First results on thermally induced porosity in chlorite cooking vessels from Merv (Turkmenistan) and implications for the formation and preservation of archaeological lipid residues

Excavations at the ancient city of Merv in Turkmenistan have yielded a significant assemblage of ceramic and stone vessel fragments from contexts dating to the Sasanian and medieval periods (5th–13th centuries AD). Many of the vessel fragments are encrusted with apparent food residue deposits offering scope for organic residue analysis and the potential to compare the use of these two very different vessel types. To enable meaningful comparison we sought to establish whether the vessel stone (a talc-chlorite schist) can absorb and preserve organic residues indicative of past use. This paper reports the first investigation to address this question using standard methods for archaeological residue analysis coupled with study of the properties of the schist fabric and basic absorption experiments. The results demonstrate that heating during cooking, even at relatively low temperatures, modifies the stone microstructure by increasing its porosity. These pores enhance the absorption capacity of the schist fabric such that chlorite cooking pots can absorb and preserve sufficient organic residue to reflect the original processing of foodstuffs, as has been previously demonstrated for ceramic fabrics. Comparison of pore capacity, archaeological residue yield and experimental absorption indicates the significance of pore-size distribution for the relative retention and preservation of organic residues in these fabrics. The results of this study indicate that a wider range of archaeological material may be suitable for absorbed residue analysis than has previously been recognised. The findings also challenge previous assumptions concerning the relationship between the properties of chlorite vessels and their mode of use in Central Asia and Near East in antiquity.     

Estimating parent population of pottery vessels from a sample of fragments: a case study from inter-tidal surface collections,Roviana Lagoon,Solomon Islands

Archaeologists frequently interpret the duration and type of prehistoric occupation at a location/site from the relative abundance of prehistoric materials (accumulations research). Taphonomic factors have the potential to alter substantially the archaeological record leading to inaccurate assumptions about the nature of prehistoric settlement. Where vessel families of potsherds can be established, we provide a general method to estimate the parent population from which the sample of sherds derives, through analysis of vessel completeness of the sample. This provides a basis for archaeological interpretation of the scale of discard represented at a location. The approach used has broad applicability to many archaeological settings where behavioural inferences are made from poorly preserved ceramic samples. Statistical analysis of a ceramic assemblage from Roviana Lagoon stilt villages indicates that most of the ceramic assemblage has been destroyed over time. An unexpectedly severe taphonomic regime is inferred for this relatively sheltered landlocked lagoon setting. Rather than marking an ephemeral occupation, estimating a parent ceramic population indicates instead that early stilt village sites in the Solomon Islands region were probably permanently occupied for several centuries. Results also suggest that the relative absence of recorded Lapita sites in the main Solomon Islands, and possibly elsewhere in Near Oceania may be a result of a harsh taphonomic regime for the remains of stilt village occupation.     

Wine and olive oil permeation in pitched and non-pitched ceramics: relation with results from archaeological amphorae from Sagalassos,Turkey

Pitch compounds are frequently identified inside archaeological ceramic vessels. As their presence might affect the permeation of oil or wine into the ceramic fabric, experiments were conducted in which the diffusion of lipids or polyphenols into pitched and non-pitched modern vessels was followed by chemical analysis. Results show that the polyphenols of wine can intrude into the ceramics even through a pitch layer. Consequently, the absence of polyphenols in archaeological sherds is not due to their inability to reach the ceramic matrix under the pitch layer. By contrast, a pitch layer is quite effective to avoid oil intrusion into the ceramic matrix. Thus, it seems logical that oil amphorae would have been coated with pitch at the inside prior to use. Experiments in which the pitched ceramic was simultaneously exposed to oil and wine, show that the wine makes the pitch more permeable for the lipid compounds. These experimental data are confronted with residue analysis results obtained on amphorae fragments excavated in Sagalassos, Turkey. Pitch and oil were frequently found together. Based on a polyphenol test, indications for wine storage could only be obtained for two vessels. Against this background, the possible uses of the Sagalassos amphorae are discussed, and the traditional association of pine pitch with wine storage in archaeological amphorae is critically assessed.     

