Archaeometric analysis of Late Roman amphorae from <Emphasis Type="Italic">Africa</Emphasis> in the ancient city of <Emphasis Type="Italic">Iluro</Emphasis> (Mataró, Catalonia,Spain)

In this paper, the results of the archaeometric study of an assemblage of Late Roman amphorae, found in several contexts from the ancient city of Iluro (Mataró, Catalonia, Spain) and with a presumable origin in Roman Africa, is presented. A total of 57 samples have been analysed, by means of optical microscopy (thin-section analysis), X-ray fluorescence and X-ray diffraction, in order to obtain an integrated petrographic, chemical and mineralogical characterisation and, from this data, to shed light on their provenance. The results indicate the presence of a large number of fabrics, most of them with a Tunisian provenance; a fabric probably from Algeria was also found, as well as a few chemical-petrographic loners that should be related to a provenance out of Africa. Concerning the Tunisian fabrics, the comparison with data from production centres allows for a more precise provenance hypothesis for many of them. These results are useful for the study of the trade networks of Iluro in Late Antiquity, since they provide new evidence on the diversity of transport amphorae that were arriving to this urban centre in Hispania Tarraconensis, showing a more complex reality than initially suggested by the archaeological evidence.     

CHARACTERIZATION OF THE AMPHORAE,STONE BALLAST AND STOWAGE MATERIALS OF THE SHIPS FROM THE ARCHAEOLOGICAL SITE OF PISA–SAN ROSSORE,ITALY: INFERENCES ON THEIR PROVENANCE AND POSSIBLE TRADING ROUTES*

In December 1998, during excavation for the construction of a new building near San Rossore railway station in Pisa, the remains of ancient ships were discovered. These findings have been dated (radiocarbon) to between the end of the 10th century bc and the fifth century ad ( Belluomini et al. 2002 ). Several transport amphorae belonging to the Hellenistic ship, samples of rocks (stone ballast) belonging to ships B, D and the Hellenistic ship, and stowage materials belonging only to ship B have been analysed. The mineralogical and petrographic data of the investigated samples provided information on the possible provenance of the raw materials utilized in the manufacture of the ceramic amphorae, as well as on the provenance of the rock materials found in the ships as ballast and stowage. The compositional data (obtained through XRD, XRF, OM and EPMA) and their statistical analyses suggest that the provenance of the Dressel amphorae belonging to the Hellenistic ship was the Middle Tyrrhenian coast of Italy, and more precisely the area between Tarquinia and Naples, according to the numerous kilns and wine production sites found in this area. The provenance of the volcanic rocks was from southern Tuscany, northern Latium and possibly the Pontine Islands, whereas the intrusive rock possibly comes from the Calabrian–Tyrrhenian coast and/or the Peloritani area. The impure limestones and the dolostone come from southern Tuscany and the Latium coast; the semi‐metamorphic rocks could come from the coast of southern Tuscany, the Tuscan Archipelago or possibly also from the Ligurian coast; only the sample of mylonitized granitoid possibly comes from either the Calabria–Peloritani arc or the Tuscan Archipelago. The stowage materials, consisting of lapilli and scoria of a pyroclastic nature, are sourced from the Neapolitan area. These data might shed some light on the centres of production of the amphorae and of the trading routes followed by the ships, according to the ports of call.     

CRITERIA FOR THE PETROGRAPHIC CHARACTERIZATION OF STONEPASTE CERAMICS

The application of petrographic analysis to the problems of provenance attribution of ceramics made in the Islamic world is complicated by the presence of the highly quartzose ‘stonepaste’body. To facilitate the differentiation of different stonepaste groups, it has been necessary to develop specific criteria for distinguishing the characteristics of each centre, including the assessment of the degree of cloudiness of the quartz as rendered by fluid inclusions. This has enabled the successful application of petrographic analysis, and the solution of a number of provenance problems.     

