ROMANO‐EGYPTIAN RED LEAD PIGMENT: A SUBSIDIARY COMMODITY OF SPANISH SILVER MINING AND REFINEMENT*

Samples of red pigment from a group of seven Roman‐period Egyptian mummies, known as red‐shroud mummies, are investigated. Elemental analysis by inductively coupled plasma time‐of‐flight mass spectrometry (ICP–TOFMS) shows that the samples contain mostly Pb (83–92% by weight), along with 0.2–2.0% Sn. All of the samples are found to have similar trace element distributions when normalized to the continental crust, suggesting that they share a common geological origin. Lead isotope ratios are found to match the mixed lead sources typically associated with Rio Tinto, Spain – a site extensively mined for silver during the first century ad . Raman microspectroscopy identifies the major phase of each sample to be red lead (Pb₃O₄) with a minor phase of lead tin oxide (Pb₂SnO₄). Lead tin oxide does not occur naturally, and its incidental occurrence within the sample indicates that the material was heated under oxidative conditions at temperatures in excess of 650°C. In archaeological contexts, the high‐temperature oxidative treatment of lead is typically associated with metallurgical refinement processes such as cupellation. Based on this evidence, it is argued that the pigment was produced out of litharge associated with silver cupellation at the Rio Tinto site.     

Cornish tin-streamers and the Australian gold rush: technology transfer in alluvial mining

Abstract

The Cornish are known around the world for their mining skills. In the 19th century the migration of Cornish mining families created a diasporic community with settlements in the United States, Mexico, South Africa and Australia centred on copper, tin and gold mines. While the Cornish are generally associated with underground mining, recent research in Australia suggests that ancient methods for working surface tin deposits played an important role during the gold rush. The identification of Cornish tin-streaming as the source of alluvial mining technology in Australia sheds light on a little-documented branch of mining that has played a significant role in shaping the landscape of goldfields regions.     

Virgin Gorda Copper Mine 1839–1862

Abstract

The small Caribbean island of Virgin Gorda, in the Virgin Island group of the Leeward Islands, was heavily mineralized with copper and molybdenum ores which were worked at irregular intervals from the island's first discovery by Columbus in 1493 through to the mid-nineteenth century. The major workings were undertaken in two separate phases by British based companies, 1839–1841 and 1859–1862. The latter were promoted by the family partnership of John Taylor and Sons, which was already well known in the major non-ferrous mining districts of England and Wales and was pioneering British involvement in developing areas throughout the world. In both cases the companies found rich deposits of ore but the workings proved short lived because of a lack of funds, the difficulties of communications and transportation to and from England, and the financial burdens placed on their operations by local taxes. With apparently valuable deposits still awaiting exploitation the story of mining on the island may yet see a concluding chapter but in the meantime the remains of earlier activity provide a fascinating example of Cornish mining technology transplanted almost unchanged several thousand miles from its native shores.     

The early roman imperial AES coinage II: Tracing the copper sources by analysis of lead and copper isotopes—copper coins of Augustus and Tiberius*

Lead and copper isotopes of Roman Imperial copper coins (denominations as and quadrans) were analysed by MC–ICP–MS. We concentrated on well‐dated coins minted at the official mint of Rome under the Emperors Augustus and Tiberius (between 16 bc and ad 37). The lead isotope results were compared with published lead isotope data of ore bodies from the Aegaean, Cyprus, Italy and Spain, in order to fingerprint the sources of Roman copper. During the Augustan period the main copper supply, as judged from the copper coins, is from Sardinia and south‐east Spain, with minor contributions from Tuscany. Except for Tuscany, this continued into the Tiberian period, when Cypriot copper also appears. Augustan quadrantes and late Tiberian asses came solely from the Rio Tinto area in south‐west Spain. Copper isotopes were applied here for the first time to systematic archaeometric studies. They are supplementary to lead isotopes and allow further grouping and classification of the copper coins.     

LUSTRE COLOUR AND SHINE FROM THE OLLERIES XIQUES WORKSHOP IN PATERNA (SPAIN), 13TH CENTURY AD: NANOSTRUCTURE,CHEMICAL COMPOSITION AND ANNEALING CONDITIONS*

