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1.
A review of five different field areas in the Gulf of Mexico sedimentary basin (GOM) illustrates some of the potentially diverse chemical and physical processes which have produced basinal brines. The elevated salinities of most of the formation waters in the GOM are ultimately related to the presence of the Middle Jurassic Louann Salt. Some of these brines likely inherited their salinity from evaporated Mesozoic seawater, while other saline fluids have been produced by subsequent dissolution of salt, some of which is occurring today. The timing of the generation of brines has thus not been restricted to the Middle Jurassic. The mechanisms of solute transport that have introduced brines throughout much of the sedimentary section of the GOM are not entirely understood. Free convection driven by spatial variations in formation water temperature and salinity is undoubtedly occurring around some salt structures. However, the driving mechanisms for the broad, diffusive upward solute transport in the northern Gulf rim of Arkansas and northern Louisiana are not known. In the Lower Cretaceous of Texas, fluid flow was much more highly focused, and perhaps episodic. It is clear that many areas of the Gulf basin are hydrologically connected and that large‐scale fluid flow, solute transport, and dispersion have occurred. The Na‐Mg‐Ca‐Cl compositions of brines in the areas of the Gulf Coast sedimentary basin reviewed in this article are products of diagenesis and do not reflect the composition of the evaporated marine waters present at the time of sediment deposition. Large differences in Na, Ca, and Mg trends for waters hosted by Mesozoic versus Cenozoic sediments may reflect differences in: (i) the sources of salinity (evaporated seawater for some of the Mesozoic sediments, dissolution of salt for some of the Cenozoic sediments); (ii) sediment lithology (dominantly carbonates for much of the Mesozoic sediments, and dominantly siliciclastics for the Cenozoic sediments); or (iii) residence times of brines associated with these sediments (tens of millions of years versus perhaps days).  相似文献   

2.
Two Acheulian occupation sites of the Kimberley District, Doornlaagte and Rooidam, are found geologically sealed and in semi-primary context within complex sequences of calcareous and arenaceous sediments. The sedimentary columns are analyzed and interpreted in terms of sedimentology and stratigraphy, indicating major occupation along the margins of shallow, seasonal lakes; sporadic visits to the fluctuating shoreline are also indicated thereafter, until the Doornlaagte playa began to dry out, and at Rooidam until the whole depression was submerged. The evolution of the related calcareous pans is discussed and attributed to cycles of alternating erosion (aeolian, chemical and fluvial) and deposition (lacustrine and colluvial, including reworked aeolian components). In addition to pedogenetic “calcretes,” most of the limestones of the pan sedimentary sequences are lacustrine in origin. Palaeosols also include fersiallitic soils. The various geomorphologic events indicate repeated and appreciable environmental changes during the mid-Pleistocene. The detailed climatic oscillations recorded at Doornlaagte and Rooidam cannot be correlated, and the latter site is appreciably younger, with a provisional ThU date of 115,000 BP for the late Acheulian (“Fauresmith”) occupation.  相似文献   

3.
Loess is an aeolian Pleistocene sediment of periglacial or arid origins, deposited without internal stratification in parcels representing geological periods. The contents of total as well as individual carbonates are comparatively uniform within a specific stratum, but the relative carbonate contents differ significantly between the various glacials as represented by loess facies. There is a consistent increase in the content of dolomite with decreasing age of stratigraphic units, which has traditionally been attributed to postdepositional alteration, notably the gradual removal of the calcite fraction by weathering. The explanation of pedogenetic enrichment in the course of aeolian recycling of glacial and glacio-fluvial deposits could convincingly account for the stepped profile of the dolomite's depth functions. The implication is that such recycled sediments can be attributed to specific cryocratic phases simply by their characteristic dolomite fraction, i.e. they can be dated. In order to test this hypothesis against the competing weathering hypothesis, strata of the Gudenus Cave in Lower Austria were subjected to carbonate differentiation analysis. The results are presented, analyzed and discussed. It is shown that the dolomite contents of the unweathered strata provide a clear trend that is even more pronounced than that found at open-air sites.  相似文献   

