Middle Bronze Age II Battleaxes from Rishon LeZion,Israel: Archaeology and Metallurgy

Thirteen bronze battleaxes from Middle Bronze Age II graves at Rishon LeZion, Israel were analysed by ED XRF at multiple surface locations in order to determine their metallurgical composition. Six of these were further subjected to neutron diffraction using an ENGIN‐X diffractometer in order to determine bulk phase composition. The results indicate that the previously established geographical and chronological variability in Sn–Cu (with occasional Pb) and As–Cu alloys found using the former method may be an artefact of preservation and conservation. In addition, the varying homogeneity determined by the latter reflects special treatment for improving on the metal cast.     

Chemical tracers of Lusitanian amphorae kilns from the Tagus estuary (Portugal)

In this paper, the characterization of Roman amphorae from the Porto dos Cacos (PC) and Quinta do Rouxinol (QR) workshops, in the Tagus estuary, dating to a period between the 1st and 5th century AD was carried out on the basis of instrumental neutron activation analysis data on 260 amphorae fragments, together with mineralogical compositional studies obtained by X-ray diffraction.     

Small angle neutron scattering study of ancient pottery from Syracuse (Sicily,Southern Italy)

This paper is focused on a spectroscopic study of some pottery shards from an archaeological site in Syracuse (Sicily, Southern Italy), dating back to the Hellenistic–Roman period. Structural characterization was performed at different scales of observation, i.e. from macroscopic to mesoscopic. The main goal was to point out the potentiality of the small angle neutron scattering (SANS) technique as a non-invasive analytical tool in archaeometry, also in conjunction with other, more usual, methodologies. Correlation of experimental data, i.e. macroscopic typology and texture, obtained from petrographic analysis, and radius of gyration and fractal dimension of the interfaces of the mesoscopic aggregates obtained using SANS, together with mineralogical X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis, allowed hypotheses to be made on the production technology of the investigated samples.     

中子衍射和成像技术在文物领域中的应用进展

中子衍射和成像技术是利用中子束穿透性强、元素分辨率高等特点,对物体进行原位、无损和块扫描,实现材料组成定性定量分析和内部结构可视化检测。在此通过介绍中子衍射和成像技术的基本原理和特点,总结其在国内外文物领域的应用研究现状,显示中子衍射和成像技术在文物研究中的突出优势和广阔应用前景,为其在中国文化遗产保护领域的应用研究提供参考。     

TIME‐OF‐FLIGHT NEUTRON DIFFRACTION CHARACTERIZATION OF CERAMIC FINDINGS FROM SOUTHERN AND WESTERN SICILY*

We present the results of a study that is part of a wider research programme regarding knowledge of the initial living phases of Sicilian agricultural and pastoral society. Three sets of ceramic samples were analysed through time‐of‐flight neutron diffraction (TOF‐ND) to derive information about the composition of the clay and the manufacturing techniques. The first two sets of sherds came from an excavation in Licata, close to Agrigento, and are composed of findings dated around the third century bc , while the third set was of samples from prehistoric sites located in the northwestern part of Sicily. Measurements were performed to obtain a quantitative identification of the mineralogical composition of the samples in a totally non‐destructive way. Hints about manufacturing techniques and firing temperatures are derived to provide information on provenance and production processes of the objects.     

Divided loyalties: Sovereignty,politics and public service in the Rhineland under French occupation, 1792–1801

In April 1792 the French Legislative Assembly declared war on the Habsburg Emperor Francis II. Within three years the forces of the Republic conquered the German‐speaking region to the west of the Rhine. Native public officials in the occupied areas faced the dilemma of whether or not to ‘collaborate’ with the invader. They confronted incompatible demands on their loyalties from the exiled Rhenish governments, the French, and the Rhineland's one‐and‐a‐half million inhabitants. The continuation of the revolutionary wars, and failure to reach an international settlement, placed public officials in the occupied areas in a state of limbo. Lacking any legal framework as a point of reference for their actions, and buffeted by the changing fortunes of war abroad and ideological conflict at home, Rhenish communities and the local officials who became their representatives were instead forced to rely on their own resources and strengths. Public officials in particular lived with the possibility of a return of the old regime and the threat of future investigation into their actions under occupation. These fears were only removed with the Treaty of Lunéville in 1801 and subsequent legal annexation of the left bank of the Rhine to the French Republic. Later attempts at assimilating the ‘New Frenchmen’ into the fabric of the Napoleonic state were nevertheless obstructed by continuing ties that bound former public officials to the German powers across the Rhine. The sovereign state's demand for an exclusive monopoly on the loyalty of all its subjects conflicted fundamentally with the Rhenish tradition of employment in the civil and military services of the major German dynasties and other European powers.     

