A STUDY ON LATE MEDIEVAL TRANSPARENT‐GLAZED POTTERY AND ARCHAIC MAJOLICA FROM ORVIETO (CENTRAL ITALY)*

Nineteen samples of medieval transparent‐glazed pottery and archaic majolica from Orvieto (central Italy) were studied. They were classified by archaeological criterion as follows: five transparent‐glazed fragments with green and brown decorations (first half of the 13th century), eight green transparent‐glazed fragments (13th century) and six tin‐glazed fragments with green and brown decorations (second half of the 13th century). SEM–EDX, XRD (the Rietveld method) and XRF were used to characterize the chemical and mineralogical compositions both of the bodies and the coatings. In all of the samples, the paste is Ca‐rich with CaO contents as high as 13–20 wt%. The mineralogical composition is compatible with a firing temperature of about 950°C, which is the typical temperature reached in a wood kiln. No difference was observed between the bodies of transparent‐ and tin‐glazed pottery. In the case of transparent glazes, the burial conditions lead to heavy weathering of the samples. However, on the basis of the analyses carried out in non‐weathered areas, the typical composition is PbO 55–65 wt%, SiO₂31–35 wt%. In tin glazes, the tin is scattered on the mass of the glaze as SnO₂crystals with a concentration of 7–14 wt%. Concerning the decorations, it is established that the green colour is due to the presence of copper, while manganese is responsible for the brown colour. These pigments, which represent the typical colours of ‘archaic majolica’, are spread through the glaze homogeneously, apart from one case in which there is clear evidence of manganese oxide crystals.     

CAMPANIAN POTTERY FROM ANCIENT BRUTTIUM (SOUTHERN ITALY): SCIENTIFIC ANALYSIS OF LOCAL AND IMPORTED PRODUCTS*

One hundred and fifty-seven sherds of Campanian pottery were analysed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and flame emission spectroscopy (FES). The sherds were found in the course of archaeological excavations carried out at the sites of Sibari, Cosenza, Crotone, Locri, Reggio and Oppido Mamertina in southern Italy (ancient Bruttium, today Calabria). Analyses were carried out on dissolved samples, determining 15 elements per sample (Al, Fe, Ca, Mg, Ti, Mn, Sr, Ba, Cr, Cu, Y, La and Sc by ICP-OES, and Na and K by FES). Analytical data were subject to multivariate statistical treatment by hierarchical cluster analysis and principal components analysis. Results indicated different compositional groups, allowing one to separate suspected imports from Campania, Etruria and Sicily from each other and from likely local products. The latter could be further classified into different groups, comprising imitations of foreign forms as well as original local products.     

THE DETERMINATION OF BRICK PROVENANCE AND TECHNOLOGY USING ANALYTICAL TECHNIQUES FROM THE PHYSICAL SCIENCES*†

This work applies established analytical techniques from the physical sciences to Irish brick, in order to gather evidence of ceramic technologies, provenance and sources of raw materials. Petrographic microscopy, X‐ray diffractometry and scanning electron microscopy with an energy‐dispersive X‐ray diffraction attachment were used to study the brick of Rathfarham Castle, Dublin, built c. 1618, where clay brick was introduced in 1771. Local clay was fired in the laboratory and analysed in a similar manner. The petrography of the pointing mortar was studied in order to gather evidence of ceramic provenance. This paper concludes that the brick was hand‐ moulded with a silica‐based, predominantly non‐calcareous clay of glacial origin, gathered locally, including fluxes and a high percentage of non‐plastic material. The mineralogy and petrography of the brick, together with the presence of pebbles and a coarse matrix, suggest that the raw clay was probably gathered from a glacial deposit. The presence of abundant pebbles and colour inhomogeneities suggests a lack of processing of the raw clay. The brick was probably fired in clamps at top firing temperatures ranging from 750°C to above 900°C. Transformation of limestone temper involving the breakdown of calcite and the generation of calcium silicates, and the new formation of plagioclase, high‐temperature quartz, hematite and spinel were revealed. The presence of spinel in ‘hot spots’ indicates that fuel was added to the raw clay in order to assist firing.     

THE SECTILIA PANELS OF FARAGOLA (ASCOLI SATRIANO,SOUTHERN ITALY): A MULTI‐ANALYTICAL STUDY OF THE RED,ORANGE AND YELLOW GLASS SLABS*

SEM–EDS, EMPA, ICP–MS and ICP–OES were applied to the study of three sectilia panels made of red, orange and yellow glass slabs. In order to determine the chemical state of Cu, XAS was also performed. The results indicate that, with the exception of the red samples, all slabs were made by mixing a siliceous sand with natron. The red slabs show significant compositional differences with respect to K₂O and MgO contents, probably linked to the use of plant ashes as a source of alkali. The red, orange and yellow slabs are coloured by metallic copper, cuprite and Pb antimonates, respectively. The comparison between the chemical composition of the Faragola samples and several glass reference groups did not provide conclusive evidence of provenance.     

