Radiocarbon dating and the “old shell” problem: direct dating of artifacts and cultural chronologies in coastal and other aquatic regions

Archaeologists have long recognized the problem of the “old wood” effect in radiocarbon dating charcoal and wood samples, the age of which may be hundreds of years older than their use by humans. Such problems have resulted in significant changes in how most researchers select wood and charcoal samples for ¹⁴C dating, with many now using relatively short-lived carbonized materials for dating. Despite the significant strides made in our understanding of the potential biases of the “old wood” effect, little emphasis has been placed on the possible impacts of dating “old shell” in archaeological deposits. The use of marine shell for ¹⁴C dating is widespread in coastal areas around the world, including a growing emphasis on the dating of individual shell artifacts via Accelerator Mass Spectrometry (AMS). In dating shell artifacts, we have obtained several dates older than associated ¹⁴C dates for short-lived subsistence remains from the same deposits, including great disparities (>10,000 years) and more subtle differences (≥100 years). These discrepancies appear to be due to the use of old shells by humans to make beads and other artifacts, including shells collected from fossil deposits, older archaeological sites, and beaches. The problems caused by the use of old shells to make beads and other artifacts are surmountable through careful sample selection, analysis of multiple ¹⁴C dates on a variety of materials, and proper calibration procedures.     

Erosion and Errors: Testing the Use of Repeated LIDAR Analyses and Erosion Modelling for the Assessment and Prediction of Erosion of Archaeological Sites?

Slope soil erosion is one of the main threats to archaeological sites. Several methods were applied to establish the erosion rates at archaeological sites. Digital elevation models (DEMs) from three different dates were used. We compared the elevations from these three models to estimate erosion. We also applied the landscape evolution model LAPSUS with the available DEMs as basis. Spatial processing errors and effects of tillage and harvesting practices explain most of the DEM elevation differences between the recordings. Increased DEM resolution does not result in more precise or reliable erosion. The present technological level of landscape evolution modelling makes it possible to indicate areas most vulnerable to soil displacement by surface runoff erosion and tillage. Future research, using sediment and surface dating techniques such as deposit of radionuclides, heavy metals and OSL dating will provide a more accurate estimation of erosion rates and the subsequent impact on archaeological sites.     

The integration of chronological and archaeological information to date building construction: an example from Shetland,Scotland, UK

This paper presents new chronological data applied to the problem of providing a date for the construction of a prehistoric building, with a case study from the Old Scatness Broch, Shetland. The innovative methodology employed utilises the combination of radiocarbon and optically stimulated luminescence (OSL) dates with the archaeological information, which includes the stratigraphic relationships of sampled deposits, context information, and evidence relating to the formation of the deposit. This paper discusses the scientific validity of the dates produced, and the advantages that the methodology employed at this site offers for archaeological interpretation. The combined dating evidence suggests that the broch at Old Scatness is earlier than the conventionally accepted dates for broch construction. More broadly it shows the value of integration of the specialists at the planning stages of the excavation. The application of a Bayesian statistical model to the sequences of dates allowed investigation of the robustness of the dates within the stratigraphic sequences, as well as increasing the resolution of the resulting chronology. In addition, the value of utilising multiple dating techniques on the same deposit was demonstrated, as this allowed different dated events to be directly compared as well as issues relating to the formation of the sampled deposit. This in turn impacted on the chronological significance of the resulting dating evidence, and therefore the confidence that could be placed in the results.     

The Potential for Dating the Old Scatness Site,Shetland, By Optically Stimulated Luminescence

A series of deposits from the agricultural infield of the multiperiod settlement mound, Old Scatness, were investigated for their potential to yield optically stimulated luminescence dates. Luminescence properties of quartz grains were found to vary through the sequence, but dates were successfully obtained from five deposits, including anthropogenic soils, windblown sands and sands within midden deposits. Single‐aliquot equivalent dose measurement was found to be the most appropriate method for dating the deposits. The OSL dates obtained accorded well with the dates provided by archaeological evidence and included the post‐medieval, Iron Age, Bronze Age and Neolithic periods of Shetland, while a substantial midden was dated to the Bronze/Iron Age transition.     

