A NEW DATING METHOD FOR HIGH‐CALCIUM ARCHAEOLOGICAL GLASSES BASED UPON SURFACE‐WATER DIFFUSION: PRELIMINARY CALIBRATIONS AND PROCEDURES*

The first European settlers came to North America in the early 17th century using glass in the form of containers and decorative objects. Thus, glass is a horizon marker for all historic period settlements and a potential source of chronometric dates at archaeological sites belonging to the historic period in the Americas. We have developed a new absolute dating method based upon water diffusion into the surface of manufactured glasses that predicts diffusion coefficients based upon variation in glass chemical constituents. Low‐temperature (< 190°C) hydration experiments have been performed on a set of five high‐calcium (21.7–28.3%) glasses that were used to manufacture wine bottles from the 17th?19th centuries. Infrared spectroscopy and secondary ion mass spectrometry was used to model the water diffusion/alkali exchange process. The ability of the model to accurately predict archaeological ages was evaluated with artefacts recovered from ceramic‐dated contexts at Thomas Jefferson's plantation known as Monticello.     

THERMAL ALTERATIONS IN ARCHAEOLOGICAL BONES*

Archaeological bones, found close to Mexico City (Tlatelcomila), with alterations due to probable thermal exposure attributed to a possible case of cannibalism, have been characterized by XRD, SAXS and SEM. It is shown how these non‐destructive techniques, which are not conventionally used in archaeological research, may provide useful information. The deterioration degree of the bone structure is quantified through parameters such as gyration radius or fractal dimension. As some of the reported modifications could be attributed to diagenesis, a discussion is presented in terms of bone crystallinity and ionic exchange. Furthermore, the hydroxyapatite crystallite size increased depending on colour: this feature is not explained by diagenesis—it can only be attributed to temperature. We conclude that the samples were thermally treated. Indeed, thermal treatment alters the structure and morphology of bone at a very fine level (microscopic and nanometric), while morphology follows the structural modifications. It is determined that the studied human bones were treated at three different temperatures close to 100, 250 and 600°C. Therefore, they were either boiled (barbacoa) or grilled.     

A NOTE ON THE DIFFERENTIAL THERMAL ANALYSIS OF ARCHAEOLOGICAL CERAMICS

Evidence is presented that the clay in ancient ware fired at a temperature below 700–800°C becomes rehydrated over the millennia, such that it behaves somewhat like an unfired clay, rendering DTA a useful tool in identifying the clay minerals present. More recent samples can be artificially rehydrated by heating in a steam autoclave.     

A NEW METHOD FOR EXTRACTION,ISOLATION AND TRANSESTERIFICATION OF FREE FATTY ACIDS FROM ARCHAEOLOGICAL POTTERY

This paper presents evidence for increased recovery of organic residues from archaeological pottery through use of a microwave‐assisted liquid chromatography protocol. C_16:0 and C_18:0 saturated fatty acids were obtained from archaeological potsherds recovered from nine Neolithic settlements in the Middle East dating between 4700 and 7300 cal bc , including materials that had not produced evidence for the survival of any lipid species through use of ‘conventional’ solvent extraction techniques. Compound‐specific isotopic analyses of C_16:0 and C_18:0 fatty acids in potsherd extracts subsequently revealed δ¹³C/δ¹²C compositions consistent with modern subcutaneous fats of wild boar and goats pastured on lands adjacent to the Jordan Valley, and residues from a modern pottery vessel used in the manufacturing of butter, cheese and yogurt in central Turkey. These results are presented as an illustration of capabilities of the microwave‐assisted recovery protocol. The reclamation of saturated and unsaturated fatty acids from archaeological pottery fragments recovered from a number of the earliest ceramic horizons in the Middle East is herewith reported, and the extraction methods and instrumental analytical techniques are described.     

GEOPHYSICAL AND ARCHAEOLOGICAL INVESTIGATIONS AT THE CLEMENT SITE,A CADDO MOUND COMPLEX IN SOUTHEASTERN OKLAHOMA

Abstract

Since the 1960s, few professional archaeological excavations have been conducted at Caddo sites in southeastern Oklahoma. This article summarizes the initial phase of a research program designed to increase our knowledge of this area. Geophysical and archaeological investigations at the Clement site (34Mc8) were conducted during the summer of 2008 by the University of Oklahoma. These revealed deep middens, intact mound stratigraphy, and architecture, and suggest that Clement had multiple Caddo occupations spanning approximately 300 years.     

OPTICAL DATING RESULTS FOR BRITISH ARCHAEOLOGICAL SEDIMENTS

In this paper optical dating results for a range of British archaeological sediments are presented to illustrate the potential this method offers for archaeologists. The optical dating is shown to offer an absolute method for directly dating the deposition of sediments for an age range of approximately 1–300ka. Problems have been found with recuperation of the optically stimulated luminescence signal and insufficient bleaching at deposition of the sediment. A suitable correction method for the recuperation has been found and a method of identifying insufficient bleaching is suggested.     

ARTIFICIAL NEURAL NETWORKS AS A TOOL FOR ARCHAEOLOGICAL DATA ANALYSIS*

Artificial neural networks (ANN) offer a supplement to traditional classification algorithms applied to archaeological data. Because of their flexible architecture, non-linearity and independence from the distribution of the underlying data, neural networks have unique advantages for such applications. In particular, ANN models are well suited for use with the sparse data sets common in archaeological work. Combining multivariate techniques with networks for data validation, pre-processing and classification exploits the merits of both and provides a comprehensive approach to the analysis and classification of archaeological data.     

A HYBRID APPROACH TO CREATE AN ARCHAEOLOGICAL VISUALIZATION SYSTEM FOR A PALAEOLITHIC CAVE

This paper presents a visualization system based on metric data to manage and disseminate archaeological information on the Internet. We describe the integration of two different types of sensors: laser scanning and close‐range photogrammetry. How we created an automatic and hierarchical approach based on processing and matching the images coming from a digital camera and a terrestrial laser scanner is also shown. This development has created a visualization system combining spherical photographs and georeferences for graphical and numerical data acquired by the sensors. The case study where we have applied this method is the Palaeolithic rock art of the Llonín Cave (Asturias, Spain), which has been declared a World Heritage Site by UNESCO and has restricted public access. Our results demonstrate that this tool integrates data, metadata, services and information, which simplifies the location, identification, selection and management of archaeological information.     

FIXED‐FREQUENCY RADIO‐WAVE IMAGING OF SUBSURFACE ARCHAEOLOGICAL FEATURES: A MINIMALLY INVASIVE TECHNIQUE FOR STUDYING ARCHAEOLOGICAL SITES*

In memoriam Tony Clark Sadly, this research marked the last field visit to the test site that the authors were able to share with their colleague Tony Clark. His enthusiasm, experience and encouragement inspired us to complete this project that, to many, must have appeared as grown men at play in a sand pit. A new approach to subsurface exploration has been developed, based on fixed‐frequency radio‐wave illumination from a buried transmitter. Data are collected from a buried, continuous wave source with a phase‐coherent surface‐scanning receiver and recorded in a digital archive from which images of the archaeological features are subsequently produced. An important feature of this approach is the opportunity to separate the data collection and archive functions, which form an uncompromised record of the site, from the more subjective image formation function. This paper reports the results of a feasibility assessment programme and discusses the future application of the method to real archaeological sites.