TRACING THE RESOURCES OF IRON WORKING AT ANCIENT SAGALASSOS (SOUTH‐WEST TURKEY): A COMBINED LEAD AND STRONTIUM ISOTOPE STUDY ON IRON ARTEFACTS AND ORES*

Lead and strontium isotope analyses were performed by thermal ionization mass spectrometry (TIMS) on Roman to Byzantine iron artefacts and iron ores from the territory of ancient Sagalassos (south‐west Turkey), to evaluate Pb and Sr isotopes for provenance determination of ores for local iron production. It can be demonstrated that for early Roman artefacts and hematite iron ore processed in early Roman times from Sagalassos proper, as well as for magnetite placer sands and early Byzantine raw iron from the territory of the city, Sr isotopes are much less ambiguous than Pb isotopes in providing clearly coherent signatures for ore and related iron objects. Late Roman iron objects were produced from iron ores that as yet remain unidentified. Early Byzantine iron artefacts display more scatter in both their Pb and Sr isotope signatures, indicating that many different ore sources may have been used. Our study demonstrates that iron objects can be precisely analysed for their Sr isotopic composition, which, compared to Pb isotopes, appears to be a much more powerful tool for distinguishing between chronological groups and determining the provenance of raw materials.     

First results of metallographic analysis and absolute dating of iron finds from Nowe Brzesko,site 26, Proszowice District

This paper presents the results of analyses of metal artefacts discovered at a multiphase site in Nowe Brzesko, Małopolskie Voivodeship, Poland. Fieldwalking prospection led to the discovery of steely iron objects, ploughed out on the site among other numerous archeological finds. A prospecting sondage yielded more corroded metal artefacts, identified mainly as agricultural tools (e.g. sickles, scythes). These chronologically nondistinctive artefacts could be assigned to the third to fourth century AD using radiocarbon dating, complemented by metallurgical analysis. The results open up new research perspectives on the economy and society of the Przeworsk culture in the Late Roman period.     

Combined Pb–Sr isotopic analysis in provenancing late Roman iron raw materials in the territory of Sagalassos (SW Turkey)

In early Roman times, iron was likely supplied to the city of Sagalassos through the smelting of close-by hematite ores. In the early Byzantine period, magnetite–titanite placer sands in some instances could have been exploited for its iron. For the intermediate late Roman period, however, the source of the locally used iron was unknown. Pb and Sr isotopic analyses of iron ores from the area of Camoluk, just south of the territory of Sagalassos, and of late Roman iron artefacts from the antique city itself, reveal a very close resemblance. This makes the use of the Camoluk ores to supply Sagalassos with raw iron in the late Roman period likely. It is also shown that combined Pb and Sr isotopic analyses provides a powerful tool to distinguish chronological groups of iron provenance and a technique that can determine the nature and source of iron raw materials used.     

A Hellenistic/Early Roman Shipwreck Assemblage off Ashkelon, Israel

Underwater surveys at Ashkelon during 1998 exposed a Hellenistic/Roman shipwreck. The ship, c .15–25 m long, sank in the 1st or 2nd century BC, and its remains include iron anchors, lead sheathing, copper nails, assorted metal artefacts, and shipwright's unused nails. Bronze vessels found—oil-lamp, shovel and ladles—could have functioned in cult rites. Weights and balance-scale parts demonstrate commercial activity. Fishing-net sinkers indicate involvement in fishing. This paper raises important points regarding the risk to shipwrecks on the Israeli coast from environmental and human interference, and suggests that Ashkelon never had a built-up port.
© 2009 The Authors     

Morphological reconstruction of Roman <Emphasis Type="Italic">styli</Emphasis> from <Emphasis Type="Italic">Iulia Concordia</Emphasis>—Italy

Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the bed of the main channel of the city. In order to shed light on the production processes used by Roman for stylus manufacturing and the conservation state of the finds, a neutron tomography analysis was performed on NEUTRA beamline in Switzerland. SEM-EDS analyses were performed on few selected objects in order to identify the composition of metal decorations. Here, we present results from our investigation conducted on 91 styli, disclosing, in a non-invasive way, the morphological characterization related to the ancient Roman working techniques.     