BAYESIAN ANALYSIS OF PLEISTOCENE CHRONOMETRIC METHODS*

Bayesian analysis of radiocarbon dates on Holocene archaeological sites has become well established. Application to Pleistocene sites dated by multiple techniques would be advantageous. This paper develops the necessary mathematical apparatus in the form of likelihoods for luminescence dating, and uranium‐series dating, and considers the possibility for amino‐acid racemization dating. Application of the new methods is illustrated using the stratigraphic sequences of dates from the sites of Saint‐Césaire and La Chaise‐de‐Vouthon. For application to amino‐acid racemization dating, fuller publication of data is found to be required.     

Relation between radiocarbon,archaeological dating and sediment properties on the example of colluvial deposits (NE Poland)

This study focuses on the analysis of the structural and textural features of the colluvial (deluvial) deposits in the Suwałki Lake District (NE Poland) and their absolute age. The colluvium has a thickness of up to 150 cm. The dates of the peat under colluvium or lowermost fossil humus-rich horizons point to the ages from 5405±80 BP to 480 BP. Deposition of material at the footslope is a result of a denudation triggered by human action (surface water erosion and tillage erosion) and usually corresponds with the settlement stages. The ¹⁴C dating of deposited sediment sometimes indicated to older dates of colluvium then the archaeological evidence available for examined sites. Locally, the overlying fossil humic horizon was older then the lowermost one. The textural features of the colluvial deposits such as: the content of fine fraction, weak sorting and relationship between the mean grain-size (Mz) and the sorting index (σ₁) were used to recognize sediment redeposited from the upper part of the slope. Basing on the mineral composition and electrical conductivity of fossil humus horizon it is possible to say whether the soil was degraded or aggraded. These features of the humus-rich horizons occurring between colluvial sediments can be used to explain discrepancy between the radiocarbon dating and archaeological evidence.     

Problems in the interpretation of radiocarbon dates: the Pastoral Neolithic of East Africa

For the Pastoral Neolithic of East Africa radiocarbon dates suggest two apparent anomalies in the archaeological record: pastoralism in the Central Rift at perhaps 7000 bp, and the very long duration of particular pottery traditions. This paper examines the dating evidence closely, in particular the assertion that apatite gives more reliable dates than collagen. Both the assertion and the anomalies appear to be false. It is shown that there is no firm evidence for pastoralism in East Africa before about 4000 bp. Similarly, the Narosura tradition is of shorter duration and more recent than previously supposed. The meagre dating evidence for the Namoratunga sites and its implications are also assessed. Examination of the dates for the Pastoral Iron Age shows that the Turkwel tradition is dated only by a single date and that the appearance of twisted cord rouletted pottery in the present millennium post-dates the end of stone tool manufacture by several centuries. The paper concludes with a plea for more critical assessment of radiocarbon dates and for greater rigour in their presentation.     

Thermoluminescent dating of the Late Bronze and Early Iron Age pottery on sites in Kłyżów and Jarosław (SE Poland)

The absolute chronology of Late Bronze and Early Iron Ages in Polish territories is a result of long-term and complex research. Here, we have investigated the absolute dating of two sites, namely K?y?ów, a cemetery of the Tarnobrzeg Lusatian culture, and Jaros?aw, a settlement spanning from the late phase of the former to Pomeranian culture, possibly with Jastorf elements. Having been spurred by promising results of thermoluminescence (TL) dating of medieval and Przeworsk materials, we have employed it in those situations, where no other chronometric methods seem to be efficient. TL dating has been combined with typological analysis of the dated pottery and, partially, with radiocarbon method. Albeit the produced TL dates do not represent the level of sought-for fine chronological resolution, they indicate the temporal trends and corroborate the typological research. Our study has shown the potential of TL dating for periods with plateaus on ¹⁴C calibration curve. We also have dealt with unexpected TL ages and suggested some solutions of the problem. Finally, we have demonstrated that the condition sine qua non for archaeological interpretation of TL dates is a thorough stylistic-chronological analysis of dated pottery and clear understanding of relations between chronometric dates and the archaeological event to be dated.     