ON THE WHITE AND COLOURED MARBLES OF THE ROMAN TOWN OF CUICUL (DJEMILA,ALGERIA)

This paper reports the results of an archaeometric study of the local and imported marbles found in the Roman town of Cuicul (now Djemila, Algeria), a research project funded by the Sixth Framework Programme of the European Union. Of the few imported coloured lithotypes that have been found, four are of Greek origin and one was imported from Asia Minor. In addition, two other classical Roman coloured stones found on the site are probably of local North African origin (most likely one from Numidia and one from Algeria). With regard to the grey and white marbles employed in the statuary and architecture, petrographic study in thin section and the δ¹³C and δ¹⁸O isotopic data emphasize the frequent use of the local fine‐grained lithotype from Filfila (Skikda) together with imported Greek lithotypes (i.e., Pentelic marble, the dolomitic variety of Thasian marble, and Parian marble from Lakkoi) as well as different varieties of the so‐called ‘greco scritto’, whose provenance in some cases still remains uncertain. In fact, the petrographic and geochemical features of the marbles do not always match those known for the classical ‘greco scritto’ from the quarry of Cap de Garde, near Annaba (Algeria).     

Geochemical signatures of Roman amphorae produced in the Sado River estuary,Lusitania (Western Portugal)

Several archaeological sites located in the Sado estuary, Lusitania province (Western Portugal), show evidence of an important amphorae production, mainly related to the Roman Tróia industrial centre of fish preserves. The chemical analysis of amphorae sherds found in Barrosinha, Bugio, Zambujalinho, Xarrouqueira and Vale da Cepa (Lower Sado) was performed by instrumental neutron activation analysis, and the mineralogical composition obtained by X-ray diffraction. The chemical results were compared with amphorae from the Herdade do Pinheiro production centre, also located in the Sado estuary. Application of several exploratory and discriminant techniques of multivariate statistical analysis using chemical data of Lower Sado amphorae allowed the characterization and differentiation of two reference groups, named Sado 1 and Sado 2. The geochemical patterns and the mineralogical composition of these groups indicate the use of two different raw materials, the selection of which appears to have been based on the proximity factor of the kilns. The amphorae produced in the Sado basin were differentiated from amphorae from the Gualdalquivir estuary (Villa Nueva, Cádiz, Spain) in Baetica province.     

New investigations into the Uluburun resin cargo

Resin found within Canaanite amphorae from the Late Bronze Age shipwreck discovered off the coast of southwest Turkey at Uluburun has previously been identified as Pistacia sp. Although evidence from Egypt suggests that this resin was in high demand and typically transported in such amphorae, it has also been proposed that the amphorae contained wine, with the resin used to seal the interior surfaces and to flavour and/or preserve the wine. To attempt to resolve this question, we have analysed five samples of pistacia resin found in amphorae from the shipwreck using a range of analytical techniques which have used in the past for the analysis of wine residues: spot tests, FT-IR, and HPLC-MS-MS. As well as the archaeological samples, we have analysed modern samples of pistacia resin, leaves and fruit to determine the effectiveness of each technique and to exclude the possibility of false positive results. In addition to the analyses for wine we also detail analysis (GC-MS) of the terpenoids for the purpose of further molecular characterisation of the resin. Bulk stable isotope analysis was used in comparison with similar resins to attempt to identify the geographical origin of the resin.     

‘GRANITO DEL FORO’ AND ‘GRANITO DI NICOTERA’: PETROGRAPHIC FEATURES AND ARCHAEOMETRIC PROBLEMS OWING TO SIMILAR APPEARANCE

Granitoid rocks were among the stone materials most frequently used for columns and pillars during the Roman period. When employed in Rome and the Mediterranean provinces, they were mainly quarried in Egypt, in Asia Minor and in Italy. Some of these rocks show very similar macroscopic features, so it is often very difficult to tell them apart with the naked eye. This is the case with the ‘Granito del Foro’ (or Marmor Claudianum), from the Gebel Fatireh, in the Eastern Desert, and the ‘Granito di Nicotera’ (Calabria), both exploited from the first century ad onwards. Both feature medium grain size and a white‐greyish colour with black patches. In order to obtain a certain microscopic and geochemical discrimination of these rocks, and to provide the first known petrographic classification of the ‘Granito di Nicotera’, a comprehensive mineralogical, petrographic and geochemical investigation was performed on several samples from the quarry. The results were compared with the corresponding data known for Marmor Claudianum in the literature. Good discrimination between the granites is possible, mainly on the basis of modal mineralogy and geochemical characteristics. The ‘Granito del Foro’ contains hornblende, while the ‘Granito di Nicotera’ contains muscovite, and has a distinctive peraluminous index and trace element abundances.     

