New Insights into the Provenance of the Obsidian Fragments of the Island of Ustica (Palermo,Sicily)

In this study we applied a multidisciplinary approach, coupling geophysical and geochemical measurements, to unveil the provenance of 170 obsidian flakes, collected on the volcanic island of Ustica (Sicily). On this island there are some prehistoric settlements dated from the Neolithic to the Middle Bronze Age. Despite not having geological outcrops of obsidian rocks, the countryside of Ustica is rich in fragments of this volcanic glass, imported from other source areas. The study of obsidian findings was carried out first through visual observations and density measurements. At least two different obsidian families have been distinguished, probably imported from Lipari and Pantelleria islands. Analysing the magnetic properties of the samples, these two main sources were confirmed, but the possibility of other provenances was inferred. Finally, we characterized the geochemical signature of the Ustica obsidians by performing microchemical analyses through electron microprobe (EMPA) and laser ablation (LA–ICP–MS). The results were compared with literature data, confirming the presence of the Lipari and Pantelleria sources (Sicily) and indicating for the first time in this part of Italy a third provenance from Palmarola island (Latium). Our results shed new light on the commercial exchanges in the peri‐Tyrrhenian area during the prehistoric age.     

Mediterranean trade of the most widespread Roman volcanic millstones from Italy and petrochemical markers of their raw materials

The petrochemical study of millstones can contribute to improve the archaeological research into reconstruction of ancient communication routes and trade networks. Volcanic rocks are geographically restricted and rather rare in the Mediterranean regions, and during the Roman period Italian volcanoes were important sources of raw materials for millstones, so the task of determining their geological origin is relatively straightforward. The Italian vesicular volcanics most frequently employed for this purpose were: trachytes from Euganean Hills (Veneto), leucite-bearing lavas from the Vulsini Volcanic District (Latium), basic-intermediate leucite-bearing lavas from Somma-Vesuvius (Campania), silica undersaturated lavas from Monte Vulture Volcano (Basilicata), a rhyolitic ignimbrite from Sardinia and basic products from Mount Etna and the island of Pantelleria (Sicily). This paper contains a general outline of the trade network for each volcanic typology used for millstones during the Roman period – updated with data concerning the leucite-bearing lavic items discovered in the archaeological sites of the ancient Cuicul (now Djemila, Algeria) – together with a summary of their petrographic and geochemical features.     

Possible obsidian sources for artifacts from Timor: narrowing the options using chemical data

Measurements made at the Australian National University using laser ablation ICPMS show that none of the 88 analyzed obsidian artifacts from East Timor match either the known Papua New Guinea or the five Island SE Asian source samples in our ANU collections. There is a coastal journey of more than 3000 km between the occurrence of obsidians from the Bismarck Archipelago volcanic province of Papua New Guinea and the Sunda-Banda Arc volcanic chain, yet obsidian artifacts from the two important PNG sources of Talasea and Lou Island are found at coastal Bukit Tengkorak in eastern Sabah at a similar distance along with material that has no known source. Timor lies south of the eastern section of the active volcanic Banda Arc island chain but it is within range of possible rhyolite sources from there. Although there is a continuous chain of around 60 active volcanoes stretching from west Sumatra to the Moluccas most are basaltic to andesitic with few areas likely to produce high silica dacite–rhyolite deposits. This does not exclude the possibility that the volcanic landscapes may contain obsidian, but without detailed survey and chemical analysis of sources from the Sunda-Banda Arc the attribution of the Timor obsidian artifacts remains to be demonstrated. Timor may seem to be an unlikely source for the presence of obsidians as it lacks reports of the silica-rich rhyolite volcanic centers necessary to produce this material. Despite the absence of detailed survey and analysis of Indonesian obsidian sources, especially from the volcanically active Banda Arc, this paper presents evidence that one of two obsidian sources is clearly from Timor while the other, with less certainty, is also from an unknown local source.     

