TL DATING OF BURNT LITHICS FROM BLOMBOS CAVE (SOUTH AFRICA): FURTHER EVIDENCE FOR THE ANTIQUITY OF MODERN HUMAN BEHAVIOUR*

This paper presents the first TL dates for burnt quartzites and silcretes from the Still Bay layers of Blombos Cave (South Africa). These layers contained engraved ochres and marine shell beads that could be an early manifestation of symbolic and thus ‘modern’ behaviour by the Middle Stone Age humans. The procedure devised to calculate the ages is presented in detail, particularly with regard to internal microdosimetry, because the problems faced in estimating the dose rates require an approach different from the one usually used on flints and sediments. A mean age of 74 ± 5 ka was obtained for five burnt lithics unearthed in the BBC M1 member of the Still Bay layers. This result is in good agreement with both ESR dates on teeth and OSL dates on sediment, and demonstrates the great antiquity of the archaeological remains discovered at Blombos Cave.     

ELECTRON SPIN RESONANCE ANALYSIS OF MARINE GASTROPODS FROM COASTAL ARCHAEOLOGICAL SITES IN SOUTHERN AFRICA

Shell samples of the marine gastropod Turbo sarmaticus have been examined to assess their potential for electron spin resonance (ESR) dating. The shells were found to be composed of aragonite. ESR analysis shows the presence of three radiation sensitive peaks. Equivalent dose (ED) values for two of the peaks have been determined for thirteen samples. When the two sets of ED values are plotted against each other, four distinct clusters are found that appear to represent four different age groups. The apparent age groups determined here are consistent with the stratigraphic record of the sites.     

ELECTRON SPIN RESONANCE STUDY OF WHITE MARBLES FROM THARROS (SARDINIA): A REAPPRAISAL OF THE TECHNIQUE,POSSIBILITIES AND LIMITATIONS*

The characterization of various samples of white marble from the archaeological site of Tharros (Sardinia) is the starting point for the reexamination of the capabilities of electron spin resonance (ESR) spectroscopy as a tool for identifying the quarries of origin of ancient marble artefacts. Existing methods and data bases are employed for the assignment of our samples, but also reviewed to see if a more extensive use of the technique is feasible. It turns out that ESR spectroscopy, coupled with other available methods, may readily provide valuable information, often yielding the final answer to the problem of marble provenance. However, it is also clear that much work has still to be done to standardize the data collection and analysis procedures and to expand the available data base.     

Characteristics of ESR signals and TLCLs of quartz included in various source rocks and sediments in Japan: A clue to sediment provenance

The variation of electron spin resonance (ESR) signal intensities and thermoluminescence colour images (TLCIs) of quartz was investigated in the present study for various rocks and sediments in Japan, to discuss the possibilities of identifying the sediment provenance. The ESR signal intensity of the E₁’ centre in the same grain size in granitic quartz varies from sample to sample, except for that in Quaternary samples of volcanic sediment, which is very low, close to the noise level. It was found that the diagram, ESR intensities of Al versus Ti-Li centre signal intensities, distinguish volcanic from the same grain size in granitic quartz as well as distinguish individual tephra from another. The TLCIs from volcanic quartz and some granitic quartz samples is almost red and that from the rest of granitic and metamudstone quartz is blue as results of TLCIs although the emission intensities are different. Our results suggest that examining the multiple-centre signal intensities of ESR and the TLCIs are effective to identify the source of quartz and to estimate the sediment provenance.     

THE CHRONOLOGY OF GROUPS OF DIES FOR LARGE ISSUES OF ANCIENT COINS USING MAHALANOBIS DISTANCES*

Discriminant analyses of distances and angles obtained from 25 coins struck by P. Crepusius in 82 BC permitted the correct chronology for five groups of closely-related dies to be obtained by the method of Carter and Frurip. Twenty distances and 15 angles were measured on 10 x projections of the coins which represented five groups of dies separated in time from each other. The use of all or many variables gave poorer results than the use of five to ten variables having a high ‘figure of merit’, defined as the maximum range of mean values for a given variable in the five groups of dies divided by the mean standard deviation of the variable in the five groups. It is recommended that chronologies of ancient coins be determined from Mahalanobis distances by using only variables of relatively high figure of merit.     

EVALUATION OF THE MANGANESE ESR METHOD OF MARBLE CHARACTERIZATION

Results suggest that ESR studies of Mn⁺² in marble can provide an excellent discriminator for the determination of marble provenance. In comparison with other methods of quantitative analysis for manganese such as AA or NAA, the ESR method determines only Mn⁺² rather than total Mn, is inexpensive and rapid with no chemical preparation required, and does not consume the sample.     