4.
We analyse the fluid flow regime within sediments on the Eastern levee of the modern Mississippi Canyon using 3D seismic data and downhole logging data acquired at Sites U1322 and U1324 during the 2005 Integrated Ocean Drilling Program (IODP) Expedition 308 in the Gulf of Mexico. Sulphate and methane concentrations in pore water show that sulphate–methane transition zone, at 74 and 94 m below seafloor, are amongst the deepest ever found in a sedimentary basin. This is in part due to a basinward fluid flow in a buried turbiditic channel (Blue Unit, 1000 mbsf), which separates sedimentary compartments located below and above this unit, preventing normal upward methane flux to the seafloor. Overpressure in the lower compartment leads to episodic and focused fluid migration through deep conduits that bypass the upper compartment, forming mud volcanoes at the seabed. This may also favour seawater circulation and we interpret the deep sulphate–methane transition zones as a result of high downward sulphate fluxes coming from seawater that are about 5–10 times above those measured in other basins. The results show that geochemical reactions within shallow sediments are dominated by seawater downwelling in the Mars‐Ursa basin, compared to other basins in which the upward fluid flux is controlling methane‐related reactions. This has implications for the occurrence of gas hydrates in the subsurface and is evidence of the active connection between buried sediments and the water column.  相似文献   

5.
The juxtaposition of fault‐bounded sedimentary basins, above crustal‐scale detachments, with warmer exhumed footwalls can lead to thermal convection of the fluids in the sediments. The Devonian basins of western Norway are examples of supradetachment basins that formed in the hanging wall of the Nordfjord‐Sogn Detachment Zone. In the central part of the Hornelen and Kvamshesten basins, the basin‐fill is chiefly represented by fluvial sandstones and minor lacustrine siltstones, whereas the fault margins are dominated by fanglomerates along the detachment contact. Prominent alteration and low‐greenschist facies metamorphic conditions are associated with the peak temperature estimates of the sediments close to the detachment shear zone. Fluid circulation may have been active during the burial of the sediments, and we quantify the potential role played by thermal convection in redistributing heat within the basins. Different models are tested with homogeneous and layered basin‐fill and with material transport properties corresponding to sandstones and siltstones. We found that thermally driven fluid flow is expected in supradetachment basins as a transient process during the exhumation of warmer footwalls. We demonstrate that the fluid flow may have significantly affected the temperature distribution in the upper five kilometers of the Devonian basins of western Norway. The temperature anomaly induced by the flow may locally reach about 80°C. The sedimentary layering formed by sand‐ and siltstones strata does not inhibit fluid circulation at the scale of the basin. The presence of fluid pathways along the detachment has an important impact on the flow and allows an efficient drainage of the basin by channelizing fluids upward along the detachment.  相似文献   

6.
Analysis of sediments from the sites of et-Tabun, Jebel Qafza, and Sefunim in Israel, of Ksar 'Aqil in Lebanon, and of Yabrud Rockshelter I and Jerf 'Ajla in Syria leads to a reconstruction of the environments of deposition, periods of weathering and erosion, and relations to changing sea level during the times of occupation of these sites by prehistoric man. The overlapping sequences span the interval from part or all of the last interglaciation through the time of the last glaciation into historic time. Aeolians and from the last interglacial littoral zone and aeolian silt from more distant deserts dominate the site sediments until the early part of the last glaciation (especially at Tabun), whereas colluvial slope deposits, alluvium (Ksar 'Aqil), and angular rockfall debris are characteristic of the mid-last glaciation sediments in most sites, commonly with an admixture of reworked terra rossa soil sediment. These latter sediments seem to reflect a period or periods of greater available moisture or surface run-off. Prominent unconformities mark many sites at times coincident with the final middle palaeolithic (mousterian) occupations or in the interval between middle palaeolithic and upper palaeolithic occupations. It is not clear, in the absence of firm radiometric dates, whether these hiatuses should be correlated from site-to-site or whether they are site-specific. Freeze/thaw phenomena appear not to have played a significant role, if any at all, in the origin of sediments in coastal Levantine sites, although the middle palaeolithic of the Syrian Desert (Yabrud, Jerf 'Ajla) is contained in typical cryoclastic rubble. Finally, the reconstructed sedimentary environments are compared with the still-too-sparse palynological record for the Near East. Parallels of more humid and less humid climatic intervals throughout the past 60,000 to 70,000 years in both of these records reinforce the growing impression of a regionally fluctuating climate in the eastern Mediterranean region during the time of the last glaciation.  相似文献   

