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1.
Studies on Old South Arabian (OSA) coinage are rare and state‐of‐the‐art materials analysis for them lags far behind that of ancient Greece and Rome. Understandably, numismatists responsible for preserving their collections discourage destructive analyses. We have selected coins of the aesthetically and technically developed Himyarite Royal Raydan series (early first to late second century ce ), so‐called Old and New Style Athenian Imitations, among others to provide a wide spectrum of information on OSA coinage. We used non‐destructive neutron diffraction to ascertain the metal compositions and corrosion products. Density determinations using gas‐pycnometry support these experiments. The results provide detailed information with regard to a small, apparently homogeneous, selection of 10 Himyarite period specimens and first insights into the actual and the original metal compositions of about 90 coins of the three main OSA numismatic groups. The analytical results make clear which OSA coins originally were struck and which ones were cast. The analyses provide not only detailed information concerning the manufacture of the selected representative coins, but also suffice to cast a shadow on the reliability of commonplace macro‐optical classification, which proves often to be inaccurate. 相似文献
2.
The probability of nuclei capturing neutrons reveals sharp peaks, so‐called ‘resonances’, which occur at neutron energies that are specific for each element. These resonances are very suitable for analysing the elemental composition of objects. They are the basis of a new analytical method, ‘neutron resonance capture analysis’ (NRCA). This is a fully non‐destructive method, which is applicable to almost all stable isotopes, determines the bulk elemental composition, does not require any sample preparation and results in a negligible residual activity. Recently, NRCA has been applied in a study of a series of bronze statuettes, obtained from the National Museum of Antiquity in Leiden (NL). 相似文献
3.
S. SIANO L. BARTOLI J. R. SANTISTEBAN W. KOCKELMANN M. R. DAYMOND M. MICCIO G. DE MARINIS 《Archaeometry》2006,48(1):77-96
Non‐destructive neutron diffraction techniques were applied to determine composition and microstructure data, and hence to derive information on manufacturing techniques of Picenum bronze artefacts. Furthermore, texture analyses were carried out on standards and suitable ancient artefacts to investigate their potential role in archaeometallurgical studies. This is a first step towards an overall characterization of the bronze collection of the Marches National Museum of Archaeology, Italy, and the analytical demonstration of relations with and differences compared to Etruscan metallurgy. The work is also an example application of the powerful non‐destructive archaeometrical approaches provided by time‐of‐flight neutron diffraction. 相似文献
4.
E. FRAHM 《Archaeometry》2012,54(4):623-642
Despite predictions in the 1980s that electron microprobe analysis (EMPA) would become a popular technique for obsidian sourcing, few studies have used it with this goal, and most of them are now outdated and unrepresentative of modern EMPA. For example, Merrick and Brown (1984 ) recorded their data on punch cards. Furthermore, these studies destructively prepared artefacts for analysis. The research at hand endeavoured: (1) to establish the modern capabilities of EMPA for obsidian sourcing; and (2) to develop and evaluate procedures for non‐destructive artefact analysis. Issues such as diagenetic effects and compatibility with NAA and XRF data were also investigated. 相似文献
5.
This paper explains, with the example of a Roman object (the ‘Mars from Oberweningen’, Switzerland), why neutrons can be used preferentially for the non‐destructive analysis of metallic objects of relatively large size. This method is superior to the conventional X‐ray tomography method due to the higher penetration ability in metals such as copper, tin and even lead. With this method, differing materials can also easily be differentiated. In this way, the inner and outer structures of objects can be observed with the help of tools based on mathematical algorithms. Slices at arbitrary positions and segmentation of different material clusters aid the understanding of manufacturing processes and can describe the present preservation status. This helps in selecting optimal and additional conservation measures in museums for further preservation. Beside the qualitative overview on structure and inner properties of the objects, quantitative information can be derived about material content and composition. This method and the subsequently needed facilities for this method are available at PSI for similar studies on demand. 相似文献
6.