Ceramics and change: an overview of pottery production techniques in northern South Africa and eastern Zimbabwe during the first and second millennium AD

In southern African Iron Age studies, there are few attempts to systematically apply and include laboratory analyses when studying archaeological ceramic materials. As demonstrated in this paper, such analyses help to understand the technological aspects such as raw materials, manufacturing techniques and vessel function. Combined with vessel shape and decoration as well as ethnographic studies, the results provide new ways to understand local and regional distribution networks of the ceramics craft. Furthermore, laboratory analyses are most useful when studying continuity and changes in the ceramics handicraft over time, which has implications both on cultural and social change as seen in the shift in ceramic production techniques. We use examples from Zimbabwe and South Africa to illustrate these changes and discuss them in a broader social and technological context in Iron Age southern Africa.     

Prehistoric animal use on the Great Hungarian Plain: A synthesis of isotope and residue analyses from the Neolithic and Copper Age

The archaeological record of Eastern Hungary indicates that settlement patterns, subsistence strategies, ceramic style, trade patterns and mortuary customs changed from the Late Neolithic to the Copper Age (5000–2700 cal BC). Despite a rich archaeological tradition, questions remain regarding the management and use of domesticated animals and the role animal husbandry played in social change during this transition. Some researchers have hypothesized that these changes reflect a shift towards an economy that intensified its focus on primary and perhaps secondary animal products. Here we synthesize isotope data from human and animal remains and residue analysis from pottery sherds from Neolithic and Copper Age assemblages. Results indicate that the consumption and use of animal protein and fat was relatively high for both periods, with an increase in animal fats in ceramic vessels during the Middle Copper Age; however, milk products do not appear to have played an important dietary role. We conclude that livestock management remained small-scale during the Neolithic and Copper Age and that dairy use was minimal. It is proposed that the cultural changes that occurred at this time were associated with the emergence of smaller, independent farmsteads and perhaps the innovative use of secondary products like manure.     

Toward an understanding of the exchange in ancient scented oils through organic residue analysis of Bronze Age Near Eastern ceramic bottles by GC-MS

This paper presents a gas chromatography-mass spectrometry (GC-MS) organic residue analysis (ORA) of samples extracted from five Early Bronze Age ceramic bottles excavated at the archaeological site of Küllüoba in Anatolia (modern Turkey), and the first attempt at directly analysing the content of this category of products. Our results show that various types of liquid have been contained in different bottles and identify the presence of dicarboxylic and oleic acids with a large amount of palmitic acid in most samples, suggesting that they may have mostly contained a plant-based oil. The presence of diterpenoids further shows the addition of ingredients such as conifer resin and other plant-derived products. Overall, the analytical results presented here indicate the exchange of scented oils in Anatolia already during the late third millennium BCE. The different organic residue profiles contained in different samples also suggest a range of different recipes for these products.     

QUANTIFICATION AND DISTRIBUTION OF LIPID IN ARCHAEOLOGICAL CERAMICS: IMPLICATIONS FOR SAMPLING POTSHERDS FOR ORGANIC RESIDUE ANALYSIS AND THE CLASSIFICATION OF VESSEL USE

Organic residue analysis has been performed on 62 reconstructed vessels from a single archaeological site (Rounds, Northamptonshire, U.K.). In order to establish regions of lipid accumulation within a vessel, sherds were sampled from different parts of a vessel, for example base, body and rim, and submitted to lipid extraction procedures. The techniques of high-temperature gas chromatography (GC) and GC/mass spectrometry (GC/MS) were then used to analyse the sherd lipid extracts. The quantitative results obtained show differential accumulation and preservation of lipid in various parts of the same vessel. This latter observation has serious implications for the sampling of potsherds for organic residue analysis. Furthermore, the amount of absorbed lipid varies quite considerably between vessel types. On this basis, a new method is proposed for classifying vessel use by comparing the concentration of lipid present in different parts of individual vessels.     