7.
Based on the analysis of major‐element compositions of detrital sediments from the Taklamakan Desert of northwestern China, this paper aims to study chemical weathering in a hyper‐arid desert environment. The major‐element compositions are basically similar to the Upper Continental Crust but show a clear enrichment of CaO and depletion of Na2O and K2O, indicating the enrichment of carbonates and the decomposition of sodium and potassium silicates. The indexes of chemical alteration are relatively low and correlate negatively with the content of Na2O, implying that the degree of chemical weathering is weak and mainly controlled by the weathering of sodium feldspars. An A‐CN‐K model demonstrates that the detrital sediments from the Taklamakan Desert have a high homogeneity in the trend of chemical weathering. They are weathered less than sands and soil in many other Chinese deserts, and also less than similar detrital sediments in many other countries. This evidence suggests a low degree of mineralogical maturity in the Taklamakan Desert. The aeolian sediments of different ages have similar indexes of chemical weathering, suggesting that the degree of chemical weathering was consistent in the Taklamakan Desert throughout the period of aeolian deposition. The low degree of chemical weathering is caused principally by extreme aridity, rapid rejuvenation of detrital sediments associated with strong aeolian processes, and an intensive input of fluvial deposits, as well as a lack of vegetation. Due to the high concentration of erodible minerals, the desert is quite vulnerable to soil erosion and land degradation.  相似文献   

8.
Large‐scale conical and saucer‐shaped sand injectites have been identified in the Upper Miocene sediments of the Lower Congo Basin. These structures are evidenced on the 3D high‐resolution seismic data at about 600 ms TWT (two‐way traveltime) beneath the seabed. The conical and saucer‐shaped anomalies range from 20 to 80 m in height, 50 to 300 m in diameter, and 10 to 20 ms TWT in thickness. They are located within a sedimentary interval of about 100 m in thickness and are aligned over 20 km in dip direction (NE‐SW), above the NW margin of an underlying Upper Miocene submarine fan. We have interpreted the conical and saucer‐shaped anomalies as upward‐emplaced sand injectites sourced from the Upper Miocene fan because of their discordant character, the postsedimentary uplifting of the sediments overlying the cones and saucer‐shaped bodies, the alignment with the lateral fringe of the Upper Miocene submarine fan, and the geological context. Sand injection dates from the Miocene–Pliocene transition (approximately 5.3 Ma). The prerequisite overpressure to the sand injection process may be due to the buoyancy effect of hydrocarbons accumulated in the margins of the fan. Additionally, overpressure could have been enhanced by the lateral transfer of fluids operating in the inclined margins of the lobe. The short duration of sand injection and the presence of many sandstone intrusions suggested that the process of injection was triggered by an event, likely due to a nearby fault displacement related to diapiric movements. This is the first time that sand injectites of seismic scale have been described from the Lower Congo Basin. The localized nature of these injectites has led to a change in the migration path of fluids through the sedimentary cover. Consequently, the sand intrusions are both evidence and vectors of fluid migration within the basin fill.  相似文献   