ESR and AMS-based 14C Dating of Mousterian Levels at Mujina Pećina,Dalmatia, Croatia

This paper presents the first chronometric dates for sediments that contain a Mousterian industry in Dalmatia (south Croatia). Electron spin resonance (ESR) dating was conducted on two teeth from the Mousterian level E1 at the site of Mujina Pećina. Additionally five bone and one charcoal sample from five different strata of origin at this site were dated by accelerator mass spectrometry (AMS). Assuming 30% moisture for both the gamma and beta dose rate calculations, the mean LU ESR age estimate is 44±5 ka for level E1, which is statistically indistinguishable from the mean EU ESR age estimate of 40±7 ka. A single, uncalibrated ¹⁴C age from the E1/E2 interface yielded an age estimate of 45,170 +2780/−2060 years bp while the mean of the five samples from overlying Mousterian levels is 39±3 ka. The true (calibrated) age of this mean is about 42 ka, which means that the entire stratigraphic profile in Mujina Pećina apparently was very rapidly deposited, and that the ESR age, regardless of uptake model is in good agreement with the calibrated ¹⁴C mean age. Temporally, Mujina Pećina overlaps with Pontinian Mousterian sites in west-central Italy and Vindija level G3 from northwestern Croatia. However, there are notable differences between the Mousterian industry from Mujina Pećina and these other sites. Collectively, the Croatian sites yield important evidence on the adaptation of European Mousterian people.     

INVESTIGATION OF THE COLOURING MATERIALS OF FUSTAT CARPET FRAGMENTS

The Benaki Museum (Athens, Greece) possesses 50 fragments that, according to its archives, are recorded as having a provenance in the Fustat area. The objects are divided into three groups on the basis of the techniques employed. Most (eight) of the objects included in the present study belong to group A (8th–11th centuries). A few (five) fragments belong to groups B and C, which include objects dated up to the 18th century. The goal is to identify the colouring compounds contained in microsamples removed from the selected Fustat carpet fragments. Identifications are achieved using high‐performance liquid chromatography (HPLC) with photodiode array detection (PDA). The following compounds are identified repeatedly in many samples: laccaic acid A and other laccaic acids (components of Kerria lacca, Kerr), alizarin, purpurin and rubiadin (madder components), luteolin, apigenin and chrysoeriol (components of Reseda luteola L.), and indigotin and indirubin (components of indigoid dyes). In one sample, the type C compound (marker compound for the identification of soluble redwoods, Caesalpinia trees) is identified. The HPLC profiles collected for the samples in which madder components are detected suggest that most probably Rubia tinctorum L. (and not Rubia peregrina L.) was used during dyeing.     

DATING OF THE HOMINID (HOMO NEANDERTHALENSIS) REMAINS ACCUMULATION FROM EL SIDRÓN CAVE (PILOÑA,ASTURIAS, NORTH SPAIN): AN EXAMPLE OF A MULTI‐METHODOLOGICAL APPROACH TO THE DATING OF UPPER PLEISTOCENE SITES

The age of Neanderthal remains and associated sediments from El Sidrón cave has been obtained through different dating methods (¹⁴CAMS, U/TH, OSL, ESR and AAR) and samples (charcoal debris, bone, tooth dentine, stalagmitic flowstone, carbonate‐rich sediments, sedimentary quartz grains, tooth enamel and land snail shells). Detrital Th contamination rendered Th/U dating analyses of flowstone unreliable. Recent ¹⁴C contamination produced spurious age‐values from charcoal samples as well as from inadequately pretreated tooth samples. Most consistent ¹⁴C dates are grouped into two series: one between 35 and 40 ka and the other between 48 and 49 ka. Most ESR and AAR samples yielded concordant ages, ranging between 39 and 45 ka; OSL dating results permitted adequate bracketing of the sedimentary layer that contained the human remains. Our results emphasize the value of multi‐dating approaches for the establishment of reliable chronologies of human remains.     

THE SIZE OF NATURE RESERVES AND COSTS OF THEIR MAINTENANCE

A paper devoted to nature reserve size in the USSR, and more specifically to whether the areas of such reserves are adequate in particular natural zones and for particular species, determines that too many zapovedniki presently are too small to carry out their intended functions properly. In fact, until quite recently, in spite of a dramatic expansion of the total area and number of nature reserves, average reserve size has decreased. A trend toward decreasing reserve size and increasing per hectare maintenance expenditures can be noted as the level of economic development characteristic of particular natural zones increases (translated by Jay K. Mitchell, PlanEcon, Inc., Washington, DC 20005).     

CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF SASANIAN AND EARLY ISLAMIC GLAZED CERAMICS FROM THE DEH LURAN PLAIN,SOUTHWESTERN IRAN*

One hundred and seventy‐five glazed ceramics from Sasanian and Early Islamic period sites located on the Deh Luran Plain in southwestern Iran were examined by instrumental neutron activation analysis for characterizing differences in ceramic pastes and by laser‐ablation inductively coupled plasma mass‐spectrometry for identifying the constituents of the ceramic glazes. The results of the analysis reveal that alkaline‐based glazed ceramics have paste compositions that are distinct from contemporary and later ceramics decorated with alkaline–low‐lead and lead‐based glazes.     

PARTICLE SIZE AND PHOSPHATE ANALYSIS-EVIDENCE FOR THE EVOLUTION OF A TELL

Soil samples were collected from a deep sounding through the centre of a tell, 11 m in height, at Sitagroi in north-eastern Greece. These samples were analysed for particle size and total phosphate in order to elucidate the formation of the tell. The phosphate results, though very varied, indicated that the tell evolved entirely as a result of occupation of the site. It is proposed that the main process of accumulation was from house collapse and that local alluvium was used for house construction. A similarity is shown between local alluvium, a remnant of a house wall and most of the samples from the deep sounding. Pearson type 1 curves are fitted to the particle size data and this permits a grouping of soil samples. Some of the divisions between the groups coincide not only with occupation phase changes but also with localized lower phosphate contents. Two periods of site abandonment are suggested.     

THE EFFECT OF LAND‐USE CONTROLS ON THE SPATIAL SIZE OF U.S. URBANIZED AREAS*

ABSTRACT On a sample of U.S. urbanized areas in 2000, we test theoretical hypotheses of the effect of land‐use controls on the spatial size of urban areas. We find that minimum lot‐size zoning and maximum FAR restrictions expand the urban area, while maximum lot‐size zoning, urban growth boundaries, minimum square footage limits, maximum building permit restrictions, minimum person per room controls, and impact fees contract the urban area. All of these findings are consistent with theoretical predictions although the effect of urban growth boundaries and minimum square footage limits are not statistically significant.     

PETROGRAPHIC AND GEOCHEMICAL EVIDENCE FOR LONG‐STANDING SUPPLY OF RAW MATERIALS IN NEOLITHIC POTTERY (MENDANDIA SITE,SPAIN)

Pottery from the Neolithic Mendandia site has been studied. The radiocarbon dating of the site corresponds to a range of dates from 7488–7546 cal bc to 5283–5437 cal bc : the first occurrence of pottery is dated at 5968–6040 cal bc for the lower level III, and up to 5386–5560 cal bc for level II. The antiquity of the potsherds places them within the oldest pottery production sequences in the Iberian Peninsula, which adds to the interest of this study. Ten potsherds from level II and five from level III are analysed for their petrographic and chemical characterization. The petrographic data show two different methods of raw materials manufacture—intentionally tempered pottery (ITP), using calcite and/or limestone and grog, and naturally or non‐intentionally tempered pottery (NTP). According to the matrix paste features, on the basis of the amount, shape, and average or size range of the mineral inclusions, clayed (type A) and sandy (type B) paste types were established and related to two different source areas. The chemical features also indicate two raw material sources and are in agreement with the petrographic paste types. The absence of significant chemical and mineralogical differences between the pottery from levels II and III suggests two contrasting areas for raw materials supply that lasted for at least 600 years.     

The craniology and relationships of four species of bos 1. Basic craniology: Bos taurus L. and its absolute size

This paper is the first of a series on the craniology of four species of Bos. Here (and in the next paper) Bos taurus in Britain is used to establish a basic craniology for the genus. In the initial sections notes are made on the nomenclature, material available, history, and age assessment of B. taurus. The subsequent section deals with the effects of sex, age and breed on absolute size.The results show that Bos taurus is very variable, particularly in the length of the horncore. Sex influences certain dimensions very greatly, particularly those of breadth. Although the horns of cows are often longer than those of bulls of the same breed the horncores may be shorter in cows. In studying the effects of age it can be seen that growth rates are initially very high, slowing down at about three years of age. Tooth row length decreases with age and hence it is a particularly unreliable indicator of size. Obviously breed affects size and it has been possible to divide the skulls studied into size groups which correspond well with known body weights.     

IDENTIFICATION OF JET AND RELATED BLACK MATERIALS WITH ESR SPECTROSCOPY

Recent studies of the thermal histories of archaeological materials with electron spin resonance (ESR) spectroscopy have been extended to black materials encountered in archaeology and in the conservation of antiquities. The ESR parameters of jet. charcoal and lampblacks are reported and comparisons made with a range of related materials Discrimination and characterization is achieved by simultaneous consideration of the three main parameters of the ESR signal due to radical carbon. This study is the first attempt using ESR spectroscopy to discriminate between jet and related coal-like substances.     

