The Chiming of Crack’d Bells: Recent Approaches to the Study of Artefacts in Archaeology

Abstract

CROSS PENDANTS, decorated with a ring-and-dot motif and made out of Whitby jet, have been found as far away as Norway and Greenland. This paper catalogues this unique group of artefacts and discusses their context. Their distribution is centred in Yorkshire, suggesting that they were made at Whitby Abbey in the late 12th century. Combining the power of the Christian cross with the magical properties of jet, they were likely worn as protective amulets.     

NEW RADIOCARBON ACCELERATOR DATES ON ARTEFACTS FROM THE EARLY MESOLITHIC SITE OF STAR CARR,NORTH YORKSHIRE*

For the well‐known early Mesolithic site of Star Carr, dating of organic artefacts by accelerator mass spectrometry (AMS) has been hampered by treatment of bone and antler recovered during the original excavations with preservatives. Some, untreated, artefacts were, however, collected after Clark's excavation in 1950. Four of these artefacts were AMS dated in 1995, but two of the dates were significantly younger than the others, and were questionable due to their low collagen yields. These suspect samples have now been re‐analysed, demonstrating that all four artefacts are of similar date. The significance of these dates for the chronology of Star Carr is discussed.     

PREHISTORIC ANTIGORITE PROCUREMENT IN CYPRUS

The Canadian Palaipaphos Survey Project in the Paphos district of south-western Cyprus investigated extensive areas of the Esouzas, Xero, and Dhiarizos River valleys, locating hundreds of archaeological sites spanning the nine millennia from the aceramic Neolithic period to the recent era (Rupp et al. s1984 and 1986). Antigorite artefacts were recovered from Neolithic, Chalcolithic and Bronze Age settlements. A number of geological sources have been proposed for the material from which these artefacts were manufactured. The results of neutron activation analyses of archaeological and geological specimens suggest that the Troodos ophiolite/Kouris River secondary deposits were the primary source of antigorite for the prehistoric populations of the study area. Extreme care must be taken when analysing antigorite samples to avoid material with grey-black magnetite-rich inclusions. since these have radically different trace element chemistries from the pure antigorite.     

MICROSCOPIC IDENTIFICATION AND SOURCING OF ANCIENT EGYPTIAN PLANT FIBRES USING LONGITUDINAL THIN SECTIONING*

Plant fibres and the artefacts constructed from them often remain overlooked in the archaeological record because of their poor survival and the problems related to the precise identification of the species to which the fibres belong. The goal of this study was to design a simple and accurate method of identifying archaeological plant fibre sources. Twenty‐two fibre samples from two sets of ancient Egyptian botanical artefacts were examined under both a stereomicroscope and a compound microscope, and compared to a large reference collection and to previously published research. By examining longitudinal thin sections of the ancient plant specimens, we identified plant fibres from the following species: Hyphaene thebeica, Cyperus papyrus, Desmostachya bipinnata, Imperata cylindrica, Phragmites australis and Linum usitatissimum. Our identification of these plant fibres reveals essential information about the materials used for producing ropes, baskets, sandals, mats and fabric. The results of this study demonstrate the value of longitudinal thin sectioning and light microscopy as a major means of identifying the source material of botanical artefacts, and advance our knowledge of ancient Egyptian plant exploitation as well as the associated technologies involved in constructing these types of artefacts.     

Evaluation of Fe isotope values as a provenance tool for chert artefacts from the north-eastern United States

Iron (Fe) isotope compositions of prehistoric stone tools and geological sources were compared to evaluate the robustness of this isotopic fingerprinting technique. Artefacts and source materials were collected from the Hatch site in central Pennsylvania, United States, where both veined chert (Bald Eagle chert) and stone tools coexist within several metres. Yellow artefacts (δ⁵⁶Fe = 0.38 ± 0.1, n = 7) and source materials (δ⁵⁶Fe = 0.42 ± 0.1, n = 8) isotopically matched within error. The source values also overlap yellow chert samples from three other Bald Eagle chert locations in the area. These values are different from six other chert locations in the north-eastern United States. These data suggest that the Fe isotope composition of chert artefacts reflect distinct geological sources. To enhance the mechanical characteristics of the stone tools, the chert experienced heat treatment, which induced a phase shift of the Fe oxide mineral goethite to hematite. This phase shift changes the colour of the chert to red. The red chert artefacts and source material also have overlapping Fe isotope values, but are 0.2‰ higher than the initial yellow chert. Experimental work where cherts were heated with different clays shows that Fe exchange with site soils induces the +0.2 fractionation. These data demonstrate that predictable Fe isotope fractionation occurs during heating, resulting in isotopically distinct artefacts.     