9.
T. K. KYSER 《Geofluids》2007,7(2):238-257
Sedimentary basins are the largest structures on the surface of our planet and the most significant sources of energy‐related commodities. With time, sedimentary successions in basins normally are subjected to increasingly intense diagenesis that results in differential evolution of basin hydrology. This hydrologic structure is in turn vitally important in determining how and where deposition of metals may occur. Fluids in all basins originate and flow as a result of sedimentological and tectonic events, so that fluid histories should reflect the control of both lithology and tectonism on ore deposition. Sandstone lithologies, in particular, reflect fluid‐flow events because they are normally the major aquifers in basins. However, early cementation results in occlusion of primary permeability in some facies (diagenetic aquitards) whereas in others, permeability develops due to the dissolution of unstable grains (diagenetic aquifers). Particularly for ore deposits in Precambrian basins, identification of paleohydrologic systems during basin evolution requires the integration of data derived from tectonics, sedimentology, stratigraphy, diagenesis, geochemistry and geology. Assessment of all these data is a prerequisite for the ‘holistic basin analysis’ needed to guide the search for basin‐hosted ores. Recent results from the Paleoproterozoic Mt Isa and McArthur basins in northern Australia serve as a template for exploring for mineral deposits in basins. Basinal fluids were saline, 200–300°C and evolved primarily from meteoric water in the Mt Isa Basin and from seawater in the McArthur Basin during burial to depths of 4–12 km. The δDfluid and δ18Ofluid values in these brines were isotopically identical to those in the Zn‐Pb, Cu and U deposits. Geochemical changes of various lithologies during alteration support detrital minerals as the major source of the U, and volcanic units proximal to diagenetic aquifers as a source for the transition metals. Ages of diagenetic phases extracted from aquifer lithologies reveal that fluid migration from the diagenetic aquifers effectively covers the period of formation for U, Zn‐Pb and Cu mineralization, and that the deposits formed in response to tectonic events reflected in the apparent polar wandering path for the area. Sequence stratigraphic analysis and models of fluid flow also indicate that basinal reservoirs were likely sources for the mineralizing fluids. Thus, diagenetic aquifer lithologies were being drained of fluids at the same time as the deposits were forming from fluids that were chemically and isotopically similar, linking diagenesis and fluid events within the basin to the formation of the deposits.  相似文献   

10.
Spatial variations in the salinity of pore waters in sedimentary basins can provide important insight into basin-scale hydrogeologic processes. Although there have been numerous studies of brine seeps in the deep water Gulf of Mexico, much less is known about porewater salinities in the vast areas between seeps. A study has been made of spatial variation in pore water salinities in sediments in an approximately 500 km by 200 km area of the northern deep water (water depth >500 m) Gulf of Mexico sedimentary basin (GOM) to provide insight into pathways and mechanisms of solute transport in this portion of the basin. A second objective was to document salinities in the upper 500 m of the sedimentary section, the approximate depth to which methane hydrates, a potential future energy resource, may be stable. Elevated salinities would reduce the P – T stability range of hydrates. Salinities were calculated from borehole logs using a dual electrical conductivity model. Even though much of the northern GOM is underlain by allochthonous salt most of the undisturbed shallow sedimentary section has not been permeated by hypersaline waters. These waters are limited to areas near brine seeps. Hypersaline waters having salinities in excess of 100 g l−1 become more common at subseafloor depths of 2 km and greater. A field study at Green Canyon 65 and published numerical simulations of fluid flow above tabular salt bodies suggest that brines produced by salt dissolution migrate laterally and pond above salt and/or within minibasins and that the dominant mechanism of vertical solute transport is a combination of compaction-driven advection and diffusion, not large-scale thermohaline overturn. Superimposed on this diffuse upward flux of dissolved salt is the more focused and localized expulsion of saline fluids up faults.  相似文献   

11.
Deep sedimentary basins are complex systems that over long time scales may be affected by numerous interacting processes including groundwater flow, heat and mass transport, water–rock interactions, and mechanical loads induced by ice sheets. Understanding the interactions among these processes is important for the evaluation of the hydrodynamic and geochemical stability of geological CO2 disposal sites and is equally relevant to the safety evaluation of deep geologic repositories for nuclear waste. We present a reactive transport formulation coupled to thermo‐hydrodynamic and simplified mechanical processes. The formulation determines solution density and ion activities for ionic strengths ranging from freshwater to dense brines based on solution composition and simultaneously accounts for the hydro‐mechanical effects caused by long‐term surface loading during a glaciation cycle. The formulation was implemented into the existing MIN3P reactive transport code (MIN3P‐THCm) and was used to illustrate the processes occurring in a two‐dimensional cross section of a sedimentary basin subjected to a simplified glaciation scenario consisting of a single cycle of ice‐sheet advance and retreat over a time period of 32 500 years. Although the sedimentary basin simulation is illustrative in nature, it captures the key geological features of deep Paleozoic sedimentary basins in North America, including interbedded sandstones, shales, evaporites, and carbonates in the presence of dense brines. Simulated fluid pressures are shown to increase in low hydraulic conductivity units during ice‐sheet advance due to hydro‐mechanical coupling. During the period of deglaciation, Darcy velocities increase in the shallow aquifers and to a lesser extent in deeper high‐hydraulic conductivity units (e.g., sandstones) as a result of the infiltration of glacial meltwater below the warm‐based ice sheet. Dedolomitization is predicted to be the most widespread geochemical process, focused near the freshwater/brine interface. For the illustrative sedimentary basin, the results suggest a high degree of hydrodynamic and geochemical stability.  相似文献   