Thermoluminescence dating

Over the last few years the Nordic Laboratory for Thermoluminescence (TL) Dating has obtained TL dates for a considerable number of archaeological samples, ceramics, bricks, burnt clay and burnt stones from the Nordic countries. The majority of TL dates have been consistent and in agreement with other dating evidence. Discrepancies caused primarily by excessive short‐term fading of the latent TL signal were encountered in a few cases. A procedure for eliminating errors caused by short‐term fading is described. A brief discussion of the sources of error in TL dating is given. Finally, results obtained by TL are compared with those obtained by radiocarbon for a number of sites.     

Reassessing the chronology of the Mississippian Central Illinois River Valley using Bayesian analysis

Chronology building has long served as a major focus of archaeological interest in the Central Illinois River valley (CIRV) of west-central Illinois. Previous methods have relied primarily upon relative dating techniques (e.g., ceramic seriation) as a means of sorting out temporal relationships between sites. This study represents the first investigation into the utility of Bayesian techniques (which consider radiocarbon dates in context with archaeological information) in the CIRV. We present the results of a detailed ceramic seriation of the region, data that we use as a priori information in our Bayesian models. We then offer contiguous, overlapping, and sequential models of site occupations in the Mississippian CIRV, review the output and appropriateness of each model, and consider their implications for the pace of sociopolitical change in the region.     

Radiometric dates and micromorphological evidence for synchronous domestic activity and sheep penning in a Neolithic cave: Cueva de El Toro (Málaga,Antequera, Spain)

We present radiocarbon dates and preliminary micromorphological information from the Neolithic cave site of Cueva del Toro (Antequera, Málaga, Spain). This site has yielded a rich early and late Neolithic archaeological record. The late Neolithic assemblage reflects specialized handcraft activity including in situ ceramic manufacture, textile production, and food processing along with sheep and goat penning, suggesting that the cave occupants and their domestic animals shared the same living space. Until now, dating of the stratigraphic sequence was incomplete, and the function of the combustion activities carried out at the cave remained unclear. New absolute dates from the main late Neolithic domestic activity area, corresponding to the most intense Neolithic occupation of the cave, allow us to place the entire sequence between 5320 and 5170 BP (or 4250–3950 to 2σ Cal BC). Micromorphological results show that many combustion features from this site represent recurrently burnt episodes on sheep/goat stabling deposits all along the sequence, corroborating human-goat/sheep cohabitation. This practice had not been previously documented in southern Spain for such early dates. Our results exemplify the importance of characterizing archaeological deposits at a microstratigraphic scale of observation.     

Archaeomagnetic dating of archaeological sites from Switzerland and Bulgaria

Baked materials from three archaeological sites in Switzerland and one in Bulgaria have been examined and dated archaeomagnetically. The detailed rock-magnetic properties of the burnt clay collected have already been studied therefore and have been published elsewhere (Geophysical Journal International 153 (2003) 146). The main aim of this paper is to determine the terminus ante quem for the last firing of the clay collected from pottery kilns or burnt layers. The directional and intensity results of the ancient geomagnetic field corresponding to the time of the structure's last firing are given for each site. These geomagnetic parameters are then compared with reference curves to provide archaeomagnetic dates for the last use of the kilns. Application of archaeomagnetism as a dating tool is only possible for those regions that already have reference curves. Bulgaria is fortunate in having established reference curves covering almost the last 8000 years. Two Swiss sites were dated using only directional results on the basis of existing palaeodirectional results for Switzerland as well as the French directional reference curves. The archaeomagnetic dates of three of the sites were then compared to archaeological evidence and available radiocarbon dates. The palaeointensity data obtained from this study will enrich the existing archaeomagnetic database for western Europe.     