THE USE OF TRACE ELEMENT ANALYSIS OF ENTRAPPED SLAG INCLUSIONS TO ESTABLISH ORE – BAR IRON LINKS: EXAMPLES FROM TWO GALLO‐ROMAN IRON‐MAKING SITES IN FRANCE (LES MARTYS,MONTAGNE NOIRE,AND LES FERRYS,LOIRET)*

Knowledge of the iron trade in ancient times rests on determining the source of the objects recovered during archaeological excavations. Unfortunately, attributing the origin is not always possible using archaeological tools alone. Trace element data of the ore and the archaeological material (reduction and reheating slags, entrapped slag inclusions from the bloom, bar iron and iron blades) from two Gallo‐Roman iron‐making centres, Les Martys (Montagne Noire) and Les Ferrys (Loiret), were determined using ICP–AES/MS and LA–ICP–MS. The results highlight a continuity of composition that makes it possible to establish a link between the initial ore and the semi‐finished iron products.     

THE PROVENANCE OF IRON ARTEFACTS FROM MANCHING: A MULTI‐TECHNIQUE APPROACH*

Iron finds from the Celtic oppidum of Manching in southern Bavaria (Germany) are analysed in view of their possible provenance. The exceptional size and the location of Manching are usually attributed to the presence of abundant iron ores in its vicinity. After a review of previous approaches for source determination of iron artefacts, we introduce lead isotope analysis as a new approach. However, only by combining the trace element patterns of slag inclusions and iron metal with lead isotope ratios in the metal is it possible to distinguish various iron ore formations near Manching. As a result, it turns out that, indeed, the most obvious ones—namely, bog ores near the Danube—constituted the main resources for iron production at Manching. It was even possible to select one occurrence as the most likely ore source.     

A long-distance copper alloy trade to the North Eastern Baltic during the late pre-Roman and Roman Iron Age (250 BCE–450 CE) explored with lead isotope MC-ICP-MS

The North Eastern Baltic has no copper resources of its own, meaning that Cu alloy was imported either as raw material or as finished objects. The north-eastern coastline of Estonia during the late pre-Roman and Roman Iron Age was connected to the south by sea to the long-distance ‘amber’ trade route and to the east by Russian river systems. This study quantitatively assesses the direction of the Cu alloy supply in the region before and after brass enters circulation at the beginning of the Roman Iron Age. After an initial portable X-ray fluorescence (pXRF) survey, 18 objects were chosen for Pb isotope analysis. This isotope analysis resolved a group of nine brass artefacts from the Roman Iron Age amongst a ‘melting pot’ of other Cu alloys. The similarity between the isotope ratios found in the Roman world suggests the presence of the same ‘melting pot’ in the North Eastern Baltic, possibly created by a large amount of Roman Cu alloy being traded north. No evidence for Cu alloy from Scandinavia or the Ural Mountains could be found. The hypothesis from this small study is that the Cu alloy entering Estonia was dominated by metal from Southern Europe from the late pre-Roman Iron Age and the Roman period.     

TOOLS TO QUALIFY EXPERIMENTS WITH BLOOMERY FURNACES*

Five experimental bloomery iron ore smelts were carried out in a reconstruction of an early medieval furnace of the Boécourt type (Switzerland). A part of the bloom from the most successful experiment was forged to a billet. Starting materials and products were weighed, described and chemically characterized (ICP-MS, LA-ICP-MS and WD-XRF). The calculation of the yield and mass balance based on the chemical analyses from the ore (optimum) and from the ore, furnace lining, slag and ash (applied) allow the determination and quantification of the materials involved in the process. This permits the interpretation of the quality of the experiments. The chemical characterization of metal produced from hematite ore from the Gonzen Mountains in Switzerland gives archaeologists the possibility to compare the metal of iron artefacts to metal from this mine. Finally a good agreement between experiments and archaeological reality can be shown.     

