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钧瓷天蓝、天青釉色中氧化铁的呈色作用
引用本文:王芬,苗建民,侯佳钰,林营,朱建锋.钧瓷天蓝、天青釉色中氧化铁的呈色作用[J].故宫博物院院刊,2012(3):100-108,162.
作者姓名:王芬  苗建民  侯佳钰  林营  朱建锋
作者单位:陕西科技大学材料科学与工程学院;故宫博物院文保科技部
基金项目:“古陶瓷保护研究国家文物局重点科研基地(故宫博物院)2010年开放课题”资助
摘    要:氧化铁在钧瓷天蓝、天青系列釉色中的着色作用以及乳光蓝色问题,一直是学术界争论的焦点。本研究通过放大氧化铁含量的实验验证方法,通过SEM(scanning electron microscope-扫描电子显微镜)、EDS(Energy Dispersive Spectrometer-能谱仪)、XRD(X-ray diffraction-X射线衍射)等分析方法,重点研究了基础组成和分相结构对釉中氧化铁呈色的影响。同时,作者通过验证研究得出,钧瓷天蓝、天青系列釉色中,真正起呈色作用的是釉中的氧化铁等着色剂,第二相微粒散射呈色并非钧釉的普遍现象,或只是辅助呈色作用。

关 键 词:钧瓷蓝釉  氧化铁  乳光  呈色机理

A Study of Iron Oxide Coloring Function in Blue Glaze & Green Glaze Jun Porcelains
Wang Fen Miao Jianmin Hou Jiayu Lin Ying Zhu Jianfeng.A Study of Iron Oxide Coloring Function in Blue Glaze & Green Glaze Jun Porcelains[J].Palace Museum Journal,2012(3):100-108,162.
Authors:Wang Fen Miao Jianmin Hou Jiayu Lin Ying Zhu Jianfeng
Institution:Wang Fen Miao Jianmin Hou Jiayu Lin Ying Zhu Jianfeng
Abstract:There remain the focus of debates in academic circle as to the function of iron oxide in the blue glaze and green glaze Jun porcelains,and the generation of blue opalescence as well.In this paper,the research group conducts a test of its coloring process and mechanism by enlarging the content of iron oxide,especially analyzes the effects caused by the basic glaze components and the microstructure of liquid-phase separation upon iron oxide coloring with XRD,SEM,EDS,etc.The result indicates that it is iron oxide and other colorings that matter more than blue opalescence that occurs accidentally or just aids to the coloring process.
Keywords:Jun Porcelain blue  enlarging the content of iron oxide  aid to coloring process
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