Archaeometric evidences of the 4th–2nd century BC amphorae productions in north eastern Sicily

This work focuses on the petro-archaeometric analysis of several transport amphorae dated back from 4th to 2nd century BC which were found in various archaeological excavations recently carried out in Messina and Milazzo (north eastern Sicily). These amphorae, generally known as Graeco-Italic, raise the problem of the identification of their production areas. Petrographic analyses proved the presence of two groups characterised by the presence of coarse metamorphic or volcanic inclusions and one group with finer metamorphic inclusions. Multivariate statistical analyses made it possible to detect the production area of the amphorae with metamorphic inclusion in north eastern Sicily, comparing them with locally produced bricks and clay sediments cropping out near the ancient cities. On the contrary, the studied amphorae rich in volcanic inclusions have petrographic and chemical features which can be attributed to production areas in the Campanian region.     

BULK STABLE LIGHT ISOTOPIC RATIOS IN RECENT AND ARCHAEOLOGICAL RESINS: TOWARDS DETECTING THE TRANSPORT OF RESINS IN ANTIQUITY?*

We have applied and refined methods for the determination of bulk hydrogen, carbon and oxygen isotope ratios in modern and archaeological resins. The modern resins have a wide range of isotopic values and vary within the same tree, between individual trees, with species and location. For all isotopes measured, there is a general trend of increasing depletion of the heavier isotope with increasing altitude. There is also a linear trend between depletion of δD and δ¹³C values with increasing latitude; this trend is less clear for oxygen, but is related to the meteoric water line. Two case studies using archaeological resins known or suspected to have been transported in antiquity have been investigated to determine whether isotopic signatures can assist in pinpointing the geographical origin of the resin: Pistacia sp. resin from Canaanite amphorae imported into Egypt from known geographical locations in the eastern Mediterranean during the Late Bronze Age, and Roman amphorae sherds lined with Pinus sp. resin from sites ranging from Britain to the eastern Mediterranean. These results show separate groupings between the two resin types (pine/pistacia) and between the modern/archaeological resins. Some archaeological samples are distinct from the others and the modern resins show differences between geographical areas. However, there are no clear patterns relating the different Canaanite fabrics or the suggested manufacturing site of the Roman amphorae.     

ARCHAEOMETRIC STUDY OF PROTOHISTORIC GRINDING TOOLS OF VOLCANIC ROCKS FOUND IN THE KARST (ITALY–SLOVENIA) AND ISTRIA (CROATIA)*

This paper presents the results of the archaeometric study of 30 grinding tools found in the Karst plateau (an area that spreads from the northeastern border of Italy to Slovenia) and in the Istria peninsula (Croatia). The petrographic and geochemical characteristics of the artefacts indicate that most of them would be made of trachytic volcanites extracted from the Euganean Hills, near Padua (Veneto). It is known that trachytic rocks from this area had been widely exploited in northern Italy during protohistoric times, but these data considerably enlarge the area of diffusion of saddle‐querns made of these rocks, extending it to Istria. Additionally, the likely provenance from Mount Etna of few other pieces of mugearites and hawaiites represents a new element, to be fully evaluated in the context of trans‐Adriatic exchange/trade connections. Analytical data and possible archaeological inferences are presented in detail in the text.     