The Social and Economic Complexity of Ancient Jerusalem as Seen Through Choices in Lighting Oils

This paper presents and discusses the results of residue analysis conducted on 78 ceramic lamps found in archaeological excavations in ancient Jerusalem, in an attempt to identify the types of oils used and the reasons for their preferential choice. The oil lamps chosen for the study were taken from a variety of contexts, which represent the different periods during which Jerusalem was settled and the different sectors of the city. The results of the study show that even the most mundane activity of lighting using oil held within it social and economic choices, as mirrored in the different excavation areas.     

Identification of the Residue in the Bolgar Medieval Sphero‐Conical Vessel by Gas Chromatography – Mass Spectrometry

The Golden Horde sphero‐conical vessel retrieved from the ruins of the medieval city of Bolgar (Russia, Republic of Tatarstan) during archaeological excavations, which contained residue in the form of encrustation on the bottom and the wall, was analysed in the NRC ‘Kurchatov Institute’ by X‐ray phase analysis and high‐performance liquid and gas chromatography with MS detectors (HPLC–MS, GC–MS). The GC–MS method established that the residue from the sphero‐conical vessel was comprised primarily of abietic acid derivatives (around 46%) and retene, which is polycyclic aromatic hydrocarbon (around 27%); this means that turpentine exuded from the stems of certain species of coniferous trees, called resin and subsequently heat‐treated, was poured into the vessel. Researchers have been trying to decipher the function of these mysterious vessels for 200 years, and this is the first time that resin stored in a sphero‐conical vessel has been documented. Potentially, this vessel was probably used as a personal ‘medical kit’.     

Differentiation of ceramic chemical element composition and vessel morphology at a pottery production center in Roman Galilee

Cooking pots and bowls from two production locations ca. 200 m from each other at the rural settlement of Kefar Hananya in Roman Galilee were compared employing chemical element composition and vessel-shape analyses. Splits of each pulverized sample, all of which were taken from ceramic wasters, were analyzed by both instrumental neutron activation and high-precision X-ray fluorescence analyses, and computerized vessel-shape analysis was employed for morphological analysis of the same vessel forms from each location. Several statistical techniques (bivariate plots, principal component analysis, cluster analysis and discriminant analysis) were used for analyzing the resultant data. It was found that both the cooking pots and bowls made at each location could be distinguished by employing either chemical composition or morphological analysis. The implications of this work, with regard to investigating both production and consumption sites, and for pottery provenance studies, are discussed. The findings suggest that these analytical techniques can be useful as an aid for chronological differentiations of archaeological pottery.     

Plainware ceramics from Sāmoa: Insights into ceramic chronology,cultural transmission,and selection among colonizing populations

The first people in Sāmoa produced a varied ceramic archaeological record including a single deposit with decorated Lapita ceramics on the island of ‘Upolu in the west of the archipelago and a nearly contemporaneous plainware deposit over 250 km to the east on Ofu Island. Post-Lapita ceramic change across Sāmoa is similar with almost no decoration, local ceramic production, limited vessel form diversity, and changing frequencies of thin- and thick-wares. This Sāmoan ceramic record is different from nearby Tonga and Fiji where early decorated Lapita ceramics are widely distributed, there are no thickness-defined ware types, and for Fiji, post-Lapita ceramics are more variable. Here we investigate the apparent uniqueness of the Sāmoan ceramic record through an analysis of early plainware ceramics, the second oldest after the Ofu deposits, from Tutuila Island in the center of the Sāmoan archipelago. Our assemblage-specific findings are similar to other Sāmoan plainware analyses, but we suggest the ceramic and other archaeological evidence from Sāmoa and the region indicates Sāmoa was colonized by a few isolated groups and that within the context of cultural transmission of ceramic variants, selection explains thickness variation and likely other aspects of Sāmoan ceramic change.     

Preservation of fungi in archaeological charcoal

During the analysis of wood charcoal remains from archaeological sites, it is common to find different microorganisms and different forms of degradation present in the plant tissue. However, one may encounter difficulties when attempting to identify these microorganisms and determine when their attack occurred. This paper focuses on preservation aspects related to the microorganisms in wood and demonstrates the structural changes that take place in different types of decayed wood after it was converted into charcoal. The study seeks to determine whether the microbial attack found in archaeological woods took place before the burning of the wood or after. Burning experiments were conducted using wood that had been decayed by various types of fungi including white-rot, brown-rot, and soft-rot. The laboratory burnt wood samples showed decay patterns that were comparable to those observed in archaeological charcoal samples, indicating that signs of fungal infestation and features of decay can be preserved after burning with micromorphological details of mycelium and cell wall attack evident. This indication may provide important information related to the gathering of deadwood as fuelwood. In addition, examples of decayed wood preserved in archaeological charcoal assemblages are described. Their relationship to the archaeological context and environmental conditions may suggest different interpretative models concerning wood management strategies applied by past societies.     