NON‐DESTRUCTIVE INVESTIGATION OF BRONZE ARTEFACTS FROM THE MARCHES NATIONAL MUSEUM OF ARCHAEOLOGY USING NEUTRON DIFFRACTION*

Non‐destructive neutron diffraction techniques were applied to determine composition and microstructure data, and hence to derive information on manufacturing techniques of Picenum bronze artefacts. Furthermore, texture analyses were carried out on standards and suitable ancient artefacts to investigate their potential role in archaeometallurgical studies. This is a first step towards an overall characterization of the bronze collection of the Marches National Museum of Archaeology, Italy, and the analytical demonstration of relations with and differences compared to Etruscan metallurgy. The work is also an example application of the powerful non‐destructive archaeometrical approaches provided by time‐of‐flight neutron diffraction.     

Effect of mollusc eating on human bone strontium levels

Empirical aspects of the movement of strontium through the food chain suggest that the level of bone strontium can be used as an indicator of the percentage of meat in human diet. In general, skeletal remains from agricultural peoples are expected to have high bone strontium levels relative to hunter-gatherers from the same geographical region because plants contain relatively higher amounts of strontium when compared with animal products. The results of the study described in this paper, however, indicate that the inclusion of molluscs as a component of the diet may produce the opposite of the expected strontium values. Burials from an Archaic (c. 2500 BC) hunting-gathering population excavated from Lu^o25, an archaeological site in northern Alabama, USA, exhibit a mean bone strontium level ( atomic absorption; neutron activation) that is higher than the mean level from an agricultural Mississippian (c. AD 1400) population ( atomic absorption; neutron activation) that was buried at the same site. The samples were analysed by two techniques (atomic absorption spectrometry and neutron activation analysis) and the results compared favourably; therefore, the results can be accepted as valid rather than being due to technique error. We propose that the ingestion of molluscs, whose meat is known to contain large amounts of strontium, has produced this reversal from expected results.     

Bison Bone Fragmentation and Survivorship: a Comparative Method

Zooarchaeologists usually describe a bone fragment as a particular portion or segment using terminology based on skeletal orientation (e.g. proximal, anterior, lateral). A more precise understanding of bone fragmentation can be achieved by naming portions for discrete anatomical features and defined zones. Since the anatomical features are the diagnostic criteria for identifying and orienting bones, each specimen normally has at least one such portion, and a complete element contains all of them. This recording method facilitates study of the relationship between survivorship and volume density, and it enhances inter-site comparisons. The method employs the minimum number of elements (MNE) and minimum animal units (MAU) across a site-wide aggregate. Although illustrated here with an analysis of bison bones, the method can be adapted for the study of other taxa as well as for inter-species comparisons.     

Analyses of measurements taken from adult femurs of a British population

The femur remains an important bone in palaeoanthropology and this paper reports various analyses of measurements taken from long-cassette radiographs of adult femurs of a reference population from the south of England (n=81, males 33, females 48). Discriminant analysis confirmed that the male femur is usually larger than the female femur, and that a femur may be sexed with some confidence. Discriminant scores have been derived to permit estimates to be made, from the whole or a part of a femur, of the probability of the male gender. Outcomes from a principal component analysis suggest: that the female proximal femur is a morphological unit; that neck length and shaft length are dissociated and there is no common factor representing linearity; and that the male bicondylar width is anomalous, a finding that is confirmed by other analyses. An estimate of the robusticity of the complete female, but not male, bone may sometimes be made from a proximal fragment. The robusticity of the complete bone may be made confidently from the shaft for both genders. The two width variables relating to a distal fragment cannot be used to predict the robusticity of the complete bone for either gender. A method of defining the position of the waist in terms of displacement in deciles down the shaft is described. The position of the waist seems to have a bimodal distribution. The positive association between age and distal displacement may be due to remoulding of the shaft with age or to a cohort (generational) effect. There is a weak correlation between a small neck–shaft angle and the distal displacement of the waist, two archaic phenotypic traits. Ten statements in the literature relating to the femur have been examined and tested; six are confirmed and four are unconfirmed, and it is suggested that there is a need for further studies relating to the morphology of the femur.     

