GEOCHEMICAL PROVENANCE OF OBSIDIAN ARTEFACTS FROM THE MSA SITE OF PORC EPIC,ETHIOPIA*

Obsidian geochemical analysis has become an indispensable tool in archaeological research and has wide applications. However, in spite of the abundance of geological and archaeological obsidian, there has been virtually no such investigation in Ethiopia. Recent instrumental characterization of 31 obsidian artefacts from the Middle Stone Age site of Porc Epic and numerous obsidian geological sources show that artefacts were being transported from as far as 250 km away. We believe this has relevance to the understanding of the emergence of modern human behaviour.     

NON‐DESTRUCTIVE SOURCING OF BRONZE AGE NEAR EASTERN OBSIDIAN ARTEFACTS: REDEVELOPING AND REASSESSING ELECTRON MICROPROBE ANALYSIS FOR OBSIDIAN SOURCING*

Despite predictions in the 1980s that electron microprobe analysis (EMPA) would become a popular technique for obsidian sourcing, few studies have used it with this goal, and most of them are now outdated and unrepresentative of modern EMPA. For example, Merrick and Brown (1984 ) recorded their data on punch cards. Furthermore, these studies destructively prepared artefacts for analysis. The research at hand endeavoured: (1) to establish the modern capabilities of EMPA for obsidian sourcing; and (2) to develop and evaluate procedures for non‐destructive artefact analysis. Issues such as diagenetic effects and compatibility with NAA and XRF data were also investigated.     

PROVENANCE STUDIES OF CHALCOLITHIC OBSIDIAN ARTEFACTS FROM NEAR LAKE URMIA, NORTHWESTERN IRAN USING WDXRF ANALYSIS

In 2005–2006 we initiated a major archaeological survey and chemical characterization study to investigate the long-term use of obsidian along the eastern shores of Lake Urmia, northwestern Iran. Previous research in the area suggested that almost all archaeological obsidian found in this area originated from the Nemrut Daĝ source located in the Lake Van region of Anatolia (Turkey). More recent research on obsidian artefacts from the Lake Urmia region has identified a significant number of obsidian artefacts with compositions different from the sources near Lake Van. This suggests that the obsidian artefacts are from a yet to be identified geological source, but possibly one that was not too distant. In order to advance our knowledge of Iranian obsidians and eventually refine provenance criteria we analysed obsidian from 22 Chalcolithic sites and some source areas. The compositions of both obsidian source samples and artefacts were determined using wave length dispersive X-ray fluorescence spectrometry (WDXRF). This paper presents results from the trace elemental analysis of both geological and archaeological obsidians, providing important new data concerning the diachronic relationship between lithic technology and raw material in the north-west of Iran.     

ARCHAEOLOGICAL PETROLOGY AND THE ARCHAEOMETRY OF LITHIC MATERIALS*

For 50 years, archaeologists and physical scientists have been dating, determining the composition of and measuring stone tools, and reporting them in Archaeometry and many other journals. In Archaeometry specifically, the number of papers devoted to the analysis of lithic material has increased at least 30 times since 1958 and volume 1. This is a reflection not only of an increase in the number of scholars devoting their time to the archaeometry of stone, but also of increases in the quality and quantity of instrumental technology available to researchers in the field.     

SOURCING OBSIDIAN FROM NEOLITHIC ÇATALHÖYÜK (TURKEY) USING ENERGY DISPERSIVE X‐RAY FLUORESCENCE*

This paper details the chemical sourcing of 42 obsidian artefacts from a single Neolithic structure at Çatalhöyük (central Anatolia), using Energy Dispersive X‐Ray Fluorescence (EDXRF). The chemical signatures of the samples match those of two geological sources in southern Cappadocia: East Göllü Da? and Nenezi Da?. The data provide a counterpoint for previous analyses at the site, and suggest possible intra‐community distinctions with regard to shifts in raw material procurement and technical change.     

THE CHEMICAL COMPOSITION OF SOME ARCHAEOLOGICALLY SIGNIFICANT FLINT FROM DENMARK AND SWEDEN

Flint was one of the most widely employed raw materials for artefact manufacture in Denmark and Sweden during the Stone Age, and it continued to be used during subsequent periods. Prehistoric flint mining and lithic manufacturing studies in these countries have attracted considerable attention, but there have been no recent attempts to chemically characterize the geological source materials. This paper builds on a pilot study ( Hughes et al. 2010 ) and uses energy‐dispersive X‐ray fluorescence (EDXRF) analysis to determine quantitative composition estimates for nine major, minor and certain trace elements in seven archaeologically significant flint sources in Denmark and Sweden, along with new data on a number of other sources of prehistoric significance. These data provide a geochemical foundation for ongoing research devoted to determining contrasts and continuities in the time and space utilization of flint sources in Scandinavian prehistory.     