RADIOCARBON DATES FROM THE OXFORD AMS SYSTEM: ARCHAEOMETRY DATELIST 34

This is the thirty‐fourth list of AMS radiocarbon determinations measured at the Oxford Radiocarbon Accelerator Unit (ORAU). Amongst the dates obtained for archaeological sites included here are the latest series of determinations from the key sites of Proskynas (Greece), Kova?evo (Bulgaria) and Khirbet Qeiyafa (Israel), as well as others dating to the Palaeolithic, Mesolithic and later periods. Submitters of the material provide comments on the significance of the results.     

Expanding the utility of Uranium-series dating of speleothems for archaeological and palaeontological applications

Uranium-series (U-series) dating of speleothems is frequently used for palaeoclimate studies but its archaeological and palaeontological applications are limited to stratigraphically significant speleothem formations, such as flowstones, to provide maximum and minimum temporal points. This study targeted soda straw stalactites for U-series dating. In contrast to other speleothem formations, soda straw stalactites are fragile, have typically short life spans (usually only years but rarely up to a few hundred years) and are frequently incorporated into cave deposits. Results of thermal ionisation mass spectrometry (TIMS) U-series dating of soda straw stalactites from palaeontological excavations at Blanche Cave, South Australia, show that small, dense, clean straws tend to yield ages closest to the time of stratigraphic deposition. A correlation between soda straw U-series ages and radiocarbon ages of charcoal from the site is shown. Multiple soda straw age determinations for a single stratigraphic unit are required in order to verify age concordance. In conjunction with other dating methods, U-series dating of soda straw stalactites may help to significantly constrain the age of stratigraphic units and associated archaeological and palaeontological deposits in order to provide more robust chronologies. Here we advocate the collection of soda straw stalactites at future excavations of limestone cave sites.     

Attempts at thermoluminescence dating of fired materials from the Przeworsk Culture settlements

The thermoluminescence (TL) dating method has a significant measurement error margin reaching almost 10%. Due to this fact it could be considered as little effective in case of such sites from the Roman period as burial grounds with many artefacts useful for archaeological dating. However, for many settlements from this period, where pottery is the only kind of artefacts, the TL method can give notable results. The main purpose of the study was to make an attempt at TL dating of pottery and clay daub samples from the Nieszawa Kolonia and Kręcieszki sites and to compare the obtained dates with the results of archaeological dating of selected features from the Przeworsk Culture settlements. In the Kręcieszki site the fragments of burnt clay daub were dated by the TL method for the first time in the Lublin laboratory. It turned out that clay daub is an equally good dating material as pottery. It can be found that the TL dating of pottery from Nieszawa Kolonia confirms two stages of settlement. The first settlement stage is related to the phases B2-B2/C1-C1a of the Roman period, i.e. from the beginning of the 2^nd to the beginning of the 3^rd century. The second group of TL dates corresponds to the phases C2D that is to the second stage of settlement, from the second half of the 3^rd century to the half of the 5^th century AD. The results of TL dating of pottery and clay daub in the Kręcieszki site are rather similar and correspond to the phase B1/B2 of the period of Roman influence, determined from pottery style, but can also indicate the phase B2/C1.     

Radiocarbon dating of marine shell samples. The marine radiocarbon reservoir effect of coastal waters off Atlantic Iberia during Late Neolithic and Chalcolithic Periods