ARCHAEOMETRIC ANALYSES ON ‘CORINTHIAN B’ TRANSPORT AMPHORAE FOUND AT GELA (SICILY,ITALY)*

The aim of this work is to throw light on the archaic production of ‘Corinthian B’ amphorae, which are widely diffused in the Western Mediterranean basin and are also present in Greece, but whose geographical provenance is still under discussion. We analysed a group of 37 samples belonging to different ceramic classes dated to the sixth and fifth centuries bc . In particular, there were 19 sherds of trade amphorae of the so‐called archaic ‘Corinthian B’ type, from archaeological excavations in Gela (Sicily, Italy). As a comparison, we also investigated 18 samples of tiles and local coarse pottery from Sibari (Calabria, Italy). The samples were analysed using different techniques, such as optical analysis with a polarized‐light microscope (OM), X‐ray diffraction (XRD), Fourier transform–infrared absorption (FT–IR) and inductively coupled plasma–optical emission spectroscopy (ICP–OES). The combination of these complementary analytical methods allowed us to characterize the samples, determine their firing temperatures and identify the probable provenance. The study of thin sections of sherds by OM allowed us to divide the investigated amphorae into two main groups: the first was characterized by a composition that suggested a Western provenance, in particular from the Calabrian–Peloritan region; the second one was very similar to the ‘Corinthian B’ amphorae that come from Corinth and have been classified as ‘fabric class 1’ by Whitbread (1995 ). The XRD and FT–IR results permitted us to determine the mineral composition of the findings and to estimate their firing temperature. The ICP–OES technique was particularly useful in identifying the production centres. In fact, in the studied pottery, this analysis revealed Ni and Cr values that were noticeably different between Greek and southern Italian production.     

AN INVESTIGATION OF THE PROVENANCE OF THE ROMAN AMPHORA CARGO FROM THE PLEMMIRIO B SHIPWRECK

Eighty-six Roman amphora sherds from the Plemmirio B shipwreck, off Sicily, have been analysed by neutron activation analysis. A large group representative of the amphora cargo, mainly of forms Africana 1 and Africana 2A (from the area of modern Tunisia), was subsequently defined. No differences between Africana 1 and Africana 2A samples were observed, thus implying a similar origin for both forms. The provenance of this cargo group was then investigated by comparison with a Roman amphora kiln data base. After elimination of the more mobile elements it was shown that the cargo amphorae were more likely to have been manufactured at kilns around Sullecthum rather than Leptis Minor. The analytical conclusions are thoroughly consistent with the known archaeological information.     

Using portable energy dispersive X-ray fluorescence (EDXRF) analysis for on-site study of ceramic sherds at El Hibeh,Egypt

As part of its geoarchaeological research program, the El Hibeh Project of the University of California, Berkeley field-tested at the site of El Hibeh, northern Middle Egypt, the utility of a portable EDXRF unit for obtaining geochemical analyses of pottery suitable for provenance and other ceramic classification studies. When the geochemical ceramic data from the field test are combined with basic petrographic analysis for the pottery sample set, compelling results are generated. In particular, a triangular scattergram using elemental iron, strontium and rubidium data, in parts per million, provides excellent temporal and spatial separation of ceramic fabrics type, origin and date. The geochemical behavior of iron, strontium and rubidium is discussed in relation to geological source materials utilized for pottery manufacture.     

Khmer sandstone quarries of Kulen Mountain and Koh Ker: a petrographic and geochemical study

Sandstone from several ancient quarries and natural outcrops located at the eastern foothill of Kulen Mountain and in Koh Ker, northern Cambodia, has been characterized by means of petrographic analysis, scanning electron microscopy, and geochemical analysis. The samples have been collected during a series of field surveys organized jointly by The Metropolitan Museum of Art and the Authority for the Protection and Management of Angkor and the Region of Siem Reap (APSARA). The data show how the sandstone quarried from these sites is characterized by an overall petrographic and geochemical homogeneity, and is consistent with the upper terms of the Lower–Middle Jurassic Terrain Rouge Formation.     

Archeometric characterization of prehistoric grindstones from Milazzo Bronze Age settlement (Sicily,Italy)

The results of a petrographic and geochemical study carried out on archeological grindstones allow to provide new constraints on protohistoric commercial exchanges over the Mediterranean area. Eleven grindstones, discovered in an archeological site located in Milazzo (Messina, Sicily) and dated from the Early Bronze Age, have been investigated by geochemical and petrographic techniques. The raw materials are mainly volcanic rocks characterized by calc-alkaline and K-alkaline affinities with volcanic arc geochemical signature. Only one sample, made of basalt belonging to the Na-alkaline series, shows an intraplate signature. The comparison with the available literature data for similar rocks allowed constraining the volcanic origin of the exploited lavas. While the intraplate-type raw material came from Mt. Etna Volcano (Sicily), the arc-type volcanic rocks are mostly trachyandesites, basaltic andesites, and one rhyolite. Although most of them come from the Aeolian Arc, a provenance of some samples from the Aegean Arc cannot be excluded. This last region could represent the most probable provenance area for the rhyolite sample.     