Pre-industrial headstones across the continental North Sea plain

This paper examines the spatial and temporal distribution of grave headstones in the relatively homogeneous North Sea plain and adjacent regions during the seventeenth and eighteenth centuries, as well as the various lithological, cultural, religious and transportation factors influencing this distribution. Findings from close inspection of cemeteries across the study area were complemented with data from existing surveys. The larger part of the production of headstones was for local consumption. High densities of cruciform (Catholic) headstones in the Boulonnais and in most of the Ardennes–Rhenish massif are illustrated with the cases of the Berwinne and Vesdre headstone production workshops. Beyond concentrations along the Meuse and Rhine rivers, there is a large area stretching from northern France to north-west Germany in which no headstones can be found (with the notable exception of a few Jewish cemeteries). Beyond this area devoid of headstones, the Marsh Islands and adjacent continental areas again have high densities (more than 1 headstone per km²), occurring in two well-differentiated clusters. One cluster contains simple poles in Belgian Palaeozoic limestone in North-Holland and the West-Frisian islands, and the other cluster, on the German and Danish Marsh Islands, holds richly decorated tablets made in sandstone from the Weserbergland. The headstones on the Marsh Islands, a unifying cultural element in this UNESCO world heritage area, bear witness to the significance of a lucrative whaling activity and the intense trade that developed despite political, religious and linguistic differences across the region.     

From the Rhenish Prussian Eifel to the Wisconsin Holyland: immigration,identity and acculturation at the regional scale

The processes and variables that contribute to the construction and maintenance of regional identity can be examined by tracing the origins and transformation of community life. In the case of immigrant communities, pre-migration experiences, social relations, power structures and public memory play significant roles in the construction of regional identity. The transplantation of several communities from the Eifel in Rhenish Prussia to Wisconsin's ‘Holyland’ in the nineteenth century provides the opportunity to study transfer and subsequent acculturation on a regional scale. The power of common cultural origins, based on kinship and an existing sense of community in the Eifel, played an enormous role in the construction of identity and community life in the Holyland. An analysis of the acculturation process within this region reveals the variables that were significant in shaping community life, and provides further insight into the ways in which acculturation and the construction of identity and borders are interrelated.     

Preliminary neutron diffraction study of two fenestrated axes from the ‘Enot Shuni' Bronze Age cemetery (Israel)

Neutron diffraction (ND) analyses of ancient metals show that this method is capable of detecting differences in the inner composition and microstructure of ancient metal objects. Here, ND measurements were conducted on two ‘eye shaped’ axes from the end of the 3rd-beginning of the 2nd millennium BC. The objects were excavated from the ancient cemetery of ‘Enot Shuni' Israel; one is made of bronze and the other of silver. Both artefacts are rare finds, with the silver axe unique in the archaeology of Israel, and therefore had to be analysed locally. For that purpose, a newly assembled diffractometer (KARL) at the IRR-1 of the Nuclear Research Centre (Soreq, Israel) was used. ND measurement on the bronze axe revealed the existence of an α-phase with a range of Cu/Sn ratios (Cu–Sn solid solutions) and some amount of a δ-phase (intermetallic compound of Cu and Sn). The silver axe ND pattern shows the existence of an α-phase (Ag–Cu solid solution) and some amount of copper metal. Our ND data are discussed in comparison with XRF surface measurements and thermal neutron radiography. The results are shedding more light on the in-depth material composition profile, as well as on the objects’ structural and compositional affinities, and help to better understand the production processes and assist in conservation decisions.     

COOKING AND PAINTED WARE FROM SAN GIUSTO (LUCERA,FOGGIA): THE PRODUCTION CYCLE,FROM THE SUPPLY OF RAW MATERIALS TO THE COMMERCIALIZATION OF PRODUCTS*

Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro‐Raman spectroscopy, X‐ray diffraction, X‐ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historical–archaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600–750°C for cooking ware; 850–1050°C for painted ware).     