Provenancing the rhyolitic and dacitic components of the Stonehenge landscape bluestone lithology: new petrographical and geochemical evidence

The source of the bluestone component found in the Stonehenge landscape has long been the subject of great interest and considerable debate. The bluestones are a mix of lithologies, the standing orthostats being predominantly dolerites, variably ‘spotted’, with only four of them being of dacitic and rhyolitic composition and the Altar Stone being sandstone. However in the 1920s the spotted dolerites were sourced to outcrops which comprise tors in the summit regions of the Mynydd Preseli in north Pembrokeshire, west Wales. There were also speculations about the possible sources of the dacitic and rhyolitic components, ideas which were elaborated on in the early 1990s when the original petrological provenancing was supplemented by whole-rock geochemical analysis. Most recently, new petrographical investigations have been combined with zircon geochemical data to determine the possible source of one type of rhyolite, the so-called ‘rhyolite with fabric’, found abundantly as débitage in the Stonehenge landscape (but not composing the four orthostats) to outcrops in the vicinity of Pont Saeson, especially a large craggy outcrop called Craig Rhos-y-felin, located in low ground to the north of the Mynydd Preseli. In order to test this provenance whole-rock geochemical analysis has been undertaken on samples of débitage from the Stonehenge landscape and from the Pont Saeson area, including Craig Rhos-y-felin. These data are then compared with other new and existing geochemical data for dacitic and rhyolitic lithologies recovered from the Stonehenge landscape, including the four orthostats, as well as geochemical data from outcrops of the same lithologies from the two main volcanic horizons exposed across north Pembrokeshire, namely the Fishguard Volcanic Group and the Sealyham Volcanic Formation, both of Ordovician age. This study concludes that previous, 20th century, attributions of provenance to a number of dacitic and rhyolitic outcrops in the north Pembrokeshire have been in error whilst the new data for the Pont Saeson rhyolite accords well with elemental contents recorded in the ‘rhyolite with fabric’ lithology from the Stonehenge landscape débitage. This study therefore endorses the proposal that the Pont Saeson area is indeed the source of the ‘rhyolite with fabric’ lithology recovered from numerous sites in the Stonehenge landscape, and is the only reliable provenance for any of the dacitic and rhyolitic bluestone material collected to date. It also serves to endorse the use of zircon chemistry as a provenancing tool in archaeopetrological investigations.     

ARCHAEOMETRIC STUDY OF PROTOHISTORIC GRINDING TOOLS OF VOLCANIC ROCKS FOUND IN THE KARST (ITALY–SLOVENIA) AND ISTRIA (CROATIA)*

This paper presents the results of the archaeometric study of 30 grinding tools found in the Karst plateau (an area that spreads from the northeastern border of Italy to Slovenia) and in the Istria peninsula (Croatia). The petrographic and geochemical characteristics of the artefacts indicate that most of them would be made of trachytic volcanites extracted from the Euganean Hills, near Padua (Veneto). It is known that trachytic rocks from this area had been widely exploited in northern Italy during protohistoric times, but these data considerably enlarge the area of diffusion of saddle‐querns made of these rocks, extending it to Istria. Additionally, the likely provenance from Mount Etna of few other pieces of mugearites and hawaiites represents a new element, to be fully evaluated in the context of trans‐Adriatic exchange/trade connections. Analytical data and possible archaeological inferences are presented in detail in the text.     

CHARACTERIZATION OF THE AMPHORAE,STONE BALLAST AND STOWAGE MATERIALS OF THE SHIPS FROM THE ARCHAEOLOGICAL SITE OF PISA–SAN ROSSORE,ITALY: INFERENCES ON THEIR PROVENANCE AND POSSIBLE TRADING ROUTES*

