regard to firing control, which was in a prevailing oxidizing atmosphere and in a narrow thermal range, between about 800 and 900°C.     

PROVENANCE OF OBSIDIAN EXCAVATED FROM LATE CHALCOLITHIC LEVELS AT THE SITES OF TELL HAMOUKAR AND TELL BRAK,SYRIA*

X‐ray fluorescence and laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses conducted on 40 obsidian samples from the Late Chalcolithic 2 levels at Tell Hamoukar and Tell Brak in north‐east Syria have shown trends towards the exploitation of obsidian sources in the eastern Taurus. While the Bingöl region appears to provide the majority of obsidian to both sites, there is also evidence of more minor exploitation of a source in the Lake Van area and an altogether unknown source (X). This paper presents the data acquired from the analyses of the archaeological obsidian and situates these results within their chronological and regional contexts.     

ARAMAIC BASALT STATUES FROM TELL HALAF,SYRIA: LOCATING THE ANCIENT QUARRIES

Tell Halaf is the locality of the ancient Aramaic city of Guzāna (c. 1000–800 bc ) in Syria. The statues of Tell Halaf were made from monolithic basalt blocks, comprising massive as well as amygdaloidal types. However, the exact location of the original quarries was as yet unknown. Reconnaissance mapping and sampling concentrated on the four basaltic centres in the vicinity of Tell Halaf, covering both south‐eastern Turkey and north‐eastern Syria. In addition, basaltic artefacts from the two archaeological sites of Tell Beydar (c. 2700–2300 bc ) and Djebelet el Beda (c. 2600–2350 bc ) were investigated. All basalt samples were analysed for their bulk rock major and trace element compositions by X‐ray fluorescence, ICP–MS analysis and the mineral chemistry of individual minerals by combined electron microprobe analysis and laser‐ablation ICP–MS. The data show that basalt works of art from all three archaeological sites were derived from the Syrian basalt plateau of Ard esh‐Sheikh, approximately 57 km south of Tell Halaf. Accordingly, this basalt quarry was actively exploited over a considerable time span of c. 1900 years. This study demonstrates that petrographic and geochemical investigations of basalt, combined with electron microprobe and laser‐ablation ICP–MS analysis of minerals, are powerful tools to discriminate between possible sources of raw materials, especially if isotopic data yield unsatisfying results.     

A MULTI‐ANALYTICAL APPROACH FOR THE CHARACTERIZATION OF COMMODITIES IN A CERAMIC JAR FROM ANTINOE (EGYPT)*

This paper describes a multi‐analytical chemical study performed on the original, almost totally conserved, content of a small ceramic jar from the Antinoe archaeological site (fifth to seventh centuries ad, Roman Egypt) and now belonging to the archaeological collection of the Istituto Papirologico ‘Girolamo Vitelli’ (Florence, Italy). Scanning electron microscopy with an energy‐dispersive X‐ray spectrometer (SEM–EDX), Fourier transformed infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) were all used to characterize the inorganic components of the archaeological material. The organic substances were analysed using FTIR, direct exposure mass spectrometry (DE–MS) and gas chromatography – mass spectrometry (GC–MS). The inorganic component essentially consisted of halite (NaCl). Among the NaCl crystals, lamellar elements were identified. They were chemically characterized by carbonato‐apatite and showed a concentric morphology typical of the scales of small fish. The most prevalent organic constituents of the sample were monocarboxylic acids, α,ω‐dicarboxylic acids, and cholesterol and its oxidation products. The organic material composition was consistent with the occurrence of lipids of animal origin. In addition, diterpenes related to pine pitch were also identified. The overall results suggest that the material recovered in the small ceramic jar found in Antinoe is a residue of fish‐based pickles such as garum, muria, allex and liquamen, which were commonly used in Roman times.     

The Faragola Ceramic Collection: Ceramic Production,Consumption and Exchange in Seventh‐Century Apulia

A collection of 30 ceramic samples, 16 of coarse wares and 14 of fine painted wares, have been investigated by optical microscopy, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, inductively coupled plasma mass spectrometry and neutron activation analysis. Further samples of clayey sediments, both locally outcropping and found within the settling tank, have been submitted to the same analytical techniques for comparison with the ceramic collection. The results demonstrated that local clayey sediments were used as received for the production of coarse wares. The same raw materials were sieved and/or refined by decantation for the production of fine painted wares, which, in fact, provided results that were perfectly comparable with those for the clayey raw materials found within the settling tank. The Faragola productions were distinguished from the neighbouring Apulian productions according to petrographic features (the presence of leucite‐bearing volcanic rocks and Mn‐rich wads) and their bulk chemical composition.     

Savoury Recipes and the Colour of the Tlatelcomila Human Bones

Bones from Tlatelcomila (Tetelpan, México D.F.) were characterized by several complementary physical and chemical techniques, such as X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, atomic force microscopy, energy‐dispersive spectroscopy and ultraviolet spectroscopy, to determine whether they were boiled or grilled. The usual correlation between thermal treatment and colour is revisited in terms of microscopic structure, morphology and texture. At temperatures less than 100°C, it is shown that colour depends not only on temperature or diagenesis but also on the cooking procedure; that is, on the presence of spice dyestuffs such as axiote (Bixa orellana) or chilli (Capsicum).     

RESEARCH ON THE PIGMENTS FROM PAINTED CERAMICS EXCAVATED FROM THE YANGQIAOPAN TOMBS OF THE LATE HAN DYNASTY (48 BC – AD 25)

The analysis of pigments on painted ceramics excavated from the Yangqiaopan Tombs of the late Western Han Dynasty was undertaken using optical microscopy (OM), micro‐Raman spectroscopy (μ‐RS), scanning electron microscopy with energy‐dispersive X‐ray spectrometry (SEM–EDS), X‐ray diffraction (XRD) and Fourier‐transform infrared spectroscopy spectra (FTIR). The pigments were identified as red lead (Pb₃O₄), carbon (C), malachite [Cu₂CO₃(OH)₂], Chinese purple (BaCuSi₂O₆) and illite {[K,H₃O]Al₂Si₃AlO₁₀(OH)₂}. Fibrous materials were observed in some pigment samples. When observed by SEM, one showed a large amount of fibre in solidified gum, which indicated that gum of ramie could have been used as the binding medium to make the pigment particles adhere together. These results provide significant insights into the characteristics of these pigments in the Qin and Han Dynasties.