Geochemical signatures of Roman amphorae produced in the Sado River estuary,Lusitania (Western Portugal)

Several archaeological sites located in the Sado estuary, Lusitania province (Western Portugal), show evidence of an important amphorae production, mainly related to the Roman Tróia industrial centre of fish preserves. The chemical analysis of amphorae sherds found in Barrosinha, Bugio, Zambujalinho, Xarrouqueira and Vale da Cepa (Lower Sado) was performed by instrumental neutron activation analysis, and the mineralogical composition obtained by X-ray diffraction. The chemical results were compared with amphorae from the Herdade do Pinheiro production centre, also located in the Sado estuary. Application of several exploratory and discriminant techniques of multivariate statistical analysis using chemical data of Lower Sado amphorae allowed the characterization and differentiation of two reference groups, named Sado 1 and Sado 2. The geochemical patterns and the mineralogical composition of these groups indicate the use of two different raw materials, the selection of which appears to have been based on the proximity factor of the kilns. The amphorae produced in the Sado basin were differentiated from amphorae from the Gualdalquivir estuary (Villa Nueva, Cádiz, Spain) in Baetica province.     

Average and core silver content of ancient-debased coins via neutron diffraction and specific gravity

The measurement of the fineness of debased ancient silver coins has proven to be a very difficult issue, which has been studied for a long time. In this paper, this subject is analysed, and the various consequences of the silver surface enrichment (SSE) are discussed exploiting the most recent investigations. A new model is proposed for the complex object that is an ancient-debased silver coin, based on the silver profiles measured on some sectioned specimens. The model is applied to a sample of 43 coins, mainly Roman victoriati, Cisalpine and Illyrian drachms (from late III to I century B.C.). The coins are investigated in two different ways: neutron diffraction (ND) and specific gravity (SG). The results of the two measurements are combined via the proposed model to provide a more complete numismatic information of the original fineness of the monetary alloy. As a result, a relation between SSE thickness and SG is derived, which, for these coinages, allows to estimate the original alloy silver content from a simple SG measurement; the same method can be used to study other debased coinages, provided that all the procedure (ND and SG) is applied.     

Mycenaean pottery from the Argolid and Achaia—a mineralogical approach where chemistry leaves unanswered questions

The chemical classification of Mycenaean pottery from the Northern Peloponnese by neutron activation analysis (NAA) resulted in two groups with very similar chemical compositions assigned to production centres in the Argolid and in Achaia, respectively. The statistical separation of these two groups on the basis only of their chemical composition was difficult, and not clear‐cut for all of the examined samples. A complementary mineralogical examination by X‐ray diffraction (XRD) of some selected samples indicated differences in the mineralogical composition, which confirmed the determined chemical differences. Furthermore, a clay sample was examined, which showed a composition similar to that of the pottery.     

Vein quartz in lithic traditions: an analysis based on experimental archaeology

Worldwide, vein quartz was a commonly used raw material for stone tools but this material has proved difficult for archaeologists to analyse because many quartz assemblages appear to be comprised of amorphous pieces, not easily recognised as humanly modified or forming ‘tools’. This paper discusses the analysis of the debitage – focusing on the debitage fragmentation rate, the debitage, break, and fragment types, and the quantitative analysis of the complete flakes – resulting from experimental knapping of quartz, which formed part of a project which investigated the use of quartz in Irish prehistoric lithic traditions. The results have highlighted the complexity involved in analysing quartz assemblages, and the significant differences between the debitage products of quartz and chert knapping assemblages. While bipolar knapping is generally easy to differentiate from direct percussion, it is harder to differentiate between soft and hard hammer percussion.     

CHEMICAL MAPPING OF BASALT FLOWS AT PALEOLITHIC SITES

In the northern Golan Heights, which is built up from volcanic ejections, paleolithic artifacts are found embedded between basalt flows, and in other stratified ejecta. The archaeological objective is to describe the styles of artifacts which belong to particular cultures, which means particular periods. This can be done if different rock stratigraphic units can be mapped in areas where the exposures of strata are not continuous. The present study made use of neutron activation analysis (NAA) to map flows by their chemical compositions. It was found that there is no difficulty in telling one rock unit from another. In addition, it was possible to show that some aspects of earlier geological mapping were deficient or faulty.