The Pottery Informatics Query Database: A New Method for Mathematic and Quantitative Analyses of Large Regional Ceramic Datasets

There is an increasing demand within the humanities and social sciences to use computers to analyze material culture and discover patterns of historical and anthropological significance. Using southern Levantine Iron Age (ca. 1200–500 BCE) ceramics as a test case, the Pottery Informatics Query Database (PIQD) provides a novel solution for constructing regional ceramic typologies. Beyond digitally archiving 2D/3D-scanned ceramics, the PIQD encodes ceramic profiles as mathematical representations. This method of digital preservation enables rapid queries to be conducted in a mathematically grounded approach. In this sense, the queries are similar to online Basic Local Alignment Search Tool searches developed in the field of genetics by rapidly associating large quantities of digital vessel profiles to each other based on similar morphological traits. The PIQD is an open-source online tool that enables scholars and students to test humanities-related hypotheses against ceramic data in ways that conventional publications or other databases cannot provide. Regional spatial patterning of the ceramic data is delivered over a Google Earth-based user interface. In this paper, we present the PIQD as an objective method for developing a comprehensive ceramic typology of an entire region of archaeological study and provide an arena to conduct novel scientific research. We then demonstrate through a case study its analytical capabilities to handle large datasets of 3D scans and digitized 2D ceramic profiles and generate cultural inferences with the ceramic assemblages of the Iron Age II “Edomite” region located in modern southern Jordan. PIQD adds an important methodological tool to the post-excavation cyber-archaeology tool box.     

Characterization of a black residue in a decorated Neolithic pot from Dikili Tash,Greece:an unexpected result

A black depositional layer on the inner surface of a Neolithic carinated vessel from the archaeological site of Dikili Tash in Eastern Macedonia was examined scientifically. The layer was initially considered as decomposed organic matter and interest was focused on identifying the original organic contents. The scientific investigation, which included FTIR spectroscopy, analytical SEM examination and optical microscopy, revealed that the black substance was not organic but a pure iron oxide layer deposited on the vessel’s inner surface, and reduced in places to black iron oxides, during a destructive fire. The conclusion is that this layer represents the remnants of the vessel’s original content, which was a red hematite pigment. This unexpected find provides, for the first time, a missing link in the evidence of pigments used in Neolithic times, previously attested to only by finished products.     

GEOCHEMICAL ANALYSIS AND SOCIOCULTURAL COMPLEXITY: A CASE STUDY FROM EARLY IRON AGE MEGIDDO (ISRAEL)*

Few archaeological sites can claim a more celebrated position than Megiddo, the Armageddon of biblical revelation. Guardian to a strategic pass on the ancient land bridge that traverses the region, it has long been known that Megiddo played a prominent role in the emergence of the Iron Age nation‐states of biblical fame. Given its pivotal location, Megiddo provides an ideal opportunity to examine the experience of a community that found itself at the centre of these developments. The archaeological and textual evidence indicates a community that enjoyed extensive contact with an array of culturally distinct sociopolitical groups emerging in its hinterland. To further explore the nature and extent of this interaction, an assemblage of 86 ceramic sherds was analysed by instrumental neutron activation analysis (INAA). This paper presents the results of this analysis, together with an evaluation of potential geochemical and archaeological interconnections. Based on this comparative analysis, implications are drawn regarding Megiddo's role in the changing cultural and political landscape of this formative period in the history of the region.     