In December 1998, during excavation for the construction of a new building near San Rossore railway station in Pisa, the remains of ancient ships were discovered. These findings have been dated (radiocarbon) to between the end of the 10th century bc and the fifth century ad ( Belluomini et al. 2002 ). Several transport amphorae belonging to the Hellenistic ship, samples of rocks (stone ballast) belonging to ships B, D and the Hellenistic ship, and stowage materials belonging only to ship B have been analysed. The mineralogical and petrographic data of the investigated samples provided information on the possible provenance of the raw materials utilized in the manufacture of the ceramic amphorae, as well as on the provenance of the rock materials found in the ships as ballast and stowage. The compositional data (obtained through XRD, XRF, OM and EPMA) and their statistical analyses suggest that the provenance of the Dressel amphorae belonging to the Hellenistic ship was the Middle Tyrrhenian coast of Italy, and more precisely the area between Tarquinia and Naples, according to the numerous kilns and wine production sites found in this area. The provenance of the volcanic rocks was from southern Tuscany, northern Latium and possibly the Pontine Islands, whereas the intrusive rock possibly comes from the Calabrian–Tyrrhenian coast and/or the Peloritani area. The impure limestones and the dolostone come from southern Tuscany and the Latium coast; the semi‐metamorphic rocks could come from the coast of southern Tuscany, the Tuscan Archipelago or possibly also from the Ligurian coast; only the sample of mylonitized granitoid possibly comes from either the Calabria–Peloritani arc or the Tuscan Archipelago. The stowage materials, consisting of lapilli and scoria of a pyroclastic nature, are sourced from the Neapolitan area. These data might shed some light on the centres of production of the amphorae and of the trading routes followed by the ships, according to the ports of call.     

BLACK AND RED GRANITES IN THE EGYPTIAN ANTIQUITY MUSEUM OF TURIN: A MINERO‐PETROGRAPHIC AND PROVENANCE STUDY

A recent project to investigate the stone artefacts preserved in the Egyptian Antiquity Museum of Turin has been undertaken, with the aim of supplying their systematic classification and suggesting the provenance site of the original raw materials. This paper focuses on seven sculptures dating back to the New Kingdom (18th–19th Dynasties): the statue of Ramses II, three of the 21 sculptures of the goddess Sekhmet, the statue of the goddess Hathor, the Ram‐headed Sphinx and the sarcophagus lid of Nefertari. Petrographic observations have shown that all the sculptures are made of granitoid rocks, with variable composition from granite to granodiorite and tonalite. The observation of strong macroscopic analogies with the so‐called black and red granites outcropping in the Aswan area has suggested a common origin of all the raw materials used for their manufacture. In order to verify this provenance hypothesis, several samples were collected in the Aswan quarry districts. According to results of a minero‐petrographic and geochemical comparison between the statues and the Aswan quarry samples, it was possible to identify the source area of the stone sculptures and finally to highlight the importance of an archaeometric approach to the solution of archaeological problems.     

Roman Millstones from Orvieto (Italy): Petrographic and Geochemical Data for A New Archaeometric Contribution

The probable site of extraction and production of Pompeian‐style leucite‐bearing millstones, singled out by Peacock (1980, 1986) in the vicinity of Orvieto, and the outcropping of the ‘Leucitophyre’ lava have been systematically studied employing standard petrographic and geochemical methods (optical microscopy and ICP–AES/MS spectrometry). The combination of petrochemical data, previously very poor, allowed us definitively to exclude the possible ‘overlap’ of phonolitic and tephri‐phonolitic lavas from other Quaternary Volcanic Districts of Latium, and provides a helpful tool for future work on leucitite millstones. Consequently, the databank obtained has been used to attribute the origin of five Roman millstones discovered in three archaeological sites in central Italy (Latium and Marche). It has also been useful to verify the geological provenance of some Sicilian and French leucitite millstones analysed by previous workers. The results point to a provenance from the Orvieto area, with the exception of the millstones from Sicily, for which a different origin was hypothesized.     

Geochemical discrimination of basaltic sources as a tool for provenance analyses of bifacial tools in the southern Levant: first results from the Jezreel Valley,Israel

The determination of groundstone tool sources bears the potential to examine aspects like raw material selection and preference, mobility, trade and exchange patterns, control over resources and long term use of raw material sources. The discovery of the Neolithic/Chalcolithic basanite bifacial quarry of Giv'at Kipod in the Jezreel Valley, Israel, provides the opportunity of raw material centred provenance studies of bifacials in the southern Levant. The basis for reliable provenance analyses is a clear geochemical characterization of the extraction site and its discrimination from other potential sources. To achieve this, the Miocene magmatic rocks of the Jezreel Valley were sampled and analysed by XRF and La-ICP-MS. The geochemical evaluation, combined with cluster analyses, resulted in a clear discrimination of the Giv'at Kipod lava from other basaltic sources in the area. Based on the geochemical field data, a Giv'at Kipod provenance for six bifacial tools found in three archaeological sites dated to the Neolithic and the Chalcolithic periods was established. The results suggest that the quarry was in use for several millennia. This pilot study demonstrates that for provenance analyses lava outcrops in the southern Levant can be geochemically discriminated from each other on a very small spatial scale, on the basis of a detailed field sampling and the application of multivariate methods.     

