Analysis of polychrome Iron Age glass vessels from Mediterranean I,II and III groups by LA-ICP-MS

In this work the analytical results obtained by ICP-MS with laser ablation solid sampling and SEM-EDS for some polychrome glass vessels from the Iron Age are presented and discussed. The samples, coming from Etruscan sites near Adria (Northern Italy), belong to the so-called Mediterranean Groups I, II and III and are dated from the 5th, 3rd and 2nd century B.C., respectively. To date, analytical data for only two sets of vessels of the Iron Age have been discussed in the literature. In spite of the low number of available samples, this is the first time that vessels of all three periods are analytically compared. Elemental concentration data show that the samples can be classified as low-magnesia-low potash (LMLK) soda-lime-silica glasses, with low phosphorus and titanium contents, in agreement with data for similar samples of the same age. Bivariate and multivariate analyses of the contents of many elements characterizing the siliceous sands showed three distinct sets corresponding to the three periods. Since the sets indicate different provenances of the sands it seems rational to assume that different glassmaking locations were involved. Chromophores and opacifiers of the blue bodies and the yellow, white and turquoise decorations of the vessels were analytically identified, while the nature of the corresponding ores was hypothesized.     

Southern African glass beads: chemistry,glass sources and patterns of trade

Three-hundred-and-sixty glass beads from 19 archaeological sites in southern Africa dating between about the 8th and 16th centuries AD were analyzed using LA-ICP-MS, determining 47 chemical elements. The eight different bead series, previously defined on morphological characteristics, possess different glass chemistries. Some bead series were made from plant-ash glasses, others from soda-alumina glasses. Zhizo series beads of the late 1st millennium AD were probably made from Iranian glass. Later bead series were made of glass probably manufactured in South Asia, though there are changes through time in both South Asian glass recipes and bead morphologies.     

The first archaeometric data on polychrome Iron Age glass from sites located in northern Italy

A large sample set of transparent and opaque glass artefacts recovered from Etruscan contexts in northern Italy (Bologna and Spina (FE) necropoleis) and dated to a period between the 6th and 4th century BC are analysed in this paper. Samples of highly decorated beads, spindle whorls and vessels of the ‘Mediterranean Group I’ (Alabastron, Oinochoes, Amphoriskos) were selected in order to determine whether these different glass artefacts were produced at the same manufacturing site. While the vessels almost certainly originate from Greece, the beads could derive from a more ancient local production ascertained at the site of Frattesina (Rovigo, Italy) and dated to the Bronze Age.     

An early Iron Age assemblage of faience beads from Ashkelon,Israel: chemical composition and manufacturing process

The microstructure and chemical composition of eight faience beads from an early Iron Age (12th century BCE) assemblage found in the ancient city port of Ashkelon (Israel) are determined by means of FTIR spectrometry, pXRF, microRaman and SEM-EDS analysis. The results are compared with published data of Egyptian and Near Eastern artifacts. Each sample exhibits a hue which is obtained by adding a specific colorant to the glazing mixture. A new gray chalcopyrite-manganese-based colorant was identified. Cementation glazing was most likely used in the manufacturing process of the specimens analyzed, except for the blue bead, which is an Egyptian blue frit. The results suggest that these objects represent a unique assemblage, quite different from contemporary Egyptian and Near Eastern materials, and provide new information regarding the Iron Age faience evidence in the southern Levant.     

Provenance of glass shards in archaeological lime plasters by LA-ICP-MS: implications for the ancient routes from the Gulf of Mexico to Teotihuacan in Central Mexico

We present the chemical characteristics of samples collected from the central courtyard of Teopancazco, a neighbourhood centre in Teotihuacan (Mexico), the most important classic Mesoamerican city. The rhyolitic glass shards used as aggregates have a composition comparable to the glass material sourced from the magmatic system of Altotonga (located along the route to the Gulf Coast). People travelling from the Gulf Coast may have transported the glass shards to Teotihuacan during the Xolalpan phase (350–550 AD). However, the reasons for using glass shards as a construction material remain unknown. These new data confirm the close relationship between inhabitants of Teopancazco and the Gulf Coast already revealed by previous archaeological and archaeometric studies.     

Investigating the production and distribution of plain ware pottery in the Samoan archipelago with laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS)

This paper presents a provenance study of 170 ceramic artifacts and 21 ceramic tiles from three islands in the Samoan archipelago using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Our analyses confirm that LA-ICP-MS can be used to differentiate between clay formations on a single island. We identify different distribution patterns for pottery recovered from lowland and highland sites on Tutuila Island. We also examine evidence for movement of pottery between islands, and find only limited evidence for such movement. Our findings suggest dynamic patterns of prehistoric interaction and site use that need to be evaluated with further data from across the archipelago.     