Lustre is a medieval ceramic decoration, corresponding to a nanostructured thin layer formed by metallic copper and silver nanocrystals embedded in a glass matrix, which required deep knowledge on the part of the artisans with regard to the raw materials used and the kiln conditions. Their empirical knowledge led to the achievement of colourful lustre decorations ranging from reddish to yellowish or even greenish, some of them with a metallic shine with an associated purplish iridescence. Lustre ceramics dating from the 13th century from the Olleries Xiques workshop in Paterna (Spain) have been studied, linking their chemical composition and nanostructure with their colours and shine. Two kinds of nanostructures are found, yellowish lustre decoration constituted by a silver metal–glass nanocomposite, and reddish lustre decoration constituted by metallic copper nanocrystals and copper oxide nanocrystals; in some cases, metallic copper nanocrystals covered with an oxidized shell of CuO and partly Cu₂O have been found. However, even with significant amounts of copper oxide, the lustre still exhibits a copper metal‐like shine. The bluish iridescence observed at a specular angle in the lustre could not be explained completely by means of the chemical composition, and metallic silver nanoparticle light scattering is proposed as a possible explanation.     

MEDIEVAL SILVER PRODUCTION AROUND SIJILMÂSA,MOROCCO

Sijilmâsa (south-east Morocco) was one of the most strategic cities in a far-reaching exchange network, that is, the Trans-Saharan trade, linking the Maghreb with West Africa during the medieval period (from the 8^th to the 15^th century CE). It was also one of the most important gold and silver monetary workshops at the time. If gold came from West Africa, we know from written sources that silver was produced in Morocco, although archaeological evidence of silver mining and smelting has remained elusive. Thanks to a thorough analysis of the lead isotopic data from silver mining districts in Morocco and from ores and slags of our study, we were able to refine the tracing of our materials and provide tangible evidence of medieval mining in the close hinterland of Sijilmâsa city.     

Soil geochemistry and detection of early Roman precious metal and copper alloy working at the Roman town of Calleva Atrebatum (Silchester,Hampshire, UK)

A geochemical soil survey was carried out over 500 m² of a first and second century AD house complex in insula IX of the Roman town of Calleva Atrebatum (Silchester, Hampshire, UK) where there was little prima facie evidence for non-ferrous metalworking. Preliminary analyses were made by XRF of lead, zinc and copper. These were followed by analysis for Au, Ag and Sn by ICP-MS of the samples with the highest concentrations of Pb, Zn and Cu. Certain of the Pb, Zn and Cu concentrations suggest the working of copper alloy including brass, and could be associated with archaeological evidence of hearths and burnt areas of second century AD date. Other samples have concentrations of the above metals and of gold and silver which do not appear to be associated with any physical remains of hearths and burnt areas. These concentrations date to the mid-first century AD.     

WAC Matters: A Different View to that of Shepherd and Haber

This paper is a response to Shepherd and Haber??s (Public Archaeol 10(2):96?C115, 2011) critiques to World Archaeological Congress, from the viewpoint of the current Secretary of WAC. While most of the issues discussed have been already answered and corrected by Smith (Public Archaeol 10(4):223?C234, 2011), this paper adds my own views on two of these controversial issues: the meeting between WAC and Rio Tinto Limited in 2007 to explore options to work together on enhancing cultural heritage management and protection in mining activities (where I attended as the WAC Treasurer), and the Archaeologists Without Borders Program (as member of the committee for this program).     

A still worm from excavations at Carrick Castle,Argyll

Abstract

During 1993 excavations at Carrick Castle, Argyll, a rare item of distilling equipment was unearthed. Possibly dating to the 17th century, the copper alloy condenser or ‘worm’ is unique in design. Pollen analysis of an associated soil sample supports a use in the production of grain spirits. The technology of manufacture and historical context of the worm are examined in depth.     

Book Review

Abstract

The year 2011 marks the twenty-fifth anniversary of the World Archaeological Congress (WAC). WAC marked a bold intervention in the politics of knowledge in archaeology in the context of the mid-1980s. But how has it fared in contemporary worlds of practice? In this paper, two senior WAC members take a close and critical look at the changing fortunes, meanings, and contexts of the organization. At its centre, is an account of the controversial meeting between the WAC Executive and Rio Tinto Limited, the mining multinational, in Melbourne in 2007. Other parts of the paper engage with notions of the Indigenous, and discuss the assumptions informing the WAC programme Archaeologists Without Borders. Framed as a challenge, the paper invites response and commentary, as a way of opening debate which allows us to envisage alternative futures for the discipline, beyond the banal prospect of 'Archaeology Inc.'.     