Archaeometric evidences of the 4th–2nd century BC amphorae productions in north eastern Sicily

This work focuses on the petro-archaeometric analysis of several transport amphorae dated back from 4th to 2nd century BC which were found in various archaeological excavations recently carried out in Messina and Milazzo (north eastern Sicily). These amphorae, generally known as Graeco-Italic, raise the problem of the identification of their production areas. Petrographic analyses proved the presence of two groups characterised by the presence of coarse metamorphic or volcanic inclusions and one group with finer metamorphic inclusions. Multivariate statistical analyses made it possible to detect the production area of the amphorae with metamorphic inclusion in north eastern Sicily, comparing them with locally produced bricks and clay sediments cropping out near the ancient cities. On the contrary, the studied amphorae rich in volcanic inclusions have petrographic and chemical features which can be attributed to production areas in the Campanian region.     

Archaeometric Study of Volcanic Lithic Objects from The Longola (Poggiomarino) Protohistoric Site,Southern Italy: Regional Versus Extra‐Regional Provenance

The Longola protohistoric village (spanning from the late Middle Bronze Age to the sixth century bc ) is a perifluvial settlement located in the Sarno River floodplain to the north‐east of Pompeii (southern Italy) and east of the Somma‐Vesuvius volcano. A great abundance of artefacts have been found at Longola and in the neighbouring areas, including a variety of volcanic stone objects, mainly related to building and to the manufacture of ordinary tools and instruments. The aim of our work is to characterize lithic objects (lava pebbles and millstones) and to understand their geological provenance by petrographic and geochemical studies. Compositions of millstone samples (porphyritic phonolitic tephrites) and of a set of pebbles (mainly phonolitic tephrites, leucite–shoshonites and trachytes) are compatible with the Somma‐Vesuvius magmas erupted before 8 ka bp . For the trachyte lithics, an additional source from the Accademia lava dome (Phlegrean Fields) cannot be ruled out. Among the pebble samples, a rhyolite and a poorly evolved trachyte clearly lie outside the compositional variation of the Somma‐Vesuvius and other volcanoes of the Naples area (e.g., Ischia and the Phlegrean Fields) and emphasize an extra‐regional provenance. Ponza Island is the best candidate for the provenance of the above two outlier samples.     

SCIENTIFIC CHARACTERIZATION OF THE POHORJE MARBLES,SLOVENIA

As a former part of the great Roman Empire, Slovenia has many archaeological sites featuring buildings and objects entirely or partly constructed from marble whose provenance is doubtful. In Slovenia, the most probable source of such marble is the Pohorje Mountains. For the purpose of supporting further provenance studies, these marbles are fully scientifically characterized. The techniques used are petrographic and geochemical analysis, stable isotope ratio analysis and EPR spectroscopy. The results show that the Pohorje marbles are highly heterogeneous in both their isotopic and geochemical parameters as well as grain sizes. The parameters of the different Pohorje marble outcrops are compared between themselves and with the parameters of known ancient quarries in the Mediterranean and Austria. The use of a multi‐technique approach with combined parameters allows the best possible discrimination.     

AMPHORAE FROM LYONS: PETROGRAPHIC AND CHEMICAL ARGUMENTS*

This paper briefly presents a method for the interpretation of quantitative petrographic data and chemical composition data from amphorae found in Lyons with the aim of determining whether or not the amphorae are of local production. We will try to define the exact place of each argument in our reasoning about the attribution of the origin of these ceramics, while insisting on the zones of uncertainty for each method. It is important to emphasize here that in assigning the origin of the Lyons amphorae all the arguments must be used conjointly. The presence of rhyolite in the temper is not enough to determine the Lyons origin of an amphora, and the geochemical arguments are often insufficient to make a decision. It is a reasoned application of petrographic, geochemical and archaeological arguments which enables us to pronounce an attribution.     