GEOCHEMICAL ANALYSIS OF VITREOUS ROCKS EXPLOITED DURING THE FORMATIVE PERIOD IN THE ATACAMA REGION,NORTHERN CHILE*

Petrographic analysis and geochemical characterization studies were carried out on vitreous dacite and/or rhyodacite artefacts from Formative period archaeological sites in the upper Salado River Basin in the Atacama Desert, northern Chile. These were compared with samples taken from two source areas located within the subregion, named Linzor and Paniri. Source samples and archaeological specimens were analysed by inductively coupled plasma – mass spectrometry (ICP–MS) combined with optical emission plasma – mass spectrometry (ICP–OES) and atomic absorption spectroscopy (AAS). Results from the limited number of samples analysed indicate that the Linzor source seems to have been the primary source exploited during the Early and Late Formative periods in the Salado River Basin.     

Starchy shells: Residue analysis of precolonial northern Caribbean culinary practices

Determining culinary practices is critical for understanding phytocultural complexes, transported landscapes and human niche constructions. Starch analysis is an exemplary method for reconstructing human–plant dependencies. However, certain types of artefacts from the Greater Caribbean region, such as flaked lithics, lithic griddles, coral artefacts and shells, have not been extensively analysed for starch remains. Moreover, there has been no comparison of culinary practices between The Bahama archipelago and the Greater Antilles (the presumed origin of foodways transported to The Bahama archipelago). The paper investigates 60 bivalve shell artefacts for starch remains, which were recovered from three archaeological sites: El Flaco and La Luperona (Dominican Republic), and Palmetto Junction (Turks & Caicos Islands). In contrast to ethnohistorical narratives that characterize shell tools exclusively as manioc peelers, the starch remains recovered in this study suggest a broader suite of plants and functions. The results provide evidence that a diversity of plants (Dioscorea spp., Dioscorea trifida L., Fabaceae, Ipomoea batatas L., Manihot esculenta Crantz, cf. Zea mays L., cf. Acrocomia media O. F. Cook, and Zingiberales) were prepared with these shells. This new evidence contributes to ongoing discussions about culinary practices in the Caribbean and other related late precolonial (c.800–1500 ce ) foodways.     

TRACING THE RESOURCES OF IRON WORKING AT ANCIENT SAGALASSOS (SOUTH‐WEST TURKEY): A COMBINED LEAD AND STRONTIUM ISOTOPE STUDY ON IRON ARTEFACTS AND ORES*

Lead and strontium isotope analyses were performed by thermal ionization mass spectrometry (TIMS) on Roman to Byzantine iron artefacts and iron ores from the territory of ancient Sagalassos (south‐west Turkey), to evaluate Pb and Sr isotopes for provenance determination of ores for local iron production. It can be demonstrated that for early Roman artefacts and hematite iron ore processed in early Roman times from Sagalassos proper, as well as for magnetite placer sands and early Byzantine raw iron from the territory of the city, Sr isotopes are much less ambiguous than Pb isotopes in providing clearly coherent signatures for ore and related iron objects. Late Roman iron objects were produced from iron ores that as yet remain unidentified. Early Byzantine iron artefacts display more scatter in both their Pb and Sr isotope signatures, indicating that many different ore sources may have been used. Our study demonstrates that iron objects can be precisely analysed for their Sr isotopic composition, which, compared to Pb isotopes, appears to be a much more powerful tool for distinguishing between chronological groups and determining the provenance of raw materials.     

MULTIVARIATE MIXTURE OF NORMALS WITH UNKNOWN NUMBER OF COMPONENTS: AN APPLICATION TO CLUSTER NEOLITHIC CERAMICS FROM AEGEAN AND ASIA MINOR USING PORTABLE XRF*

Multivariate techniques and especially cluster analysis have been commonly used in archaeometry. Exploratory and model‐based techniques of clustering have been applied to geochemical (continuous) data of archaeological artefacts for provenance studies. Model‐based clustering techniques such as classification maximum likelihood and mixture maximum likelihood have been used to a lesser extent in this context and, although they seem to be suitable for such data, they either present practical difficulties—such as high dimensionality of the data—or their performance gives no evidence that they are superior to standard methods. In this paper standard statistical methods (hierarchical clustering, principal components analysis) and the recently developed model‐based multivariate mixture of normals with an unknown number of components, are applied and compared. The data set provides chemical compositions of 188 ceramic samples derived from the Aegean islands and surrounding areas.     