Geological setting, nature of ore fluids and sulphur isotope geochemistry of the Fu Ning Carlin-type gold deposits, Yunnan Province, China

Carlin‐type gold deposits in southern China are present in Palaeozoic to Mesozoic siliciclastic and carbonate rocks. The border region of Yunnan, Guizhou and Guangxi Provinces contains gold deposits on the south‐western margin of the Pre‐Cambrian South China Craton in south‐eastern Yunnan Province. The Fu Ning gold deposits host epigenetic, micron‐sized disseminated gold in: (i) Middle Devonian (D₁p) black carbonaceous mudstone at the Kuzhubao gold deposit and (ii) fault breccia zones at the contact between Triassic gabbro (β ) and the Devonian mudstone (D₁p) at the Bashishan gold deposit. The deposits are associated with zones of intense deformation with enhanced permeability and porosity that focused hydrothermal fluid flow, especially where low‐angle N‐S striking thrust faults are cut by NW striking strike‐slip and/or NE striking normal faults. Major sulphide ore minerals in the Fu Ning gold deposits are pyrite, arsenopyrite, arsenic‐rich pyrite, stibnite and minor iron‐poor sphalerite. Gangue minerals are quartz, sericite, calcite, ankerite and chlorite. Hypogene ore grades range from 1 to 7 g t^?1 Au and up to 18 g t^?1 Au at the Kuzhubao gold deposit and are generally less than 3 g t^?1 Au at the Bashishan gold deposit. Sub‐microscopic gold mineralization is associated with finely disseminated arsenic‐rich pyrite in the Stage III mineral assemblage. Two types of primary fluid inclusions have been recorded: Type I liquid–vapour inclusions with moderate‐to‐high liquid/vapour ratios, and Type II inclusions containing moderate liquid/vapour ratios with CO₂ as determined from laser Raman analysis. Temperature of homogenization (T_h) data collected from these primary fluid inclusions in gold‐ore Stage III quartz ranged from 180 to 275°C at the Kuzhubao gold deposit and 210 to 330°C at the Bashishan gold deposit. Salinity results indicate that there were possibly two fluids present during gold deposition, including: (i) an early fluid with 0.8–6.5 wt.% NaCl equivalent, similar to salinity in shear‐zone‐hosted gold deposits with metamorphic derived fluids; and (ii) a late fluid with 11.8–13.4 wt.% NaCl equivalent, indicating possible derivation from connate waters and/or brine sources. CO₂ and trace CH₄ were only detected by laser Raman spectrometry in gold‐ore‐stage primary fluid inclusions. Results of sulphur isotope studies showed that δ³⁴S values for pyrite and arsenopyrite associated with gold‐ore mineralization during Stage III at the Kuzhubao and Bashishan gold deposits are isotopically similar and moderately heavy with a range from +9 to +15 per mil, and also fall into the range of δ³⁴S values reported for Carlin‐type gold deposits. Sulphur isotopes suggest that the Fu Ning gold deposits were formed from connate waters and/or basinal brines. Fluid geochemistry data from the Fu Ning gold deposits suggest a Carlin‐type genetic model, involving fluid mixing between: (i) deep CO₂‐rich metamorphic fluids, (ii) moderately saline, reduced connate waters and/or basinal brines; and (iii) evolved meteoric waters.     

“Terms of Engagement,” A WAC Drama in Multiple Acts and Scenes: Acts Three Through Five and a Call for Public Discussion

After plans for a potential partnership with Rio Tinto fell apart, the World Archaeological Congress applied for funds from the transnational mining corporation for the purpose of developing a policy on external engagement. This cautionary tale recounts the work that took place in 2007?C2008 as part of this project, some of the discussions that ensued, and a turn of events that delayed the ongoing process. In this paper the draft ??Principles to Guide External Engagement?? and ??Outline of a Process for Engagement?? (Appendices) are presented in the context of their formation, with an open call for further comment and discussion.     

Early medieval T⊘nsberg — dating problems and the results

According to the 13th century Icelandic Saga writer Snorre Sturlasson, there was a marketplace (in old Norwegian: Kaupstadir) in the T?nsberg area by the end of the 9th century. The origin of the medieval town of T?nsberg has therefore been much discussed in the light of this statement. Viking Age and early medieval settlements often lack material datable by archaeology alone. In T?nsberg radiocarbon dating has been used to distinguish between Viking Age deposits and medieval deposits, when stratigraphy alone does not state the differences. However, this dating method has produced various results and there is obvious need for a local calibration.     

Post-Medieval Archaeology in Periodical Literature, 1966

Abstract

This paper describes the marked clay pipes found in the Barbican area of Plymouth, and lists all the unmarked types found. The deposits are rich in pipes of Dutch manufacture, particularly of the early 17th century. New light is thrown on local pipemaking from the 17th to the 19th century. The influence of London and southern England is strong both in the styles of Plymouth-made pipes and in the imports to Plymouth. Few pipes from Bristol were found and none from Broseley or the North.     