THE AMINOCHRONOLOGY OF MAN‐INDUCED SHELL MIDDENS IN CAVES IN NORTHERN SPAIN*

Here, we provide the first report on the ages of 54 archaeological levels in 38 caves in northern Spain by means of the aspartic acid d /l ratio measurements in Patella shells, with good results. For this purpose, we developed an age calculation algorithm that allows the numerical dating of deposits from other archaeological localities in the area and nearby regions. We conclude that the sample size—that is, the number of shells analysed within a single level—reinforces the importance of analysing numerous specimens per horizon and the understanding of the time‐averaging concept. The ultrastructure of different species of Patella shells was also studied, showing calcite in their apexes and aragonite at their margins.     

THE COMPLEMENTARY USE OF NEUTRONS AND X‐RAYS FOR THE NON‐DESTRUCTIVE INVESTIGATION OF ARCHAEOLOGICAL OBJECTS FROM SWISS COLLECTIONS*

This paper shows the possibilities offered by the combined use of non‐destructive neutron and X‐ray beams in archaeological research on metallic finds. The following five artefacts from Swiss excavations were submitted to investigation, each with dedicated aims: a Roman sword, a Roman dagger, an Iron Age bucket, Iron Age spearheads and a Roman finger ring. The images obtained with both methods—neutrons and X‐rays—are discussed in length in this paper. The investigations took place at the Paul Scherrer Institute and the archaeologists who studied the objects come from the Universities of Lausanne and Zurich.     

INVESTIGATING SEASONALITY AND SEASON OF BIRTH IN PAST HERDS: A REFERENCE SET OF SHEEP ENAMEL STABLE OXYGEN ISOTOPE RATIOS

Intra‐tooth sequential analysis of enamel δ¹⁸O is currently used to investigate birth seasonality in past animal populations, offering new insights into seasonal availability of animal resources, herd management and seasonality of site occupation. Reference data sets are still required to address two major difficulties: (1) that inter‐individual variability in the record of the seasonal cycle is affected by tooth size; and (2) that the season of birth cannot be directly estimated from the timing of tooth growth, because of a delay in enamel mineralization. We present a data set acquired on the lower second molar of 10 modern sheep from Rousay (Orkney) born within a few weeks of each other in April/May and submitted to the same environmental conditions until death. All sheep have recorded a sinusoidal pattern of δ¹⁸O variation spanning approximately a year. From the difference between the expected and the measured time sequence, the delay of enamel mineralization is estimated to be 5–6 months. The data set is then described using a model mainly based on a cosine function. The period, corresponding to the length of the M2 crown formed over a year, averaged 35.8 mm. A very slight variation of tooth growth rate with time and no attenuation of the isotopic signal towards the cervical margin of the crown could be detected in this data set. The lowest δ¹⁸O values, corresponding to the sheep's first winter, were tracked at a distance from the enamel/root junction that varied between 23.0 and 30.3 mm (x_min mean = 27.6 mm); the highest δ¹⁸O values, corresponding to the sheep's second summer, were between 6.3 and 11.6 mm (x_max mean = 9.9 mm). Most of the variability can be attributed to tooth size. When normalized on the period, x_min and x_max are 0.28 (± 0.05) and 0.78 (± 0.05) on average, meaning that the Rousay sheep have recorded the minimum and maximum δ¹⁸O values on average at 78% and 28%, respectively, of the end of the periodic cycle recorded in the second molar.     

ARCHAEOLOGICAL AMBERS FROM NORTHERN ITALY: AN FTIR–DRIFT STUDY OF PROVENANCE BY COMPARISON WITH THE GEOLOGICAL AMBER DATABASE*

European geological ambers of five different localities and types, and Italian geological ambers from seven different deposits have been studied with Fourier transform infrared spectroscopy (FTIR) and diffuse‐reflectance infrared Fourier transform (DRIFT). Ambers from several localities have been characterized for the first time. The research aims to create a database of European ambers, containing both FTIR and DRIFT data. The FTIR spectra are easily comparable with the data commonly available in the literature, whereas DRIFT analyses are shown to be more useful to characterize the archaeological finds. The provenance of several archaeological ambers from northern and southern Italy, dating from the Middle Bronze Age to the Iron Age, is assessed on the basis of the developed database. Of the 35 analysed archaeological objects, all but five are composed of Baltic succinite amber.