Using portable energy dispersive X-ray fluorescence (EDXRF) analysis for on-site study of ceramic sherds at El Hibeh,Egypt

As part of its geoarchaeological research program, the El Hibeh Project of the University of California, Berkeley field-tested at the site of El Hibeh, northern Middle Egypt, the utility of a portable EDXRF unit for obtaining geochemical analyses of pottery suitable for provenance and other ceramic classification studies. When the geochemical ceramic data from the field test are combined with basic petrographic analysis for the pottery sample set, compelling results are generated. In particular, a triangular scattergram using elemental iron, strontium and rubidium data, in parts per million, provides excellent temporal and spatial separation of ceramic fabrics type, origin and date. The geochemical behavior of iron, strontium and rubidium is discussed in relation to geological source materials utilized for pottery manufacture.     

Roman lava quarries in the Eifel region (Germany): geochemical data for millstone provenance studies

Roman millstones of assumed Eifel origin were produced and exported in huge quantities to many parts of Roman Europe and can be used as tracers for trade patterns in Roman times. This study presents for the first time a raw-material centred geochemical definition of the 13 well-known Roman basaltic lava quarries in the Quaternary East and West Eifel volcanic fields. The aim is to find a way to characterize the individual exploitation sites precisely by means of their geochemical composition and to recommend a standard procedure for further millstone provenance analysis. Based on major and trace element composition analyses by XRF, a differentiation of each quarry is achieved by using a combination of geochemical discrimination and cluster and discriminant analysis. Therefore, for provenance analysis of a unknown millstone sample the following procedure is recommended: (1) geochemical discrimination to check if it actually belongs to the volcanic Eifel quarries; (2) cluster analysis to check to which quarry or cluster of quarries the millstone can be affiliated; and (3) discriminant analysis to assign the sample to its quarry of origin with a certain confidence.     

Identifying a technological style in the making of lime plasters at Teopancazco (Teotihuacan,México)

The aim of this article is to focus on the technology of archeological plasters at Teotihuacan (Central Mexico), from the Classic Period (200–650 A.D.), focusing in the study of Teopancazco, a neighborhood center in the city. Petrographic and chemical analyses by OM, SEM-EDS, and LA-ICP-MS were conducted to characterize samples from different constructive phases and sectors of the neighborhood center, to determine the provenance of the raw materials employed in the manufacturing (e.g., volcanic glass shards) and to assess whether a shift occurred in the manufacturing of plasters and in the procurement strategies of raw materials during the different phases. The results of the analyses show that almost no changes occurred in the making of the plaster during more than four centuries and allow us to consider the presence of a technological style in their manufacture, which is characterized by the making of plaster by mixing lime with volcanic glass shards, which in the case of Teopancazco were derived from the Altotonga (Veracruz) magmatic system. The data at our disposal suggest that this style was developed in Teopancazco and later introduced throughout the city of Teotihuacan in the Early Xolalpan phase (A.D. 350), although we still do not know whether the provenance of the raw materials is the same. The wide distribution of this technological tradition could be due to the technological properties of the materials and/or the influence of the intermediate elite who ruled over Teopancazco. The paper confirms that the study of material culture and technology sheds light on broader cultural aspects of ancient societies.     

Mineralogical and Chemical Constraints on the Provenance of Copper Age Polished Stone Axes of ‘Ljubljana Type’ from Caput Adriae

In this paper we show the results of a study concerning 42 axes, mainly discovered in the Copper Age pile dwellings of Ljubljansko barje (central Slovenia) and in the neighbouring areas of Caput Adriae. The studied shaft‐hole axes, characterized by homogeneous typology but slightly different raw materials, have been called ‘Ljubljana‐type’ axes (Lt). The raw materials show a common OIB‐like signature and metamorphic and spilitization features that recall oceanic conditions. The typological and geochemical characteristics and the very high percentage of Lt axes among the polished stone axe assemblages of Ljubljansko barje suggest that the raw material was probably gathered from one or more relatively small outcrops close to Ljubljansko barje. Similar igneous rock types outcrop in the presumably Palaeozoic diabase/shale complex (Eisenkappler Diabaszug), intruded by the northern Karawanken plutonic belt. A probable provenance from this area, particularly rich in copper ore deposit, would confirm the important role of Ljubljansko barje as a metallurgical district, as well as a strong relation between lithic raw materials and Cu cultivation districts during the Copper age.     