Identifying stone tools used in mining,smelting, and casting in Middle Bronze Age Cyprus

Abstract

Metallurgical production sites are often difficult to identify in the archaeological record because ore beneficiation and slag processing in the past involved the use of ground stone tools that were similar to those used in other contexts to prepare cereals and foods. Analysis of the ground stone assemblage from a Middle Bronze Age copper mining and production site at Ambelikou Aletri in Cyprus provided an opportunity to distinguish industrial and domestic ground stone tools and to identify the types of tools used in different stages of metal production. A comparison of tool morphologies, raw materials, and wear and breakage patterns from Ambelikou Aletri with those from contemporary domestic contexts, suggests that distinctions in the nature and structure of industrial and domestic tool kits do exist and those distinctions have an important role to play in identifying mining, smelting, and casting sites in the future.     

Defying Comprehension: Resistance to Uniform Appearance in Depicting the Poor, 1770s to 1830s

Abstract

Applied to contemporary Western clothing as part of the new cultural turn in textile history, anthropology provides unique insights into the relationship between commerce and culture; into the symbolic and social processes that influence the market; and into the ways capitalism functions as a cultural system, not just as a purely economic one. This paper takes an anthropological approach to children's clothing and the changing consumer culture of childhood in Britain in the mid-twentieth century, seen through a particular company (Pasolds Ltd.), their Ladybird symbol and its associated popular culture, and an iconic garment, the Ladybird dressing gown. It provides a case study in a field and period dominated to date by studies of American children's garments and material culture and focuses on the production, advertising and indirect marketing of children's clothing through public culture, from the producer's point of view, a perspective hitherto generally overlooked in work on children's clothes and consumer culture in the mid-twentieth century.     

Roman mining on Exmoor: a geomorphological approach at Anstey's Combe,Dulverton

Abstract

A survey of valley fills in south-facing combes (headwater valleys) along the south side of the Exmoor massif revealed an anomalously deep infill in one valley. This infill of up to 5 m depth had been gullied revealing a complex stratigraphy. Studies of the stratigraphy, clast orientation and shape suggested several accumulation episodes under different environmental conditions commencing in a periglacial climatic regime. Later units included sandy silts which can be dated using optically stimulated luminescence (OSL) of quartz grains. The OSL dates, indicate that the inter-gravel silts accumulated in two periods, the Romano-British period and the 16th–17th centuries AD. A survey of the very small valley catchment revealed a linear trench of a type associated with early iron mining. Given the anomalously high volume of accumulated sediment from such a small catchment and evidence of mining on the slope above the site, the geomorphic mechanism is almost certainly the downslope transport of mining debris from the slope to the valley floor. This study suggests that the systematic survey of headwater valleys in metalliferous uplands may be one way of locating areas of early mining activity and that such deposits could provide a chronology of working and abandonment.     

Pyrite–sulfosalt reactions and semimetal fractionation in the Chinkuashih,Taiwan, copper–gold deposit: a 1 Ma paleo‐fumarole

The mineralized fracture system that underlay paleo‐fumarole field at Chinkuashih, Taiwan has been exposed by copper–gold mining to depths of about 550 m below the paleo‐surface. Its mineralogy and systematic variations in metal and semimetal (Fe, Cu, As, Sb, Bi, Hg, Cd, Sn, Zn, Pb, Se, Te, Au, Ag) concentrations provide insights into the chemical responses of a magmatic‐vapor phase as it expands through fracture arrays to the surface and discharges as fumaroles associated with more extensive solfatara. At Chinkuashih, following initial sealing of the fractures by silica‐alunite alteration, brittle failure reestablished discharge from an underlying reservoir of magmatic vapor. Crystalline pyrite was deposited first in the fractures and was succeeded and replaced by ‘enargite’ (Cu₃(As,Sb)S₄) as sulfosalt encrustations (‘sublimate’) on fracture surfaces and in extensional cracks. Subsequent recrystallization resulted in complex exsolution intergrowths with antimony fractionation to the evolving crystal–vapor interface. Heavy metal fractionation between sulfosalt and vapor enriched the vapor phase in heavy metals that subsequently precipitated as complex Bi–Hg–Sn sulfosalts in discrete areas (paleo‐fumaroles) close to the paleo‐surface in a manner analogous to modern‐day fumaroles on active volcanoes such as Vulcano, Italy. As in similar paleo‐fumaroles (e.g., El Indio, Chile and Lepanto, Philippines), the most characteristic reaction sequence is the partial replacement of the early pyrite by enargite and Fe‐tennantite. It is proposed that this reaction tracks the decrease in the pressure of the underlying magmatic‐vapor reservoir because of the sustained discharge of vapor to the surface.