Forming and Shaping Pottery Boundaries in Contemporary South-Eastern Botswana

In southern African archaeology, the equation of pottery styles with archaeological ‘cultures’ and their attribution to the antecedents of contemporary ethnic groups has been a common practice for a long time. Ethnoarchaeological studies from other parts of Africa and beyond have shown that the matter is complex and that stylistic and technological boundaries in ceramic distributions can reflect different kinds of social boundaries under different circumstances. To expand on these findings and make them locally relevant, a large-scale ethnoarchaeological study of 41 potters in south-eastern Botswana aims for a better understanding of ceramic technological style and boundary relations. Here, we present and explain only the results concerning the boundaries in the forming and shaping stage of ceramic vessel manufacture. We conclude that learning networks explain the visible boundaries in the technological style of forming and shaping pots in south-eastern Botswana today; language and ethnic affiliation do not. Boundaries in the other stages in the operational sequence of pottery manufacture, such as clay sourcing and preparation, vessel surface treatment and decoration, firing and finishing, will be presented in a series of further publications.     

Chemical and Petrographic Analysis of Pre‐Hispanic Pottery from the Southern Abaucán Valley,Catamarca, Argentina

Neutron activation (NAA) and petrographic analyses were carried out on Late and Inca Period pottery from 15 archaeological sites and several clay samples in the southern Abaucán Valley, Catamarca, Argentina. The results from the NAA and petrographic analyses provide new data concerning local versus non‐local pottery production and vessel exchange for these two pre‐Hispanic cultural periods. The chemical data demonstrate the use of different clay sources over time until the Inca appearance in the region, when a more structured and controlled production is observed. Petrographic analyses show a similar change in the ceramic paste recipes used by ancient potters.     

Organic residue analysis of Iron Age ceramics from the archaeological site of Kani-zirin,western Iran

Organic residue analysis of potshards excavated from the Iron Age archaeological site of Kani-zirin, western Iran, was achieved with acidified methanol extraction and gas chromatography-mass spectrometry (GC-MS). The GC-MS data showed plant and animal commodities incorporated in the shards. Also, the investigations confirmed the presence of plant resin together with a tartrate ion within a group of the shards, suggesting a probable use of grape-related products. Evidence of resins from the Pinaceae family, as an exotic species in Iran, was evinced in several of the shards.     

Teotihuacan pottery as evidence for subsistence practices involving maguey sap

As in most other pre-industrial cities, urban life at Teotihuacan was closely intertwined with ceramic technology, perhaps nowhere more so than in the realm of foodways. Here, we use two kinds of information derived from ancient pottery—ceramic residues and intra-site sherd distribution patterns—to shed new light on the city’s subsistence economy. We concentrate in particular on the amphora, a type of vessel that may have been used to contain aguamiel and pulque, liquid foodstuffs made of maguey sap. Distributional data distilled from surface collections of the Teotihuacan Mapping Project are informative about patterned variation in the use of these pots at the scale of the entire city. More focused analyses are aimed at chemical characterization of organic residues preserved in ceramic sherds recovered from recent excavations. Part of a broader project aimed at identifying both animal and plant remains, the results of the residue analysis provide the first direct identification of pulque remains in Teotihuacan pottery.     

Cross-cultural interaction on Wuvulu Island,Papua New Guinea: the perspective from use-wear and residue analyses of turtle bone artifacts

Recent studies have emphasized the importance of Indigenous producers and traders in the formation of ethnographic museum collections, but have found difficulty in finding concrete evidence for their active roles. A use-wear and residue study of turtle bone cleavers from Wuvulu Island, Papua New Guinea provides the opportunity to test whether objects that comprise a significant component of early collections were made specifically for sale, as hypothesized by contemporary observers in the late 19th century. Comparative studies of used and unused turtle bone artifacts from the Caroline Islands and Papua New Guinea identified differences between wear traces resulting from manufacture and use. Analyses of the Wuvulu turtle bone cleavers showed they had been heavily used prior to sale. Rather than produce artifacts to meet the high demand from German traders, the local people sold old, worn-out objects, many of which had been repaired. The study demonstrates that archaeological approaches to ethnographic museum collections can trace Indigenous agency within cross-cultural interaction. It also showcases the potential of use-wear and residue analytical techniques for the analysis of bone tools and the utility of digital, hand-held microscopes for the analysis of large artifacts.