PROVENANCING AND ARCHAEOLOGY OF ROMAN MILLSTONES FROM SARDINIA (ITALY)

Summary. Sardinia was an important Roman settlement and trade centre between 238 BC–500 AD and is an ideal site for study of Roman trade. Study of Roman millstones in Sardinia shows that the commonest type is the Pompeian (hour-glass) mill (forty-eight stones studied), with smaller numbers of cylindrical hand querns (sixteen stones studied). Most of these millstones are composed of igneous rocks which include grey vesicular lavas of basic/intermediate composition and a distinctive reddish rhyolitic ignimbrite. There is historical and archaeological evidence for millstone manufacture at six localities in Sardinia. Visual and petrographic study and X-ray fluorescence analysis for major and trace elements of seventeen millstone samples, and fifty rock samples from potential source areas have been used to provenance the igneous rock millstones. The grey vesicular lava millstones have varied sources within the Tertiary-Recent volcanic rocks of Sardinia, while the millstones composed of rhyolitic ignimbrite are from a single source of Tertiary ignimbrite at Mulargia (central west Sardinia). A single hand mill from the north of Sardinia was imported probably from Agde in southern France, and is the only sample composed of non-local rock. Mulargia millstones were widely traded within the western Mediterranean and show a rapid decrease in frequency of occurrence with increasing distance from the source. Sardinia was therefore an important centre of Roman millstone production and a source of millstone trade during the period of Roman settlement.     

Characteristics of ESR signals and TLCLs of quartz included in various source rocks and sediments in Japan: A clue to sediment provenance

The variation of electron spin resonance (ESR) signal intensities and thermoluminescence colour images (TLCIs) of quartz was investigated in the present study for various rocks and sediments in Japan, to discuss the possibilities of identifying the sediment provenance. The ESR signal intensity of the E₁’ centre in the same grain size in granitic quartz varies from sample to sample, except for that in Quaternary samples of volcanic sediment, which is very low, close to the noise level. It was found that the diagram, ESR intensities of Al versus Ti-Li centre signal intensities, distinguish volcanic from the same grain size in granitic quartz as well as distinguish individual tephra from another. The TLCIs from volcanic quartz and some granitic quartz samples is almost red and that from the rest of granitic and metamudstone quartz is blue as results of TLCIs although the emission intensities are different. Our results suggest that examining the multiple-centre signal intensities of ESR and the TLCIs are effective to identify the source of quartz and to estimate the sediment provenance.     

Unglazed pottery from the masjed-i jom’e of Isfahan (Iran): technology and provenance

The masjed-i jom’e of Isfahan is one of the earliest mosques of Iran. Since 1970, Italian researchers performed an extensive archaeological investigation uncovering huge amounts of finds. This study aims at investigating the technological features and provenance of the unglazed pottery finds by using a minero-petrographic approach. Twenty-three samples of storage, table and cooking wares were selected based on the recurrence of typologically identifiable fragments and fabrics. Two bricks, seven production indicators (spacers, kiln furniture, slags) and a local clay were analysed for comparison. The production indicators and most of the pottery show high-CaO concentration. Thick-walled wares contain coarse sedimentary/metamorphic inclusions. Samples with thinner walls contain similar but fine/well-sorted inclusions. The mineralogy and microstructure indicate firing temperatures mainly ranging from 850 to 1000 °C. Low-CaO samples contain coarse sedimentary inclusions; in one sample, volcanic lithics are present. Firing temperatures range from about 800 to 950 °C, and the low-CaO character can be related to their specific function for cooking foods. One sample, found in older stratigraphic levels, differs for its peculiar calcitic temper and lower firing temperature. Local production of most samples was constrained by the composition of the inclusions compatible with the sediments of the Isfahan area. High-CaO pottery shows compositional affinity with production indicators, local clay and tiles produced in Isfahan during the Safavid period. Cooking ware usually contains local temper, with the exception of a sample with volcanic inclusions, for which a non-local provenance is supposed. No appropriate information is, however, available regarding the low-CaO clays used in the area.