A non-invasive study of Roman Age mosaic glass tesserae by means of Raman spectroscopy

Ancient mosaic tesserae are a range of materials of very varied and complex nature, including pottery, stone and glass. Raman spectroscopy is a powerful tool for the analysis of all these kinds of materials. In the particular case of glasses, this technique can be used both for a study of surface weathering and for the characterization of bulk structure, but it has not yet been extensively used for the characterization of mosaic glass tesserae. We carried out Raman analyses on a set of Roman and Late Antiquity period mosaic glass samples, which allowed a good characterization of both the glass matrix and the crystalline inclusions. All the samples show the typical Raman signatures of soda-lime-silicate glasses. Several crystalline phases were also identified, being relics of raw materials used during the glass manufacturing process, such as quartz and feldspars, or linked to the glass color/opacification, such as bindheimite and cuprite. The analyses also led to the identification in some blue, turquoise and green tesserae of calcium antimonate, whose Raman signature has only recently been recognized in the scientific literature on mosaic glasses. Some emphasis is given to the analysis of red lead-containing tesserae, colored with Cu⁺ ions or even Cu⁰ (or Au⁰) metal nanoparticles. Samples with peculiar compositions, as well as “modern” (and restoration) samples, could quite easily be distinguished from the ancient ones by their Raman spectra.     

Intensive El Niño and the Iron Age of South-eastern Africa

Burnt daga structures in Iron Age villages serve as proxies for severe drought on the plateau of southern Africa. The distribution of burnt daga remains in two other rainfall areas, KwaZulu-Natal and the Inter-Tropical Convergence Zone over Zimbabwe, Zambia and Malawi, establishes a sequence of simultaneous burnings that parallels the severe droughts recorded for the interior plateau. These widespread correspondences suggest a common cause. Another correspondence with natural proxy data from South America indicates that intensive El Niño events most likely caused the droughts.     

The urban ecology of Iron Age Tel Megiddo: using microvertebrate remains as ancient bio-indicators

The potential of microvertebrate remains for reconstructing the paleoecology of urban sites remains largely untapped except for extensive research carried out at Roman and medieval sites in Britain. We apply taphonomic and ecological approaches to analyzing an assemblage of microvertebrate remains from the Iron Age IIA of Tel Megiddo, Israel. Sampling in a dense residential area including house floors and various fills produced 1080 identifiable specimens including fish, mammal, reptile and bird remains. The mammalian remains show a number of distinct patterns pointing to accumulation from the community of small animals which lived and died on-site. These patterns include evidence for fragmentation due to trampling and presence of burned specimens. The mammalian remains also differed in their taphonomy from an assemblage from Early Bronze Age II Megiddo which originated from predator accumulation during a period of abandonment. These analyses point to an especially low taxonomic diversity in the Iron Age residential assemblage suggesting that the urban environment of Megiddo supported a unique community of small mammalian animals. This differs markedly from ecological conditions in modern day cities which in some cases show greater than background levels of diversity and suggests a dense, homogenous urban environment. We suggest that reconstructing the evolution of urban fauna in greater detail will provide a sensitive tool for tracing historical processes of growth, decline and increasing complexity of urban sites in the Near East as well as other regions of the world.     

Temporal changes in diet: a stable isotope analysis of late Iron Age and Roman Dorset,Britain

This study investigates the relationship between diet and cultural change in late Iron Age and Romano-British populations from Dorset, England (1st century BC to the early 5th century AD). Dorset was the only region in Britain to exhibit continuity in inhumation burial rites through these periods and a wide array of environmental, archaeological and material culture evidence is available there. A sample of N = 77 human adult and N = 17 faunal rib samples were utilized for carbon and nitrogen stable isotope analysis to test the hypothesis that Romanization of the diet would result in greater dietary variation.     

Synchrotron radiation-based x-ray analysis of bronze artifacts from an Iron Age site in the Judean Hills

Seven bronze bangles from Tell en-Nasbeh, northern Judah, were investigated to understand the phase composition and manufacturing process of the artifacts, and possibly suggest a provenance for their origin. Synchrotron x-ray radiation diffraction (XRD) and fluorescence (XRF) were used in the analysis to avoid any destructive sampling and at the same time penetrate through the surface into the core metal. These techniques enabled us to determine that the bangles were not just tin bronze, but leaded tin bronze. Based on excavation reports, it is unlikely that the metal objects were manufactured locally at Tell en-Nasbeh; rather, preliminary XRD and XRF data point towards the neighboring region of Edom as their origin. Despite their political enmity during the Iron Age II, the data suggest that Judahite social demands for bronze may have fostered a strong economic relationship between these two polities.     