GLAZED CERAMIC MANUFACTURING IN SOUTHERN TUSCANY (ITALY): EVIDENCE OF TECHNOLOGICAL CONTINUITY THROUGHOUT THE MEDIEVAL PERIOD (10TH–14TH CENTURIES)*

Archaeometric investigation allowed the characterization of two important classes of ceramics: ‘vetrina sparsa’ and ‘invetriata grezza’. Their archaeological peculiarity makes them particularly suited for tracing the evolution of glaze manufacturing in southern Tuscany throughout the medieval period (10th–14th centuries). These ceramics were found in different sites of historical importance, and also from a mining perspective. Local copper, lead, zinc and iron mineralizations supported the growth of several settlements in the vicinity of the mines. The many castles and different archaeological finds (ceramics, glazed ceramic, slag etc.) attest to the intense mineral exploitation of the area from at least the first millennium bc up to the modern period. In light of these geological and archaeological characteristics, archaeometric investigation was intended to provide insight into ancient technical knowledge of ceramic glazing and to determine the source area for raw materials in the medieval period (10th–14th centuries). Ceramic bodies were analysed through OM, XRDp, SEM–EDS and XRF, while coatings were investigated through SEM–EDS. Mineralogical, petrographic and chemical analyses revealed slightly different preparation and firing processes for the two classes of ceramics. These data suggest the continuity through the centuries of the ‘vetrina sparsa’ and ‘invetriata grezza’ production technology. The mineralogical phases, such as monazite, xenotime, zircon, barite, Ti oxide, ilmenite, titanite, tourmaline and ilvaite, and the lithic (intrusive and volcanic) fragments detected within the ceramic bodies suggest a source area in the vicinity of the Campiglia mining district. Lastly, the presence of Cu–Zn–Pb (Ag) and Fe sulphide mineralizations (materials used to produce glaze) in the area supports the hypothesis of local manufacture.     

COMPOSITION AND ORIGIN OF IAPYGIAN POTTERY FROM ROCA VECCHIA,ITALY

We have studied 35 samples of fragments of ceramic containers dated between the eleventh and the eighth centuries BC, found at the archaeological site of Roca Vecchia, some 20 km from Lecce along the Adriatic (Salentine) coastline. Analysis of the elemental composition of the finds has been performed by means of atomic emission spectroscopy in plasma and the results obtained have been treated with diverse multivariate statistical techniques. Except for some minor differences, the statistical analysis confirms the grouping structures indicated by typological and stylistic evaluations of the samples, in accordance with the validity of the above methods.     

THE SECTILIA PANELS OF FARAGOLA (ASCOLI SATRIANO,SOUTHERN ITALY): A MULTI‐ANALYTICAL STUDY OF THE GREEN,MARBLED (GREEN AND YELLOW), BLUE AND BLACKISH GLASS SLABS

Analyses at the Cu–K, Fe–K and Mn–K edge were performed to study the green, marbled (green and yellow), blue and blackish (deep greyish olive green) glass slabs decorating three sectilia panels from the archaeological site of Faragola. Results indicate that all slabs were made by mixing siliceous sand with natron, sometimes probably mixed with small percentages of plant ash. Cu²⁺ and Pb antimonates should be responsible for the opaque green colours. The dark green and yellow portions of the marbled slabs are respectively comparable to the slabs comprising only one of these colours. Cu²⁺ together with Ca antimonates probably produced light blue slabs, whereas cobalt was used to produce dark blue slabs. We consider it possible that the abundance ratio of Fe²⁺/Fe³⁺ and the complex Fe³⁺S^2? would have an effect on the blackish slabs. The contribution of Mn cannot be ascertained even if it could have played a role in darkening glass colour. The comparison between the chemical composition of Faragola samples and several glass reference groups provided no conclusive evidence of provenance; whereas, the presence of a secondary local workshop can be hypothesized.     

QUICK ESTIMATES OF SOFT SEDIMENT THICKNESSES FROM AMBIENT NOISE HORIZONTAL TO VERTICAL SPECTRAL RATIOS: A CASE STUDY IN SOUTHERN ITALY

An approach devoted to quickly assess the thickness of soft sedimentary cover in areas of unknown subsurface morphology is applied in this study. In particular, soil thickness (h) is derived by combining estimates of the resonance frequency (f _r ) relative to soft sediments with the local shear-wave velocity (V_s) profile. For this purpose, (f _r ) values are assessed from horizontal to vertical (H/V) spectral ratios of seismic noise recordings and the (V _s ) profile is obtained by considering information from shallow seismic surveys. Results obtained for a Quaternary sedimentary basin in Southern Italy are discussed. Since in the investigated area only weak independent constraints are available, special emphasis is given to the assessment of uncertainties involved in this estimate of soil thickness.     