STEATITE SOURCE CHARACTERIZATION IN EASTERN NORTH AMERICA: NEW RESULTS USING INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS*

Doubts have recently been cast on the ability to characterize steatite sources using rare earth elements (REEs). By increasing the number of samples and elements examined using instrumental neutron activation analysis (INAA) and multivariate statistics, this study shows that, with unhomogenized samples, transition metals, not REEs, make the greatest contribution in characterizing steatite sources in the Middle Atlantic region of eastern North America. Preliminary results suggest that INAA has the potential to assign provenance to steatite artefacts, at least at a regional level.     

Antifungal activity of some plant extracts and essential oils against fungi-infested organic archaeological artefacts

The determination of the antifungal activities of nine kinds of powdered plant extracts and five essential oils was studied in vitro against four of the most common fungal species (Aspergillus flavus, A. versicolor, Penicillium sp. and P. purpurogenum), which were isolated from different organic materials from archaeological artefacts such as papyrus and linen. The essential oils showed greater efficacy than the powdered plant extracts, where thyme and lemongrass oils were the most potent. Also, the minimum inhibitory concentration and minimum fungicidal concentration of these oils were determined. Furthermore, their chemical components were identified using gas chromatography-mass spectrometry (GC-MS) analysis. In vivo, studies were performed using biodeteriorated samples for applying treatment, in which the microbiological test revealed that both oils can eradicate both tested fungi completely after exposure time, ranging from two weeks for papyrus samples to 14 weeks for linen. A scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and colorimeter were used to assess the treatment process, leading to the final results, which suggest that the essential oils could be useful sources of fungicidal preparations for the disinfection of biodeteriorated linen and papyrus artefacts. Nevertheless, further studies are strongly recommended to introduce these sources into practical use in preventive conservation.     

LASER ARGON DATING AND GEOLOGICAL PROVENANCING OF A STONE AXE FROM THE STONEHENGE ENVIRONS*

The recently-developed laser microprobe ⁴⁰argon-³⁹ argon technique has been used to give a geological date for a rhyolitic tuff stone axe fragment from the Stonehenge environs. The method requires only milligramme-sized samples and gives dates of sufficient accuracy to aid in provenancing artefacts to sources, as well as information on the heating history of samples. The axe sample is of Lower Carboniferous date (341 ± 5 Ma) and this limits possible sources to outcrops within the Scottish Midland Valley and small altered exposures in Dartmoor. X-ray fluorescence analysis of the axe suggests the Scottish Midland Valley as the more likely source. The laser argon analysis also shows that the implement had not been heated in antiquity. Laser argon-argon dating can, therefore, be a useful tool in artefact study.     

TRACE ELEMENT GEOCHEMISTRY OF NATIVE COPPER FROM THE WHITE PINE MINE,MICHIGAN (USA): IMPLICATIONS FOR SOURCING ARTEFACTS*

Eighty-five samples of native copper from the White Pine mine in upper Michigan were analysed by neutron activation to document geochemical variability within a single locality. Silver, sodium, antimony and scandium contents vary by two orders of magnitude, whereas arsenic values vary by three orders of magnitude. This variability reinforces the need for provenance studies of artefacts to examine sufficient samples to test for heterogeneity within the source area. The White Pine suite contains some of the most impure native copper that has been analysed to date. Arsenic and silver values of these impure samples overlap with those of European coppers, but consideration of several elements can still distinguish native copper from European copper.     

THE ESTABLISHMENT OF A DATA BASE OF NEUTRON ACTIVATION ANALYSES OF WHITE MARBLE*

The establishment of a data base of trace element analysis results obtained by neutron activation analysis of 183 marble samples, each weighing about 200 mg, from eight different quarrying localities for use in provenance studies is described and a summary of the results presented. The problems of sampling museum artefacts are discussed, and details of tests of the reproducibility of the technique are given together with those obtained from multiple-samples from single museum objects. Replicate analyses of a marble standard are also discussed. Thus these data are a measure of the accuracy and precision of the technique, as well as allowing an assessment of the variation in trace element composition within quarry sources and single blocks of marble, as used for artefacts.     

THE AMBER OF EL DORADO: CLASS IB ARCHAEOLOGICAL AMBERS ASSOCIATED WITH LAGUNA GUATAVITA*

Laguna Guatavita, a crater‐like lake located in central Colombia, was used by pre‐Columbian Muisca people for a variety of socio‐religious ceremonies, many of which involved casting offerings into the lake. Of these, the installation of a new ‘king’ became the basis of the El Dorado myth that was carried back to Europe by 16th century conquistadores. In the present study, beads collected from Laguna Guatavita during a late 19th/early 20th century attempt to recover valuables from the lake bed, have been subjected to geochemical analysis. Results establish that these artefacts have been fabricated from Class Ib amber. Class Ib ambers have not previously been reported in either the geological or archaeological records of Central or South America, and their existence in this context implies that the Muisca people had access to a unique local or regional source of amber, knowledge of which has subsequently been lost.     