ON THE STABILITY OF HOUSING SECTOR INTERACTION: EVIDENCE FROM 42 METROPOLITAN AREAS*

ABSTRACT. Residential vacancy chain models based on White's (1971) application of Markov chain theory are used to simulate flows of housing vacancies through a set of interdependent housing market sectors. Measures of housing sector interaction are derived from such models. Our purpose here is to address the issue of time stationarity raised by their use. U.S. census data are available to calibrate such models at two, and sometimes three, points in time. Data from 42 different SMSAs are used to generate 56 cross-temporal comparisons with interobservation periods ranging from three to eight years. Stability of interaction is addressed from two perspectives–the sectoral perspective and the areawide perspective. Results are mixed and depend upon which measure of interaction is used, which perspective is addressed, and the duration of the interobservation period. However, within limits, findings support continued use of vacancy chain models.     

MECHANICAL PROPERTIES OF STONE ARTEFACT MATERIALS AND THE EFFECT OF HEAT TREATMENT*

Mechanical testing of lithologies used for stone tool manufacture has shown that fracture toughness is the most objective measure of the quality of raw materials shaped by either flaking or pecking/grinding. Materials amenable to pressure flaking and blade manufacture have low values of fracture toughness, whereas those shaped by pecking/grinding have high values. The fracture toughness test is also the most definitive for quantifying the improvement in flaking properties of materials subjected to intentional heat treatment. Cryptocrystalline and macrocrystalline siliceous lithologies demonstrate a well-defined, gradual reduction in fracture toughness with increased temperature. When heated to optimum temperatures, their fracture toughness approaches that of obsidian, the lithology generally regarded as having the best flaking properties.     

MULTIPLE PRIMARY AND SECONDARY SOURCES FOR CHEMICALLY SIMILAR OBSIDIANS FROM THE AREA OF PORTADA COVUNCO,WEST‐CENTRAL NEUQUÉN,ARGENTINA

In west‐central Neuquén Province, Argentina, in the area around Estancia Llamuco, west of Zapala, south of Las Lajas and north‐east of Lago Aluminé, there are multiple primary and secondary sources of obsidian. Primary sources occur within the south‐east extension of the Plio‐Quaternary volcanic chain that runs from Copahue volcano through Pino Hachado. Secondary sources include river‐bed gravels within the valleys of Arroyo Cochicó Grande and Río Kilca as far south as where this river joins with Río Aluminé, and the Quaternary fluvial–glacial sediments cut by the valley of Río Covunco as far east as Portada Covunco. Visually variable obsidians from these two secondary sources include homogeneous black and grey‐translucent types, porphyritic and banded types, and an abundant quantity of oxidized red and black obsidian. However, all these visually distinct obsidians have similar and unique chemistry, with Ba between 220 and 340 ppm, different from any other obsidians previously reported from Neuquén, which all have Ba > 500 ppm, as do obsidians from sources to the north in Mendoza and to the west in Chile. This chemical distinctive obsidian has been exploited and transported over a wide area, beginning prior to 4000 bp , and occurs in local archaeological sites, as well as sites ≥ 300 km to the north‐east in La Pampa Province, ～430 km to the south in Chubut Province, and >75 km to the west across the Andean drainage divide in Chile.     

OBSIDIAN IN THE MEDITERRANEAN AND THE NEAR EAST: A PROVENANCING SUCCESS STORY

Obsidian provenancing studies comprise one of the most productive and successful research programmes of archaeological science. Obsidian characterization has been successful because workable obsidian is homogeneous on a small scale, analysable by a large number of methods, and is restricted to a small number of mainly readily distinguishable geological sources. Analytical, dating, source, and trade studies within the western Mediterranean, central and eastern Europe, the Aegean, and Anatolia and the Near East during the last 30 years or so are reviewed. Research has shown that distributions are mainly separate in the four regions examined, and that obsidian was traded up to 900km in the prehistoric period. Publications on obsidian in the areas under review reached a peak of frequency in the later 1970s and 1980s, but have now decreased in number. This may reflect changing fashions in archaeometric studies, and a current lack of routine application of the provenancing methods developed.     

IBERIAN CERAMIC PRODUCTION FROM BASTI (BAZA,SPAIN): FIRST GEOCHEMICAL,MINERALOGICAL AND TEXTURAL CHARACTERIZATION

Ceramic fragments from the archaeological excavation of the Iberian–Roman city of Basti (Spain) were studied from a geochemical point of view and by applying a statistical tool to X‐ray fluorescence data to discover similarities between ceramic materials. The analysis of these samples was completed by performing a mineralogical analysis, textural observation, and by characterizing the porous system and the colour of the pieces. Our results enabled us to identify the source area of the clayey raw material in the surroundings of Basti and to estimate the firing temperature of the ceramics. Differences in the chemistry were confirmed by characteristics of the pastes and the mineralogical composition of the pieces. Some samples show black cores, which would suggest the presence of organic matter in the raw material and fast firing of the ceramics. The main types of temper were quartz grains and gneiss fragments, although carbonate grains were also identified. Our evidence suggests that most of the samples were well fired. New silicate phases were found to be present in several samples. The mercury intrusion porosimetry verified and confirmed the firing temperature of non‐carbonated samples. Colorimetry showed that the colour of the ceramics varied according to the amount of CaO that they contained.     