Radiocarbon dates on marine shells have not been used as extensively as charcoal or bone dates for the setting up of absolute chronologies because interpreting these dates is complicated by the marine radiocarbon reservoir effect. Nevertheless marine shellfish were used widely at least during the Holocene and their shells are abundant and usually well preserved in archaeological deposits located near shorelines. Consequently prior research concerning the oceanographic conditions and the marine radiocarbon reservoir effect of a particular coastal area is needed in order to set up reliable chronologies for that region. Values of regional marine radiocarbon reservoir effect – ΔR – of coastal waters off Atlantic Iberia, some of its variability along the Holocene and its correlation with the upwelling phenomenon were determined during previous research. More data related to the ΔR values for western Portuguese coastal waters during the Late Neolithic and the Chalcolithic, a time interval badly sampled in previous research, were recently obtained. These values can be compared with ΔR values already determined for the Gulf of Cadiz. Besides the importance of these values for a better knowledge of the palaeoceanography and palaeoclimatology of Atlantic Iberia, from now on archaeologists can set up reliable chronologies for Late Neolithic and Chalcolithic contexts using marine shell samples of that origin for radiocarbon dating.     

Archaeological investigations and OSL dating of terraces at Ramat Rahel,Israel

Abstract

Dating terraces, the most prominent feature of the agricultural landscape in many parts of the world, is a problem for archaeologists. This study presents an interdisciplinary approach that combines archaeological survey and excavations with direct sediment dating of terrace fill using Optically Stimulated Luminescence (OSL). The study focuses on Ramat Rahel, a multi-period site located in the southern outskirts of modern Jerusalem, Israel, where, on a defined terraced slope chosen for a small-scale landscape archaeology project, three main phases of terrace construction and use were identified. The earliest phase dates to the Late Byzantine/Early Islamic period, the second to medieval times, and the last to the Ottoman period. The results enable a comprehensive reconstruction of the changing local landscape through time and demonstrate the validity of OSL, when combined with archaeological investigations, as a reliable method for terrace dating.     

Interpreting,dating, and reevaluating the botanical assemblage from tell Kedesh: a case study of historical contamination

Botanical assemblage including charred and mineralized macro plant remains were examined from tell Kedesh in the Upper Galilee, Israel. Flotation samples were collected from various contexts within and outside a large Persian-Hellenistic administrative building complex at tell Kedesh, dated to the 5th to the 2nd century BC, based on the archaeological material. Four AMS radiocarbon dates were obtained on plant macro remains recovered from the flotation samples from the complex. The radiocarbon dates range from the 9th century BC to 17th century AD. The discrepancy among the radiocarbon dates obtained from plant remains and those based on archaeological material can be attributed to bioturbation, including the deep burrowing of harvester ants. The study demonstrates the need for direct radiocarbon dating of the charred plant remains generally assumed to be of ancient origin. This research improves the understanding of depositional and postdepositional processes of plant macro remains and explains their mode of arrival, relevant for the sites with a long occupational history by humans and animals.     

Thermoluminescence Dating of Surface Lithic Artefacts from the Chacabuco Valley,Chilean Patagonia

This work presents several thermoluminescence (TL) dates of six archaeological sites located in the Andean valley of the Chacabuco River, central Patagonia. We discuss the advantages of this method to assess the chronology of human occupations, employing samples of lithic artefacts with evidence of fire exposure from surface contexts in the area. We compare the results with stratigraphic archaeological dating by ¹⁴C. We discuss these results in the context of previously formulated hypotheses on the past behaviour of the human population in this area.     

A new approach for geomagnetic archaeointensity research: insights on ancient metallurgy in the Southern Levant

We present results from an archaeointensity investigation based on a relatively unexploited recording medium, copper slag deposits. Together with a recently improved experimental design for the archaeointensity experiment, we demonstrate the applicability of this medium, as well as other archaeometallurgical artifacts, for the study of the ancient geomagnetic field intensity. In addition to archaeointensity data from well-dated archaeological contexts, we obtained reliable archaeointensity results from poorly dated or contentious archaeometallurgical sites in the Southern Levant. These results shed new light on the dating of these sites, among them the copper smelting installation of Timna 39b – a site that has important implications for the beginning of metallurgy during the fifth millennium BCE. The paper also aims to introduce archaeointensity research to the archaeologist scholar, and to encourage further collaboration between the disciplines in future research.