Cargoes of Iron Semi‐Products Recovered from Shipwrecks off the Carmel Coast,Israel

Underwater surveys along the Israeli Carmel coast have revealed six cargoes of iron semi‐products associated with shipwrecks. They are described and dated according to the associated artefacts. Metallographic and chemical analyses on samples from the biggest cargo have determined the stages of the chaîne opératoire, identified the properties of the iron and characterized the iron trade along the Israeli coast. The new discoveries contribute to our understanding of the circulation of iron in the South Levant, which was characterized by an almost complete absence of local iron production. During the Byzantine and Crusader periods, this absence was compensated by long‐distance sea trade, depending on political circumstances and restrictions. Three main types of iron semi‐products were identified: (a) partly consolidated blooms, (b) short pointed bars and (c) elongated pointed bars. The cargoes discovered represent a time period of nearly a millennium. Altogether, 148 iron semi‐products were studied. Of these, 166 were from cargo a, which was dated by coins to around 1130–1200 ce . Those coins could have been imported from Europe for Crusader military and civil uses in the Levant. The iron from cargoes b, d and f, dated perhaps to the Byzantine period, could have been imported from Anatolia or Venice for military and civil purposes.     

Slag inclusion analyses for studying ferrous alloys employed in French medieval buildings: supply of materials and diffusion of smelting processes

This paper aims to propose a data treatment method in order to efficiently exploit the major element compositional analyses made on slag inclusions (SI) of ferrous archaeological artefacts. This method is employed to study the reinforcements used in medieval monuments. The first part of the paper shows: (i) that SI composition can be very variable in an artefact and that it is necessary to analyse a sufficiently redundant number of inclusions; and (ii) that on the one hand a local concentration effect and, on the other hand additives during forging can cause this variability. Nevertheless, after filtering this data, it is showed that specific compounds (called here Non-Reduced Compounds – NRC) have in most of cases a constant ratio in the SI. This allows to evidence the signature of the system (ore, charcoal and pollutant) that produced the ferrous alloys. Moreover, a weighted average compound can be extracted from the results. It is demonstrated that, considering some specific elements with a different behaviour in the direct and indirect processes, it is possible to differentiate the two processes. A methodology is then proposed and applied to several samples gathered on different French medieval buildings to follow the diffusion of the indirect process in France.     

A MULTIDISCIPLINARY APPROACH TO THE CHARACTERIZATION OF ROMAN GRAVESTONES FROM AQUILEIA (UDINE,ITALY)*

The results of an archaeometric study on gravestone production in Aquileia (northeastern Italy) during Roman Republican times are reported here. The artefacts are made of limestone, quarried from the sedimentary sequence of the Trieste Karst (Carnican Alps, northeastern Italy), as testified by historical sources which refer to the ‘Roman Quarry’ at Aurisina. The rock types used for the gravestones are petrographically, geochemically and geochronologically homogeneous, and display similar faunal assemblages. In addition, their age is restricted to the Santonian – Lower Campanian. Comparisons between archaeological finds and rock specimens from various active and inactive quarries in this area suggest that quarrying during Roman Republican times was limited to a specific stratigraphic horizon of the sedimentary sequence, corresponding to the higher part of the ‘Roman Quarry’.     

INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROSCOPY ANALYSES OF ROMAN MILITARY COPPER-ALLOY ARTEFACTS FROM THE EXCAVATIONS AT MASADA,ISRAEL*

A selection of Roman military fittings and associated copper-alloy artefacts was analysed by inductively coupled plasma-atomic emission spectroscopy. The method used was a variant on those previously published and gives very good precision and accuracy. The Roman metalwork analysed conforms extremely well to similar artefacts analysed from, contemporaneous European sites and suggests, despite the strongly ‘local’ nature of the Judaean legions, a considerable uniformity of alloying practice within the Roman army during the first century AD.     

A Lead Danubian Rider Plaque

A small lead relief in the hands of a British collector can be identified as belonging to the Danubian Rider cult, so called because the names of deities associated with this Roman-period religion are unknown and artefacts are identified by a pair of horsemen flanking a female deity and accompanied by other distinctive iconographic elements. This example, of unknown origin but probably discovered in east-central Europe, shows the typical composition. Other examples cast from the same mould are known. Although there is little hard fact about this cult and almost nothing written has survived, it is possible to suggest interpretations for much of the imagery by reference to contemporaneous religious activity within the Roman Empire during the second and third centuries AD.     