THE PROVENANCE OF OBSIDIAN ARTEFACTS FROM THE WĀDĪ ATH‐THAYYILAH 3 NEOLITHIC SITE (EASTERN YEMEN PLATEAU) BY LA–ICP–MS

The geological sources of obsidian in the Red Sea region provide the raw material used for the production of obsidian artefacts found in prehistoric sites on both sides of the Red Sea, as far afield as Egypt, the Persian Gulf and Mesopotamia. This paper presents the chemical characterization of five obsidian geological samples and 20 prehistoric artefacts from a systematically excavated Neolithic settlement in highland Yemen. The major element concentrations were determined by SEM–EDS analysis and the trace element concentrations were analysed by the LA–ICP–MS method, an almost non‐destructive technique capable of chemically characterizing the volcanic glass. A comparison of archaeological and geological determinations allows the provenance of the obsidian used for the Neolithic artefacts to be traced to definite sources in the volcanic district of the central Yemen Plateau.     

THE EURASIAN ORIGINS OF EMPTY TIME AND SPACE: MODERNITY AS TEMPORALITY RECONSIDERED

Understood as a form of temporality, modernity is seen as consisting of empty time and space. However, careful examination of the origins of modern notions of empty time and space suggest they arose from background assumptions in wide use across Eurasia in the early modern period, and also that they arose prior to, and independent of, the emergence of the modern nation‐state. Here, various Eurasian versions of astronomy and philology are examined to show that they relied on such background assumptions and could therefore be readily translated and shared across the boundaries separating quite different cosmologies.     

A MULTIDISCIPLINARY APPROACH TO THE CHARACTERIZATION OF ROMAN GRAVESTONES FROM AQUILEIA (UDINE,ITALY)*

The results of an archaeometric study on gravestone production in Aquileia (northeastern Italy) during Roman Republican times are reported here. The artefacts are made of limestone, quarried from the sedimentary sequence of the Trieste Karst (Carnican Alps, northeastern Italy), as testified by historical sources which refer to the ‘Roman Quarry’ at Aurisina. The rock types used for the gravestones are petrographically, geochemically and geochronologically homogeneous, and display similar faunal assemblages. In addition, their age is restricted to the Santonian – Lower Campanian. Comparisons between archaeological finds and rock specimens from various active and inactive quarries in this area suggest that quarrying during Roman Republican times was limited to a specific stratigraphic horizon of the sedimentary sequence, corresponding to the higher part of the ‘Roman Quarry’.     

COOKING AND PAINTED WARE FROM SAN GIUSTO (LUCERA,FOGGIA): THE PRODUCTION CYCLE,FROM THE SUPPLY OF RAW MATERIALS TO THE COMMERCIALIZATION OF PRODUCTS*

Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro‐Raman spectroscopy, X‐ray diffraction, X‐ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historical–archaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600–750°C for cooking ware; 850–1050°C for painted ware).     

PRE-COLUMBIAN METALLURGY: TECHNOLOGY,MANUFACTURE, AND MICROPROBE ANALYSES OF COPPER BELLS FROM THE GREATER SOUTHWEST*

Twenty-four cast copper crotals (commonly called bells), one 'spilled bell’, one tinkler bell and a number of minerals from locations throughout the Greater Southwest were analysed for their elemental composition by a PIXE nuclear microprobe at Los Alamos National Laboratory, New Mexico, USA. Sixteen bells contained minor and trace amounts of silver, antimony, arsenic, lead, and in some cases tin, strontium, and selenium. Nine bells contained little or no detectable amounts of these elements. This suggests that several workshops throughout the Greater Southwest and Mexico might have manufactured these bells.     

FROM SUSA TO ANURADHAPURA: RECONSTRUCTING ASPECTS OF TRADE AND EXCHANGE IN BITUMEN‐COATED CERAMIC VESSELS BETWEEN IRAN AND SRI LANKA FROM THE THIRD TO THE NINTH CENTURIES AD*

In contrast with artefactual studies of long‐distance trade and exchange in South Asia during the Prehistoric and Early Historic periods ( Ardika et al. 1993 ; Gogte 1997 ; Krishnan and Coningham 1997 ; Tomber 2000 ; Gupta et al. 2001 ; Ford et al. 2005 ), few scientifically orientated analyses have focused on artefacts from the region's Historic period. During excavations at the ancient city of Anuradhapura, Sri Lanka, a number of buff ware ceramics with a putative organic coating on the interior were recovered ( Coningham 2006 ). Dated stylistically to between the third and ninth centuries ad , analysis of the coatings using gas chromatography–mass spectrometry (GC–MS) and stable isotope analysis (carbon and deuterium) confirmed that the coatings are bitumen—an organic product associated with petroleum deposits. There are no known bitumen sources in Sri Lanka, and biomarker distributions and isotopic signatures suggest that the majority of the samples appear to have come from a single bitumen source near Susa in Iran. The relationship between the bitumen coatings and the vessels is discussed, and it is suggested that the coatings were used to seal permeable ceramic containers to allow them to transport liquid commodities. This study enhances our knowledge of networks of trade and exchange between Sri Lanka and western Asia during Historic times.