Short Note: Provenancing of Pottery— The Need for an Integrated Approach?

The method of chemical provenance determination of pottery is described as a very useful tool, which gives reliable results in most cases, if it is applied correctly and to its full power. Therefore, it is claimed that additional petrographic analysis, the so‐called ‘integrated approach’, should not be considered as a must for each project, but is only needed in cases in which the chemical approach leaves questions to be answered.     

CORRESPONDENCE AND DISCRIMINANT ANALYSES OF SAND AND SAND TEMPER COMPOSITIONS,TONTO BASIN,ARIZONA*

Geologists use petrographic modal analysis to relate fluvial sand composition to source rock composition, thus establishing provenance. Archaeologists seeking to establish provenance of sand temper in pottery can use similar petrographic methods, but their finer scale of investigation requires more precise statistical tools than those employed by geologists. A quantitative method for performing that task is presented. It utilizes correspondence analysis and discriminant analysis of logratio transformed point‐count data to define petrofacies, or sand temper resource procurement zones. The procedure is illustrated with sand and sand‐tempered sherd samples collected from the Tonto Basin, central Arizona; temporal trends in utilitarian ceramic production c. AD 100–1350 are reviewed.     

The transport amphorae of Gela: a multidisciplinary study on provenance and technological aspects

Mineralogical, petrographic and chemical analyses were performed on thirty-eight samples of transport amphorae found at Gela, an important Greek colony on the southern coast of Sicily. Based on macroscopic observation, the amphorae, which are datable between the second half of the 6th and the end of the 5th century B.C., were supposed to be local because of similarities to the common wares from the same site. Therefore, in order to verify the provenance of the samples, they were compared to a reference group of locally made ceramics (kiln spacers, kiln wasters, common wares, ancient mud bricks, modern bricks) and twelve samples of local clayey sediments. The results of the analyses have allowed the assignment of all the amphorae to Gela, with the exclusion of five samples, maybe produced in neighbouring sites, and to determine for the first time the archaeometric characteristics of the Geloan medium-coarse ceramics. The aim of our research has also been to investigate some technological aspects of this production, as the location of the clay sources, the methods of clay preparation, and, in particular, the causes of the typical whitening effect on the surface of the vessels.     

Mediterranean trade of the most widespread Roman volcanic millstones from Italy and petrochemical markers of their raw materials

The petrochemical study of millstones can contribute to improve the archaeological research into reconstruction of ancient communication routes and trade networks. Volcanic rocks are geographically restricted and rather rare in the Mediterranean regions, and during the Roman period Italian volcanoes were important sources of raw materials for millstones, so the task of determining their geological origin is relatively straightforward. The Italian vesicular volcanics most frequently employed for this purpose were: trachytes from Euganean Hills (Veneto), leucite-bearing lavas from the Vulsini Volcanic District (Latium), basic-intermediate leucite-bearing lavas from Somma-Vesuvius (Campania), silica undersaturated lavas from Monte Vulture Volcano (Basilicata), a rhyolitic ignimbrite from Sardinia and basic products from Mount Etna and the island of Pantelleria (Sicily). This paper contains a general outline of the trade network for each volcanic typology used for millstones during the Roman period – updated with data concerning the leucite-bearing lavic items discovered in the archaeological sites of the ancient Cuicul (now Djemila, Algeria) – together with a summary of their petrographic and geochemical features.     

THE ORIGIN AND GEOCHEMICAL CHARACTERIZATION OF RED OCHRES FROM THE TITO BUSTILLO AND MONTE CASTILLO CAVES (NORTHERN SPAIN)*

Ochres were the most common source materials for pigments used in Palaeolithic rock art paintings. This work analyses the petrographic and geochemical signatures of different ochre samples from outcrops inside Tito Bustillo Cave and the Monte Castillo Caves using the most common techniques (petrography, XRD, SEM–EDS and ICP–MS) in archaeological pigment characterization studies. The results obtained permit the identification and characterization of the different source ochre types and, furthermore, allow the establishment of mineralogical and geochemical proxies for the study of questions related to ochre characterization, formation processes and provenance.