12.
The sedimentary sequence at Diepkloof Rock Shelter formed through a complex interaction of depositional and post-depositional processes and was variously influenced by biogenic, geogenic, and anthropogenic agents. Here, we present the results of a micromorphological study of the sediments at Diepkloof, focusing in particular on the numerous anthropogenic inputs and modifications recorded within the sequence. By applying the microfacies concept, we were able to identify hearth burning and maintenance, bedding construction and burning, and surface modification by trampling as major processes that contributed to the formation of the site. The human activities recorded within the sediments show a marked change throughout the sequence, implying a shift in the use of the site over time. The present study also provides a context for evaluating other classes of artifacts and data collected from the site.  相似文献   

13.
J. J. Adams  S. Bachu 《Geofluids》2002,2(4):257-271
Physical properties of formation waters in sedimentary basins can vary by more than 25% for density and by one order of magnitude for viscosity. Density differences may enhance or retard flow driven by other mechanisms and can initiate buoyancy‐driven flow. For a given driving force, the flow rate and injectivity depend on viscosity and permeability. Thus, variations in the density and viscosity of formation waters may have or had a significant effect on the flow pattern in a sedimentary basin, with consequences for various basin processes. Therefore, it is critical to correctly estimate water properties at formation conditions for proper representation and interpretation of present flow systems, and for numerical simulations of basin evolution, hydrocarbon migration, ore genesis, and fate of injected fluids in sedimentary basins. Algorithms published over the years to calculate water density and viscosity as a function of temperature, pressure and salinity are based on empirical fitting of laboratory‐measured properties of predominantly NaCl solutions, but also field brines. A review and comparison of various algorithms are presented here, both in terms of applicability range and estimates of density and viscosity. The paucity of measured formation‐water properties at in situ conditions hinders a definitive conclusion regarding the validity of any of these algorithms. However, the comparison indicates the versatility of the various algorithms in various ranges of conditions found in sedimentary basins. The applicability of these algorithms to the density of formation waters in the Alberta Basin is also examined using a high‐quality database of 4854 water analyses. Consideration is also given to the percentage of cations that are heavier than Na in the waters.  相似文献   

14.
Historical evidence of aeolian activity in the outer coastal zone of Jæren, southwest Norway, is presented. Meteorological factors such as wind force and wind direction are discussed. Special attention is devoted to meteorological factors causing drought (evaporation and precipitation) as a necessary condition for the occurrence of sand drift. Several aeolian periods after 6000 BP have been identified in the sediments along the coast of Jæren. It is suggested that the changes in the aeolian activity observed have arisen from changes in the environmental state, such as lowering sea level, climatic variation and environmental stress caused by man's interference in connection with increasing agricultural activity (forest clearing, cultivation and so on).  相似文献   

15.
Luminescence dating has been applied to volcanogenic outburst flood sediments (Takuma gravel bed) from Aso volcano, Japan, and tephric loess deposits overlying the gravel bed. The poly-mineral fine grains (4–11 μm) from loess deposits were measured with pulsed optically stimulated luminescence (pulsed OSL) and post-IR infrared stimulated luminescence (pIRIR) methods, whereas the Takuma gravel bed containing no quartz, was measured with IRSL and pIRIR methods using sand sized (150–200 μm) plagioclase. The loess deposits date back at least to ~50 ka by consistent IRSL, pIRIR and pulsed OSL ages from the lowermost part of the loess deposits from one section. The ages obtained from the bottom part of the other loess section are not consistent each other. However, we consider that the pIRIR age (72±6 ka) which showed negligible anomalous fading is most reliable, and regard as a preliminary minimum age of the Takuma gravel bed. The equivalent doses (De) for the plagioclase from the Takuma gravel bed have a narrow distribution and the weighted mean of the three samples yield an age of 89±3 ka. This age is in agreement with the last caldera-forming eruption of Aso volcano (~87 ka) and it is likely that the pIRIR signal has not been bleached before the deposition. IRSL dating without applying pIRIR using small aliquots was also conducted, however, the IRSL signal shows no clear evidence of an additional bleaching during the event of outburst flood from the caldera lake.  相似文献   