CERAMIC SHELL CUP EFFIGIES FROM ILLINOIS AND THEIR IMPLICATIONS

Abstract

Ceramic effigies of marine shell cups have long been known from Mississippian sites in Illinois and elsewhere in the Southeast, and have been included in studies of other ceramic effigies, such as animal figures and head pots (Holmes 1886). This paper focuses on 31 known Illinois specimens. I will show that, in Illinois, the geographic range of these effigies is primarily restricted to the American Bottom around Cahokia, and their occurrence is largely limited to Late Mississippian Moorehead and Sand Prairie phases (A.D. 1200 to 1400). I also explore possible meanings of shell cups and, by extension, ceramic effigies of shell cups. Ethnohistoric as well as archaeological evidence show that lightning whelk cups and, by analogy, shell cup effigies functioned in contexts of uncertainty and conflict, consistent with their context in Illinois.     

A CHALCOLITHIC MACE HEAD FROM THE NEGEV,ISRAEL: TECHNOLOGICAL ASPECTS AND CULTURAL IMPLICATIONS

An interdisciplinary case study of the role of technology in ancient society is presented here based on a single copper object from the beginning of metallurgy in Israel during the late fifth to fourth millennium BC. This research is based on a combination of typological, chronological and technological analyses. The mace head is made of copper alloyed with arsenic and antitmony, cast in a ‘lost wax’ technique over a stone core. The metallurgical, metallographic and petrographic analyses not only help reconstruct the production technology but also shed light on fundamental questions concerning the origin, ore selection and function of this sophisticated type of metal production in prehistoric society.     

FLEXIBLE SPECIALISATION AND SMALL FIRMS IN ITALY: MYTHS AND REALITIES

This paper offers a critical evaluation of the ‘Flexible Specialisation’ model which asserts that a new and dominant model of industrial organisation based upon craft principles is emerging, or can be nurtured in places where it does not yet exist. Drawing upon recent evidence from Italy, the country whose economic resurgence around small firms has become a cornerstone for the flexible specialisation thesis, the paper argues that there is little cause for the thesis's optimism for small flexible firms and their emancipatory role for the working class.     

CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF SASANIAN AND EARLY ISLAMIC GLAZED CERAMICS FROM THE DEH LURAN PLAIN,SOUTHWESTERN IRAN*

One hundred and seventy‐five glazed ceramics from Sasanian and Early Islamic period sites located on the Deh Luran Plain in southwestern Iran were examined by instrumental neutron activation analysis for characterizing differences in ceramic pastes and by laser‐ablation inductively coupled plasma mass‐spectrometry for identifying the constituents of the ceramic glazes. The results of the analysis reveal that alkaline‐based glazed ceramics have paste compositions that are distinct from contemporary and later ceramics decorated with alkaline–low‐lead and lead‐based glazes.     

ETHNICITY AND THE RURAL ECONOMY: ILLUSTRATIONS FROM SOUTHERN MANITOBA, 1961–1971

V ariation in behaviour stemming from cultural differences has long been recognized as a possible key influence on attitudes towards economic development. The seminal work of Max Weber (1958) relating economic performance to religious allegiances is an obvious example. However, variations in the attitudes of economic actors may also derive from differences in endowments stemming from ethnic heritage. In Canada, for instance, the role of the British group in dominating corporate directorships has been well documented (Porter 1957) and is of special significance in a nation attempting to establish a balanced power situation between its Anglophone and Francophone elements. The problems of attaining cultural equality in Canada are, of course, compounded by the concentration of the Francophone element in Quebec and this spatial concern introduces new complexities in prescribing solutions.     

PASTE CHARACTERIZATION OF WEEDEN ISLAND POTTERY FROM KOLOMOKI AND ITS IMPLICATIONS FOR SPECIALIZED PRODUCTION

Abstract

We report the results of a petrographic analysis of pottery from Kolomoki, a Middle and Late Woodland period mound and village complex in southwestern Georgia. Thin sections of 65 sherds representing several prestige and utilitarian Weeden Island pottery types, from both domestic (midden) and ceremonial (mound) contexts, were obtained. For comparison, we also analyzed samples from a few potential clay sources. We characterize the range of variability in paste/resource groupings present in the Kolomoki assemblage and use these data to address patterns of manufacture and exchange of Weeden Island pottery through comparisons to thin sections of comparable types from the McKeithen site and other Weeden Island sites in the region.     

THE CHEMICAL ANALYSIS OF ORIENTAL CERAMIC BODY COMPOSITIONS: PART 1: WARES FROM NORTH CHINA*

This paper presents the body analyses of 70 sherds of ceramics made in north China during the Late Tang and Northern Song dynasties (c. AD 80–1200). The major types represented are Ding, Xing and Cizhou-type wares. The analyses were obtained by atomic absorption spectrometry, giving information on nine major and minor constituents. These have been used to differentiate chemically between the major kiln sites in the north, with the aid of multivariate computer analysis. This has demonstrated that there are differing chemical characteristics associated with these kilns, but the study is hampered by the lack of authentic material from controlled excavations of the kiln sites.