D. A. Scott 《Archaeometry》2001,43(4):475-482
The use of a new analytical technique for the elemental characterization of artefacts is described. The new equipment is capable of X‐ray fluorescence analysis in conventional mode as well as for elemental scanning of small objects, fragments or microsamples. The Omicron, manufactured by Kevex Instruments Inc., is equipped with a microfocused X‐ray tube, which can be collimated to a 50 μ beam and used to scan objects over a maximum range of 256 × 256 pixels. False‐colour elemental distribution maps allow the user to image small features, differently pigmented areas, or whole objects in the machine completely non‐destructively. Analyses can be carried out in air, under helium or in vacuum. Two examples of the application of the new technique are described: first, to the surface decoration on a Greek Attic white ground lekythos; and, second, to the pigments used on a small painting, a ‘Pittura’, on copper by the Dutch artist, Frans van Mieris (1635–81) in the collections of the J. Paul Getty Museum. 相似文献
7.
The results of the lead isotope analysis (LIA) of 15 copper‐base artefacts from the Bronze Age site of al‐Midamman, Yemen, are reported. The LIA data suggest the existence of an indigenous Bronze Age metal production and exchange system centred on the southern Red Sea region, distinct from those in neighbouring regions of Arabia and the Levant. These preliminary results are highly significant for the archaeology of the region, suggesting that local prehistoric copper extraction sites have thus far gone unrecorded, and highlighting the need for systematic archaeometallurgical fieldwork programmes in the countries surrounding the southern Red Sea. 相似文献
8.
Many important cultural and religious objects from Asia consist of outer metallic shapes, usually bronze, which fully enclose inner contents made of organic materials such as wood, bark, paper, textile, plants and others. Bronze and other metallic materials, such as copper and silver, are generally more transparent to neutrons than to X‐rays. However, organic materials are less transparent to neutrons than to X‐rays and therefore organic materials, enclosed by metallic materials, can be made visible with neutrons. Therefore, neutron imaging (radiography and tomography) was found to be an ideal tool for the inspection of objects that consist of metal outside and organic materials inside. This has been successfully demonstrated here with four metallic Tibetan Buddha statues, providing archaeometry with a powerful new tool. The first successful applications of this novel technique are described in this article. Further possible and useful applications of neutron imaging of cultural objects are outlined. 相似文献
9.
Ancient glass vessel fragments belonging to the seventh to ninth centuries ad , from the Ko Kho Khao, Laem Pho and Khuan Lukpad sites in southern Thailand, were studied. The glass vessel fragment samples are a collection belonging to the Department of Archaeology, the 15th Regional Office of Fine Arts of Thailand. The chemical compositions of the glasses were analysed using a modified portable energy‐dispersive X‐ray fluorescence spectrometer (OURSTEX 100FA‐II) by the introduction of a MOXTEK® AP3.3 polymer window (5 mm2?) to the KETEK silicon drift detector for the measurement of light elements. The non‐destructive analysis was performed at the National Museum, Phuket, in Thailand. It is shown that the glass chemical compositions belong to mineral and plant‐ash based soda–lime–silicate glass. The origins of the glass artefacts are discussed in terms of raw materials and glass decoration, and compared with previously reported similar typological glasses from sites in the port city of Rāya and the Monastery of Wadi al‐Tur in Egypt. 相似文献
10.
Fe K‐XANES spectra of a series of pottery sherds excavated from the archaeological site of Kaman‐Kalehöyük, Turkey, were measured to reveal the firing technique of the pottery. The analysis disclosed relationships among the chemical form of the iron, the firing conditions and the colour of the pottery. The pottery referred to as ‘Grey Ware’ found at this site was classified into two groups according to the chemical form of the iron. Also, it was revealed that the Iron Age pottery referred to as ‘Cream Ware’ was produced first under reducing conditions, and then fired under oxidizing conditions. 相似文献
11.