Assessing Ceramic Compositional Data: A Comparison of Total Reflection X‐ray Fluorescence and Instrumental Neutron Activation Analysis On Late Iron Age Spanish Celtiberian Ceramics

A solid‐phase, non‐chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X‐ray fluorescence (TXRF). Following this methodology, TXRF can provide semi‐quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi‐quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies.     

Petrographic and geochemical analysis on the provenance of the Middle Bronze and Late Bronze/Early Iron Age ceramics from Didi Gora and Udabno I, Eastern Georgia

We report thin section petrographic and geochemical analysis of a total of 20 Middle Bronze, Late Bronze/Early Iron Age ceramics excavated from Didi Gora and Udabno I located in the Eastern part of the Republic of Georgia and 31 clay samples from eight different regions in the surrounding areas of the sites. The major and trace element compositions of the ceramics and clays were determined using a wavelength dispersive X-ray fluorescence technique. The results indicate that the ceramics were manufactured from local clays in Eastern Georgia, mainly from two local clays without any preference of one of the sources during the Middle Bronze, Late Bronze/Early Iron Age.     

Sourcing Iron Age softstone artefacts in southeastern Arabia: results from a programme of analysis using Inductively Coupled Plasma-Mass Spectrometry/Optical Emission Spectrometry (ICP-MS/OES)

Iron Age softstone vessels manufactured in southeastern Arabia are widely distributed across that region and in lesser amounts throughout Western Asia. Results from a pilot programme of analysis using Inductively Coupled Plasma Mass Spectrometry/Optical Emission Spectrometry on vessel fragments from two southeast Arabian sites are presented. These results indicate the existence of geochemically distinct groups that are separated by both transition metals and rare earth elements. While this indicates the potential for the application of the provenance postulate in softstone analysis, these promising results need to be further tested by an expanded programme of analysis which includes quarry fragments.     

Investigation of palaeodiet in the North Caucasus (South Russia) Bronze Age using stable isotope analysis and AMS dating of human and animal bones

This paper addresses the question of human palaeodietary adaptation in the Eneolithic and Early Bronze Age periods of the North Caucasus (South Russia) using stable isotope analysis. One of the key questions is the presence of fish in the diet. AMS radiocarbon dating of archaeological bone collagen has also been carried out to investigate potential radiocarbon reservoir effects in human skeletal material as a result of an aquatic diet. A fish component has previously been suggested in the diet of Iron Age and Bronze Age humans across Eurasia by isotopic research and radiocarbon dating of contemporaneous human and animal bones. In the North Caucasus however, isotopic data is scant. This study presents a new set of stable isotopic data from several Early Bronze Age sites, mainly belonging to the Maikop culture of the North Caucasus. The results show that the diversity in climate and environment across the northern Caucasus may be a causal factor for the patterns observed in the stable isotope values of terrestrial herbivores. This affects the isotopic values of the humans consuming them. The differences in δ¹⁵N and δ¹³C ranges of both humans and fauna were found to correlate strongly with geography and climate; the most enriched isotopic values are found in the dry steppe areas to the north. Overall, a relatively high enrichment in δ¹⁵N values of humans compared to local terrestrial herbivores and carnivores was observed. This indicates that aquatic resources were probably part of the Bronze Age diet in the region although the extent of this needs further investigation. The dramatic effect of environmental factors on isotopic values in the Early Bronze Age of the North Caucasus illustrates how confident conclusions cannot be drawn on the basis of a small number of samples from widely differing regions and time periods. Radiocarbon dating can provide a useful tool for identifying dietary derived reservoir ages in humans, potentially caused by a fish diet. With two possible exceptions, the nine human–animal bone pair dated as part of this study showed no consistent indication for a consistent reservoir effect.     

Provenance of Early Bronze Age metal artefacts in Western Switzerland using elemental and lead isotopic compositions and their possible relation with copper minerals of the nearby Valais

Ten Early Bronze Age (BzA1, 2200–2000 BC) copper artefacts from the central Valais region from Switzerland were studied for their elemental composition and lead isotope ratios. In order to answer the archaeological question of a local copper supply, a database for copper minerals across the Valais (Switzerland) has been established. This database contains 69 data on lead isotope ratios as well as additional information on the minerals and geochemical associations for copper minerals from 38 locations in the Valais. Comparisons of the artefacts were also made with data pertaining to minerals from various deposits from Europe and Anatolia taken from the literature. The provenance of the materials is very diverse. Some of the data are compatible with the data from the copper mineral deposits of the Valais region. Moreover, three copper lunulae were identified as possibly Tuscan, which suggests contacts between Italy and the Valais region. This pattern also establishes a multiplicity of provenances for the metal and cultural influences in the Alpine environment of the Rhone Valley of Switzerland at the beginning of the Early Bronze Age.