THE OCCURRENCE OF PALYGORSKITE IN THE YUCATÁN PENINSULA: ETHNO‐HISTORIC AND ARCHAEOLOGICAL CONTEXTS*

Palygorskite is a rare clay mineral used by the ancient Mayas for fabricating the Maya blue pigment and for other purposes. It seems to have been obtained from a restricted area in the Yucatán peninsula where important archaeological sites are found. Geological samples from different localities in this area show a high content in palygorskite, indicating that this clay is widespread in Yucatán. Combining structural, morphological, compositional and geochemical methods, we analysed the common characteristics of Yucatecan palygorskites, and compared them with palygorskites from other origins around the world. These results can be used for defining a fingerprint of Yucatecan palygorskite to be used in provenance studies of archaeological artefacts, in particular the Maya blue pigment.     

THE EARLIEST USE OF CORUNDUM AND DIAMOND,IN PREHISTORIC CHINA*

The majority of prehistoric lithic artefacts were fashioned from rocks and minerals no harder than quartz, and there is no prehistoric evidence for the working of harder materials, such as corundum and diamond. The earliest physical evidence for the use of corundum (ruby, sapphire) is thought to be the abrasive grit recovered from Bronze Age Minoan quartz beads (c. 1700–1500 bc ), while diamond is thought to have been used no earlier than 500 bc , in India. Here we show that corundum was worked c. 4000–3500 bc during the Neolithic period in China, in the form of polished axes from the Liangzhu and Sanxingcun cultures. We also present physical evidence that later Liangzhu axes (c. 2500 bc ), made from the same previously undescribed rock whose most abundant component is corundum, were polished to a mirror‐like finish with a diamond abrasive. Our findings, which are the first to support the use of corundum and diamond in a prehistoric context, may also help to explain the trademark feature of the Neolithic in China, vast quantities of finely polished nephrite jade artefacts.     

MAGNETIC SUSCEPTIBILITY THICKNESS CORRECTIONS FOR SMALL ARTEFACTS AND COMMENTS ON THE EFFECTS OF‘BACKGROUND’MATERIALS*

Correction factors for magnetic susceptibility measurements on thin (<c. 50 mm thick > artefacts have been determined experimentally for a KT‐5 Exploranium G S. instrument using prepared blocks of Whin Sill dolerite. The cor rection factor is large (> 1.4) for samples less than 10mm thick, and reduces to 1 01 for samples of 50mm thickness. Measurements on thin samples can also be affected by the backing or substrate material on which they are measured. ‘Background’material, for example, soil or plaster, can contribute significantly to recorded measurements on artefacts, particularly for thin artefacts with low susceptibilities     

WHITE,VEINED MARBLE FROM ROMAN AMMAIA (PORTUGAL): PROVENANCE AND USE

A multimethod approach using petrography and strontium (Sr) isotopic analysis was applied to determine the geological source of 17 marble artefacts from the Roman town of Ammaia (Portugal). All samples are calcitic, with dolomite, quartz and muscovite as accessory minerals. The marbles are characteristically medium‐grained with a maximum grain size (MGS) between 0.98 mm and 1.82 mm, have a heteroblastic texture, and have curved to embayed calcite grain boundaries. ⁸⁷Sr/⁸⁶Sr values of marble leachates range from 0.708488 to 0.708639. Comparison with Hispanic and Mediterranean marbles suggests the Estremoz Anticline as the most likely source for the Ammaia marble, especially for architectural marble. This hypothesis is supported by the geographical proximity of the Estremoz marble district and the long and expensive overland transport required for other marbles to reach Ammaia.     

GEOCHEMICAL PROVENANCE OF OBSIDIAN ARTEFACTS FROM THE MSA SITE OF PORC EPIC,ETHIOPIA*

Obsidian geochemical analysis has become an indispensable tool in archaeological research and has wide applications. However, in spite of the abundance of geological and archaeological obsidian, there has been virtually no such investigation in Ethiopia. Recent instrumental characterization of 31 obsidian artefacts from the Middle Stone Age site of Porc Epic and numerous obsidian geological sources show that artefacts were being transported from as far as 250 km away. We believe this has relevance to the understanding of the emergence of modern human behaviour.