J. Buxeda I Garrigs R. E. Jones V. Kilikoglou S. T. Levi Y. Maniatis J. Mitchell L. Vagnetti K. A. Wardle S. Andreou 《Archaeometry》2003,45(2):263-284
The study of technology transfer in pottery production to the periphery of the Mycenaean world has been addressed by considering two different areas, southern Italy and central Macedonia. Technological features such as ceramic paste, decoration and firing have been determined for different ceramic groups established according to provenance criteria. The studies of technology and provenance have been performed following an archaeometric approach, using neutron activation analysis, petrographic analysis, X‐ray diffraction and scanning electron microscopy. The results have revealed the existence of two different models. On the one hand, southern Italy seems to exhibit a more organized pottery production, which follows a Mycenaean‐like technology, while in central Macedonia production is probably more varied, being based in part on the technology of the local tradition. 相似文献
12.
Fifty‐eight porcelain samples in Guan ware style from the collections of the Palace Museum in Beijing were analysed using non‐destructive ED‐XRF. These included 40 vessels that were traditionally ascribed as Guan wares of the Song Dynasty, and 18 vessels traditionally ascribed as imitation Guan wares, made during the Ming and Qing Dynasties. The purposes of this study were: (1) to cross‐check the traditional identification of these wares with the new classification based on their chemical compositions; and (2) to carry out a provenance study of the authentic Song Guan wares—that is, to compare the chemical compositions of the authentic Song Guan wares with those of the shards unearthed from the known Guan ware kilns of the Song Dynasty. This study shows that: (1) the chemical compositions of the glaze are significantly different between the Song Guan wares and the imitation wares—among the 58 wares tested, seven are likely to have been misidentified by the traditional method; and (2) the glaze compositions of the authentic Song Guan wares themselves are not homogeneous, and they can be divided into three groups. The provenance of these groups was briefly investigated. 相似文献
13.
The application of FT‐Raman spectroscopy and visible Raman microscopy to the non‐destructive analysis of pigment specimens excavated from Tell el Amarna by Flinders Petrie in the 1890s has provided information about the chemical composition of the materials used by XVIIIth Dynasty artists in the New Kingdom at the time of King Akhenaten, c. 1340 bc. Comparison of the Raman spectra of the samples labelled ‘red and yellow ochre’ with documented, archival material from geological collections provided a clear indication of the materials used in the iron(III) oxide/hydroxide system, including α‐hematite, goethite, maghemite, magnetite and lepidocrocite. The yellow–orange specimen labelled ‘realgar’ proved to be a mixture of realgar and pararealgar; since the specimen had been sheltered from light since its excavation, this could indicate that the ancient Egyptian artists recognized the colour variation and may have used this to effect in their decorations. A specimen of yellow ochre contained goethite, α‐FeO.OH, with particles of crystalline, highly ordered graphite; in contrast, the red ochre specimens contained amorphous carbon particles. 相似文献
14.
This paper shows how visual analytics methodology can be used to facilitate interpretation of multi‐temporal thermographic imagery for the purpose of restoration of cultural heritage. We explore thermographic data in a visual environment from the unifying spatio‐temporal perspective in an attempt to identify spatial and spatio‐temporal patterns that could provide information about the structure and the level of decay of the material, and the presence of other physical phenomena in the wall. The approach is tested on a thermographic dataset captured on the façade of a Romanesque building from the 13th century—the Cathedral in Matera (Italy). 相似文献
15.
Among the Nigerian cast copper‐alloy artefacts, the chronology of the Benin memorial heads has been the most fully worked out. Therefore, a study focused upon their elemental compositions is particularly likely to be interpretable in terms of development of the alloys used in their making. The elemental analyses, both published and unpublished, of 66 Benin heads, supplemented with seven analyses of some artefacts excavated from a well‐dated, very early Benin site, have been collected, analysed statistically and computed to the elemental analyses of 11 heads and figures from Udo. All but a very few of the Benin heads and artefacts separate into five compositional groups, indicating a chronological sequence of different alloying traditions. All but one of the Udo objects fall into a distinctly separate compositional group, together with two Medicine heads. The compositional groups correlate remarkably well with the stylistic types proposed by Dark. 相似文献
16.