Chemical characterisation and manufacturing technology of late Roman to early Byzantine glass from Beit Ras/Capitolias,Northern Jordan

The finding of considerable collections of glass artefacts, together with considerable lumps of glass chunks, fuel ash slag and kiln fragments related to glass processing strongly suggests a local secondary production (working) of glass at the Beit Ras/Capitolias archaeological site in northern Jordan from the late Roman to the early Byzantine period. The chemical analysis of ancient glasses can provide important information regarding the manufacturing technology of the glass made during a specific period. The aim of this study is to characterise the chemical and technological aspects of late Roman to early Byzantine glasses excavated from this main archaeological site. Furthermore, the present paper aims to provide incontrovertible evidence that this site must be considered as a major centre for the secondary production of glass during a period between the 3rd and the 6th centuries. For this purpose, a considerable group of raw glass chunks and vessel fragments of different colours and typologies were collected. The results of chemical analyses indicated that the glass did not show a clear difference in chemical composition between late Roman and early Byzantine times. All the glasses (artefacts and chunks) are of the soda-lime-silica type and correspond to the previously defined Levantine I glass group. The chemical composition of the glass chunks, identical to that of contemporary glass of the same colour, strongly suggests that these chunks were used for the manufacture of late Roman to early Byzantine glass at Beit Ras. The observation of technological features indicates that glass chunks were produced in massive tank furnaces in other primary production centres elsewhere, and were meant for local reworking. According to the microscopic examination, it can also be observed that mould-blowing was the main technique used for forming glass.     

Roman Rhine settlement dynamics evidenced by coin distribution in a fluvial environment (Oedenburg,Upper Rhine,France)

On the basis of archaeological and alluvial records, this paper presents the first spatial analysis of artefacts in relation to the evolution of the Rhine River, at the Gallo-Roman site of Oedenburg, during the first four centuries AD. The dataset consisted of several thousand Roman artefacts found by pedestrian prospecting over the last twenty years, over half of which were coins. This dataset was used together with high-resolution topography and geomagnetic mapping, to reconstruct settlement evolution, both on the terrace and in the floodplain. A comprehensive monetary chart has been compiled for the Oedenburg site, which highlights four major phases of settlement. These results provide a possible causal link connecting historical factors and alluvial events with intra-site evolution. Therefore, while changes observed during Phases I (until AD 68), II (AD 69 to AD 180) and III (AD 180 to AD 295) seem largely related to historical and societal events, Phase IV (AD 295 to AD 402) shows patterns of abandonment of the lower part of the floodplain that may well be related to an unusually humid period in the fourth century. These results are set in a broader context, from the Rhine catchment area to the Alps, and are in agreement with the wet conditions also documented in alluvial, lacustrine, geomorphological and palynological records in Germany (Lahn River, Lake Constance, Lake Nussbaumen, Kaisersthul area and the Black Forest). Studying the intra-site spatial distribution of artefacts with high temporal constraints, at a long-lived site with contrasted topography, opens new avenues for the detection of discreet events such as a higher water table, affecting only the lower zone.     

A NEW SETTING FOR THE NORTHERN BORDER OF THE VENETI: METALLIC FINDS FROM THE VENETIC SITE OF MONTE CALVARIO,AURONZO DI CADORE*

In 2000 several bronze and lead objects were discovered at the Venetic‐Roman site (200 bc –ad 200) of Monte Calvario di Auronzo, in the Italian eastern Alps. They were mostly finished artefacts plus semi‐worked products. Analysis included SEM–EDS, EMPA, XRPD, TMS and AMS spectrometry. The compositional results of the finished artefacts suggest that the choice of the alloy had been made according to the decorative techniques to be used. A semi‐worked high‐leaded bronze object indicates the existence of a metallurgical production of cast artefacts at the site. TMS analyses of a lead ingot exclude local provenance, proving the existence of important trade routes.