ANALYSIS OF COPPER-BASED METALLIC ARTIFACTS BY PROMPT GAMMA-RAY NEUTRON ACTIVATION ANALYSIS

Non-destructive analysis of the major elements in copper-alloyed artifacts by prompt gamma neutron activation analysis is reported. Copper, zinc, tin and lead were measured in several ancient Roman, Greek and Iranian objects. Good agreement was found in comparison with analysis of similar objects by destructive methods.     

CHARACTERIZATION OF SAMIAN WARE SHERDS BY MEANS OF NEUTRON ACTIVATION ANALYSIS

Neutron activation analysis has been employed for the characterization of Samian ware sherds. The analysed samples were classified in ten groups, seven of which belonged to the Arretine production, according to archaeological evidence. By means of high resolution gamma-ray spectroscopy, 22 elements have been identified and analysed. Compositional characterization was looked for by taking counting rate ratios of different nuclides in the samples. The compositional pattern of the sherds was found to be fairly uniform both for each pot and for each group so that, at least in the examined cases, it can be assumed to be characteristic of a given workshop.     

TRACE ELEMENT CONTENT OF ROMAN LEAD BY NEUTRON ACTIVATION ANALYSIS

The trace element contents of 13 lead pigs and 20 water pipes, all of Roman origin, were determined by instrumental neutron activation analysis. The contents of Cu, As, Ag, Sn, Sb, and Au were determined with an experimental reproducibility of ±7%; the analytical values are given for all samples. The results are discussed with respect to the homogeneity of samples, the difference between pipes and pigs, the difference between bulk and joint material in pipes, and the possible correlation of the trace element contents with the place of origin.     

NEUTRON ACTIVATION ANALYSIS OF ANCIENT BURMESE SILVER COINS WITH A LOW FLUX AMERICIUM/BERYLLIUM NEUTRON SOURCE

Nondestructive neutron activation analysis is by now a well-established technique for the analysis of ancient silver coins. The high activation cross-section of silver for thermal neutrons makes it possible to also use this method with the low neutron fluxes available from an isotopic neutron source. In this case due consideration must be given to minimize the self-shielding effect which is encountered with coins above a few tenths of a millimetre thickness. A simple method for the determination of the silver, copper and gold content in silver coins based on the self-shielding properties of silver alloys of different fineness is described. The method has been found to be useful for the quick routine assay of silver coins for the purpose of their classification. Seventeen ancient Burmese silver coins from three different cultural periods of Burma, and two British coins for comparison have been analyzed by this method.     

NEUTRON ACTIVATION ANALYSIS OF FAIENCE BEADS

A selection of faience beads has been examined using neutron activation analysis, with a view to distinguishing the provenance of individual specimens. Evidence is presented that the tin content in beads from British sites is significantly higher than in those from other areas. Characteristic features of beads from other sources are also discussed.     

CORRECTIONS FOR DRILL-BIT CONTAMINATION IN SAMPLING ANCIENT POTTERY FOR NEUTRON ACTIVATION ANALYSIS

The routine measurement of tungsten concentrations in pottery sampled with tungsten-carbide drill bits has enabled the measured concentrations of cobalt, tantalum, and lutetium to be corrected for drill-bit contamination. The corrected data, for cobalt at least, are sufficiently accurate that they regain their value as chemical indicators of pottery provenance.     

NEUTRON ACTIVATION ANALYSIS OF PREHISTORIC FLINT MINE PRODUCTS

Specimens of flint from English and Continentai prehistoric factory/mine sites have been analysed using neutron activation and element compositions compared. The possible use of element concentration patterns as a means of characterising such sites is discussed.     

PERSPECTIVES ON THE DATING OF PREHISTORIC GREAT BASIN PETROGLYPHS BY NEUTRON ACTIVATION ANALYSIS

The possible relative dating of petroglyphs by nuclear measurements on desert varnish is explored. The abundances of 30 major and trace elements in desert varnish samples from the Grimes Point petroglyph site in western Nevada were measured by neutron activation analysis techniques. Samples of both desert varnish and heart rock from a non-artifactual test boulder of andesite were studied and the elements tungsten, arsenic, antimony, thorium, uranium, manganese and cerium exhibited the greatest enrichments in the surface samples and may be of use for dating purposes.     

NEUTRON ACTIVATION ANALYSIS OF ARCHAEOLOGICAL MATERIALS: AN OVERVIEW OF THE ITN NAA LABORATORY,PORTUGAL

Instrumental neutron activation analysis (INAA) has been applied to archaeological samples at the Portuguese Research Reactor (RPI) since 1973, and the number of samples analysed has increased steadily since the mid‐1990s. Archaeometric applications of INAA at RPI include the analysis of archaeological ceramics and the stones used in monumental architecture (menhirs) and other historical monuments. A programme of analysis also exists for measuring the precision of and contributing to the certified values of geochemical reference samples. In addition, the study of interference factors is performed to obtain better accuracy in the determination of concentrations of some elements (e.g., corrections for spectral interferences from uranium fission products in the determination of barium, rare earth elements and zirconium).     

ACKNOWLEDGING FIFTY YEARS OF NEUTRON ACTIVATION ANALYSIS IN ARCHAEOLOGY

Neutron activation analysis has been an important analytical technique for chemical characterization studies of archaeological materials since 1957, and remains one of the best analytical approaches for bulk chemical characterization of archaeological ceramics and other materials. This paper introduces a series of reports that document the history of NAA applied to archaeological materials.