On experimentally fired briquettes made of five chemically and mineralogically different clays, trace element concentration profiles from the centre to the surface of the briquettes have been measured by Neutron Activation in order to examine if drying and firing of the clays lead to a mobilization and subsequent migration of single components within a sherd. Mineralogical changes during firing have been determined by X‐ray diffraction. Generally, no such migration could be found. For two clays, arsenic was lost from the briquette during firing, forming non‐constant concentration profiles. If NaCl is present in the clay paste, sodium migrates towards the surface. Additionally, in the special case in which the presence of NaCl coincides with that of calcite, the heavier alkali elements evaporate, forming significant concentration profiles within the sherd. 相似文献
17.
The approaches of comparative studies and profile measurements, often used in order to detect post‐depositional alterations of ceramics, have been applied simultaneously to two sets of Roman pottery, both of which include altered individuals. As analytical techniques, Neutron Activation Analysis and X‐Ray Diffraction have been used. Both approaches lead to substantially different results. This shows that they detect different levels of alteration and should complement each other rather than being used exclusively. For the special process of a glassy phase decomposition followed by a crystallization of the Na‐zeolite analcime, the results suggest that it changes high‐fired calcareous pottery rapidly, and so fundamentally that the results of various archaeometric techniques can be severely disturbed. 相似文献
18.
Portable gamma ray spectrometry (PGRS) provides a non destructive means to analyst quantitatively large artefacts, such as building stones, for the radioelements K. U and Th. Nine Raman granitoid columns at the Leptis Magna Ruins in Windsor Great Park, London, were measured in situ by PGRS. Corrections for the environmental background contribution to the gamma ray flux measured, and for the shape and size of the columns, are described Comparison of the PGRS data with a radioelement data base for Roman granite sources indicates that most of the columns originated in the Troad area of Turkey. Two columns could not be unambiguously provenanced using PGRS alone because there is insufficient difference between radioelement concentrations in certain sources. However, non‐destructive measurements of magnetic susceptibility, used in conjunction with PGRS data, suggest that these two columns originated in the Kozak Daǧ, also in Turkey. 相似文献
19.
C. M. BELFIORE P. M. DAY A. HEIN V. KILIKOGLOU V. LA ROSA P. MAZZOLENI A. PEZZINO 《Archaeometry》2007,49(4):621-653
Pottery from the Late Minoan I kiln at Haghia Triada in the Mesara Plain, southern Crete, was analysed by a range of techniques, comprising thin‐section petrography, scanning electron microscopy, X‐ray diffraction, X‐ray fluorescence and neutron activation analysis. The project characterizes the ceramic fabrics and probable raw materials, correlates paste recipes with shape, reconstructs the firing conditions of the kiln and establishes a chemical reference group, taking into account post‐burial alteration and contamination. Comparison of the reference group formed with that from the neighbouring, broadly contemporary, kiln at Kommos shows an unexpected differentiation of the two kilns. 相似文献
20.
The restoration of a Greek black‐figure amphora provided an opportunity to study the provenance and production technology of the vase. The composition of the ceramic body, determined by inductively coupled plasma optical emission spectroscopy (ICP–OES), matches that of Attic products. Investigation by X‐ray diffraction and reflectance spectroscopy suggests a maximum firing temperature around 900°C and a body re‐oxidation temperature around 800°C, respectively. The morphology and composition of black, red and dark red surface areas were studied by scanning electron microscopy and X‐ray energy‐dispersive analysis; the black areas show the features of a typical well‐vitrified black gloss, while the red areas were most probably obtained by simple burnishing of the body; the dark red additions, on the other hand, are the likely result of a partial re‐oxidation of a clay–ochre mixture. 相似文献