16.
In many papers different authors was described problem of systematic underestimation of TL ages for sediments older then 100 ka. We presented the results which probably are not significantly rejuvenated. This is another example of the TL dates made in Lublin laboratory which are likely in agreement with the stratigraphic interpretation. In 2002 Kusiak et al. published the TL ages ranging from 200 to 800 ka for the Zahvizdja loess profile in Ukraine. These first promising results of TL dating of so old deposits encouraged us to undertake further studies. In next years were discovered other Ukrainian loess profiles with the Middle and Lower Pleistocene deposits, among others in the Skala Podils’ka, Mamalyha and Vendychany sites. The thermoluminescence dating made for these profiles in the Lublin laboratory gave the next, after Zahvizdja, series of 15 TL ages ranging from 200 to 700 ka. This way we confirmed the possibility of TL dating of the deposits older than 400 ka BP.  相似文献   

17.
Scanning electron microscope analysis of sediments from Tabun Cave has revealed a detailed palaeoenvironmental history for the area. Basal units (Garrod's F and G layers) derive from wind-blown materials, intermediate units (E) are wind-blown derivatives but with marine modification, and the upper units (D, BC) exhibit only aeolian modification to grain surfaces. As had been previously postulated, the analyses also provide supporting evidence for chemical alteration phases within the sediments.  相似文献   

18.
The study of fabrics, that is, the analysis of the orientation and slope of archaeological and sedimentary materials associated with the Middle Palaeolithic/Upper Palaeolithic (MP/UP) transition at Cova Gran shows substantial differences. Archaeological assemblages are characterised by greater isotropy in the fabrics than the sedimentary levels within which they are located, indicating that these differences may be generated by anthropic processes. One of the anthropogenic processes associated with horizontal and vertical displacement of archaeological artefacts is trampling and circulation caused by later occupations. In order to evaluate the effect of movement on materials, we undertook experiments simulating geological and archaeological conditions at Cova Gran. The results show that human trampling does not cause major isotropy in fabrics, but arranges archaeological assemblages towards planar or linear materials according to surface geometry. We were not able to replicate the fabric pattern of materials from the archaeological levels of Cova Gran, suggesting that they must be associated with the activities of human occupation at each level.  相似文献   

19.
J. BREDEHOEFT 《Geofluids》2009,9(3):179-181
High fluid pressures in old geologic basins, where the mechanisms that generate high fluid pressure have ceased to operate, pose the problem of how high fluid pressures are maintained through geologic time. Recent oil and gas exploration reveals that low permeability shales, the source beds for oil and gas, contain large quantities of gas that are now being exploited in many sedimentary basins in North America. No earlier analyses of how to maintain high fluid pressure in older sedimentary basins included a shale bed as a source of adsorbed gas; this is a new conceptual element that will fundamentally change the analysis. Such a large fluid source can compensate for a low rate of bleed off in a dynamic system. If the fluid source is large enough, as the gas within these shale source beds appears to be, there will no appreciable drop in pressure accompanying a low rate of leakage from the basin for long periods. For the dynamic school of basin analysts this may provide the missing piece in the puzzle, explaining how high fluid pressures are maintained for long periods of geologic time in a crust with finite, non-zero permeability. This is a hypothesis which needs to be tested by new basin analyses.  相似文献   

20.
元代以来洛川塬区沟谷发育速度和土壤侵蚀强度研究   总被引:1,自引:0,他引:1  
文章用史料考证和实地考察相结合的方法 ,以陕西洛川旧县古城的兴废为地面解译标志 ,以旧县南沟为研究小流域 ,恢复了元代以来洛川黄土塬区沟谷发育与土壤侵蚀过程。计算出了不同时段南沟的沟谷发育速度、土壤侵蚀强度。通过分析得出元代以来洛川塬区沟谷发育速度、土壤侵蚀强度有加剧的趋势 ,其变化与气候变迁、人类活动关系密切 ;降水量较丰富时沟谷发育、土壤侵蚀较强 ;人为加速侵蚀与自然侵蚀相叠加是近现代洛川塬区沟谷发育、土壤侵蚀剧烈的主要原因。建国后黄土高原水土保持效果显著  相似文献   

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